• Resources Recycling
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• v.29 no.6
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• pp.3-14
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• 2020

This study aims to introduce and review on the recovery technologies of rare earth elements(REEs) from coal ash. Many researchers have been carried out by various beneficiation processes, such as particle size separation, magnetic separation, specific gravity, and flotation to recover rare earth elements from coal ash generated from Pulverized Coal(PC) boiler. Through the beneficiation process, it was confirmed that concentration of rare earth elements was much lower than the 4,700 ppm, and that additional enrichment treatment through wet process was needed for the products recovered after the beneficiation process. It was confirmed that the rare earth elements contained in coal ash were applied to the leaching process after pretreatment such as alkali-fusion to improve leaching efficiency. Although beneficiation and leaching methods have been studied, its optimum recovery technologies for rare earth elements not been confirmed up to now, research on the recovery of rare earth contained in coal ash is reported to continue. In case of Korea, the technology for the recovery of rare earth elements from coal ash and coal by-product could not been confirmed up to present. In these reasons, it is urgent to develop technologies such as beneficiation and leaching process continuously.

• Clean Technology
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• v.26 no.2
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• pp.116-121
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• 2020

In this paper, the recycling of waste Ni-MH battery by-products for electric vehicle is studied. Although rare earths elements still exist in waste Ni-MH battery by-products, they are not valuable as materials in the form of by-products (such as an insoluble substance). This study investigates the recovering of rare earth oxide for solvent extraction A/O ratio, substitution reaction, and reaction temperature, and scrubbing of the rare earth elements for high purity separation. The by-product (in the form of rare earth elements insoluble powder) is converted into hydroxide form using 30% sodium hydroxide solution. The remaining impurities are purified using the difference in solubility of oxalic acid. Subsequently, Yttrium is isolated by means of D2EHPA (Di-[2-ethylhexyl] phosphoric acid). After cerium is separated using potassium permanganate, lanthanum and neodymium are separated using PC88A (2-ethylhexylphosphonic acid mono-2-ethylhexyl ester) and it is calcinated at a temperature of 800 ℃. As a result of the physical and chemical measurement of the calcined lanthanum and neodymium powder, it is confirmed that the powder is a microsized porous powder in an oxide form of 99.9% or more. Rare earth oxides are recovered from Ni-MH battery by-products through two solvent extraction processes and one oxidation process. This study has regenerated lanthanum and neodymium oxide as a useful material.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.10
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• pp.86-92
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• 2016

A high-capacity battery installed in a hybrid vehicle or electric vehicle is used to power, or as a power supply for, electric sub-assemblies. In order to use a high-capacity battery as a power supply for electric sub-assemblies, such as an electronic control unit or for lighting, radio, and navigation, there is a need for a DC converter that changes a high voltage of 240-400V to a low voltage of 12-14V, which is done with a low-voltage DC-DC converter (LDC). An LDC undergoes long-term aging so as to reduce latent defects in the production process. With regard to the usual aging method, an LDC is a DC-DC converter. So, a DC power supply is connected and used as input, and a programmable DC electronic load is the output. For stable operation, a product having a larger capacity by 10% (compared to an LDC) is used, and has a structure where electric power is dissipated into 100% heat. So, there is a problem with volume, based on the use of two pieces of equipment to test the LDC, and another problem based on the generation of heat in the programmable DC electronic load. Hence, this paper suggests a load test method as a way of recycling, where a significant portion of the electricity dissipated as heat in a load tester is returned as input. The method realizes savings of 80% or more in the electricity dissipated as heat through improvement in the efficiency of the recycling load tester.

• Resources Recycling
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• v.26 no.2
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• pp.11-17
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• 2017

Many problems are occurred by using industrial by-product and municipal solid waste in the cement manufacturing process. The main components of chlorine by-pass dust generated by the use of the wastes are $K^+$, $Cl^-$, and a slight amount of heavy metals is also contained. In terms of waste recycling, it is necessary to eliminate the heavy metals. Therefore, in this study, the experiments for the removal of heavy metals from KCl which was produced by chlorine by-pass dust were conducted. In order to find optimum conditions for the removal of heavy metals, we have controlled the amount of water and precipitator. The type and concentration of heavy metals in KCl were analyzed. The concentration of heavy metals decreased as amount of precipitator increased. The heavy metals such as Pb, Cd, and As were not detected in dust A and B, when the mixing ratios between dust A(B) and water were controlled to be 1:2 (1:2, 1:3.5) with the addition of 3% precipitator (NaOCl).

• Resources Recycling
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• v.16 no.6
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• pp.28-33
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• 2007

Coal is the most abundant energy source and deposited in every area of world. Combustion process with lower efficiency has been mainly used. Therefore, implementation of more efficient technologies, involving gasification, combined cycles and fuel cells, would be a key issue in the plans for more efficient power generation. In these technologies, gasification has been studied for decades. However, coal gasification to high value combustible gas such as hydrogen and carbon monoxide is focused again due to high oil price. The gaseous product, called syngas, can be effectively utilized in a variety of ways ranging from electricity production to chemical industry (as feedstock). In this study, coal gasification with ultra high temperature steam has been performed. The effect of steam/carbon ratio on the produced gas concentrations, gasification rate and additional products like tar, ammonia and cyan compounds has been determined.

