• Title/Summary/Keyword: Reduction of Metal Surface

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Characterization of Ionic-Polymer Metal Composite Actuators Varying Electroless Plating Method of Platinum (백금 무전해 도금 방법의 변화에 따른 이온성 고분자 및 금속 복합체 액추에이터의 특성 분석)

  • 차승은;김병목;조성환;이승기;박정호;김병규
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.51 no.12
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    • pp.601-607
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    • 2002
  • IPMC(Ionic Polymer Metal Composite)actuators were optimized for producing improved forces by changing multiple parameters including repetition of number of plating, surface electroding and additive(PVP)-treatment on reduction. The platinum electrode is deposited on the surface of the material where platinum particle stay in a dense form that appears to introduce a significant level of surface electrode resistance. Actuation tests were performed for such IPMC actuators under a low voltage. The test results show that the lower surface-electrode resistance generates higher actuation capability in the IPMC actuators. In order to investigate relaxation behavior of bending and repeatability in dry condition, the IPMC was coated by$rubber(KRATON^{TM})$to minimize the effect of water evaporation from IPMC. This actuator can be used in air with surface coating to avoid membrane drying.

A Study on the NOx Reduction According to the Space Velocity Variation and Binder Content of Metal foam SCR Catalyst for Cogeneration Power Plant Application (열병합발전소 적용을 위한 Metal foam SCR촉매의 공간속도와 바인더 함량에 따른 NOx 저감에 관한 연구)

  • Na, Woo-Jin;Park, Hea-Kyung
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.1
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    • pp.153-164
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    • 2019
  • To develop a high performance SCR catalyst which has better specific surface area, lightness of weight and fast temperature response than those of existing commercial SCR catalyst, metal foam type SCR catalysts were prepared by washcoating with vanadium, tungsten and binder. The de-NOx performance test of the prepared catalysts was carried out on atmospheric micro-test unit at lab. scale according to space velocity variation and temperature change, and the characteristics of them were analyzed by Porosimeter, SEM(scanning electron microscope), EDX(energy dispersive x-ray spectrometer), ICP(inductively coupled plasma) and Stereomicroscope. The NOx reduction performance decreased as the space velocity increased and was found to be the best at 3.5 wt.% contents of the vanadium and tungsten. It was found that the larger amount of binder was added, the worse the NOx reduction performance was, which was considered to be that the number of active sites of the prepared catalyst surface was occupied by the binder. We found that the amount of binder to be added to prepare the catalyst should be properly controlled by the condition of coated catalyt surface.

THE EFFECT OF SUREACE TREATMENTS ON THE REBONDED RESIN-BONDED RETAINERS

  • Kim Sang-Pil;Kang Dong-Wan
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.6
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    • pp.590-596
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    • 2002
  • The resin : metal interface is at the basis of most bonding failures in resin-bonded prosthesis. Although debonding has been a problem with adhesive fixed partial dentures, various dentists classify them as long-term restorations. The advantages of resin-bonded fixed partial dentures include minimal tooth reduction and the possibility of rebonding. if resin-bonded protheses can be easily rebounded, it is of clinical importance to know if the lutingagents rebond as well the second time as they did originally. Several retentive systems for resin-to-metal bonding have recommended. Treatments such as electrolytic etching and silicone coating, despite the good result of bond strength, have proved to be time-consuming and technique-sensitive. Therefore a simple and more reliable method is desirable. This study evaluated the effect of metal surface treatments on the rebond strength of panavia 21 cement to a nickel-chromium(Ni-Cr) alloy. The samples were received the following surface treatments : Group No.1 (control or served as the control) treatment with sandblasting with 50um aluminum oxide and ultrasonically cleaned for 10minutes in double-deionized water, Group No.2 were no surface treatments. Group No.3 were treated with metal primer. Group No.4 were treated with sandblasting as previously described, and then metal priming. From the analysis of the results, the following conclusions were drawn. 1. Sandblasting and metal priming appears to be an effective method for treatment of metal after accidental debonding. 2. Group without surface treatment had significantly lower bond strengths compared with other groups. 3. The combination of sandblasting and metal priming may not develop superior bonding strengths compared with other techniques that used the Ni-Cr alloys. 4. Combination of cohesive and adhesive failures were the most common type observed. The results support the use of sandblasting as a viable procedure when rebonding accidentally lost adhesive partial denture. We concluded that sandblasting and metal priming of metal surface before bonding could provide the adequate bond strength during rebonding of resin-bonded fixed partial denture.

