• 제목/요약/키워드: Reduction agent

검색결과 1,040건 처리시간 0.027초

수축저감재료의 영향을 고려한 고성능 콘크리트의 자기수축 예측 모델 (Prediction Model on Autogenous Shrinkage of High Performance Concrete Used Material for Shrinkage Reduction)

  • 고경택;강수태;유성원;김도겸;한천구;이장화
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2004년도 추계 학술발표회 제16권2호
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    • pp.285-288
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    • 2004
  • Generally, the autogenous shrinkage of high performance concrete is important in that it can lead the early cracks in concrete structures. In the previous study, The. autogenous shrinakge of HPC was found to decrease with incresing expansive additive and shrinakge reduction agent. In case of combined use, the autogenous shrinakge was more reduction than in case separate use. The purpose of this study is to derive a realistic equation to estimate the autogenous shrinakge model of high performance concrete with exapnsive agent and shrinakge reduction agent. investigated the durability of high performance concrete using expansive additive and shrinkage reducing agent. The proposed equation showed reasonably good correlation with test data on autogenous shrinakge of high performance concrete with material for shrinkage reduction.

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인산나트륨계 염화암모늄 pH저감제의 반응성 검토 (Study on the Reactivity of Sodium Phosphate Ammonium Chloride pH Reduction Agents)

  • 신기돈;고산;이건철
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.105-106
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    • 2017
  • Previous studies have confirmed the performance of pH reduction agents using liquid sodium phosphate based ammonium chloride as a pH reduction agent. In this study, the pH reduction performance considering economical and applicability as a practical stage and the property change analysis for the identification of the reaction mechanism of the pH reduction agent were carried out. As a result, the pH reduction performance at a low rate of the pH reducing agent was confirmed. The specific gravity of CaO decreased significantly after XRF analysis. It is also believed that this reduces the amount of Ca(OH)2 produced and contributes to pH reduction.

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습식 화학적 환원법에 의한 AgNO3로부터 Ag 분말의 제조 1. 균일한 구형 Ag 분말의 제조를 위한 최적 반응계 확립 (Preparation of Ag Powder from AgNO3 by Wet Chemical Reduction Method1. The Establishment of Optimum Reaction System for the Preparation of Spherical Ag Powder)

  • 윤기석;박영철;양범석;민현홍;원창환
    • 한국분말재료학회지
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    • 제12권1호
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    • pp.56-63
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    • 2005
  • Ag powder was prepared from $AgNO_3$ by wet chemical reduction method using various reduction agent system involving $AgNO_3$, $AgNO_2$(AgCl) and Ag complex ion aqueous solution. The pure Ag powder could be prepared regardless of reaction system but the particle shape and distribution were affected very much according to the kind of reduction agents and reaction systems. The optimum reaction system for the preparation of the silver powder having the uniform particle shape and size distribution was Ag complex ion aqueous solution-reduction agent system and in particular, $H_2O_2$ and $C_6H_8O_6$as a reduction agent leaded the more uniform particle shape and size distribution.

습식환원법에서 NaBH4환원제를 이용한 Ag분말의 제조 (Preparation of Ag Powder by Wet Reduction Method using NaBH4 Reducing Agent)

  • 원창환;이혁희
    • 한국분말재료학회지
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    • 제13권4호
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    • pp.278-284
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    • 2006
  • Spherical Ag powder was prepared in the system of $AgNO_3\;and\;NaBH_4$ by wet chemical reduction method. The size of Ag powder was increased as the reaction temperature and the concentration of reducing agent was decreased in the constant concentration of dispersion agent. Optimum conditions of producing Ag powder having $1.39{\mu}m$ of D50 was 1M of $AgNO_3$, 0.5M of $NaBH_4$, 1.5g of Gelatine in the room temperature.

HFCs 감축에 따른 온실가스 감축량 산정방법론 연구 - 발포산업을 중심으로 - (A Study on the Methodology of Calculating Greenhouse Gas Emission Reduction by HFCs Reduction - Focusing on the Foam Industry -)

  • 최지원;김정만;안준관
    • 한국기후변화학회지
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    • 제9권4호
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    • pp.399-406
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    • 2018
  • The purpose of this study is to propose a methodology for estimating greenhouse gas emission reduction through HFCs used in the foam industry. This study investigated characteristics of HFCs and greenhouse gas emissions from production processes in the foam industry, which uses HFCs as a blowing agent. Also, we investigated fluorinated gas removal technology to determine a proper technology for the foam industry. And we confirmed the criteria and characteristics of External Project for methodology development. According to criteria of External Project and foam industrial process emission, a methodology for calculating the amount of greenhouse gas emission reduction in foam industry was developed. Lastly, we analyzed the amount of greenhouse gas emission reduction and KOC (Korea Of Offset) in the foam industry based on the domestic government's plan to reduce HCFCs and imported amount of HFCs used as a blowing agent. The results of this study demonstrate that linking greenhouse gas reduction in the foam industry and the domestic greenhouse gas reduction system can contribute to achieve the domestic greenhouse gas reduction goal.

