• Title/Summary/Keyword: Reduction-diffusion method

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Chloride diffusion study in different types of concrete using finite element method (FEM)

  • Paul, Sajal K.;Chaudhuri, Subrata;Barai, Sudhirkumar V.
    • Advances in concrete construction
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    • v.2 no.1
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    • pp.39-56
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    • 2014
  • Corrosion in RCC structures is one of the most important factors that affects the structure's durability and subsequently causes reduction of serviceability. The most severe cause of this corrosion is chloride attack. Hence, to prevent this to happen proper understanding of the chloride penetration into concrete structures is necessary. In this study, first the mechanism of this chloride attack is understood and various parameters affecting the process are identified. Then an FEM modelling is carried out for the chloride diffusion process. The effects of fly ash and slag on the diffusion coefficient and chloride penetration depth in various mixes of concretes are also analyzed through integrating Virtual RCPT Lab and FEM.

Probe Diffusion in Polymer Solutions by Forced Rayleigh Scattering

  • Jaeyung Lee;Taiho Park;Jungmoon Sung;Sangwook Park;Taihyun Chang
    • Bulletin of the Korean Chemical Society
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    • v.12 no.5
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    • pp.569-574
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    • 1991
  • Methyl red diffusion in polymer solutions was studied by a transient holographic method, forced Rayleigh scattering. In semi-dilute solutions of a polystyrene, where no specific interaction with the probe exists, we found within experimental uncertainty that the retardation of diffusion rate of methyl red is independent of the solvents used. This indicates that the hydrodynamic interaction in polymer coils is not affected by the nature of solvents enough to exhibit a detectable change in the diffusion rate of the probe. On the other hand, a substantial reduction of diffusion rate was observed in poly(methyl methacrylate) solutions in toluene. Together with the similar observation reported with poly(vinyl acetate), it is confirmed that hydrogen bond between the probe and the polymer is responsible for the retarded diffusion. The decay-growth-decay profile found in this system reveals a finite difference in diffusion coefficients of cis and trans isomer of methyl red. We estimate the difference and suggest that the cis isomer interacts with the polymer more strongly than the trans isomer.

Growth and characterization of lead bromide: application to mercurous bromide

  • Kim, Geug-Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.2
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    • pp.50-57
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    • 2004
  • Mercurous Bromide ($Hg_2Br_2$) crystals hold promise for many acousto-optic and opto-electronic applications. This material is prepared in closed ampoules by the physical vapor transport (PVT) growth method. We investigate the effects of solutal convection on the crystal growth rate in a horizontal configuration for diffusive-convection conditions and purely diffusion conditions achievable in a low gravity environment. Our results show that the growth rate is decreased by a factor of one-fourth with a ten reduction of gravitational acceleration near y = 2.0 cm. For 0.1 $g_O$ the growth rate pattern exhibits relatively flat which is intimately related to diffusion-dominated processes. The growth rate nonuniformity is regardless of aspect ratio across the interfacial positions from 0 to 1.5. Also, the effect of a factor of the ten reduction in the gravitational acceleration is same to both Ar = 5 and 2. The enlargement in the molecular weight of B from 50 to 500 by a factor 4 causes a decrease in the maximum growth rate by the same factor, indicative of the effect of solutal gradients.

Fast GPU Implementation for the Solution of Tridiagonal Matrix Systems (삼중대각행렬 시스템 풀이의 빠른 GPU 구현)

  • Kim, Yong-Hee;Lee, Sung-Kee
    • Journal of KIISE:Computer Systems and Theory
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    • v.32 no.11_12
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    • pp.692-704
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    • 2005
  • With the improvement of computer hardware, GPUs(Graphics Processor Units) have tremendous memory bandwidth and computation power. This leads GPUs to use in general purpose computation. Especially, GPU implementation of compute-intensive physics based simulations is actively studied. In the solution of differential equations which are base of physics simulations, tridiagonal matrix systems occur repeatedly by finite-difference approximation. From the point of view of physics based simulations, fast solution of tridiagonal matrix system is important research field. We propose a fast GPU implementation for the solution of tridiagonal matrix systems. In this paper, we implement the cyclic reduction(also known as odd-even reduction) algorithm which is a popular choice for vector processors. We obtained a considerable performance improvement for solving tridiagonal matrix systems over Thomas method and conjugate gradient method. Thomas method is well known as a method for solving tridiagonal matrix systems on CPU and conjugate gradient method has shown good results on GPU. We experimented our proposed method by applying it to heat conduction, advection-diffusion, and shallow water simulations. The results of these simulations have shown a remarkable performance of over 35 frame-per-second on the 1024x1024 grid.

Fabrication of $Nd_{2}Fe_{14}B$ Powders by Spray-Drying and Reduction-Diffusion Processes

  • Park, C. J.;Kim, B. K.;X. L. Dong
    • Proceedings of the Korean Magnestics Society Conference
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    • 2000.09a
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    • pp.393-394
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    • 2000
  • The magnetic alloy of $Nd_{2}Fe_{14}B$-type was synthesized by a mechano-chemical method, including the processes of spray-drying, de-binding, milling, $H_{2}$- and Ca-reduction and washing. The very fine $Nd_{2}Fe_{14}B$ particles smaller than $1\mu\textrm{m}$ could be achieved without the inevitable pulverization step in conventional processes.

