• Title/Summary/Keyword: Recycling agents

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A Study on the Performance Comparison of the Agents for Asphalt Pavement Recycling (재생 아스팔트 첨가제의 성능비교 연구)

  • Kim, In-Soo;Kang, Min-Soo;Suh, Young-Chan;Lee, Bong-Won
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.82-88
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    • 2012
  • The usage of recycling agent is the most effective way of enhancing the performance of recycled asphalt pavement. Generally, many countries accepted these recycling agents retarding the various types of cracks resulted in binder aging. Contrary to such general tendency, recycling agents are used as very small amount in domestic recycling plant. The main reason of this is relatively high price of recycling agent. Even though agent price is high, agent can be a effective and economical way of alternative in asphalt recycling. In this study, penetration and softning point test performed by using RTFO(Rolling Thin Film Oven) aged binder. And, PG(Performance Grade) at high temperature, fatigue and MSCR(Multi Stress Creep and Recovery) tests exercised. The oil type agent is worked well to retrieving target penetration number. In PG test, $G^*/sin{\delta}$ of agents identically showed high value and polymer type agent is good at recovery value.

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Study on the reuse and recycling of the used foundry sands (폐주물사의 재활용 활성화 방안에 관한 연구)

  • Kim, Young-Jun;Chung, Myung-Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.18 no.4
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    • pp.38-44
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    • 2010
  • Foundry sands are made up of silica and some coking agents, such as bentonite or resin, and used as templates for the production of various casting products. Foundry sands, which are repeatedly used, were finally transformed into the waste materials by heat, losing their proper functions. The used foundry sands have been treated as general wastes according to the contents of coking agents used. Silica, however, can be recycled through the proper treatment due to its physical property not to changed by heat. In this study, we have identified and investigated at the occurrence, treatment and recycling status of the used foundry sands, as well as for the regime and inhibitory factors of the recycling of them in domestic and foreign cases.

The Recycling of End-of-Life Vehicles(ELVs) in Taiwan

  • Tsai, Min-Shing;Chen, Wei-Sheng;Wu, Chung-Liu
    • Resources Recycling
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    • v.14 no.3
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    • pp.6-15
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    • 2005
  • The overall area of Taiwan is 36,006 km$^2$ and population was about 22,535,000 persons in 2003. The population density became 625persons/km$^2$. The economic of Taiwan progress since 1970. Gross national production in 2004 increased by 2.3 trillion or 493% relative to 1981. The number of automobiles in 1981 was 821,862, and increase to 6,389,186 in 2004. The number of motorcycles in 1981 were 4,591,547 and increase to 12,793,950 in 2004. The vehicle growth rate of automobile and motorcycle was 677% and 178% respectively. The recycling end-of-life vehicles(ELVs) is specified in the Waste Disposal Act. Its main content is the system of asking the vehicle manufacturer and importing agents, who are responsible for recycling of the ELVs. The recycling task on ELVs was startedinitially in 1993. It is required that the manufacturers and importing agents deposit certain ratios of Waste Vehicle Disposal Fees proportional to the number of vehicle they manufacture and import into Taiwan under sales. This report will introduce the current status of ELVs recycling in Taiwan, and the future direction, as well as measures proceeding for the EPA- Fund Management Committee(RMFC) operating in the fiture.

The Direct Recycling of Electric Arc Furnace Stainless Steelmaking Dust

  • Zhang, Chuanfu;Peng, Bing;Peng, Ji;Lobel, Jonathan;Kozinski, Janusz A.
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.404-408
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    • 2001
  • This paper focuses on the pilot-scale investigation of direct recycling of electric arc furnace (EAF) stainless steelmaking dust. The direct recycling of EAF dust is to make pellets with the mixture of the dust and the reducing agent carbon, then introduce the pellets to the EAF. The valuable metals in the dust are reduced and get into the steel as the alloying elements. Experiments simulating direct recycling in an EAF were performed using an induction furnace. But it seems difficult to reduce all metal oxides in the dust so that some metal reducing agents added in the late stage of reduction process. The valuable metals in the dust were reduced partly by carbon and partly by metal reducing agent for the economical concern. The recovery of iron, chromium and nickel from the flue dust and the amount of metal oxides in the slag were measured. The results showed that the direct recycling of EAF stainless steelmaking dust is practicable. It wes also found that direct recycling of flue EAF stainless steelmaking dusts does not affect the chemistry and quality of stainless steel produced in the EAF. It is benefit not only for the environmental protection but also for the recovery of valuable metal resources in this way.

