• Title/Summary/Keyword: Resin Fraction

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Mechanical properties of TiO2/epoxy resin nanocomposites

  • Ahn, Seok-Hwan;Nam, Ki-Woo;Moon, Chang-Kwon
    • Journal of Power System Engineering
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    • v.17 no.5
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    • pp.69-77
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    • 2013
  • The purpose of this study is to improve the properties of epoxy resin using the big-sized titanium oxide nanoparticles. The effects of particle weight fraction and shape of sample on the thermal and mechanical properties in titanium oxide reinforced epoxy resin has been investigated. In addition, the effect of particle dispersion situation on the mechanical properties of nanocomposites has been studied. As a result, the Tg was almost same regardless of the content of nanoparticles. Storage modulus increased up to the content of 3wt% particles and then decreased. Tensile strength and modulus of film-shaped sample with 1wt% was higher than the one of pure epoxy, while other composites were not. The tensile strength of dogbone-shaped sample with 1wt% was only higher than the one of pure epoxy, while other composites were lower than the one of pure epoxy. Tensile modulus of dogbone-shaped samples increased with the content of particles.

Investigation of sequential separation method for $^{90}Sr,\;^{241}Am,\;^{239,240}Pu$ and $^{238}Pu$ isotopes ($^{90}Sr,\;^{241}Am,\;^{239,240}Pu$$^{238}Pu$ 동위원소들을 분리하기위한 축차분리법에 대한 고찰)

  • Lee Myung-Ho;Song Byoung-Chul;Park Young-Jai;Gee Kwang-Young;Kim Wein-Ho
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2005.06a
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    • pp.248-254
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    • 2005
  • This paper presents a quantitative method of sequential separation of $^{90}Sr,\;^{241}Am$ and Pu nuclides with an anion exchange resin and a Sr-Spec resin. The Pu isotopes were purified with an anion exchange resin. The americium and strontium fractions were separated from the matrix elements with an oxalate co-precipitation method. Americium fraction was separated from the strontium fraction with iron co-precipitation method and purified from lanthanides with anion exchange resin. Strontium-90 was purified from other hindrance elements with the Sr-Spec resin after oxalate co-precipitation. The measurement of Pu and Am isotopes was carried out by an ${\alpha}$-spectrometer. Strontium-90 was measured by a liquid scintillation counter. The radiochemical procedure of $^{90}Sr,\;^{241}Am$ and Pu nuclides investigated in this study has been validated by application to IAEA-Reference soils.

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Numerical simulation of a single bubble suspension in polyol resin

  • Dongjin Seo;Lim, Yun-Mee;Youn, Jae-Ryoun
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10a
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    • pp.47-48
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    • 2003
  • Dilute bubble suspensions are prepared by introducing carbon dioxide bubbles into polyol resin. The apparent shear viscosity is measured with a wide gap parallel plate rheometer. A numerical simulation for deformation of a single bubble suspended in a Newtonian fluid is conducted by using a finite volume method (FVM) where multigrid algorithms are incorporated. Transient and steady results of bubble deformation were obtained and were in good agreement with experimental results. At high capillary number, viscosity of the suspension increases as the volume fraction increases, while at low capillary number, the viscosity decreases as the volume fraction increases.

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Dependence of Na+ leakage on intrinsic properties of cation exchange resin in simulated secondary environment for nuclear power plants

