• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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• pp.1394-1397
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• 2006

Polymer Dispersed Liquid Crystal (PDLC) films, of which the liquid crystal has negative dielectric anisotropy, were prepared from the phase separation between MJ001317 and a variety of compositions of resins by common polymerization induced phase separation method. In this work, the effects of resin compositions have been systematically investigated and it was found that the morphology and size of droplet, which is closely related to electro-optic properties, mainly depend on the rate of polymerization and cross-linking density for each resin composition. The reverse mode PDLC films from this newly developed formulation containing TPGDA/EHA/HMPPO showed the good off-state transmittance, contrast ratio (19/1), and relatively low driving voltage(10V).

• 전기화학회지
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• 제11권1호
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• pp.11-15
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• 2008

The composite membrane for direct methanol fuel cell (DMFC) was developed using $H_3O^+-{\beta}"-Al_2O_3$ powder and perfluorosulfonylfluroride copolymer (Nafion) resin. The perfluorosulfonylfluroride copolymer (Nafion) resin was mixed with $H_3O^+-{\beta}"-Al_2O_3$ powder and it was made to sheet form by hot pressing. The electrodes were prepared with 60 wt% PtRu/C and 60wt% Pt/C catalysts for anode and cathode, respectively. The morphology and the chemical composition of the composite membrane have been investigated by using SEM and EDXA, respectively. The composite membrane and $H_3O^+-{\beta}"-Al_2O_3$ were analyzed by using FT-IR and XRD. The methanol permeability of the composite membranes was also measured by gas chromatography (GC). The performance of the MEA containing the composite membrane (2wt% $H_3O^+-{\beta}"-Al_2O_3$) was higher than that of normal pure Nafion membrane at high operating temperature (e.g. $110^{\circ}C$), due to the homogenous distribution of $H_3O^+-{\beta}"-Al_2O_3$, which decreased the methanol permeability through the membrane and enhanced the water contents in the composite membrane.

• 펄프종이기술
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• 제44권3호
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• pp.41-48
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• 2012

Materials used for the inks in the printing industry is an important material following the paper. The composition of the ink is pigment and organic solvents. However, Ink is used in a variety of chemicals, they are classified as non-green. Therefore, rosin-modified phenolics manufactured by the reaction of phenol and formaldehyde can take the place of eco-phenol free resin and by experiment density, gloss, trapping, contrast and dot gain of printing has been studied as printability. The result of study can support that the properties of printing using eco-phenol free resin such as density, gloss, contrast and trapping is similar to existing ink. In the part of dot gain, the result is excellent. So we were thought to be able to improve some characteristics such as dispersion of black ink, that will be possible for the field applicability.

• Korean Chemical Engineering Research
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• 제53권4호
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• pp.463-467
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• 2015

We investigated catalytic activity of ion-exchange resins in acetalization of 1,2-propylene glycol with acetaldehyde. The impacts of reaction variables, such as temperature, reaction time, catalyst loading and feedstock composition, on the conversion of 1,2-propylene glycol were measured. The life of the catalyst was also studied. Furthermore, the reaction kinetics of 1,2-propylene glycol acetalization was studied. It was found that reaction rate followed the first-order kinetics to acetaldehyde and 1,2-propylene glycol, respectively. Therefore, overall acetalization reaction should follow the second-order reaction kinetics, expressed as. Key words: 1,2-propylene Glycol, 2,4-dimethyl-1,3-dioxolane, Ion-exchange Resin, Polyhydroxy Compounds, Acetalization $r=kC^{nA}_AC^{nB}_B=19.74e^{\frac{-6650}{T}}C^1_AC^1_B$.

• 한국자기학회지
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• 제24권3호
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• pp.86-89
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• 2014

이방성 희토류 본드자석은 자성분말과 유기 바인더로 구성되며 본드자석 내에서 유기 바인더는 분말의 배향을 유리하게 하는 역할을 한다. 유기 바인더는 고분자 수지, 활제, 경화제, 커플링제 등으로 구성되며 자성분말에 적합한 유기 바인더를 제조하기 위해 본 연구에서는 다양한 성분을 선정하여 유기 바인더를 제조하였고 구성비 및 첨가량을 조절하여 이를 본드자석에 적용하였다. 특성평가를 통해 자기특성 및 기계적 특성을 측정하였고 이로부터 본드자석에 적합한 유기 바인더의 성분 및 비율을 확인하였다.

• Korean Chemical Engineering Research
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• 제56권1호
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• pp.14-23
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• 2018

The effect of dodecylbenzene sulfonic acid (DBSA) with different addition amount of DBSA ($M_{DBSA}$), temperatures and solvent-to-oil ratio (SOR, v/v) on asphaltene aggregation in a solvent deasphalting system was investigated. Increasing the $M_{DBSA}$ at SOR 10 and $55^{\circ}C$ caused the asphaltene removal ratio (ARR) to increase first, then maximize at 1 wt% of $M_{DBSA}$ and then decrease continuously. Based on the SARA (saturate, aromatic, resin, asphaltene) composition, the adsorption amount of DBSA on the asphaltene surface and the self-aggregation of the DBSA, the reason for the change in ARR with $M_{DBSA}$ was found due to the adsorption mechanism. In addition, the asphaltene-resin-DBSA colloidal size confirmed the change of adsorption behavior between the asphaltene and DBSA. Based on the results of this study, a hypothetical adsorption mechanism of DBSA on asphaltene aggregation in the solvent deasphalting system was conceived of and proposed.

