• Title/Summary/Keyword: Reduction agents

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Study on properties of eco-friendly reduction agents for the reduced graphene oxide method

  • Na, Young-il;Song, Young Il;Kim, Sun Woo;Suh, Su-Jeong
    • Carbon letters
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    • v.24
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    • pp.1-9
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    • 2017
  • We studied the basic properties and fabrication of reduced graphene oxide (rGO) prepared using eco-friendly reduction agents in the graphene solution process. Hydrazine is generally used to reduce graphene oxide (GO), which results in polluting emissions as well as fixed nitrogen functional groups on different defects in the graphene sheets. To replace hydrazine, we developed eco-friendly reduction agents with similar or better reducing properties, and selected of them for further analysis. In this study, GO layers were produced from graphite flakes using a modified Hummer's method, and rGO layers were reduced using hydrazine hydrate, L-ascorbic acid, and gluconic acid. We measured the particle sizes and the dispersion stabilities in the rGO dispersed solvents for the three agents and analyzed the structural, electrical, and optical properties of the rGO films. The results showed that the degree of reduction was in the order L-ascorbic acid ${\geq}$ hydrazine > glucose. GO reduced using L-ascorbic acid had a sheet resistance of $121k{\Omega}/sq$, while that reduced using gluconic acid showed worse electrical properties than the other two reduction agents. Therefore, L-ascorbic acid is the most suitable eco-friendly reduction agent that can be substituted for hydrazine.

A STUDY ON THE REDUCTION OF GALVANIC CURRENT BETWEEN AMALGAM AND GOLD ALLOY WITH VARIOUS CHEMICAL AGENTS (수종 아말감과 금합금의 갈바닉 전류 측정에 관한 연구)

  • Kim, Seung-Soo;Um, Chung-Moon
    • Restorative Dentistry and Endodontics
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    • v.18 no.2
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    • pp.469-481
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    • 1993
  • The purpose of this study was to achieve the reduction of the galvanic current between the dental amalgam alloy and gold alloy. In order to measure the galvanic current between these two metals a prep in the size of $4{\times}13mm$ which was filled with amalgam and another prep of $4{\times}2mm$ was filled with gold alloy was made in the acrylic resin. These two preps were then connected to a 2mm diameter copper wire. Using an ammeter to measure the galvanic current, six different kinds of amalgam and gold alloy were immersed in saline solution with approximately 10mm distance between the two alloys. Chemical agents that are thought to reduce the galvanic current such as hydrazine. silver nitrate, potassium chromate, and bonding agents such as Scotch bond 2(3M) and All bond 2(Bisco) were applied to the alloy surface. Cathodic inhibitor such as hydrazine was applied to gold alloy where as anodic inhibitor such as silver nitrate and potassium chromate were applied to amalgam. Both bonding agents, Scotch bond 2(3M) and All bond 2 (Bisco), were applied to amalgam. The following results were obtained when the currency on the coated alloy surface was compared to the uncoated surface. 1. The galvanic currency went down as the time elapsed and after 30 minutes no change was detected. 2. Initial currency was higher in low copper amalgam compared to high copper amalgam. Intitial currency was the highest in low copper lathe-cut amalgam. 3. Group of gold coated with hydrazine had the most reduction in galvanic currency. 4. Group of amalgam coated with silver nitrate or potassium chromate also showed significant reduction in galvanic currency. 5. The bonding agents also helped reduce galvanic currency. 6. Of all the agents used to reduce galvanic currency, silver nitrate showed the best result.

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A Study on the Well-being Technique Natural Dyeing with Natural Resources (2) -Effect of Monazite Treatment on the Cotton Fabric with Natural Dyeing using Perilla frutescens var. acuta - (천연물질을 활용한 웰빙기법 천연염색에 관한 연구 (2) -소엽염색 면직물의 모나자이트 처리효과-)

  • Kim, Sang-Yool
    • Fashion & Textile Research Journal
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    • v.12 no.2
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    • pp.240-245
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    • 2010
  • The effects of monazite and fixing agents on cotton fabric dyed with Perilla frutescens var. acuta extract were investigated. The proper monazite treatment concentration, temperature and time were 10%(o.w.b.), $50^{\circ}C$ and 60minutes. By various fixing agent treatment, $FeSO_4$ showed a relatively high K/S value and the order of K/S value decreased as follows, cation surface active agents, soybean and NaCl. And the monazite and $FeSO_4$ fixing agent showed higher anion emissity than those of untreated cotton and other fixing agents. The cotton fabrics showed improved color fastness by monazite and fixing agents treatments with the exception of light fastness. And the cotton fabrics fixed with fixing agents were showed effective bacterial reduction with the exception of NaCl.