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Electrocatalytic Reduction of Molecular Oxygen at Poly(1,8-diaminonaphthalene) and Poly(Co(II)-(1,8-diaminonaphthalene)) Coated Electrodes

  • Park, Hyun;Kwon, Tae-guen;Park, Deog-Su;Shim, Yoon-Bo
    • Bulletin of the Korean Chemical Society
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    • v.27 no.11
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    • pp.1763-1768
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    • 2006
  • The application of poly(Co(II)-(1,8-diaminonaphthalene))(poly(Co-DAN)) and poly(1,8-diaminonaphthalene) (Poly(1,8-DAN)) to the electrocatalytic reduction of molecular oxygen was investigated, which were electrochemically grown by the potential cycling method on the glassy carbon electrodes. The reduction of oxygen at the polymer and its metal complex polymer coated electrodes were irreversible and diffusion controlled. The Poly(1,8-DAN) and Poly(Co-DAN) films revealed the potential shifts for the oxygen reduction to 30 mV and 110 mV, respectively, in an aqueous solution, compared with that of the bare electrode. Hydrodynamic voltammetry with a rotating ring-disk electrode showed that Poly(1,8-DAN) and Poly(Co-DAN) coated electrodes converted respectively 84% and 22% of $O_2$ to $H_2O$ via a four electron reduction pathway.

Evaluation of Chloride Resistance with Application Method of Coating Materials Using Electric Acceleration Test (코팅재료의 도포 특성에 따른 전기적 촉진을 통한 염해 저항성 평가)

  • Kim Myung Yu;Yang Eun Ik;Yeon Kyu Seok;Joo Myung Ki
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.11a
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    • pp.551-554
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    • 2005
  • The durability of concrete is decreased by various deterioration factors such as a crack, spalling, corrosion. Many repair and rehabilitation methods have been introduced to extend service life of RC structure. An application of coating material is one of repair and rehabilitation methods. However, there is a problem due to reduction of bonding strength and damage of coating material in the case of existed coating material. Thus, this paper is aim to investigate the chloride resistance according to application method of coating material which improve the existed problem. According to the results, it is showed that application of coating material reduces diffusion of chloride into concrete. In special, application of MMA polymer showed the best resistance for chloride attack. However, variation of application method and number of times has a minor effect on chloride diffusion.

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A Study on the Combustion Characteristics of a Hybrid Cyclone Jet Combustor (하이브리드 사이클론 제트 연소기의 연소특성에 관한 연구)

  • Jung, Won-Suk;Hwang, Chul-Hong;Lee, Gyou-Young;Lee, Chang-Eon
    • 한국연소학회:학술대회논문집
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    • 2002.11a
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    • pp.149-155
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    • 2002
  • A promising new approach to achieve low pollutants emission and improvement of flame stabilities is tested experimentally using a hybrid cyclone jet combustor employing both premixed and diffusion combustion mode, Three kind of nozzles are used for LNG(Liquified Natural Gas) as a fuel. The combustor is operated by two method, One is ATI(Air Tangential Injection) mode, generated swirl flow by air as general swirl combustor, and the other is PTI(Premixed gas Tangential Injection) mode, The PTI mode consists of diffusion flame of axial direction and premixed cyclone flame of tangential direction in order to stabilized the diffusion flame. The results showed that the stable region of the PTI mode is more larger than the ATI mode. In addition, the reduction of NOx emission in PTI mode, as compared with that for the ATI mode is at least 50% in stable region. Also, even using the low calorific fuel as $CO_2$-blended gas, the cyclone jet combustor has high performance of flame stability.

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Micro-crack Detection in Silicon Solar Wafer through Optimal Parameter Selection in Anisotropic Diffusion Filter (비등방 확산 필터의 최적조건 선정을 통한 태양전지 실리콘 웨이퍼의 마이크로 크랙 검출)

  • Seo, Hyoung Jun;Kim, Gyung Bum
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.3
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    • pp.61-67
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    • 2014
  • Micro-cracks in crystalline silicon wafer often result in wafer breakage in solar wafer manufacturing, and also their existence may lead to electrical failure in post fabrication inspection. Therefore, the reliable detection of micro-cracks is of importance in the photovoltaic industry. In this paper, an experimental method to select optimal parameters in anisotropic diffusion filter is proposed. It can reliably detect micro-cracks by the distinct extension of boundary as well as noise reduction in near-infrared image patterns of micro-cracks. Its performance is verified by experiments of several type cracks machined.

Studies on the Diffusion Current of Ideal Streaming Merury Electrode under Gravity (重力下의 理想噴出水銀電極의 擴散電流에 關한 硏究)

  • Kim, Hwang-Am;Jin, Chang-Hi
    • Journal of the Korean Chemical Society
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    • v.5 no.1
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    • pp.80-83
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    • 1961
  • Solution of the diffusion problem applicable to steady state reduction at the ideal streaming mercury electrode are presented, with special attention being given to the influence of stream contraction caused by the gravity. To eliminate the convection occurring in the layer between the streaming mercury and the electrolytic solution, a new method have been invented, in this case the solution being tested was streamed with same velocity of the streaming mercury. Experiment have been made in order to compare the experimental value with the theoretical value and the experimental diffusion current was approached more to the theoretical value than the value obtained by earlier form of the streaming mercury electrode used by Heyrovsky.

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