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Mechanical properties of TiO2/epoxy resin nanocomposites

  • Ahn, Seok-Hwan (A+LINC of PKNU, Pukyong National University) ;
  • Nam, Ki-Woo (Department of Materials Science and Engineering, Pukyong National University) ;
  • Moon, Chang-Kwon (Department of Materials Science and Engineering, Pukyong National University)
  • Received : 2013.03.04
  • Accepted : 2013.05.28
  • Published : 2013.10.31

Abstract

The purpose of this study is to improve the properties of epoxy resin using the big-sized titanium oxide nanoparticles. The effects of particle weight fraction and shape of sample on the thermal and mechanical properties in titanium oxide reinforced epoxy resin has been investigated. In addition, the effect of particle dispersion situation on the mechanical properties of nanocomposites has been studied. As a result, the Tg was almost same regardless of the content of nanoparticles. Storage modulus increased up to the content of 3wt% particles and then decreased. Tensile strength and modulus of film-shaped sample with 1wt% was higher than the one of pure epoxy, while other composites were not. The tensile strength of dogbone-shaped sample with 1wt% was only higher than the one of pure epoxy, while other composites were lower than the one of pure epoxy. Tensile modulus of dogbone-shaped samples increased with the content of particles.

Keywords

References

  1. J. Cho, M. S. Joshi and C. T. Sun, 2006, "Effect of inclusion size on mechanical properties of polymeric comosites with micro and nanoparticles", Composites Science and Technology, Vol. 66, pp. 1941-1952. https://doi.org/10.1016/j.compscitech.2005.12.028
  2. R. A. Narayanan, P. Thiyagarajan, S. Lewis, A. Bansal, L. S. Schadler and L. B Lurio, 2006, "Dynamics and Internal Stress at the NanoscaleRelated to Unique Thermomechanical Behavior in Polymer Nanocomposites", Physical Review Letters, Vol. 97, pp. 5505-5508.
  3. B. J. Ash, W. S. Richard and S. S. Linda, 2004, "Mechanical Behavior of Alumina/Poly (methyl methacrylate)Nanoco-mposites", Macromolecules, Vol. 37, pp. 1358-1369. https://doi.org/10.1021/ma0354400
  4. L. Y. Zheng, K. T. Lau, L. X. Zhao, Y. Q. Zhang and D. Hui, 2009, "Mechnical and Thermal Properties of Nano-Al2O3/Nylon 6 composites", Chemical Engineering Com-munications, Vol. 197, pp. 343-351. https://doi.org/10.1080/00986440903088892
  5. L. Tang, W. Wang, G. L. Zhao and Q. J. Li, 2009, "Colossal positive Seebeck coefficient and low thermal conductivity in reduced $TiO_{2}$", Journal of physics : Condednsed Matter, Vol. 21, No. 20, pp.5703.
  6. E. Bugnicourt, J. Galy, J. F. Gerard and H. Barthel, 2007, "Effect of sub-micron silica fillers on the mechanical performances of epoxy-based composites", Polymer, Vol. 48, pp. 1596-1605. https://doi.org/10.1016/j.polymer.2007.01.053
  7. G. C. Cheng, S. J. Ryan, W. S. Dale and W. B. Jeffery, 2008, "Highly dispersed nanosilicaepoxy resins with enhanced mechanical properties", Polymer, Vol. 49, pp. 3805-3815. https://doi.org/10.1016/j.polymer.2008.06.023
  8. Y. Y. Sun, Z. Q. Zhang, K. S. Moon and C. P. Wong, 2004, "Glass transition and relaxation behavior of epoxy nanocompo-sites", Journal of Polymer Science Part B: Polymer Physics, Vol. 42, pp. 3849-3858. https://doi.org/10.1002/polb.20251
  9. P. Rosso and L. Ye, 2007, "Epoxy/Silica Nanocomposites : Nanoparticle-Induce CureKinetcs and Microstructure", Micro-molecular rapid communications, Vol. 28, pp. 121-126. https://doi.org/10.1002/marc.200600588
  10. M. Ghaemy and N. S. Amini, 2008, "Preparation and nonisothermal cure kinetics of DGEBA-nanosilica particles composites", Polymer Composites, Vol. 29, pp. 165-172. https://doi.org/10.1002/pc.20363
  11. S. Deng and L. Ye, 2007, "Fracture behaviours of epoxy nanocomposites with nano-silica at low and elevated temperatures", Journal of Materials Science, Vol. 42, pp. 2766-2774. https://doi.org/10.1007/s10853-006-1420-x
  12. G. J. Papakonstantopoulos, K. Yoshomoto, M. Doxastakis, P. F. Nealey and J. J. De Pablo, 2005, "Local mechanical properties of polymeric nanocomposites", Phys. Rev, Vol. 72, pp. 1801-1806.
  13. D. Ma, Y. A. Akpalu, Y. Li, R. W. Siegel and L. S. Schadler, 2005, "Effect of titania nanoparticles on the morphology of low density polyethylene", Journal of Polymer Science Part B: Polymer Physics, Vol. 43, pp. 488-497. https://doi.org/10.1002/polb.20341
  14. D. Shah, P. Maiti, D. D. Jiang, C. A. Batt and E. P. Giannelis, 2005, "Effect of Nanoparticle Mobility on Toughness of Polymer Nanocomposites", Advanced materials, Vol. 17, pp. 525-528. https://doi.org/10.1002/adma.200400984
  15. B. Wetzel, F. Haupert and M. Q. Zhang, 2003, "Epoxy nanocomposites with high mechanical and tribological performance", Composites Science and Technology, Vol. 63, pp. 2055-2067. https://doi.org/10.1016/S0266-3538(03)00115-5
  16. H. Wang, Y. Bai, S. Liu, J. Wu and C.P. Wong, 2002, "Combined effects of silica filler and its interface in epoxy resin", Acta materialia, Vol. 50, No. 17, pp. 4369-4377 https://doi.org/10.1016/S1359-6454(02)00275-6
  17. Y. Ou, F. Yang and Z. J. Yu, 1998, "A new conception on the toughness of nylon 6/silica nanocomposite prepared via in situ polymerization", Journal of Polymer Science Part B: Polymer Physics, Vol. 36, pp. 789-795. https://doi.org/10.1002/(SICI)1099-0488(19980415)36:5<789::AID-POLB6>3.0.CO;2-G
  18. C. Becker, H. Krug and H. Schmidt, 1996, "Tailoring of Thermomechanical Properties of Thermoplatic Nanocomposites by surface Modification of Nanoscale Silica Particles", Materials Research Society Symposium Proceedings, Vol. 435, pp. 237-242.
  19. B. J. Ash, Stone, J. Stone, D. F. Rogers, L. S. Schadler and R.W. Siegel, 2001, "Investigation into the Thermal and Mechanical Behavior of PMMA/Alumina Nanocomposites", Appl Mater Res Soc. Sympo Proc, Vol. 661.
  20. C. B. Ng, B. J. Ash, L. S. Schadler and R. W. Siegel, 2001, "A study of the mechanical and permeability properties of nano- and micron-$TiO_{2}$ filled epoxy composites", Advanced Composites Letters, Vol. 10, pp.101-111.
  21. C. K. Moon, 2013, "Study on the mechanical and thermal properties of Tio2/epoxy resin composites" Journal of applie polymer science, submitted.