  • Hyun Kyoung Ahn;Chi Hyun An;Byung Gi Park;In Hyoung Rhee
    • Nuclear Engineering and Technology
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    • v.55 no.2
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    • pp.640-647
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    • 2023
  • Material corrosion in nuclear power plant (NPP) is not controlled only by amine injection but also by ion exchange (IX) which is the best option to remove trace Na+. This study was conducted to understand the Na+ leakage characteristics of IX beds packed with ethanolamine-form (ETAH-form) and hydrogen-form (H-form) resins in the simulated water-steam cycle in terms of intrinsic behaviors of four kinds of cation-exchange resins through ASTM test and Vanselow mass action modeling. Na+ was inappreciably escaped throughout the channel created in resin layer. Na+ leakage from IX bed was non-linearly raised because of its decreasing selectivity with increasing Na+ capture and with increasing the fraction of ETAH-form resin. Na+ did not reach the breakthrough earlier than ETAH+ and NH4+ due to the increased selectivity of Na+ to the cation-exchange resin (H+ < ETAH+ < NH4+ ≪ Na+) at the feed composition. Na+ leakage from the resin bed filled with small particles was decreased due to the enhanced dynamic IX processes, regardless of its low selectivity. Thus, the particle size is a predominant factor among intrinsic properties of IX resin to reduce Na+ leakage from the condensate polishing plant (CPP) in NPPs.

A Study on the Control Strategy to Minimize Voids in Resin Transfer Mold Filling Process (RTM 공정에서 기공 최소화를 위한 공정 제어에 관한 연구)

  • Lee Doh Hoon;Jeon Young Jae;Lee Woo Il;Um Moo Kwang;Byun Joon Hyung
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.292-296
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    • 2004
  • In case of Resin Transfer Molding(RTM) process, 'race-track' effects and non-uniform fiber volume fraction may cause undesirable resin flow pattern and thus result in dry spots, which affect the mechanical properties of the finished parts. In this study, a real time RTM control strategy to prevent these unfavorable effects is proposed. The control strategy consists of two 'stages' depending on the extent the resin front has reached. Through numerical simulations and experiments, the validity of the proposed scheme is demonstrated. The results show that the proposed scheme is effective in reducing the void formation during RTM mold filling.

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Manufacturing Fiber-Reinforced Composite Materials Based on PLA (Poly L-Lactide) Resin Using In-Situ Polymerization and Molecular Weight Measurement Using GPC (현장 중합을 이용한 PLA(Poly L-Lactide) 수지 기반 섬유 강화 복합 재료 제조 및 GPC를 이용한 분자량 측정)

  • Seon-Ju Kim;Beom-Joo Lee;Hyeong-Min Yoo
    • Design & Manufacturing
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    • v.17 no.3
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    • pp.28-33
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    • 2023
  • The conventional FRP (Fiber Reinforced Plastic) manufacturing process used thermoset resins for ease of molding but faced the issue of non-recyclability. To address these shortcomings, a new process utilizing thermal plastic resin was developed. However, due to the high viscosity of thermal plastic resin, problems such as fiber deformation and a reduced fiber volume fraction occurred during the high-temperature, high-pressure process. In this study, to overcome the limitations of the conventional process, fiber-reinforced composite materials were manufactured through in-situ polymerization using PLA (Poly L-Lactide) resin in the VA-RTM (Vacuum Assistance Resin Transfer Molding) process. The fiber volume of the produced specimens was calculated, and resin impregnation and porosity were confirmed through optical microscopy. Additionally, molecular weight analysis using GPC (Gel Permission Chromatography) demonstrated improvements over the conventional process and emphasized the essential requirement of temperature control.

A Study on Real Time Control of Resin Transfer Molding (RTM 공정의 실시간 제어에 관한 연구)

  • Jeon Young Jae;Um Moon Kwang;Byun Joon Hyung;Lee Woo Il
    • Composites Research
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    • v.18 no.4
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    • pp.35-43
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    • 2005
  • In resin transfer molding(RTM), race-track effects and non-uniform fiber volume fraction may cause undesirable resin flow patterns and thus result in dry spots, which affect the mechanical properties of the finished parts. In this study, a real time RTM control strategy to reduce these unfavorable effects is proposed. This control rule is accomplished by means of the permeability mapping and pressure regulation. Through numerical simulations, the validity of the proposed scheme is demonstrated.