An Analysis on the Reduction Effect of Freight Volume by Supply Chain Redesign for the Alliance of Distributors: A Simulation Using System Dynamics (유통업체간 제휴를 위한 공급체인 재설계에 의한 물동량 감소효과 분석: 시스템다이내믹스를 이용한 시뮬레이션)

  • Park, Se-Hoon;Moon, Seong-Am
    • Korean System Dynamics Review
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    • v.12 no.3
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    • pp.67-86
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    • 2011
  • This study shows the reduction effect of freight volume by the supply chain redesign for the alliance of distributors with system dynamics simulation. The as-is model is composed of 3 independent companies which one has 3 distribution centers (DCS) and 24 agents, another has 1 dc and 9 agents, the other has 3 DCS and 15 agents each. The to-be model is an integrated logistics model and composed of 1 company having 5 areal DCS and 38 agents. Each agent in the same area is integrated with each other. Two models have same demands but very different result. As a result, the freight volume between DCS and agents is reduced by 33.55%. This case study will be useful to analyze the similar cases about the logistics integration by supply chain redesign.

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Neuroprotective Agents in the Intensive Care Unit -Neuroprotective Agents in ICU -

  • Panahi, Yunes;Mojtahedzadeh, Mojtaba;Najafi, Atabak;Rajaee, Seyyed Mahdi;Torkaman, Mohammad;Sahebkar, Amirhossein
    • Journal of Pharmacopuncture
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    • v.21 no.4
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    • pp.226-240
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    • 2018
  • Neuroprotection or prevention of neuronal loss is a complicated molecular process that is mediated by various cellular pathways. Use of different pharmacological agents as neuroprotectants has been reported especially in the last decades. These neuroprotective agents act through inhibition of inflammatory processes and apoptosis, attenuation of oxidative stress and reduction of free radicals. Control of this injurious molecular process is essential to the reduction of neuronal injuries and is associated with improved functional outcomes and recovery of the patients admitted to the intensive care unit. This study reviews neuroprotective agents and their mechanisms of action against central nervous system damages.

Study on the Reactivity of Sodium Phosphate Ammonium Chloride pH Reduction Agents (인산나트륨계 염화암모늄 pH저감제의 반응성 검토)

  • Shin, Ki-Don;Gao, San;Lee, Gun-Cheol
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2017.11a
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    • pp.105-106
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    • 2017
  • Previous studies have confirmed the performance of pH reduction agents using liquid sodium phosphate based ammonium chloride as a pH reduction agent. In this study, the pH reduction performance considering economical and applicability as a practical stage and the property change analysis for the identification of the reaction mechanism of the pH reduction agent were carried out. As a result, the pH reduction performance at a low rate of the pH reducing agent was confirmed. The specific gravity of CaO decreased significantly after XRF analysis. It is also believed that this reduces the amount of Ca(OH)2 produced and contributes to pH reduction.

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Antimicrobial Characterictics of Antimicrobial Agent (Antibiotics) and Reduction Effect on Mal-ordour. (항균제의 항균특성 및 악취제거 효과)

  • Shin, Choon-Hwan;Kim, Jong-Hyun;Han, Sun-Hong
    • Journal of Environmental Science International
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    • v.3 no.2
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    • pp.157-164
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    • 1994
  • Various antimicrobial agents are widely used for the purpose of antimicrobial process. We investigated antimicrobial activity and reduction efficiency of mal-ordour by the diphenyl ether compound (2,4,4'- trichloro -2'- hydroxy diphenyl ether) against Sraphylocom aureus(S.aureus and Proton vulgaris(p.vulgaris causing the mal-ordour, Especially, the diphenyl ether compound is not restricted to the regulation of water-contamination. In this research, we found that the optimum concentration of diphenyl ether compound was 1.5w% for both strains and antimicrobial expressions were c0.38t= 2.56 for S.aureus, c0.38t=2.67 for P.vulgaris. We found also that -OH group played the role of antimicrobial functional group. Lastly, reduction effect of mal-ordour was more than 90% for both strain at the optimum conditions. Key Words : antimicrobial agents, antimicrobial activity, reduction effect of mal-ordour, antimicrobial expression, antimicrobial functional group.