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Preparation and Characterization of the Hydrolyzed Protein from Shaving Scraps of Leather Waste Containing Chromium by the Combination Treatment with Alkaline Inducing Agent and Alkaline Proteolytic Enzyme (Alkaline Inducing Agent 및 Alkaline Proteolytic Enzyme 혼용처리에 의한 Shaving Scraps 가수분해 단백질의 제조 및 특성)

  • Kim, Won-Ju;Cho, Ju-Sik;Lee, Hong-Jae;Heo, Jong-Soo
    • Journal of the Korea Organic Resources Recycling Association
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    • v.6 no.1
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    • pp.1-12
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    • 1998
  • To examine the possibility of protein recycling of shaving scraps containing chromium generated from manufacturing process of leather, the optimum hydrolysis conditions and the withdrawal methods of low molecular weight protein for using the liquid fertilizer sources by investigation of solubilities of hydrolyzed protein, inorganic nutrients contents and molecular weight distributions of hydrolyzed protein from shaving scraps treated with mixed alkaline inducing agents and mixed alkaline proteolytic enzymes including MgO were investigated. In hydrolysis of shaving scraps treated with mixed alkaline inducing agents, the solubility of shaving scraps were clearly different with 65~85% according to the sorts of the inducing agents, and the degree of hydrolysis was high in the order of NaOH, $Ca(OH)_2$ and KOH. The average molecular weights of withdrawal hydrolyzed protein were 10, 40 and 80 KD treated with NaOH, $Ca(OH)_2$ and KOH, respectively. And the chromium contents was about 15 ppm. In hydrolysis of shaving scraps treated with mixed alkaline proteolytic enzymes, the bility of shaving scraps were high in the order of alcalase, esperase and savinase. In c of treating 0.5% alcalase, the low molecular weight of hydrolyzed protein could be withdrawn. The solubility of the hydrolyzed protein was about 85%, the average molecular weight of the protein was below 1 KD and chrome content of the protein was below 10 ppm.

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Analysis of the Behavior of Fluorescent Whitening Agents in Recycling Process of White Ledger (형광증백제가 함유된 백상고지의 재활용에 따른 형광증백제의 거동 분석)

  • Lee, Ji Young;Kim, Chul Hwan;Park, Jong-Hye;Kim, Eun-Hea;Sung, Yong Joo;Heo, Young-Jun;Kim, Young-Hoon;Kim, Yeon-Oh
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.47 no.1
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    • pp.52-58
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    • 2015
  • White ledger usually includes white office paper, computer paper, and copy machine paper. Because these grades need high optical properties, fluorescent whitening agents (FWAs) are widely used in the papermaking process. FWAs are the most powerful and effective chemical used to obtain high CIE whiteness and ISO brightness in papers. The rising demand for white or ultra-white papers has increased the use of FWAs. However, FWAs used in white ledger can restrict its use, even though white ledger is widely used as a raw material in paperboard mills. Therefore, it is necessary to develop methods to control FWAs from white ledger to increase its use in paperboard mills. In this study, the behaviors of disulpho fluorescent whitening agent (D-FWA), tetrasulpo fluorescent whitening agent (T-FWA), and hexasulpho fluorescent whitening agent (H-FWA) during the recycling process were identified as a first step to remove FWAs from white ledger. We prepared four types of papers (dyed with D-FWA, T-FWA, and H-FWA), disintegrated these papers, and made handsheets. This recycling process was carried out three times in a laboratory. After each round of recycling, the hand-sheets' CIE whiteness and fluorescence index were measured, and the distribution of FWAs in the Z-direction was observed using CLSM images. FWA reductions in the model papers were calculated using fluorescence indices as a function of the number of recycling. FWAs in handsheets containing T-FWA and H-FWA decreased linearly as a function of the number of recycling, but D-FWA did not show a significant reduction in the fluorescence index after recycling. T-FWA and H-FWA showed similar distributions of D-FWA after recycling. Therefore, as much T-FWA and H-FWA as possible must be detached in the early processes of papermaking at paperboard mills.