Biofilm formation on denture base resin including ZnO, CaO, and TiO2 nanoparticles

  • Anwander, Melissa;Rosentritt, Martin;Schneider-Feyrer, Sibylle;Hahnel, Sebastian
    • The Journal of Advanced Prosthodontics
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    • v.9 no.6
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    • pp.482-485
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    • 2017
  • PURPOSE. This laboratory study aimed to investigate the effect of doping an acrylic denture base resin material with nanoparticles of ZnO, CaO, and $TiO_2$ on biofilm formation. MATERIALS AND METHODS. Standardized specimens of a commercially available cold-curing acrylic denture base resin material were doped with 0.1, 0.2, 0.4, or 0.8 wt% commercially available ZnO, CaO, and $TiO_2$ nanopowder. Energy dispersive X-ray spectroscopy (EDX) was used to identify the availability of the nanoparticles on the surface of the modified specimens. Surface roughness was determined by employing a profilometric approach; biofilm formation was simulated using a monospecies Candida albicans biofilm model and a multispecies biofilm model including C. albicans, Actinomyces naeslundii, and Streptococcus gordonii. Relative viable biomass was determined after 20 hours and 44 hours using a MTT-based approach. RESULTS. No statistically significant disparities were identified among the various materials regarding surface roughness and relative viable biomass. CONCLUSION. The results indicate that doping denture base resin materials with commercially available ZnO, CaO, or $TiO_2$ nanopowders do not inhibit biofilm formation on their surface. Further studies might address the impact of varying particle sizes as well as increasing the fraction of nanoparticles mixed into the acrylic resin matrix.

ACOUSTIC EMISSION ANALYSIS FOR FRACTURE CHARACTERISTICS OF DENTAL POSTERIOR COMPOSITES (구치부 수복용 복합레진의 파괴특성에 관한 Acoustic Emission 연구)

  • Park, Jin-Hoon;Kim, Kyo-Han
    • Restorative Dentistry and Endodontics
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    • v.17 no.1
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    • pp.153-165
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    • 1992
  • Dental composite resin is a kind of the particle - reinforced composite material, and is widely used in recent dental restoration of anterior and posterior tooth region. The purpose of this study was to investigate the fracture behaviour according to volume fractions and external findings of the filler particles for better interpretation of the fracture characteristics of posterior dental composite resins by analytic method of fracture mechanics. The plane strain fracture toughness($K_{IC}$) and Acoustic Emission were determined with three - point bending test using the single edge notch specimen according to the ASTM - E399, and its analyzed data was compared with filler volume fractions derived from the standard ashing test and scanning electron fractographs of each specimen including the unfilled experimental resin as a control. The results were that the value of fracture toughness of the composite resin material was in the range from 0.85 MPa$\sqrt{m}$ to 1.60 MPa$\sqrt{m}$ and was higher than the value of the unfilled experimental resin, and the fracture behaviours dervied from Acoustic Emission analysis show prominent differences according to the volume fraction and the size of filler particles used in each composite resin. The degree of resistance against crack propagation seems to be increase and the fractographs demonstrate the high degree of surface roughness and irregularity according with the increase of fracture toughness value.

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Evaluation of Void Content in Carbon Fiber/Epoxy Composites Manufactured by Different Manufacturing Process (제작공법을 달리한 탄소섬유/에폭시 복합재의 기공함유율 평가 기법)

  • Yoona, Sungho;Jang, Jungkeun
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.2
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    • pp.32-40
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    • 2017
  • In this study, the procedures for quantitative measurement of void contents of carbon fiber/epoxy composites were suggested. Two types of the composites were considered: autoclave cured composite and filament wound composite. Void contents of the composites were evaluated by the density of the composites and their constituents, which was determined from weights in the air and water, and the weight fraction and volume fraction of the constituents obtained from the digestion method and combustion method. The surfaces of filtered carbon fibers were examined by FE-SEM in order to investigate the validity of resin removal from the composites. According to the results, the resin in the composites could be fully removed by the digestion method and combustion method. Therefore, the weight fraction and volume fraction of the constituents, and void content of the composites could be quantitatively obtained by the suggested procedures.