• Computers and Concrete
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• v.26 no.1
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• pp.11-20
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• 2020

Concrete are the most widely used manmade materials for infrastructure construction across the world. These constructions gradually aged and damaged due to long-term use. However, there does not exist an efficient concrete recycling method with low energy consumption. In this study, concrete was regarded as a heterogeneous material composed of coarse aggregate and cement mortar. And the failure mode of concrete under ultrasonic dynamic loading was investigated by finite element (FE) analysis. Simultaneously, a 3D random aggregate concrete model was programmed by APDL and imported into ABAQUS software, and the damage plastic constitutive model was applied to each phase to study the damage law of concrete under dynamic loading. Meanwhile, the dynamic damage process of concrete was numerically simulated, which observed ultrasonic propagating and the concrete crushing behavior. Finally, the FE simulation considering the influence of different aggregate volume and aggregate size was carried out to illustrate the damage level of concrete.

• Journal of Ocean Engineering and Technology
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• v.24 no.3
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• pp.52-58
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• 2010

This study investigated the engineering properties of waste tire powder-bottom ash added composite soil, which was developed to recycle dredged soil, bottom ash, and waste tire powder. Test specimens were prepared using 5 different percentages of waste tire powder content(0%, 25%, 50%, 75%, and 100% by weight of the dry dredged soil), three different percentages of bottom ash content (0%, 50%, and 100% by weight of the dry dredged soil), and three different particle sizes of waste tire powder (0.1~2 mm, 0.9~5 mm, and 2~10 mm). Several series of unconfined compression tests, direct shear tests, and flow tests were conducted. The experimental results indicated that the waste tire powder content, particle size of waste tire powder, and bottom ash content influenced the strength and stress-strain behavior of the composite soil. The flow value increased with an increase in water content, but decreased with an increase in waste tire powder content.

• Steel and Composite Structures
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• v.27 no.2
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• pp.185-192
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• 2018

Fly ash can significantly improve concrete workability and performance, and recycling fly ash in concrete can contribute to a cleaner environment. Since fly ash influences pozzolanic reactions in concrete, mechanical behaviors of concrete containing fly ash differ from traditional concrete. Creep behaviors of fly ash concrete filled steel tube arch were experimentally investigated for 10% and 30% fly ash replacement. The axes of two arches are designed as circular arc with 2.1 m computed span, 0.24 m arch rise, and their cross-sections are all in circular section. Time dependent deflection and strain of loading and mid-span steel tube were measured, and long term deflection of the model arch with 10% fly ash replacement was significantly larger than with 30% replacement. Considering the steel tube strain, compressive zone height, cross section curvature, and internal force borne by the steel tube, the compressive zone height and structural internal forces increased gradually over time due to concrete creep. Increased fly ash content resulted in more significant neutral axis shift. Mechanisms for internal force effects on neutral axis height were analyzed and verified experimentally.

• Macromolecular Research
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• v.12 no.3
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• pp.293-302
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• 2004

We added surface-modified silica nanoparticles to poly(ethylene 2,6-naphthalate) (PEN) to investigate their effect on the mechanical properties on the PEN nanocomposite material. The torque and total torque values of the composites decreased in the silica nanoparticle composites. The tensile modulus of the composites reinforced with unmodified silica nanoparticles increased upon increasing the silica content, while the tensile strength and elongation decreased accordingly. In contrast, stearic acid-modified, silica nanoparticle reinforced PEN composites exhibited an increase in elongation and a decrease in tensile modulus upon addition of the silica nanoparticles because the stearic acid that had adsorbed onto the surface of the silica nanoparticle in multilayers could act as a plasticizer during melt compounding. Stearic acid modification had a small effect on the crystallization behavior of the composites. We calculated theoretical values of the tensile modulus using the Einstein, Kerner, and Nielsen equations and compared these values with the experimental data obtained from the composites. The parameters calculated using the Nielsen equation and the Nicolais- Narkis model revealed that the interfacial adhesion between silica nanoparticles and the PEN matrix could be improved.

• Korean Journal of Materials Research
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• v.19 no.7
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• pp.397-402
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• 2009

In this study, Ti powder was fabricated from Ti scrap by the Hydrogenation-Dehydrogenation (HDH) method. Hydrogenation reactions of Ti scrap occurred at near 450 $^{\circ}C$ with a sudden increase in the reaction temperature and the decreasing pressure of hydrogen gas during the hydrogenation process in the furnace. The dehydrogenation process was also carried out at 750 $^{\circ}C$ for 2hrs in a vacuum of $10^{-4}$ torr. After the HDH process, a deoxidation treatment was carried out with the Ca(purity: 99.5) at 700 $^{\circ}C$ for 2hrs in the vacuum system. It was found that the oxidation content of Ti powder that was deoxidized with Ca showed noticeably lower values, compared to the content obtained by HDH process. In order to fabricate Ti compacts, Ti powder was sintered at $1100\sim1400^{\circ}C$ for 2hrs under a vacuum of $10^{-4}$ torr. The relative density of compact was 94.9% at 1300 $^{\circ}C$. After sintering, all of the Ti compacts showed brittle fracture behavior, which occurred in an elastic range with short plastic yielding up to a peak stress.

