• Title/Summary/Keyword: Recovered Material

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Influence of Moisture Absorption on the Mechanical Properties in the Laminated Composites (적층형 복합재료의 기계적 성질에 미치는 수분의 영향)

  • Moon, Chang-Kwan;Choi, Hee-Lark;Lee, Bong
    • Journal of Ocean Engineering and Technology
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    • v.14 no.3
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    • pp.90-99
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    • 2000
  • This study has been investigated about the influence of moisture environment properties in the unidirectional and cross laminated carbon fiber/epoxy and glass fiber/epoxy composites. As a results, it was found that the weight gain of water increased with the immersion time and the mechanical properties were decreased with the weight gain of water. And it was also shown that the mechanical properties of carbon fiber/epoxy laminates were better than those of glass fiber/epoxy laminates. And a gap of the mechanical properties between the two kinds of laminates was increasing with the immersion time in distilled water of 80$^{\circ}C $. Mechanical properties which decreased by moisture absorption in the CF and GF reinforced laminates were recovered up to some extent by drying in oven at 80$^{\circ}C $ for 10 days.

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Decomposition of PVC and Ion exchange resin in supercritical water

  • Lee, Sang-Hwan;Yasuyo, Hosgujawa;Kim, Jung-Sung;Park, Yoon-Yul;Hiroshi, Tomiyasu
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2005.05a
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    • pp.267-271
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    • 2005
  • This experiment was carried out at 450"C, which is relatively lower than the temperature for supercritical water oxidation (600-650$^{\circ}C$). In this experiment, the decomposition rates of various incombustible organic substances were very high. In addition, it was confirmed that hetero atoms existed in organic compounds and chlorine was neutralized by sodium(salt formation).However, to raise the decomposition rate, relatively large amount of sodium nitrate(3-4 times the equivalent weight) was required. When complete oxidation is intended as in the case with PCB, the amount of oxidizer and decomposition cost is important. But when vaporization reduction is required as in the case with nuclear wastes, the amount of radioactive wastes increases instead. But as can be seen in the result of XRD measurement, unreacted sodium nitrate remained unchanged. If oxidation reaction of organic substance simply depends on collision frequency, unreacted sodium nitrate can be recovered and reused, then oxidation equivalent weight would be sufficient. In the gas generated, toxic gas was not found. As the supercritical water medium has high reactivity, it is difficult to generate relatively low energy level SO$_{X}$, and NO$_{X}$.

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Electrical properties improvement of PZT thin films etched into $CF_4/(Cl_2+Ar)$ plasma (식각된 PZT 박막의 전기적 특성 개선에 관한 연구)

  • Koo, Seong-Mo;Kim, Dong-Pyo;Kim, Kyoung-Tae;Kim, Chang-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.13-17
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    • 2004
  • The PZT thin films are well-known material that has been widely studied for ferroelectric random access memory (FRAM). We etched the PZT thin films by $CF_4/(Cl_2+Ar)$ plasma and investigated improvement in etching damage by $O_2$ annealing. PZT thin films were etched for 1 min in an ICP using a gas mixture of $Cl_2$(80%)/Ar (20%) with 30% $CF_4$ addition. The etching conditions were fixed at a substrate temperature of $30^{\circ}C$, an rf power of 700 W, a dc-bias voltage of -200 V and a chamber pressure of 2 Pa. To improve the ferroelectric properties of PZT thin films after etching, the samples were annealed for 10 min at various temperatures in $O_2$ atmosphere. After $O_2$ annealing, the remanent polarization, fatigue, and the leakage current were gradually recovered to the characteristics of the as-deposited film, according as the temperature increased.

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A CONCEPTUAL STUDY OF PYROPROCESSING FOR RECOVERING ACTINIDES FROM SPENT OXIDE FUELS

  • Yoo, Jae-Hyung;Seo, Chung-Seok;Kim, Eung-Ho;Lee, Han-Soo
    • Nuclear Engineering and Technology
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    • v.40 no.7
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    • pp.581-592
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    • 2008
  • In this study, a conceptual pyroprocess flowsheet has been devised by combining several dry-type unit processes; its applicability as an alternative fuel cycle technology was analyzed. A key point in the evaluation of its applicability to the fuel cycle was the recovery yield of fissile materials from spent fuels as well as the proliferation resistance of the process. The recovery yields of uranium and transuranic elements (TRU) were obtained from a material balance for every unit process composing the whole pyroprocess. The material balances for several elemental groups of interest such as uranium, TRU, rare earth, gaseous fission products, and heat generating elements were calculated on the basis of the knowledge base that is available from domestic and foreign experimental results or technical information presented in open literature. The calculated result of the material balance revealed that uranium and TRU could be recovered at 98.0% and 97.0%, respectively, from a typical PWR spent fuel. Furthermore, the anticipated TRU product was found to emit a non-negligible level of $\gamma$-ray and a significantly higher level of neutrons compared to that of a typical plutonium product obtained from the PUREX process. The results indicate that the product from this conceptual pyroprocessing should be handled in a shielded cell and that this will contribute favorably to retaining proliferation resistance.

