• Title/Summary/Keyword: Resources utilization

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Study for Manufacturing of Zinc Sulfate from Electric Arc Furnace Dust by Hydrometallrugical Process (제강분진으로부터 습식제련공정에 의한 황산아연의 제조 연구)

  • Dong Ju Shin;Sung-Ho Joo;Dongseok Lee;Shun Myung Shin
    • Resources Recycling
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    • v.32 no.1
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    • pp.33-41
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    • 2023
  • Herein, we selectively recovered Zn and produced ZnSO4 from electric arc furnace dust using a hydrometallurgical process. The analysis of the properties of the electric arc furnace dust revealed that the Fe content (9.9%) was relatively low while the Mn content (19%) was high as compared to the composition of general dust. Therefore, an appropriate hydrometallurgical process was designed based on the properties of the raw materials. In the leaching process involving the use of 1.6 M sulfuric acid and 20% solid-liquid ratio at 60℃ for 1 h, 85% of the Zn and Mn got dissolved while the Fe was not leached. To selectively recover Zn, a solvent extraction process using D2EHPA as the extractant was chosen, and 99% of the Zn was extracted using 0.8 M D2EHPA with 32% saponification and an O/A ratio of 2 using counter-current 3-stage extraction. Mn was entirely scrubbed with an aqueous sulfuric acid solution of pH 1.5. Finally, Zn was concentrated and stripped using 1.5 M sulfuric acid at an O/A ratio of 4 using counter-current 4-stage stripping. The stripping solution contained 40 g/L of Zn, and 99.9% of ZnSO4∙H2O was obtained by vacuum distillation.

Leaching Behavior of Vanadium and Possibility of Recovery of Valuable Metals from VTM Concentrate by Sulfuric Acid Leaching (바나듐함유 티탄철석 정광으로부터 황산 침출법에 의한 바나듐의 침출거동 및 유가금속의 회수가능성)

  • Joo, Sung-Ho;Shin, Dong Ju;Lee, Dongseok;Park, Jin-Tae;Jeon, Hoseok;Shin, Shun Myung
    • Resources Recycling
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    • v.31 no.1
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    • pp.65-77
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    • 2022
  • A study was conducted in Korea on the leaching behavior and possibility of recovery of vanadium and other valuable metals from domestic vanadium titanomagnetite (VTM) by direct acid leaching. In this study, a VTM concentrate containing 0.8% V2O5 was used, and the ratio of magnetite to ilmenite was calculated as 1.9:1 by using the HSC program. The leaching behavior of vanadium from the VTM was similar to that of iron, and it was affected by the concentration of sulfuric acid and temperature. Further, titanium could be leached in the form of TiOSO4 at a temperature higher than 75℃. To improve the leaching efficiency of V, Fe, and Ti in VTM, reductive sulfuric acid and oxidative sulfuric acid leaching were performed. When Na2SO3 was used as a reducing agent, the leaching rate of vanadium was 80% of that in that case of leaching by sulfuric acid. Similarly, the leaching rate of titanium increased from 20% to 50%. When Na2S2O8 was used as an oxidation agent, most of the vanadium was leached, and the main residue found by XRD analysis was ilmenite. In studies on the possibility of recovering valuable metals, the selective extraction of metals is hardly achieved by solvent extraction from oxidation leaching solutions; however, in this study, Cyanex 923, a solvation extractant from reductive leaching solutions, could selectively extract Ti.

Predicting the potential distribution of the subalpine broad-leaved tree species, Betula ermanii Cham. under climate change in South Korea

  • Shin, Sookyung;Dang, Ji-Hee;Kim, Jung-Hyun;Han, Jeong Eun
    • Journal of Species Research
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    • v.10 no.3
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    • pp.246-254
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    • 2021
  • Subalpine and alpine ecosystems are especially vulnerable to temperature increases. Betula ermanii Cham. (Betulaceae) is a dominant broad-leaved tree species in the subalpine zone and is designated as a 'Climate-sensitive Biological Indicator Species' in South Korea. This study aimed to predict the potential distribution of B. ermanii under current and future climate conditions in South Korea using the MaxEnt model. The species distribution models showed an excellent fit (AUC=0.99). Among the climatic variables, the most critical factors shaping B. ermanii distribution were identified as the maximum temperature of warmest month (Bio5; 64.8%) and annual mean temperature (Bio1; 20.3%). Current potential habitats were predicted in the Baekdudaegan mountain range and Mt. Hallasan, and the area of suitable habitat was 1531.52 km2, covering 1.57% of the Korean Peninsula. With global warming, future climate scenarios have predicted a decrease in the suitable habitats for B. ermanii. Under RCP8.5-2070s, in particular, habitat with high potential was predicted only in several small areas in Gangwon-do, and the total area suitable for the species decreased by up to 97.3% compared to the current range. We conclude that the dominant factor affecting the distribution of B. ermanii is temperature and that future temperature rises will increase the vulnerability of this species.

Density, Bonding Strength, Bending strength and Decay Resistance of Radiata Pine Laminated Veneer Lumber (라디에타소나무 단판적층재의 밀도·접착·강도성능 및 내부후성)

  • Suh, Jin-Suk;Lee, Dong-Heub;Hwang, Won-Joung;Oh, Hyung-Min;Park, Young-Ran;Kang, Sung-Mo
    • Journal of the Korean Wood Science and Technology
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    • v.39 no.4
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    • pp.344-350
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    • 2011
  • In this study, LVLs of radiata pine were fabricated with non-preservative treated veneers, CuAz treated veneers, and ACQ treated veneers, using aqueous vinyl urethane adhesive and phenol modified resorcinol resin adhesive. Then density gradient, bonding strength, bending properties and decay resistance of LVLs were evaluated. As results, the cone-shaped and higher density gradient pattern was found in layer close to glueline. After cyclic water boiled test, the LVL bonded with aqueous vinyl urethane resin adhesive was delaminated in all layers or partly delaminated including check, chasm in glueline layer. In the case of LVL bonded with phenol modified resorcinol resin adhesive, despite slight cupping due to great glueline stress and vertical check between glueline layers, it was observed that the bonding strength to delamination was higher, owing to most absence of delamination through overall glueline. On the other hand, in the decay test, mass loss by brown rot fungi was greater than white rot fungi in LVL bonded with aqueous vinyl urethane resin adhesive. However, in LVL bonded with phenol modified resorcinol resin adhesive, the mass loss by brown rot fungi was slight and non-preservative treated LVL was low. The mass loss of preservative-treated LVL was 0 (zero), showing the high decay resistance effect.