A Study on the Leaching Effect and Selective Recovery of Lithium Element by Persulfate-based Oxidizing Agents from Waste LiFePO4 Cathode (과황산계 산화제에 따른 폐LiFePO4 양극재에서 리튬의 침출 효과와 선택적 회수에 대한 연구)

  • Kim, Hee-Seon;Kim, Dae-Weon;Jang, Dae-Hwan;Kim, Boram;Jin, Yun-Ho;Chae, Byung-Man;Lee, Sang-Woo
    • Resources Recycling
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    • v.31 no.4
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    • pp.40-48
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    • 2022
  • In waste lithium iron phosphate (LFP) batteries, the cathode material contains approximately 4% lithium. Recycling the constituent elements of batteries is important for resource circulation and for mitigating the environmental pollution. Li contained in the waste LFP cathode powder was selectively leached using persulfate-based oxidizing agents, such as sodium persulfate, potassium persulfate, and ammonium persulfate. Leaching efficiency and waste LFP powder properties were compared and analyzed. Pulp density was used as a variable during leaching, which was performed for 3 h under each condition. The leaching efficiency was calculated using the inductively coupled plasma (ICP) analysis of the leachate. All types of persulfate-based oxidizing agents used in this study showed a Li leaching efficiency over 92%. In particular, when leaching was performed using (NH4)2S2O8, the highest Li leaching percentage of 93.3% was observed, under the conditions of 50 g/L pulp density and an oxidizing agent concentration of 1.1 molar ratio.

Direct Observation on Pyrolysis of Some Plastics

  • Takasu, Tomio;Itou, Hideyuki;Shibata, Etsuro;Kasai, Eiki;Nakamura, Takashi
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.742-745
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    • 2001
  • Plastics are one of difficult materials for recycling due to their characteristics in use. Recycling ratio of waste plastics was around 40% in last year in Japan, which includes energy recovery. Feed stock recycling and mechanical recycling are not easy because of additives in commercial plastics. Then, pyrolysis treatments have been done to recovery energy. Although plastics are easy to fire, complete combustion of them is not easy if anti-firing agents are added especially. Therefore, researches on pyrolysis or combustion behaviors of plastics containing additives are important from a view point recycling of plastics. Direct observation of popular plastics like polystyrene (PS), polycarbonate (PC), polyphenyle ether (PPE) and polyvinyl chloride (PVC) to investigate their pyrolysis behaviors in the present study. In case of PS, melting and gas evolution started at 9$0^{\circ}C$ and 39$0^{\circ}C$ respectively. And combustion finished at 445$^{\circ}C$. On the other hand, more than $600^{\circ}C$ and sufficient oxygen are required for complete combustion of PC and PPE.

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Industrial Applications of Optium De-inking Agent by Waste-paper Recycling Simulation Technology (고지재생 시뮬레이션 기술에 의한 최적 탈묵제의 공업적 이용)

  • Nam, Ki-Dae
    • Applied Chemistry for Engineering
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    • v.5 no.6
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    • pp.917-924
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    • 1994
  • In this paper, we briefly introduce applications of optimum de-inking agent by waste-paper recycling stimulation technology. From the aspects of environmental protection and efficient use of natural sources requirement of recycle paper and higher quality pulp will be increasing. By developement of high-performance de-inking agents and its system, we would like to contribute for advance of waste paper treatment technology and higher quality pulp recycling.

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