Recovery of Roasting-Molybdenite Concentrate by Froth Flotation (부유선별법에 의한 제련용 몰리브덴 정광의 회수)

  • Park, Chul-Hyun;Jeon, Ho-Seok;Kim, Byoung-Gon;Han, Oh-Hyung
    • Korean Journal of Materials Research
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    • v.19 no.12
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    • pp.661-666
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    • 2009
  • Froth flotation has been carried out in order to produce roasting-molybdenite concentrate from molybdenite ore in the Shin-yeomi mine. In our study, roasting-molybdenite (Mo 0.43%) from Shin-yeomi mine was recovered by varying the conditions of regrinding time, dosage of collector and alkalinity. Liberation and flotation efficiency more were effective at regrinding time of six minutes than at single grinding. Mo recovery curves increased considerably as dosage of kerosene increased, whereas Mo grade curves decreased gradually. The separation efficiency of molybdenite was effective when the dosage of collector (kerosene) was adjusted to 300 g/t. The molybdenite concentrate was agglomerated in the range of pH 5-7 and its separation efficiency increased to pH 9-10. The concentrate of 49.5% Mo grade ($MoS_2$, 82.6%) with 81.5% recovery from Shin-yeomi molybdenite ores was obtained under conditions of 20% pulp concentration, 300 g/t kerosene 325 g/t frother (AF65), 2.5 kg/t depressant ($Na_2SiO_3$), pH 9-10 and four cleaning times. In the future, a trial run that can separate up to 50% Mo grade from Shin-yeomi molybdenite ores will be performed.

Materials Properties of Nickel Electrodeposits as a Function of the Current Density, Duty Cycle, Temperature and pH

  • Kim, Dong-Jin;Kim, Myung Jin;Kim, Joung Soo;Kim, Hong Pyo
    • Corrosion Science and Technology
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    • v.5 no.5
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    • pp.168-172
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    • 2006
  • Alloy 600 having a superior resistance to a corrosion is used as a steam generator tubing in nuclear power plants. In spite of its high corrosion resistance, there are many tubings which experience corrosion problems such as a SCC under the high temperature and high pressure environments of nuclear power plants. The Alloy 600 tubing can be repaired by using a Ni electroplating having an excellent SCC resistance. In order to carry out a successful Ni electrodeposition inside a steam generator tubing, the effects of various parameters on the material properties of the electrodeposit should be elucidated. Hence this work deals with the effects of an applied current density, duty cycle($T_{on}/(T_{on}+T_{off})$) of a pulse current, bath temperature and solution pH on the material properties of Ni electrodeposit obtained from a Ni sulphamate bath by analyzing the current efficiency, potentiodynamic curve, hardness and stress-strain curve. Hardness, YS(yield strength) and TS(tensile strength) decreased whereas the elongation increased as the applied current density increased. This was thought to be by a concentration depletion at the interface of the electrodeposit/solution, and a fractional decrease of the hydrogen reduction reaction. As the duty cycle increased, the hardness, YS and TS decreased while the elongation increased. During an off time at a high duty cycle, the concentration depletion could not be recovered sufficiently enough to induce a coarse grain sized electrodeposit. With an increase of the solution temperature and pH, the YS and TS increased while the elongation decreased. The experimental results of the hardness and the stress-strain curves can be supplemented by the results of the potentiodynamic curve.

Data driven inverse stochastic models for fiber reinforced concrete

  • Kozar, Ivica;Bede, Natalija;Bogdanic, Anton;Mrakovcic, Silvija
    • Coupled systems mechanics
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    • v.10 no.6
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    • pp.509-520
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    • 2021
  • Fiber-reinforced concrete (FRC) is a composite material where small fibers made from steel or polypropylene or similar material are embedded into concrete matrix. In a material model each constituent should be adequately described, especially the interface between the matrix and fibers that is determined with the 'bond-slip' law. 'Bond-slip' law describes relation between the force in a fiber and its displacement. Bond-slip relation is usually obtained from tension laboratory experiments where a fiber is pulled out from a matrix (concrete) block. However, theoretically bond-slip relation could be determined from bending experiments since in bending the fibers in FRC get pulled-out from the concrete matrix. We have performed specially designed laboratory experiments of three-point beam bending with an intention of using experimental data for determination of material parameters. In addition, we have formulated simple layered model for description of the behavior of beams in the three-point bending test. It is not possible to use this 'forward' beam model for extraction of material parameters so an inverse model has been devised. This model is a basis for formulation of an inverse model that could be used for parameter extraction from laboratory tests. The key assumption in the developed inverse solution procedure is that some values in the formulation are known and comprised in the experimental data. The procedure includes measured data and its derivative, the formulation is nonlinear and solution is obtained from an iterative procedure. The proposed method is numerically validated in the example at the end of the paper and it is demonstrated that material parameters could be successfully recovered from measured data.

