• Title/Summary/Keyword: Reinforcing Agent

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Foaming Behavior, Structure, and Properties of Rubber Nanocomposites Foams Reinforced with Zinc Methacrylate (아연 메타아크릴레이트로 보강된 발포고무 나노복합체의 발포거동, 구조 및 특성)

  • Basuli, U.;Lee, G.B.;Jang, S.Y.;Oh, J.;Lee, J.H.;Kim, S.C.;Jeon, N.D.;Huh, Y.I.;Nah, C.
    • Elastomers and Composites
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    • v.47 no.4
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    • pp.297-309
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    • 2012
  • Different amounts of foaming agents were employed in natural rubber(NR)/butadiene rubber(BR) blends to understand the foaming behavior in presence of nano-reinforcing agent, zinc methacrylate (ZMA). The ZMA greatly improved most of the mechanical properties of the rubber foams, however it did not show considerable effect on the cell morphology, such as cell size, density and porosity. It was also observed that the foaming agent concentration affected all the mechanical parameters. When the content of foaming agent was increased, the number of foams was increased leading to a decrease in density of the compounds. But the size and distribution of foams remained unchanged with increased foaming agent. The effect of high styrene-butadiene rubber (HSBR) was also studied. The size of cells became smaller and the cell uniformity was improved with increasing HSBR. The foam rubber compounds showed much efficient energy absorbing capability at higher strains.

Airtightness performance evaluation of ultra-high performance concrete using polymer coating materials (그래핀을 활용한 폴리머 도막재료의 물리적 특성 평가)

  • Lee, Hyun Seung;Kim, Kang Min;Yoon, Seob;Seo, Tae Suk
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.257-258
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    • 2023
  • In this study, it was conducted to improve the physical properties of VAE polymer matrix used as a coating material. A nanocomposite was manufactured using graphene as a reinforcing agent based on a VAE matrix. As a result, improvements in tensile strength, adhesion strength, and porosity were confirmed.

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The Governance and Agent Problems of Public Agency: Focused on the Port Authority of New York and New Jersey (공기업 거버넌스 제도와 대리인 문제: 뉴욕.뉴저지 항만공사를 중심으로)

  • Kang, Yun-Ho
    • Journal of Navigation and Port Research
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    • v.33 no.10
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    • pp.743-756
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    • 2009
  • This paper tries to analyze how the governance institutions of the Port Authority of New York and New Jersey overcome agent problems in public agencies based on the Principal-Agent Theory, and find the implications that will be helpful to the governance of port authorities in Korea. The Port Authority's governance is characterized by decentralization of personnel rights, open meetings policy, freedom of information policy, public hearings, and fiscally self-supporting system. Those characteristics are helpful in overcoming the agent problems of public agency, such as adverse selection, moral hazard, and complicated external structure, through reinforcing of monitoring agent by principal, easing of information asymmetry between principal and agent, and clarification of organizational ownership structure. Those characteristics may give many implications for the design of governance structures of port authorities in Korea.

Electric Properties of Silicone Rubber on Reinforcing Agent Dependence (보강제 변화에 따른 실리콘 고무의 전기 특성)

  • 이성일
    • Journal of the Korea Safety Management & Science
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    • v.6 no.1
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    • pp.301-309
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    • 2004
  • An inorganic filling agent, ATH (alumina trihydrate) was used to induce inorganic-organic coupling by mixing with stearic acid, acryl silane, vinyl silane as surface treatment agents in order to apply as a high voltage insulating material. Volumetric resistivity was shown to vary with surface treatment agents, and the highest value was obtained in case of the mixture with vinyl silane. The dielectric breakdown intensity was shown to decrease gradually and saturate to a stable value, possibly due to the increase of cross link density in the vinyl radicals introduced to silica surface, resulting in stable dielectric breakdown intensity in the final stages. Tracking and flame retardant properties were also shown to be the best among the samples investigated in this study.

An Evaluation on Concrete incorporating blame blast furnace slag powder adding Durability Improvement Agent (고로슬래그 미분말에 내구성향상 혼화제를 첨가한 콘크리트의 기초물성에 관한 실험적 연구)

  • Lee, Jong-Rok;Lim, Sang-Jun;Song, In-Myung;Yun, Jae-Hwan;Jung, Sang-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2007.04a
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    • pp.147-150
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    • 2007
  • As recent buildings often use low-quality concrete materials, are constructed defectively, and are put in extreme environmental conditions, many of them show the shortening of life resulting from the corrosion of reinforcing rods by salt damage, carbonization, freezing and thawing, cracking. This in turn raises the cost of repair and maintenance, so it is required to extend the life of structures through enhancing the durability of concrete. In response to the demand, researches on high-durability concrete are being made actively focused on the maximum water-cement ratio, the maximum unit quantity, the minimum cover thickness, the addition of mineral admixtures, etc. With this background, the present study examined the basic physical properties of concrete containing admixtures for enhancing the durability of concrete.

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Properties of polypropylene fibers using the green chemical orotic acid as nucleating agent

  • Vogel, Roland;Brunig, Harald;Haussler, Liane
    • Advances in materials Research
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    • v.4 no.4
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    • pp.207-214
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    • 2015
  • It has been reported in the technical literature that orotic acid can be used in order to induce improved crystallization of biodegradable and biocompatible polymers like poly(L-lactic acid), polyhydroxybutyrate and poly(hydroxybutyrate-co-hydroxyhexaonat). The expected advantage of the changed crystalline structure is a reinforcing effect of the polymers. A lot of papers reported about the application of inorganic and organic agents for acceleration of heterogeneous nucleation. This study reports on an attempt to use orotic acid as appropriate non-toxic nucleating agent for improving mechanical properties of isotactic polypropylene. Special attention is given to demonstrate the effect of nucleation in a typical melt spinning process in order to improve the mechanical properties. The effects were demonstrated using rheology, thermal analysis and tensile testing.

