• Title/Summary/Keyword: Reducing $CO_2$

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Development of a Durable Startup Procedure for PEMFCs (고분자전해질 연료전지 내구성 향상을 위한 시동 기술 개발에 관한 연구)

  • Kim, Jae-Hong;Jo, Yoo-Yeon;Jang, Jong-Hyun;Kim, Hyung-Juhn;Lim, Tae-Hoon;Oh, In-Hwan;Cho, Eun-Ae
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.288-294
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    • 2009
  • Various polymer electrolyte membrane fuel cell (PEMFC) startup procedures were tested to explore possible techniques for reducing performance decay and improving durability during repeated startup-shutdown cycles. The effects of applying a dummy load, which prevents cell reversal by consuming the air at the cathode, on the degradation of a membrane electrode assembly (MEA) were investigated via single cell experiments. The electrochemical results showed that application of a dummy load during the startup procedure significantly reduced the performance decay, the decrease in the electrochemically active surface area (EAS), and the increase in the charge transfer resistance ($R_{ct}$), which resulted in a dramatic improvement in durability. After 1200 startup-shutdown cycles, post-mortem analyses were carried out to investigate the degradation mechanisms via various physicochemical methods including FESEM, an on-line $CO_2$ analysis, EPMA, XRD, FETEM, SAED, FTIR. After 1200 startup-shutdown cycles, severe Pt particle sintering/agglomeration/dissolution and carbon corrosion were observed at the cathode catalyst layer when starting up a PEMFC without a dummy load, which significantly contributed to a loss of Pt surface area, and thus to cell performance degradation. However, applying a dummy load during the startup procedure remarkably mitigated such severe degradations, and should be used to increase the durability of MEAs in PEMFCs. Our results suggest that starting up PEMFCs while applying a dummy load is an effective method for mitigating performance degradation caused by reverse current under a repetition of unprotected startup cycles.

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Usefullness of Mask Pack Sheets Including Marine Materials: Skin Regeneration Effect (해양소재를 이용한 마스크팩의 유용성 : 피부재생효과)

  • Park, Dae-Hwan;Park, Sang-Uk;Choi, Sung-Gon
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.45 no.2
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    • pp.167-172
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    • 2012
  • Minerals from marine materials such as deep ocean water and Dead Sea water have been used since ancient times. We made a mask pack sheet including deep ocean water and salt from the Dead Sea and evaluated the function of the mask pack sheet through animal study. Three full-thickness skin defects were made on the backs of Sprague-Dawley rats. The wounds were left untreated in group Con, and mask pack sheets including deep ocean water or deep ocean water and Dead Sea water were used as treatment for 20 min on the skin of animals in groups DP and DDP, respectively. We analyzed the gross, histological and biochemical findings. Groups DDP and DP showed decreases in wound size, as compared to group Con at 7 days after wound infliction. The histological findings revealed that wound healing had progressed further in groups DP and DDP than in group Con, with more rapid collagen deposition and regression of neutrophils. Also, the expression of vascular endothelial growth factor and transforming growth factor ${\beta}1$ were increased in groups DDP and DP compared with those in group Con at 3 days after wound infliction. Mask sheet packs including deep ocean water and Dead Sea salt affected wound healing by reducing the inflammatory phase and stimulated wound contracture by facilitating the deposition of collagen.

Assessments of the Nutrient Losses in the Sloped Farm Land (경사지 밭토양에서의 양분유실량 평가)

  • Jung, Pil-Kyun;Eom, Ki-Cheol;Ha, Sang-Keon;Zhang, Yong-Seon;Hur, Seung-Oh
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.spc
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    • pp.47-50
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    • 2009
  • Nutrient losses, especially nitrogen and phosphorus, in agricultural runoff can contaminate surface and ground water, leading to eutrophication. Thus, erosion control is crucial to minimizing nutrient losses from agricultural land. Assessments of various erosion control practices were carried out under various cropping system, soil management practices, and slope conditions by means of a lysimeter study and under artificial rainfall. Soil and nutrient losses were monitored in a small agricultural field to evaluate the soil conservation practices. Nutrient losses occur in runoff and leachate (dissolved nutrient) and in sediments (particulate nutrient). Dissolved nitrates accounted for the majority (about 90%) of nitrate transport within the soil. Particulate phosphate in sediments represented the majority (60% to 67%) of phosphate transport. Recently, engineering and agronomic erosion-control practices haver been used to reduce erosion problems in fields on slopes. These practices reduced soil loss, runoff, and nutrient loss to 1/6, 1/2,and 1/3 their original levels, respectively. Bioavailable particulate phosphate in sediments represents a variable but longterm source of phosphate for algae. Dissolved nitrate and phosphate are immediately available for algal uptake, so reducing fluxes of these nutrients should also reduce the risk of eutrophication.

