• Title/Summary/Keyword: Residual cement

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Hydraulic conductivity of cemented sand from experiments and 3D Image based numerical analysis

  • Subramanian, Sathya;Zhang, Yi;Vinoth, Ganapathiraman;Moon, Juhyuk;Ku, Taeseo
    • Geomechanics and Engineering
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    • v.21 no.5
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    • pp.423-432
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    • 2020
  • Hydraulic conductivity is one of the engineering properties of soil. This study focusses on the influence of cement content on the hydraulic conductivity of cemented sand, which is investigated based on the results from numerical analysis and laboratory testing. For numerical analysis the cemented samples were scanned using X-ray Computed Tomography (CT) while laboratory testing was carried out using a triaxial setup. Numerical analysis enables us to simulate flow through the sample and provides insight to the microstructure. It quantifies the pore volume, proportion of interconnected voids and pore size distribution in both cemented and uncemented samples, which could be computed only through empirical equations in case of laboratory testing. With reduction in global voids, the interconnecting voids within the samples also reduce with cement content. Gamma cumulative distribution function is used to predict the percentage of voids lesser than a given pore volume. Finally, the results obtained from both numerical analysis and laboratory testing are compared.

Nanostructural Deformation Analysis of Tricalcium Silicate Paste by Atomic Pair Distribution Function (원자짝 분포 함수를 이용한 칼슘 실리케이트 경화체의 나노 구조 변형 거동 해석)

  • Bae, Sung-Chul;Chang, Yoo-Hyun;Jee, Hyeon-Seok
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.10a
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    • pp.94-95
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    • 2016
  • Calcium Silicate Hydrate (C-S-H), which takes up most of the hydration products of Portland Cement (PC), has the greatest impact on the mechanical behavior and strength development of concrete. The exact mechanism of its deformation, however, has not yet been elucidated. The present study aims to demonstrate the mechanism of nano-deformation behavior of C-S-H in tricalcium silicate paste under compressive loading, unloading and reloading by interpreting atomic pair distribution function (PDF) based on synchrotron X-ray scattering. The strain of the tricalcium silicate paste for a short-range of 0 ~ 20 Å under compressive load exhibited two stages, I) nano-packing of interlayer of C-S-H and II) micro-packing of C-S-H globules, whereas the deformation for a long-range order of 20 ~ 40 Å was similar to that of a calcium hydroxide phase measured by Bragg peak shift. Moreover, the residual strains due to the plastic deformation of C-S-H was clearly observed.

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The Preparation and Properties of Petroleum Sulfonate Dispersant (열분해 잔유를 원료로 한 분산제의 제조 및 특성)

  • Choi, Sang-Won;Kim, Eun-Young;Chang, Woo-Seok;Kim, Viktor;Moon, Jang-Soo
    • Applied Chemistry for Engineering
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    • v.18 no.5
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    • pp.490-494
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    • 2007
  • Dispersants were prepared from petroleum pyrolysis residual oil (PPRO) through sulfonation. Without employing a conventional polynaphthalene sulfonate formaldehyde condensate (PNS) process, the dispersants (NPS) were synthesized by a simpler process only in 2 h. The chemical structure of new dispersant, which has various naphthalene derivative groups, was similar to PNS conformed by UV-visible spectroscopy curves. The new dispersants demonstrated high dispersing ability in inorganic suspension ; cement, $Fe_2O_3$, and $CaCO_3$.

Characterization of Unburned Carbon Particles from Fly Ash Using SEM (비산회로부터 회수한 미연탄소분의 전자현미경을 이용한 특성분석)

  • Ahn, Yang-Kyu;Kil, Dae-Sup
    • Analytical Science and Technology
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    • v.15 no.6
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    • pp.567-573
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    • 2002
  • The most important and largest commercial outlet of fly ash in Korea is a replacement material of Portland cement in concrete industry. The high level of unburned carbon in ash brings about some malfunctions in concrete. Therefore, fly ash is refined to improve the quality as a concrete additive. In this process, a lot of the residual carbon is produced, and discarded now. In the present study, to find out a valuable outlet of the enriched carbon samples, the basic morphology of residual carbon in fly ash from Boryung power plant was investigated. The unburned carbon characterization included shape, size measurement, and chemical analysis was examined using scanning electron microscope (SEM) and energy dispersive X-ray spectrometer (EDX).