A Study on the Manufacture of Composite W Powder for Low Sintering Temperature by Liquid Reduction Precipitation Method (액상환원침전법에 의한 저온활성화소결용 복합W분말의 제조방법 및 소결특성에 관한 연구)

  • 김창욱;이철;정인;윤성렬
    • Journal of Surface Science and Engineering
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    • v.28 no.4
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    • pp.207-218
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    • 1995
  • Tungsten(W) metal has excellent properties in heat-resistance, corrison-resistance and impact-resistance but W-Metal is hard to sinter because higher than $2,000^{\circ}C$ is required to sinter W-powder. Con-sequently, a deposit technique of Nikel Phosphorus(NiP) on W-powber by the liquid reduction precipitation method was performed. Sintering temperature of the resulting W-NiP composite was lowered around to $1,000^{\circ}C$, and the mechanical properties of the sintered body was studied. The most suitable conditions for NiP thin film deposit on W-Powder by the liquid reduction precipitation method, which are composition, concentration, pH and temperature of the liquid reduction solution, were considered. The activated sintering was carried out in a reducing condition furnace. Components and properties of the sintered body were investigated by the density and the hardness measurements, X- ray diffraction analysis, and microscopic photographs of the surface. Quantity of NiP thin film on W-powder could be varied by the change of the liquid reduction solution composition. The sintering temperature of W-NiP composite powder is lowered to $950^{\circ}C$ from $2,000^{\circ}C$ and the hardness is increased (ca. 720 Hv). Large shrinkage could be observed since density was increased from 5.5 to 11.0 g/$cm^2$ which 86.2% of theoretical density. W metal and $Ni_3P$ crystal were detected through X-ray diffraction on the sintered body. Perfectly activated sintering was observed by microscopic photographs.

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Micro-Filtration Performance of Metal Membrane md Fouling Reduction by Intermittent Ozonation (금속 막의 정밀 여과 특성 및 간헐적 오존 처리에 의한 막 오염 저감)

  • 김종오;정종태
    • Membrane Journal
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    • v.14 no.1
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    • pp.66-74
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    • 2004
  • Total resistance of membrane in a micro-filtration system using a metal membrane was mainly attributed to the permeate resistance of cake layer($R_c$), which was formed by deposited particles from the physico-chemical interactions of solids on membrane surface. Intermittent back ozonation was highly effective than the air backwashing for fouling reduction. As far the operational effect, under same ozone injection, the increase of gas flow-rate was more favorable than the increase of injection time far the recovery of permeation flux. As the filtration time was longer, the effect of flux recovery by intermittent back-ozonation decreased. Therefore, it is preferable to operate membrane cleaning before the foulant is consolidated on membrane surface.

The feasibility of algorithm for iterative metal artifact reduction (iMAR) using customized 3D printing phantom based on the SiPM PET/CT scanner (SiPM PET/CT에서 3D 프린팅 기반 자체제작한 팬텀을 이용한 iMAR 알고리즘 유용성 평가에 관한 연구)

  • Min-Gyu Lee;Chanrok Park
    • The Korean Journal of Nuclear Medicine Technology
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    • v.28 no.1
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    • pp.35-40
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    • 2024
  • Purpose: To improve the image quality in positron emission tomography (PET), the attenuation correction technique based on the computed tomography (CT) data is important process. However, the artifact is caused by metal material during PET/CT scan, and the image quality is degraded. Therefore, the purpose of this study was to evaluate image quality according to with and without iterative metal artifact reduction (iMAR) algorithm using customized 3D printing phantom. Materials and Methods: The Hoffman and Derenzo phantoms were designed. To protect the gamma ray transmission and express the metal portion, lead substance was located to the surface. The SiPM based PET/CT was used for acquisition of PET images according to application with and without iMAR algorithm. The quantitative methods were used by signal to noise ratio (SNR), coefficient of variation (COV), and contrast to noise ratio (CNR). Results and Discussion: The results shows that the image quality applying iMAR algorithm was higher 1.15, 1.19, and 1.11 times than image quality without iMAR algorithm for SNR, COV, and CNR. Conclusion: In conclusion, the iMAR algorithm was useful for improvement of image quality by reducing the metal artifact lesion.

Experimental Study on Friction Characteristics of Metal Surface Treated by LST (레이저 표면처리 된 금속의 마찰특성에 관한 실험적 연구)

  • Park, Sung-Yong;Min, Joon-Won;Lee, Eun-Gil;Chu, In-Gil
    • Laser Solutions
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    • v.13 no.1
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    • pp.16-20
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    • 2010
  • The studies on the fine processing on the surface of the metal utilizing the technique for LST (Laser surface texturing) have been performed recently. This study has acquired the lower frictional coefficient and endurance in the harsh environment of motion in the low lubricating range of low frictional coefficient in addition to storing of lubricant through fine processing on the frictional part of metal.

