Journal of the Korean Chemical Society (대한화학회지)

Korean Chemical Society (대한화학회)
권호 표지

Studies on the Diffusion Current of Ideal Streaming Merury Electrode under Gravity

重力下의 理想噴出水銀電極의 擴散電流에 關한 硏究

  • Kim, Hwang-Am (Department of Chemistry, College of Liberal Arts and Science, University of Sung Kyun) ;
  • Jin, Chang-Hi (Department of Chemistry, College of Liberal Arts and Science, University of Sung Kyun)
  • 김황암 (成均館大學敎 文理科大學 化學科) ;
  • 진창희 (成均館大學敎 文理科大學 化學科)
  • Published : 19610700
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Abstract

Solution of the diffusion problem applicable to steady state reduction at the ideal streaming mercury electrode are presented, with special attention being given to the influence of stream contraction caused by the gravity. To eliminate the convection occurring in the layer between the streaming mercury and the electrolytic solution, a new method have been invented, in this case the solution being tested was streamed with same velocity of the streaming mercury. Experiment have been made in order to compare the experimental value with the theoretical value and the experimental diffusion current was approached more to the theoretical value than the value obtained by earlier form of the streaming mercury electrode used by Heyrovsky.

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References

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