Compressive Behaviour of Geopolymer Concrete-Filled Steel Columns at Ambient and Elevated Temperatures

  • Tao, Zhong;Cao, Yi-Fang;Pan, Zhu;Hassan, Md Kamrul
    • International Journal of High-Rise Buildings
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    • v.7 no.4
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    • pp.327-342
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    • 2018
  • Geopolymer concrete (GPC), which is recognised as an environmentally friendly alternative to ordinary Portland cement (OPC) concrete, has been reported to possess high fire resistance. However, very limited research has been conducted to investigate the behaviour of geopolymer concrete-filled steel tubular (GCFST) columns at either ambient or elevated temperatures. This paper presents the compressive test results of a total of 15 circular concrete-filled steel tubular (CFST) stub columns, including 5 specimens tested at room temperature, 5 specimens tested at elevated temperatures and the remaining 5 specimens tested for residual strength after exposure to elevated temperatures. The main variables in the test program include: (a) concrete type; (b) concrete strength; and (c) curing condition of geopolymer concrete. The test results demonstrate that GCFST columns have similar ambient temperature behaviour compared with the conventional CFST counterparts. However, GCFST columns exhibit better fire resistance than the conventional CFST columns. Meanwhile, it is found that the GCFST column made with heat cured GPC has lower strength loss than other columns after exposure to elevated temperatures. The research results highlight the possibility of using geopolymer concrete to improve the fire resistance of CFST columns.

Influence of mineral by-products on compressive strength and microstructure of concrete at high temperature

  • Sahani, Ashok Kr.;Samanta, Amiya K.;Roy, Dilip K. Singha
    • Advances in concrete construction
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    • v.7 no.4
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    • pp.263-275
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    • 2019
  • In the present work, Granulated Blast Furnace Slag (GBFS) and Fly ash (FA) were used as partial replacement of Natural Sand (NS) and Ordinary Portland Cement (OPC) by weight. One control mix, one with GBFS, three with FA and three with GBFS-FA combined mixes were prepared. Replacements were 50% GBFS with NS and 20%, 30% and 40% FA with OPC. Preliminary investigation on development of compressive strength was carried out at 7, 28 and 90 days to ensure sustainability of waste materials in concrete matrix at room temperature. After 90days, thermo-mechanical study was performed on the specimen for a temperature regime of $200^{\circ}-1000^{\circ}C$ followed by furnace cooling. Weight loss, visual inspection along with colour change, residual compressive strength and microstructure analysis were performed to investigate the effect of replacement of GBFS and FA. Although adding waste mineral by-products enhanced the weight loss, their pozzolanicity and formation history at high temperature played a significant role in retaining higher residual compressive strength even up to $800^{\circ}C$. On detail microstructural study, it has been found that addition of FA and GBFS in concrete mix improved the density of concrete by development of extra calcium silicate gel before fire and restricts the development of micro-cracks at high temperature as well. In general, the authors are in favour of combined replacement mix in view of high volume mineral by-products utilization as fire protection.

Crack Control of Flexure-Dominant Reinforced Concrete Beams Repaired with Strain-Hardening Cement Composite (SHCC) Materials (변형경화형 시멘트 복합체를 활용한 휨항복형 철근콘크리트 보의 균열제어)

  • Cha, Jun-Ho;Park, Wan-Shin;Lee, Young-Oh;Kim, Sun-Woo;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.23 no.1
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    • pp.109-120
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    • 2011
  • This paper presents an experimental study results on the crack control of flexure-dominant reinforced concrete beams repaired with strain-hardening cement composite (SHCC). Five RC beams were fabricated and tested until failure. One unrepaired RC beam was a control specimen (CBN) and remaining four speciemens were repaired with SHCC materials. The test parameters included two types of SHCC matrix ductility and two types of repair method (patching and layering). Test results demonstrated that RC beams repaired with SHCC showed no concrete crushing or spalling until final failure, but numerous hair cracks were observed. The control specimen CBN failed due to crushing. It is important to note that SHCC matrix can improve crack-damage mitigation and flexural behavior of RC beams such as flexural strength, post peak ductility, and energy dissipation capacity. In the perspective of crack width, crack widths in RC beams repaired with SHCC had far smaller crack width than the control specimen CBN under the same deflection. Especially, the specimens repaired with SHCC of PVA0.75%+PE0.75% showed a high durability and ductility. The crack width indicates the residual capacity of the beam since SHCC matrix can delay residual capacity degradation of the RC beams.

A STUDY ON THE SHEAR BOND STRENGTH OF LIGHT-CURED GLASS IONOMER CEMENT (광중합형 글래스아이오노머 시멘트의 전단결합강도에 대한 연구)

  • Kim, Hyun-Yang;Tae, Ki-Chul;Kook, Yoon-Ah;Kim, Sang-Cheol
    • The korean journal of orthodontics
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    • v.28 no.5 s.70
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    • pp.689-698
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    • 1998
  • The purpose of this study was to evaluate the shear bond strength of light cured glass ionomer cement to enamel surface which treated with $37\%$ phosphoric acid, $10\%$ polyacrylic acid, $1.23\%$ acidulated phosphate fluoride gel and no etching agent. To compare the shear bond strength of glass ionomer cement, light-cured composite resin and chemically-cured composite resin were empoloyed as controls. Eight experiments groups were composed. 10 specimens of each group were bonded by metal bracket by tested in universal testing machine for shear bond strength, in stereoscope for adhesive remnants index. The data were evaluated statistically by SPSS/PC+. The results were as follows. 1. Among the groups of $37\%$ phosphoric acid treated and dry and bonded with light cured glass ionomer, light cured composite resin, and chemically cured composite resin, the shear bond strength of glass ionomer group showed no significant difference to the others, but the shear bond strength of chemically cured resin showed statistically lower than that of light cured resin (p<0.05). 2. The shear bond strengths of glass ionomer cement to enamel treated group with $1.23\%$ acidulated phosphate fluoride gel and $10\%$ polyacrylic acid and $37\%$ phosphoric acid showed statistically higher than that of no etched enamel group(p<0.U). 3. In the groups of glass ionomer cement, the presence of moisture was not significantly effect to the shear bond strength (p<0.05). 4. After debonding, no etched enamel group showed less residual materials on the enamel surface than the group of enamel etched with $37\%$ Phosphoric acid.