Design of a 100kW-class radial inflow turbine for ocean thermal energy conversion using R32 (R32를 이용한 100kW급 해양온도차발전용 반경류터빈의 설계)

  • Kim, Do-Yeop;Kim, You Taek
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.9
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    • pp.1101-1105
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    • 2014
  • Ocean Thermal Energy Conversion(OTEC) which uses the temperature difference between warm surface sea-water and cold deep sea-water to produce electric power is the promising technology. OTEC is able to be utilized as the $CO_2$ reducing technology by using the consistent temperature differential, while the system efficiency is very low. Thus, the design and development of a efficient turbine is essential to improve the system efficiency for OTEC. In this study, a 100kW-class radial inflow turbine using R32 was designed for OTEC and this turbine's performance was estimated by analysis of CFD. According as the simulation results, turbine's geometry was corrected. The radial inflow turbine satisfying the requirements is designed by the repeated attempts.

The Prospect of Methanol and Its Meaning (메탄올의 전망(展望)과 그 의미(意味))

  • Uhm, Sung-Jin
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.1-6
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    • 1992
  • In this energy and environment conscious age, methanol has come to attention increasingly since the well established process is commercially available to produce methanol from abundant low grade carbonaceous resources ; methane, carbon dioxide, coal and biomass etc. Methanol is a Clean energy source which is a readily storable and transportable liquid. It is elaborated to correlate power generation, city gas and chemical feed stocks including transportation fuel, enhancing the national efficiency of resource utilization as well as reducing the environmental problems for the future via C1 technology. It is emphasized that $CO_2$ could be used to produce methanol as a mean of hydrogen storage as in the nature, which will alleviate the environmental problem such as green house effect.

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LDBAS: Location-aware Data Block Allocation Strategy for HDFS-based Applications in the Cloud

  • Xu, Hua;Liu, Weiqing;Shu, Guansheng;Li, Jing
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • v.12 no.1
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    • pp.204-226
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    • 2018
  • Big data processing applications have been migrated into cloud gradually, due to the advantages of cloud computing. Hadoop Distributed File System (HDFS) is one of the fundamental support systems for big data processing on MapReduce-like frameworks, such as Hadoop and Spark. Since HDFS is not aware of the co-location of virtual machines in the cloud, the default scheme of block allocation in HDFS does not fit well in the cloud environments behaving in two aspects: data reliability loss and performance degradation. In this paper, we present a novel location-aware data block allocation strategy (LDBAS). LDBAS jointly optimizes data reliability and performance for upper-layer applications by allocating data blocks according to the locations and different processing capacities of virtual nodes in the cloud. We apply LDBAS to two stages of data allocation of HDFS in the cloud (the initial data allocation and data recovery), and design the corresponding algorithms. Finally, we implement LDBAS into an actual Hadoop cluster and evaluate the performance with the benchmark suite BigDataBench. The experimental results show that LDBAS can guarantee the designed data reliability while reducing the job execution time of the I/O-intensive applications in Hadoop by 8.9% on average and up to 11.2% compared with the original Hadoop in the cloud.

Proteome Profiling Unfurl Differential Expressed Proteins from Various Explants in Platycodon Grandiflorum

  • Kim, Hye-Rim;Kwon, Soo-Jeong;Roy, Swapan Kumar;Cho, Seong-Woo;Kim, Hag-Hyun;Cho, Kab-Yeon;Boo, Hee-Ock;Woo, Sun-Hee
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.60 no.1
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    • pp.97-106
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    • 2015
  • Platycodon grandiflorum, commonly known as Doraji in Korea, has a wide range of pharmacologic properties, such as reducing adiposity and hyperlipidemia, and antiatherosclerotic effects. However, the mechanisms underlying these effects remain unclear. In order to profile proteins from the nodal segment, callus, root and shoot, high throughput proteome approach was executed in the present study. Two dimensional gels stained with CBB, a total of 84 differential expressed proteins were confirmed out of 839 protein spots using image analysis by Progenesis SameSpot software. Out of total differential expressed spots, 58 differential expressed protein spots (${\geq}$ 2-fold) were analyzed using MASCOT search engine according to the similarity of sequences with previously characterized proteins along with the UniProt database. Out of 58 differential expressed protein, 32 protein spots were up-regulated such as ribulose-1,5-bisphosphate carboxylase, endoplasmic oxidoreductin-1, heat stress transcription factor A3, RNA pseudourine synthase 4, cysteine proteinase, GntR family transcriptional regulator, E3 xyloglucan 6-xylosyltransferase, while 26 differential protein spots were down-regulated such as L-ascorbate oxidase precursor, late embryogenesis abundant protein D-34, putative SCO1 protein, oxygen-evolving enhancer protein 3. However, frequency distribution of identified proteins using iProClass databases, and assignment by function based on gene ontology revealed that the identified proteins from the explants were mainly associated with the nucleic acid binding (17%), transferase activity (14%) and ion binding (12%). In that way, the exclusive protein profile may provide insight clues for better understanding the characteristics of proteins and metabolic activity in various explants of the economically important medicinal plant Platycodon grandiflorum.