Behavior of Concrete Bridge Deck Using Hybrid Reinforcement System (Hybrid Reinforcement System을 이용한 콘크리트 교량상판 슬래브의 거동)

  • Park Sang-Yeol;Cho Keun-Hee
    • Journal of the Korea Concrete Institute
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    • v.16 no.4 s.82
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    • pp.451-458
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    • 2004
  • This study describes the basic concept and the applicability of Hybrid Reinforcement System using conventional steel reinforcing bars and Fiber Reinforced Polymer bars. The concrete bridge decks are assumed to be supported by beams and reinforced with two layers of reinforcing bars. In concrete bridge deck using HRS, the top tensile force for negative moment zone on beam supports is assumed to be resisted by FRP reinforcing bars, and the bottom tensile force for positive moment zone in the middle of hem supports is assumed to be resisted by conventional steel reinforcing bars, respectively. The FRP reinforcing bars are non-corrosive. Thus, the steel reinforcement is as far away as possible from the top surface of the deck and protected from intrusion of corrosive agent. HRS concrete bridge deck has sufficient ductility at ultimate state as the following reasons; 1) FRP bars have lower elastic modulus and higher ultimate strain than steel re-bars have, 2) FRP bars have lower ultimate strain if provided higher reinforcement ratio, 3) ultimate strain of FRP bars can be reduced if FRP bars are unbonded. Test results showed that FRP and HRS concrete slabs are not failed by FRP bar rupture, but failed by concrete compression in the range of ordinary reinforcement ratio. Therefore, in continuous concrete bridge deck using HRS, steel reinforcing bars for positive moment yield and form plastic hinge first and compressive concrete fail in the bottom of supports or in the top of the middle of supports last. Thus, bridge deck consumes significant inelastic strain energy before its failure.

Effects of Silane-treated Silica on the Cure Temperature and Mechanical Properties of Elastomeric Epoxy (실란 커플링제로 처리된 실리카가 탄성에폭시의 경화온도 및 기계적 물성에 미치는 영향)

  • Choi, Sun-Mi;Lee, Eun-Kyoung;Choi, Seo-Young
    • Elastomers and Composites
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    • v.43 no.3
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    • pp.147-156
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    • 2008
  • In this work, epoxy/carboxyl-terminated butadiene acrylonitirile (EP/CTBN) composites were prepared by employing a reinforcing filler, silica treated with silane coupling agent in different ratio by dry and wet method. Their curing characteristics, surface free energy, interface morphologies and mechanical properties such as tensile strength and impact resistance were carefully investigated. Differential scanning calorimetry(DSC) results showed that curing temperature was lowered with the increase of silane coupling agent because of the increase of relative curing agent cotent by filling the pores of silica. Wet method was proved to be more effective for lowering curing temperature of EP/CTBN composite. In general, surface free energy and impact resistance were increased with the increase of silane coupling agent in this work. Tensile strength, however, was observed to be decreased at 4 wt% of silane coupling agent. It was found that the dry method was proved to be preferable for pretreatment of silica with coupling agent.

Effect of high energy ball milling on the structure of iron - multiwall carbon nanotubes (MWCNT) composite

  • Kumar, Akshay;Pandel, U.;Banerjee, M.K.
    • Advances in materials Research
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    • v.6 no.3
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    • pp.245-255
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    • 2017
  • High energy ball milling is employed to produce iron matrix- multiwall carbon nanotube (MWCNT) reinforced composite. The damage caused to MWCNT due to harsh ball milling condition and its influence on interfacial bonding is studied. Different amount of MWCNT is used to find the optimal percentage of MWCNT for avoidance of the formation of chemical reaction product at the matrix - reinforcement interface. Effect of process control agent is assessed by the use of different materials for the purpose. It is observed that ethanol as a process control agent (PCA) causes degradation of MWCNT reinforcements after milling for two hours whereas solid stearic acid used as process control agent, allows satisfactory conservation of MWCNT structure. It is further noted that at a high MWCNT content (~ 2wt.%), high energy ball milling leads to reaction of iron and carbon and forms iron carbide (cementite) at the iron-MWCNT interface. At low percentage of MWCNT, dissolution of carbon in iron takes place and the amount of reinforcement in iron matrix composite becomes negligibly small. However, under the present ball milling condition (ball to metal ratio~ 6:1 and 200 rpm vial speed) iron-1wt.% MWCNT composite of good interfacial bonding can retain the tubular structure of reinforcing MWCNT.

Evaluation of Shrinkage Properties Based on Mock-Up Testin High Performance Concrete (Mock-Up 시험에 의한 고성능 콘크리트의 수축특성 분석)

  • Han, Cheon-Goo;Kang, Su-Tae;Koh, Kyung-Taek;Hann, Chang-Pyung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.5
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    • pp.106-114
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    • 2006
  • This paper investigates the fundamental properties and shrinkage characteristics of low shrinkage high performance concrete(LSHPC), using mock-up specimens. According to the test results, the most suitable mix proportions of LSHPC need a higher dosage of SP agent and AE agent, in order to obtain the target of slump flow and air content. This is due to reduce fluidity and air content respectively. It also presented earlier setting time than control concrete by 6 hours and exhibited compressive strength of 60MPa at age 28 days. Autogenous shrinkage of LSHPC was the half of the value of control concrete. Drying shrinkage of center section of LSHPC showed similar tendency with autogenous shrinkage, because of no internal moisture movement, while surface section had larger drying shrinkage. The specimen with embedded reinforcing bar had smaller deformation owing to confinement of reinforcing bar.