인디고 염료의 전기화학적 특성 연구 (Studies on the Electrochemical Properties of Indigo Dye)

  • 이송주;장홍기;허북구;박동원
    • 한국염색가공학회지
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    • 제17권4호
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    • pp.1-6
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    • 2005
  • We studied the degree of variety of indigo for the electrochemical redox reaction in addition of reducing agent and the electrokinetic parameters. The electrokinetic parameters such asthe number of electron and the exchange rate constant were obtained by cyclic voltammetry. With increasing scan rate, the reduction currents of indigo were increased and the reduction potentials were shifted to the negative direction. As the results, the reduction processes of the indigo were proceeding to totally irreversible and diffusion controlled reaction. Also, exchange rate constant ($k^0$) and diffusion coefficient ($D_0$) of indigo were decreased by increasing concentration of reducing agent. We found that the less concentration, the more easily diffused and electron transferred and the product was more stable.

수축저감제 혼입량에 따른 건조수축 특성 검토 (Study on Properties of Dry Shrinkage according to Amount of Shrinkage Reduction Agent)

  • 서태석;이현승;김강민;윤섭
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2021년도 봄 학술논문 발표대회
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    • pp.209-210
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    • 2021
  • This study aims to develop ultra-low-shrinkage high-quality concrete. Therefore, the concrete drying shrinkage characteristics according to the type and amount of the shrinkage reducing agent were reviewed. As a result, the performance of Hexylene Glycol(HG) and Polyol was superior to that of PolyEthylene Glycol(PEG), which is most widely used in Korea. In addition, the shrinkage reduction effect was improved as the amount of PEG was increased, but the disadvantage of the strength reduction when excessive use was confirmed.

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고순도 수소 생성을 위한 SIP법에서 첨가제에 따른 환원 특성 (Characteristics of Redox Agent with Additive in Steam-Iron Process for the High Purity Hydrogen Production)

  • 전법주;김선명;박지훈
    • 한국수소및신에너지학회논문집
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    • 제22권3호
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    • pp.340-348
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    • 2011
  • Effects of various inorganic-metal oxide (Zr, Zn, Si, Al and Ca as promoters and stabilizers) additive on the reduction rate of iron oxide and the composition of forming hydrogen using the steam-iron cycle operation was investigated. The reduction rate of redox agent with additive was determined from weight change by TGA. The changes of weight loss and reduction rate according to redox agent with various additive affected the hydrogen purity and cycle stability of the process. The cyclic micro reactor showed that hydrogen purity exceeding 95% could be obtained by the water splitting with Si/Fe, Zn/Fe, Zr/Fe redox agents. The redox agents with these elements had an affect on redox cycle stability as a good stabilizer for forming hydrogen by the steam-iron process.

서울지역 대형연소시설에서의 질소산화물 제거효율과 배출계수 산정 (Evaluation of NOx Reduction Efficiency and Emission Factor from Large Combustion Facilities in Seoul)

  • 신진호;오석률;김정영;전재식;신정식
    • 환경위생공학
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    • 제18권2호
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    • pp.27-33
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    • 2003
  • This survey was performed to investigate the NOx emission factors at 3 Municipal Solid Waste Incinerators(MSWI) and 5 Power generation boilers in Seoul. The NOx concentrations were measured before and after control systems. The results were as follows. 1) The NOx reduction efficiencies of Selective Catalytic Reduction (SCR) using ammonia as reducing agent ranged from 53.7% to 89.9%. The NOx reduction efficiencies of SCR using methanol as reducing agent, Non- Selective Catalytic Reduction (NSCR) using ethanol as reducing agent and low-NOx burner were 20.8%, 29.1% and 24.7%, respectively. 2) The NOx emission factors at A-1, A-2 and A-3 facilities of MSWI were 0.786, 0.127 and 0.594 kg Nox/ton fuel, respectively. The factors of A-1 and A-3 facilities were higher than the average value of Korea. 3) The NOx emission factors at B-1, B-2, B-3, B-4 and B-5 facilities of Power generation boiler were 2.109, 0.726, 4.106, 8.378 and 5.168 kg Nox/ton fuel, respectively. The factors of B-4 and B-5 facilities were higher than the average value of Korea.

염화동 수용액으로부터 Cu 미립자의 합성 (Synthesis of Uniform Cu Particles from Copper Chloride Solution)

  • 윤지희;권현우;유연태;김병규;김광수
    • 한국재료학회지
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    • 제15권4호
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    • pp.263-270
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    • 2005
  • In order to prepare the uniform copper particles from copper chloride solution, the reduction behavior of copper particles from copper chloride and the effects of reduction agent and dispersing agent was investigated. In the case that 2.56 M of $C_6H_8O_6$ was used as a reduction agent, the highly dispersed Cu particles with sharp size distribution were generated from 0.96M of copper chloride solution, and the size of Cu particles was $6\~10\;{\mu}m$. To form $Cu(NH_3)_4Cl_2$ complex solution, $NH_4OH$ was added in the copper chloride solution before the reductive reaction of Cu ion. The generated Cu particles have a two kind of shape, spherical and rod-like. In the case that $N_2H_4{\cdot}H_2O$ was used as a reduction agent, the very fine spherical Cu particles with the size of $0.2\~0.5\;{\mu}m$ was obtained. Arabic gum as a dispersing agent was more effective than $Na_4P_2O_7{\cdot}10H_2O$.