• Carbon letters
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• 제15권4호
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• pp.262-267
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• 2014

Pyrolized fuel oil (PFO) was reformed by novel electron beam (E-beam) radiation, and the elemental composition, chemical bonds, average molecular weight, solubility, softening point, yields, and density of the modified patches were characterized. These properties of modified pitch were dependent on the reforming method (heat or E-beam radiation treatment) and absorbed dose. Aromaticity ($F_a$), average molecular weight, solubility, softening point, and density increased in proportion to the absorbed dose of E-beam radiation, with the exception of the highest absorbed dose, due to modification by free radical polymerization and the powerful energy intensity of E-beam treatment. The H/C ratio and yield exhibited the opposite trend for the same reason. These results indicate that novel E-beam radiation reforming is suitable for the preparation of aromatic pitch with a high ${\beta}$-resin content.

• Bulletin of the Korean Chemical Society
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• 제10권6호
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• pp.485-488
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• 1989

A carbon paste coated-wire ion-selective electrode for chloride (carbon chloride-CWE) was constructed using epoxy resin, ion-exchanger and carbon powder as a polymer membrane. Its utility, the composition of a polymer membrane, the response characteristics, and the selectivity were examined and applied to the environmental water analysis. The carbon chloride-CWE was prepared using a silver wire, which was covered with silver chloride and then coated with epoxy resin into which chloride ion-exchanger and carbon powder were previously incorporated in advance. The response of the carbon chloride-CWE was Nernstian for $1.0{\times}10^{-2}-2{\times}10^{-5}$ M chloride and the useful pH range from $10^{-2} M Cl- to 10^{-4} M Cl^-$ was 3.0-9.0. Furthermore, the selectivity of chloride over iodide, bromide, and cyanide was much improved compared with those for a solid state epoxy body chloride electrode and a liquid membrane chloride electrode. The carbon chloride-CWE was applied to determine Cl^-$ in tap and ground water. The obtained results were in good agreement with those by the established methods such as spectrophotometric or other chloride-selective electrode methods.

• 한국인쇄학회지
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• 제28권1호
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• pp.15-24
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• 2010

Photovoltaic solar cells are all in the incident because they are not converted into electrical energy, high-efficiency solar cells in order to reduce the loss of elements must be. Significant factor in the loss of solar cells, optical loss and electrical loss can be divided into. Optical losses occur when the sun will be joined on the surface of the reflection, the shadow loss due to electrodes, and the losses are in the solar wavelengths. Commercialization is currently the most common solar cells on the front of the light incident on the electrode is formed. Therefore, the shadow caused by the electrode to cover the dead area of the sun, due to factors that hinder the absorption of sunlight which is shadowing them and conversion efficiency of solar cells is the inhibition factor. These barriers to eliminate the electrode linewidth reduces the shadowing to reduce, but simply of the electrode line width is reduced electrode area by reducing the series resistance elevates this because to improve the electrode Aspect ratio(height/width) to increase Ag development of paste is required. In this study, aspect ratio of screen-printing method to increase the electrode Ag paste composition of the binder for the characterization of rheology in the shadow of the electrode by reducing the optical loss of the photoelectric conversion efficiency of solar cells to boost the performance measures was. Properties and printability of the paste, the binder resin sintered characteristics that affect the thermal properties are excellent with a good screen printability acrylic resin, ethyl cellulose, using a resin were evaluated. Prepared paste rheology properties, was formed to evaluate the electrode conductivity and aspect ratio.

• Nuclear Engineering and Technology
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• 제21권4호
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• pp.277-286
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• 1989

PWR 핵연료의 연소도측정은 삼중스파이크(U-233. Pu-242, Nd-150)를 사용한 동위원소 희석 질량분석법으로 U, PU, Nd-148 및 Nd-(145+146)을 정량하여 수행하였다. 이 방법은 먼저 두개의 연속적 이온교환수지 분리과정을 거친다. Pu는 첫번째 음이온 교환수지 분리관(Dowex AG 1 X 8)으로부터 12 M HCl-0.1 M HI 혼합용액으로 분리하고 이어서 0.1 M HCl로 U을 분리하였다. Nd은 질산-메탄올 용리액으로 두번째 음이온 교환수지분리관(Dowex AG 1 X 4) 상에서 분리하였다. 각 부분을 열이온화질량분석법으로 각각의 동위원소비를 측정하였다. Nd-148과 Nd-(145+146) 방법 사이의 차이는 평균 2.07%로 나타났다. 이 결과를 U과 Pu동위원소를 이용한 무거운 원소방법 및 Cs-137의 파괴 감마분광측정법과 비교하였다. 연소도에 대한 U과 Pu의 동위원소 조성의존도와 동위원소사이의 상관관계를 그래프로서 설명하였다.