Radiation Protection Effects of Dendranthema Zawadskii Var. Latilobum (Maxim.) Kitam. Extracts on Blood Cells, Intestine, and Uterus of Female SD Rats Irradiated with Gamma-Ray 10 Gy (구절초 추출물이 감마선 10 Gy에 조사된 암컷 SD Rat의 혈구 및 소장, 자궁에 미치는 방사선 방호효과)

  • Sung-Hyun, Joo;Hae-Suk, Kim;Sang-Hyun, Jeong;Jae-Gyeong, Choi;Seong-Ok, Jin;Byung-In, Min
    • Journal of radiological science and technology
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    • v.46 no.1
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    • pp.23-28
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    • 2023
  • The purpose of this study is to see the radiation protection effect of the oral injected Dendranthema zawadskii var. latilobum (Maxim.) Kitam. extracts on the small intestine and uterus of female SD Rat as a natural radiation protection agent. The experimental group was divided into four groups: Normal Control group (NC group), Injected Dendranthema zawadskii var. latilobum (Maxim.) Kitam. extracts group (DZ group), irradiated group after injecting Dendranthema zawadskii var. latilobum (Maxim.) Kitam. extracts (DZ+IR group). The whole body of SD Rat was irradiated with gamma-ray 10Gy, and the administration of oral Dendranthema zawadskii var. latilobum (Maxim.) Kitam. Extract was 2 cc (71.56 mg/day/kg) once a day for 2 weeks. For this study, chages in blood cell levels, SOD assay, small intestine and uterus were observed. In the 21st white blood cell level, the DZ+IR group recovered to a normal level, and the IR group didn't. The IR group villus length was lower than other groups on Day 1. IR group was partially recovered, and DZ+IR group was recovered like the NC group on Day 21. In the case of the first-day endometrium, the IR group was thin and the boundary was cloudy, and the DZ+IR group was thicker and the boundary was clearer than the IR group. Day 21 IR group still did not recover, and DZ+IR group recovered like NC group. This is believed to have radiation protection effects in the blood cells and small intestine and uterus of the irradiated female SD Rat, and is expected to be useful for the study of natural radiation protection materials.

Diversity and Chemical Defense Role of Culturable Non-Actinobacterial Bacteria Isolated from the South China Sea Gorgonians

  • Jiang, Peng;Zhang, Xiaoyong;Xu, Xinya;He, Fei;Qi, Shuhua
    • Journal of Microbiology and Biotechnology
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    • v.23 no.4
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    • pp.437-443
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    • 2013
  • The diversity of culturable non-actinobacterial (NA) bacteria associated with four species of South China Sea gorgonians was investigated using culture-dependent methods followed by analysis of the bacterial 16S rDNA sequence. A total of 76 bacterial isolates were recovered and identified, which belonged to 21 species of 7 genera, and Bacillus was the most diverse genus. Fifty-one percent of the 76 isolates displayed antibacterial activities, and most of them belonged to the Bacillus genus. From the culture broth of gorgonian-associated Bacillus methylotrophicus SCSGAB0092 isolated from gorgonian Melitodes squamata, 11 antimicrobial lipopeptides including seven surfactins and four iturins were obtained. These results imply that Bacillus strains associated with gorgonians play roles in coral defense mechanisms through producing antimicrobial substances. This study, for the first time, compares the diversity of culturable NA bacterial communities among four species of South China Sea gorgonians and investigates the secondary metabolites of gorgonian-associated B. methylotrophicus SCSGAB0092.

Recovery of Palladium (Pd) from Spent Catalyst by Dry and Wet Method and Re-preparation of Pd/C Catalyst from Recovered Pd (폐촉매로부터 Pd회수 및 이를 이용한 Pd/C 촉매 재제조 기술 개발)

  • Kim, Ji Sun;Kwon, Ji Soo;Baek, Jae Ho;Lee, Man sig
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.376-381
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    • 2018
  • The purpose of this study is to investigate and optimize an effectiveness process for the recovery of Pd from the spent Pd/C catalyst by the process of hydrogenation of maleic anhydride over Pd/C. Pd solution recovered from Pd/C catalyst was used to prepare Pd/C catalysts. Their characteristics were compared to those of Pd/C catalyst prepared by using a reagent grade precursor solution. Pd in the spent catalyst was leached by the modified process with dry and wet methods to obtain the high recovery ratio of Pd. The burn-out of carbon in the spent Pd/C catalyst was carried out in the rage of $600-900^{\circ}C$. Pd content of carbonized catalyst was confirmed by XRF and ICP. Pd was extracted from carbonized spent catalysts with acid solutions of 1,2 and 4 M HCl at a leaching temperature of $90^{\circ}C$ for 2 h. The high recovery ratio of Pd was shown as 92.4% that leached in 4 M HCl. Also Pd/C catalysts were prepared by using the leached solution and the reagent grade of $H_2PdCl_4$ as a precursor solution and the characteristics were analyzed by XRD, CO-chemisorption and FE-TEM. As a result, the dispersion of the catalyst prepared by using the leached solution was 34.6%, which was found to be equal to or more than that of the Pd/C catalyst prepared by the reagent grade precursor solution.