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The Effect of Oxidizing Agents on Alkaloid Reduction of Tobacco Extract (담배추출물의 알카로이드감소에 미치는 산화제의 영향)

  • 황건중
    • Journal of Environmental Health Sciences
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    • v.8 no.2
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    • pp.33-46
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    • 1982
  • This experiment was carried out for the purpose of reducing alkaloid in reconstituted tobacco sheet and effluent of reconstituted tobacco sheet manufacturing company by treating oxidizing agents such as ozone, sodium hypochlorite, perchloric acid and hydrogen peroxide to tobacco extract created from the manufacturing process of reconstituted tobacco sheet. The effect of alkaloid reduction in tobacco extract by the volume added, time of treatment and pH of oxidizing agents were as follows: 1. When the solid rate of tobacco extract stood at 10 percent, the content of alkaloid, total sugar, total nitrogen and chlorine was 1,600mg/l, 11,000mg/l, 3,200mg/l and 4,000mg/l, respectively. 2. The effect of alkaloid reduction through ozone treatment was in proportion to time of ozone treatment. Alkaloid showed a 31.2 percent reduction under 8 hours' ozone treatment and 0.23g ozone consumed to remove lmg alkaloid. 3. Alkaloid reduction through sodium hypochlorite treatment was influenced by quantity of chlorine in sodium hypochlorite solution. To remove lmg alkaloid, 36.3mg chlorine was used. Reduction of alkaloid was not affected by time of sodium hypochlorite treatment, while showed the best reaction under pH 5-7. 4. The effect of alkaloid reduction by perchloric acid was under the control of the volume added and time of treatment of perchloric acid. The volume of perchloric acid required to remove alkaloid was on the decrease as time of treatment was getting longer. lmg alkaloid was removed by 0.15g perchloric acid under 8 hours' perchloric acid treatment. 5. Alkaloid reduction reacted slowly to the volume added and time of treatment of hydrogen peroxide. Under 8 hours' hydrogen peroxide treatment, it showed maximum removal, registering 10 percent alkaloid reduction.

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Thirty Six Years of Research on the Selective Reduction and Hydroboration

  • Cha, Jin-Soon
    • Bulletin of the Korean Chemical Society
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    • v.32 no.6
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    • pp.1808-1846
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    • 2011
  • From 1975 to 2011, for thirty six years, the author and his collaborators have developed a variety of reducing and hydroborating agents, and applied them to organic synthesis, which involves the 1,2-reduction of ${\alpha}$,${\beta}$-unsaturated carbonyl compounds, stereoselective reduction of cycloalkanones, regioselective ring-opening of epoxides, partial reduction of carboxylic acid derivatives to aldehydes, regioselective addition to carbon-carbon multiple bonds, etc. by utilizing metal hydrides and the newly-devised the Meerwein-Ponndorf-Verley (MPV) type reagents. Such developments provide a new synthetic methodology making possible valuable selective reductions and hydroborations, not practical previously.

The Effect of Contrast Agent on the Change of Hepatic Uptake of 99mTc-Mebrofenin in Patients with Liver Transplantation

  • Seung-Hun Yeom;Sang-Hyeong Kil;Yeong-Hyeon Lim;Gwang-Yeol Park;Gyeong-Nam Cho;Seong-Muk Cho;Ji-Ho Seong
    • The Korean Journal of Nuclear Medicine Technology
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    • v.28 no.1
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    • pp.23-29
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    • 2024
  • Purpose: 99mTc-mebrofenin hepatobiliary scintigraphy (HBS) is an important and clinically useful diagnostic imaging study for detecting complications after liver transplantation. CT contrast agents due to their high atomic numbers, lead to a decrease in gamma ray count rates. This study investigated the impact of CT contrast agents on the uptake of 99mTc-mebrofenin in the liver. Materials and Methods: The quantitative HBS was performed on sixty-two liver transplantation patients (male:female=36:26), with a mean age of 59.4±6.4 years. Statistical comparison of hepatic uptake reduction ratio (HURR%) before and after the injection of CT contrast agents was performed using a paired t-test. Results: Hepatic uptake of the reduction ratio was 94.47±3.65% for the pre-CT contrast agents and 92.17±4.00% for the post-CT contrast agents. HURR% after CT contrast agent injection showed a statistically significant difference compared to before the injection (t=11.09, P<0.001). Conclusion: It will be necessary to pay attention when examining the HBS of patients with liver transplantation after the injection of CT contrast medium. It is advisable to schedule the examination on a different day to prevent residual contrast medium in the body from interfering with the quantitative evaluation of the nuclear medicine examination.