• Resources Recycling
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• v.15 no.6 s.74
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• pp.48-55
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• 2006

This study was carried out for establishing the physical recycling technique for commercializing process on household batteries. The procedure involves shape separator, crushing, magnetic separation, classification and eddy current separation in sequence. The separation capacity was 400-600 unit cell/hr with shape separation system. The impurities such as manganese and zinc in the magnetic product were below 0.1% respectively, the concentration of iron was above 99% in spent carbon zinc battery. Also non-magnetic products are composed of 22-30% En, 16-22% Mn, 1-3% Fe in the case oi spent zinc carbon battery. The amounts of other components such as carbon rod, plastics and separator were about 37-50%. From the eddy current separation of nonferrous products, the plate-type zinc components were separated up to 96% with 2,250-2,750 meter/min of the conveyor speed.

• Resources Recycling
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• v.11 no.1
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• pp.9-18
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• 2002

Printed wiring boards(PWBs) of the obsolete computers are composed of various organic and inorganic compounds as well as metals and alloys. As convinced that the valuable metals obtained from the PWBs are effectively utilized as secondary resources when recovered by economical methods, in this study, an investigation for characterizing the physical separation techniques is conducted. For the recovery of them, the sockets and chips dismantled from PWBs by scraping and residual resin boards are subjected to the appropriate separation processes according to the physical properties of each part. In the case of crushed socket scraps size ranged from -2.36 mm to +1.18 mm, approximately 97 wt% of the product obtained by magnetic separation consists of metallic compounds. In the case of chip scraps, 97% of Fe-Ni alloy and 95% of Cu metal are recovered by the combined process of air classification and dry magnetic separation in the size range from -2.36 mm to +0.15 mm. Ball milling is adopted in order to improve the removal efficiency of the thin-printed metallic materials on the residual resin boards and approximately 77% of Cu metal is recovered by zigzag separation after ball milling.

• Resources Recycling
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• v.25 no.1
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• pp.40-47
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• 2016

Nickel laterite ore is classified into two principal ore types: saprolite (silicate ore) and limonite (oxide ore). Saprolite-type ore characterized by high magnesia and silica contents is treated by pyrometallurgy process. On the other hand, limonite-type ore is subjected to hydrometallurgy process to produce nickel products. Hydrometallurgy process requires that a raw material to meet the demands that Si+Mg contents lower than 10% and Fe content over than 40%. It is therefore required that separation of saprilite-type ore to use nickel laterite ore as a raw material for hydrometallurgy process. In this study, separation of sparolite-type ore and limonite-type ore from nickel laterite ore from New Caledonia has been tried by dry classification. The results show that -5 mm size fraction and +5 mm size fraction of the nickel laterite ore contains mainly limonite-type ore and saprolite-type ore, respectively. To understand the moisture content of the raw ore on the dry classification, nickel laterite ore with different moisture contents of 23.0% and 9.1% were subjected to the dry classification. The results show that drying of the ore makes the separation more efficient as the amount of the fine product, that can be subjected to hydrometallurgy process without further separation or drying operations, was increased.

• Resources Recycling
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• v.24 no.2
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• pp.62-68
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• 2015

The high pure tin production was conducted from crude-tin containing waste solder by electro-refining process. The electro-refining process maintained at 0.2V produced tin with purity of 99.98%, whereas a little increase of voltage to 0.3 V resulted tin purity of 99.92%. The high pure tin of 3N in the present process was produced by fixing the voltage at 0.3V. Considering the high pure tin production, the current density was maintained within $100-120A/m^2$ with current efficiency of 94%. Addition of sulfuric acid of 20 ~ 25 g/L to the electrolyte solution was performed in order to keep Pb (lead) concentration below 100 mg/L in the final tin product. The anode slime generated during electro refining process was analyzed by X-ray diffraction (XRD) study to understand the phases of impurities in it. It detected the presence of Cu and Ag in the slime as in the form of $Cu_6Sn_5$, $Ag_3Sn$, whereas Pb occurred as $PbSO_4$ compound.

• Journal of the Korea Organic Resources Recycling Association
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• v.28 no.4
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• pp.15-22
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• 2020

The landfill gas produced in landfill is generally made up of methane(CH4) and carbon dioxide(CO2) of more than 90%, with the remainder made up of hydrogen sulfide(H2S). However, separate pre-treatment facilities are essential as hydrogen sulfide contained in landfill gas is combined with oxygen during the combustion process to generate sulfur oxides and acid rain combined with moisture in the atmosphere. Various desulfurization technologies have been used in Korea to desulfurize landfill gas. Although general desulfurization processes apply various physical and chemical methods, such as treatment of sediment generation according to the CaCO3 generation reaction and treatment through adsorbent, there is a problem of secondary wastes such as wastewater. As a way to solve this problem, a biological treatment process is used to generate and treat it with sludge-type sulfide (S°) using a biological treatment process.In this study, as a basic study of technology for utilizing the biological treatment by-products of hydrogen sulfide in landfill gas, an experiment was conducted to use the by-product as a mixture of concrete. According to the analysis of the mixture concrete strength of sulfur products, the mixture of sulfur by-products affects the strength of concrete and shows the highest strength value when mixing 10%.