Characteristics of Seepage Water and Groundwater in Incheon Coastal LPG Storage Cavern (인천 해안 저장공동 유출수 및 주변 지하수의 수질특성)

  • Jo, Yun-Ju;Lee, Jin-Yong;Choi, Mi-Jung;Cho, Byung-Wook
    • The Journal of Engineering Geology
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    • v.20 no.1
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    • pp.1-12
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    • 2010
  • The objective of this study was to examine the hydrogeochemical and microbiological characteristics for stable maintenance of coastal LPG storage cavern. Cavern seepage water and groundwater in the vicinity of the LPG storage cavern were sampled and analyzed (February, May, August and October 2007). Groundwater samples of propane cavern showed high pHs of 8.1~12.4 due to dissolution of cement grouting materials that had been applied during the well and cavern construction. The EC values showed distinctive seasonal variation. The negative ORP indicated reduced condition. The seepage and surrounding groundwater are classified as Na-Cl type, which represents seawater effects. All of aerobic bacteria, anaerobic bacteria, slime forming bacteria and sulfate reducing bacteria were less than 500 CFU/mL, which indicated that there was no abrupt increase of bacteria in the cavern. Therefore there exist no hydrochemical symptoms to indicate unstable conditions of the cavern operation. However, regular and continuous monitoring is essentially required.

Numerical Analysis of Effect of Inhomogeneous Pre-mixture on Pressure Rise Rate in HCCI Engine by Using Multizone Chemical Kinetics (화학반응수치해석을 이용한 HCCI기관의 예혼합기의 성층화성이 연소시의 압력 상승률에 미치는 영향)

  • Lim, Ock-Taeck
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.34 no.5
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    • pp.449-456
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    • 2010
  • The HCCI engine is a prospective internal combustion engine with which high diesel-like efficiencies and very low NOx and particulate emissions can be achieved. However, several technical issues must be resolved before HCCI engines can be used for different applications. One of the issues concerning the HCCI engine is that the operating range of this engine is limited by the rapid pressure rise caused by the release of excessive heat. This heat release is because of the self-accelerated combustion reaction occurring in the engine and the resulting engine knock in the high-load region. The purpose of this study is to evaluate the role of thermal stratification and fuel stratification in reducing the pressure rise rate in an HCCI engine. The concentrations of NOx and CO in the exhaust gas are also evaluated to confirm combustion completeness and NOx emission. The computation is carried out with the help of a multizone code, by using the information on the detailed chemical kinetics and the effect of thermal and fuel stratification on the onset of ignition and rate of combustion. The engine is fueled with dimethyl ether (DME), which allows heat release to occur in two stages, as opposed to methane, which allows for heat release in a single stage.

Development of Liquid Fertilizer Spreading System for a Sloped Land (경사지용 가축분뇨 액비 살포장치 개발)

  • Oh, I.H.;Jang, C.H.;Kim, W.K.;Song, J.H.
    • Journal of Animal Environmental Science
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    • v.16 no.2
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    • pp.115-122
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    • 2010
  • A major problem within the agricultural/farming community concerns the enormous amount of manure produced by livestock; one possible solution to this problem is to use the animal slurry as a liquid fertilizer. While there are several areas where this fertilizer could be used, one promising area of application is within chestnut tree fields. However, since most of these fields are located on slopes of varying grades and not on flat land, a different spread system is required. Generally, chemical fertilizer is spread in the chestnut field manually by hand; not only does this require a great deal of manpower it is also very difficult and hard work. In our lab experiment, we investigated the relationship between the amount of fertilizer spread and the length of pipe used at varying pressure levels. The hose in our system utilized PVC piping with evenly spaced holes for the fertilizer to dissipate. We initially found that the amount of spread was greatly reduced by reducing pipe pressure. While the difference of the amount of spread during fertilizing was not great, we did find that the reduction of the spread could be correlated to the frictional resistance of the inner lining of the pipe. Based on this, we hypothesized that an increase in pipe pressure would yield a consistent spread. Additionally, a similar outcome could be obtained by regulating the distance of the holes in the pipe and their diameter.