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A PHOTOELASTIC STRESS ANALYSIS IN MANDIBULAR DISTAL EXTENSION REMOVABLE PARTIAL DENTURE DESIGNED UNILATERALLY WITH DIFFERENT DIRECT RETAINERS (편측성으로 설계된 하악 유리단 국소의치에서 직접유지장치의 설계 변화에 따른 광탄성 응력 분석에 관한 연구)

  • Son Hong-Suk;Kay Kee-Sung
    • The Journal of Korean Academy of Prosthodontics
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    • v.30 no.1
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    • pp.25-42
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    • 1992
  • The purpose of this study was to analyze the magnitude and distribution of stress using a photoelastic model from a unilateral distal extention removable partial dentures with five kinds of the direct retainers, that is, the bilaterally designed bar clasp of the cross-arch lingual bar and the unilaterally designed bar clasp, circumferential clasp, mini-Dalbo attachment, and telescope retainer. A photoelastic model for mandible was made of the epoxy resin(PL-1) and hardner (PLH-1) with the acrylic resin teeth used and was coated with plastic cement-1 at the lingual surface of the model, and then five kinds of removable partial dentures were set, A unilateral vertical load of about 16Kg was applied on the first molar and the stress pattern of the photoelastic model under each condition was analyzed by the reflective circular polariscope. The following results were obtained: 1. The conventional removable partial denture with the bilaterally cross arch lingual bar produced the most favorable stress distribution on the residual ridge and supporting structure of abutment teeth than the unilaterally designed removable partial dentures. 2. The unilaterally designed removable partial denture with the bar clasp produced the stress distribution on the residual ridge, except sligtly higher stress concentration on the supporting structure of the abutment teeth, similar to the conventional removable partial denture with the bilaterally designed cross arch lingual bar. 3. On the unilaterally designed removable partial dentures, the bar clasp produced greater stress distribution on the residual ridge and supporting structure of the abutment teeth than the circumferential clasp. 4. On the unilaterally designed removable partial dentures, the mimi-Dalbo attachment produced relatively higher stress concentration on the residual ridge, but produced lesser stress concentration on the supporting structure of the abutment teeth than the other direct retainers. 5. On the unilaterally designed removable partial dentures, the telescope retainer produced uniform stress distribution on the residual ridge, but produced higher stress concentration at the root apex of the terminal abutment tooth than the other direct retainers. 6. On the unilaterally designed removable partial dentures the circumferential clasp and telescope retainer produced slightly higher stress concentration on the residual ridge and supporting structure of the abutment teeth than the bar clasp and mini- Dalbo attachment.

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A Study on the Residual Mechanical Properties of Fiber Reinforced Concrete with High Temperature and Load (고온 및 하중에 따른 섬유보강 콘크리트의 잔존 역학적 특성에 관한 연구)

  • Kim, Young-Sun;Lee, Tae-Gyu;Nam, Jeong-Soo;Park, Gyu-Yeon;Kim, Gyu-Yong
    • Journal of the Korea Concrete Institute
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    • v.23 no.3
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    • pp.321-330
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    • 2011
  • Recently, the effects of high temperature and fiber content on the residual mechnical properties of high-strength concrete were experimentally investigated. In this paper, residual mechanical properties of concrete with water to cement (w/c) ratios of 0.55, 0.42 and 0.35 exposed to high temperature are compared with those obtained in fiber reinforced concrete with similar characteristics ranging from 0.05% to 0.20% polypropylene (PP) fiber volume percentage. Also, factors including pre-load levels of 20% and 40% of the maximum load at room temperature are considered. Outbreak time, thermal strain, length change, and mass loss were tested to determine compressive strength, modulus of elasticity, and energy absorption capacity. From the results, in order to prevent the explosive spalling of 50 MPa grade concretes exposed to high temperature, more than 0.05 vol. % of PP fibers is needed. Also, the cross-sectional area of PP fiber can influence the residual mechanical properties and spalling tendency of fiber reinforced concrete exposed to high temperature. Especially, the external loading increases not only the residual mechanical properties of concrete but also the risk of spalling and brittle failure tendency.