• Korean Journal of Materials Research
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• v.30 no.12
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• pp.655-659
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• 2020

Hydrogen isotopes (i.e. deuterium and tritium) are supplied to the tokamak in the International Thermonuclear Experimental Reactor (ITER) fuel cycle. One important part of the ITER fuel cycle is the recycling of unused fuel back to the tokamak, as almost 99 % of fuel is unburned during fusion reaction. For this, cryogenic distillation has been used in the isotope separation system (ISS) of ITER, but this technique tends to be energy-intensive and to have low selectivity (typically below 1.5 at 24 K). Recently, efficient isotope separation by porous materials has been reported in the so-called quantum sieving process. Hence, in this study, hydrogen isotope adsorption behavior is studied using chemically stable ZIF-11. At low temperature (40 K ~ 70 K), the adsorption increases and the sorption hysteresis becomes stronger as the temperature increases to 70K. Molar ratio of deuterium to hydrogen based on the isotherms shows the highest (max. 14) ratio at 50 K, confirming the possibility of use as a potential isotope separation material.

• Korean Journal of Metals and Materials
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• v.48 no.5
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• pp.430-435
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• 2010

Solvent extraction experiments of Rh(III) and Ir(IV) were performed on the HCl solution by using Alamine336 and TBP. The extraction percentage of Rh and Ir by Alamine336 was much higher than that by TBP. For the solvent extraction with Alamine336, the extraction percentage of Rh and Ir decreased with a HCl concentration. However, the extraction percentage of both metals by TBP was below 12% in our experimental range and increased with an increasing HCl concentration of up to 8 M. From the mixed solution of Ir with an excess SnCl$_{2}$, most of the tin was extracted by Alamine336 and TBP. However, the extraction percentage of Ir by Alamine336 was reduced and no iridium was extracted by TBP. The extraction behavior of Ir and Sn was investigated by scrubbing experiments on the loaded Ir with a SnCl$_{2}$ solution.

• Steel and Composite Structures
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• v.44 no.3
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• pp.389-406
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• 2022

Recycling concrete construction waste is an encouraging step toward green and sustainable building. A lot of research has been done on recycled aggregate concretes (RACs), but not nearly as much has been done on concrete made with recycled aggregate. Recycled aggregate concrete, on the other hand, has been found to have a lower mechanical productivity compared to conventional one. Accurately estimating the mechanical behavior of the concrete samples is a most important scientific topic in civil, structural, and construction engineering. This may prevent the need for excess time and effort and lead to economic considerations because experimental studies are often time-consuming, costly, and troublous. This study presents a comprehensive data-mining-based model for predicting the splitting tensile strength of recycled aggregate concrete modified with glass fiber and silica fume. For this purpose, first, 168 splitting tensile strength tests under different conditions have been performed in the laboratory, then based on the different conditions of each experiment, some variables are considered as input parameters to predict the splitting tensile strength. Then, three hybrid models as GWO-RF, GWO-MLP, and GWO-SVR, were utilized for this purpose. The results showed that all developed GWO-based hybrid predicting models have good agreement with measured experimental results. Significantly, the GWO-RF model has the best accuracy based on the model performance assessment criteria for training and testing data.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.2
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• pp.205-224
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• 2023

The emission of off-gas streams from used fuel recycling is a concern in nuclear energy usage as they contain radioactive compounds, such as, ³H, ¹⁴C, ⁸⁵Kr, ¹³¹I, and ¹²⁹I that can be harmful to human health and environment. Radioactive iodine, ¹²⁹I, is particularly troublesome as it has a half-life of more than 15 million years and is prone to accumulate in human thyroid glands. Organic iodides are hazardous even at very low concentrations, and hence the capture of ¹²⁹I is extremely important. Dynamic adsorption experiments were conducted to determine the efficiency of sodium mordenite, partially exchanged silver mordenite, and fully exchanged silver mordenite for the removal of methyl iodide present at parts per billion concentrations in a simulated off-gas stream. Kinetic analysis of the system was conducted incorporating the effects of diffusion and mass transfer. The possible reaction mechanism is postulated and the order of the reaction and the values of the rate constants were determined from the experimental data. Adsorbent characterization is performed to investigate the nature of the adsorbent before and after iodine loading. This paper will offer a comprehensive understanding of the methyl iodide behavior when in contact with the mordenites.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.21 no.1
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• pp.9-22
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• 2023

Spin-off pyroprocessing technology and inert anode materials to replace the conventional carbon-based smelting process for critical materials were introduced. Efforts to select inert anode materials through numerical analysis and selected experimental results were devised for the high-throughput reduction of oxide feedstocks. The electrochemical properties of the inert anode material were evaluated, and stable electrolysis behavior and CaCu generation were observed during molten salt recycling. Thereafter, CuTi was prepared by reacting rutile (TiO₂) with CaCu in a Ti crucible. The formation of CuTi was confirmed when the concentration of CaO in the molten salt was controlled at 7.5mol%. A laboratory-scale electrorefining study was conducted using CuTi(Zr, Hf) alloys as the anodes, with a Ti electrodeposit conforming to the ASTM B299 standard recovered using a pilot-scale electrorefining device.