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Effects of Co-Existent Additives and the Role of Reacted Surface Film on the Friction with an Organo-Molybdenum Compound

  • Kim, Young-Hwan
    • Tribology and Lubricants
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    • v.10 no.4
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    • pp.43-50
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    • 1994
  • In order to elucidate the effects of co-existing additives (S$_{8}$, TBP: Tri butyl phosphate, ZnDTP: Zinc-dialkyl dithiophosphate) and the role of reacted surface film on the friction behavior of MoDTP (molybdenum dialkyl dithiophosphate), a friction experiment using a dual circular pipe edge surface type friction tester and XPS (X-ray photoelectronic spectrum) surface analysis were conducted. Friction reduction with MoDTP lubricant was proved to be greatly influenced by co-existing additive species. It was dependent on the properties of the film formed through the reaction between the additive and the surface. Phosphate film reduced the friction coefficient of MoDTP through suppression of diffusion of Mo compounds towards the metal substrate. On the other hand, sulfate film, which is inherently rich in lattice defects, did not lead to any appreciable friction reduction with MoDTP since the diffusion of the Mo compound towards the metal substrate was not effectively suppressed. With ZnDTP additive, the sulfide film formed through decomposition greatly influenced the lubricating performance of MoDTP. As such, properties of surface films formed from additives were proved to yield significant influence on the lubrication performance of MoDTP.

EFFECT OF COBALT-CHROMIUM ALLOY SURFACE TREATMENT WHEN BONDING WITH 4-META/MMA-TBB RESIN (Cobalt-Chromium 합금의 표면처리가 4-META/MMA-TBB 레진과의 접착에 미치는 영향)

  • Jin, Jae-Sik;Kim, Kyo-Han;Lee, Cheong-Hee;Jo, Kwang-Hun
    • The Journal of Korean Academy of Prosthodontics
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    • v.38 no.4
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    • pp.510-525
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    • 2000
  • The effects of pretreatment of Co-Cr alloy, including two adhesive primers that contain either MDP or MAC-10, and silicoating on the bond The result sobtained as follows; o Strength of 4-META/MMA-TBB resin were investigated using FT-IR, SEM, and EDAX. o In the SEM observation of surface morphologies, the sandblasted specimen exibited a very rough surface, whereas the surfaces of the two groups primed with either MDP or MAC-10 were covered with a layer of primer, and the surface morphology of the silicoated specimen remained almost the same after sandblasting. o Before the thermocycling tests, the group treated with MDP demonstrated the highest mean tensile bond strength and the sandblasted group showed the lowest bond strength. o After 20,000 thermocyling, the mean tensile bond strength of the sandblasted group exhibited a 50% reduction in bond strength, while the others showed a $20\sim30%$ reduction. o Observation of the metal-resin interface revealed that in all groups the resin permeated the rough surface formed by sandblasting thereby producing a mechanical bond between the metal and the resin. It was also found that thermocycling resulted in a gap formation at the metal-resin interface of the specimens, and the sandblasted group exhibited a larger gap width than the other groups. o In fracture mode, all specimens indicated a cohesive fracture within the resin before thermocycling. However, thermocyling produced adhesive failure at the edge of the resin-metal interface in most specimens. The sandblasted group, which exhibited the lowest bond strength after thormocycling, also demonstrated the largest area of adhesive failure.

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Synfuel Production Technology : Catalyst for Fischer-Tropsch Synthesis (합성액화연료 생산 기술: Fischer-Tropsch 합성용 촉매)

  • Park, Jo-Yong
    • Journal of the Korean Applied Science and Technology
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    • v.30 no.4
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    • pp.726-739
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    • 2013
  • Fischer-Tropsch synthesis (FTS) converts synthesis gas (CO and $H_2$) into longer chain hydrocarbons by a surface polymerization reaction. Cobalt- or iron-based catalysts normally show excellent activity for syngas conversion to petroleum products leading to super clean diesel fuels. The catalytic activities of the catalysts in FTS depend on the number of active sites on the surface. The number of active site was determined by the active metal particle size, loading amount, reduction degree and support-active metal interaction. The investigation adopts new methodology in preparing FT catalyst, which contains the controlled synthesis of active metal. The main focus of this paper is to give an overview of the types of catalysts, also including their preparation and reduction; the types of FT reactors; and also including the reaction conditions.