• 제목/요약/키워드: Rearrangement

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An Analysis on the Situation of Forestry Mechanization in the Production and Supply of Timber (목재생산 및 공급에서 임업기계화의 현황 분석)

  • Kim, Jae-Hwan;Mun, Ho-Seong;Han, Sang-Yoel;Park, Sang-Jun
    • Journal of Korean Society of Forest Science
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    • 제104권4호
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    • pp.607-614
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    • 2015
  • This study aims to analyze the current status of timber production operation and the effects of the forestry mechanization projects on timber production. In order to increase the domestic timber production, it is necessary to propel forestry mechanization project, improve policy and institution, broaden forest-road network, enlarge the number of forest workers, enhance timber production and supply system, provide forestry machines, establish forest operation system, and train forest workers. In addition, the reestablishment of policy goals, the consistency of policy, and the rearrangement of laws and institution are considered more important. To improve the results and effects of forestry mechanization project, it is necessary to drive of forestry mechanization project, the spread of forestry machines, the cultivation of trainer ability, the development of training materials, and the teaching of field skill. In order to meet timber buyersí preference, timber needs to be produced through whole tree logging operation system. Expanding the proportion of domestic timber among total timber demand in Korea requires price competitiveness, and the supply ability of high quality product from the perspective of length and width.

A Political-Economic Study on Cooperative Squid Fishing East to the $E128^{\circ}$ (동경 128도 이동 오징어 공조조업에 관한 정치경제학적 연구)

  • Park Seong-Kwae
    • The Journal of Fisheries Business Administration
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    • 제35권2호
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    • pp.91-115
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    • 2004
  • The main purpose of this study is to analyze the cooperative squid fisheries problems surrounding the $E128^{\circ}$, established by the 1965 Korea - Japan Fisheries Agreement which banned Korean large trawlers' fishing east to the $E128^{\circ}$ In fact, the moratorium was put on by Japans request. However, such issue did not occur until the filefish stock in the southern Korean sea, which was a major target fish species of the large trawl fisheries, The filefish stock collapsed completely around 1991 and at the same time most of bottom fish stocks in the East China Sea began to show a symptom of over - exploitation. Thus, the off - shore large trawlers learned to have a little opportunity of finding out alternative fish stocks as well as fishing grounds. Fortunately, at that time squid resource stock and consumption were on the increasing trend. The large trawl fisheries were able to economically exploit squid stock east to the $E128^{\circ}$ through cooperative fishing with squid angling light boats in the East and East - South Sea, even though such cooperative fishing activities violate the existing fishery laws apparently. Some important reasons that the large trawlers have continued the cooperative fishing seem to be because (ⅰ) squid resource stock has been on the increasing state over time, (ⅱ) the trawl fisheries have made a significant contribution to meeting domestic and export demands and stabilizing squid prices, and (ⅲ) they have kept domestic squid market from foreign competition. However, the new Korea - Japan fisheries agreement in 1998 provided a momentum of questioning the effectiveness of the $E128^{\circ}$ by the squid - related fisheries other than the squid angling. Serious conflicts between squid - related fisheries began to emerge and to be much intensified. Squid angling industries in the East opposed to large trawlers's efforts to formalize such illegal cooperative squid fishing activities. Their main argument was that such formalizing would definitely make the East coast squid prices lower and in turn their business performance would be worse off. The results of quantitative analysis suggest that the trawlers' massive landing may have a significant influence on lowering the east coast squid prices. Now, an important issue that the squid - related fisheries and the government are facing is to solve such complex squid fishing problems through a multi - participatory negotiation process, including price stabilization, total allowable catch level and its operation schemes, $E128^{\circ}$ rearrangement, and so on.

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A Study on the Stereochemistry of 1,3-Thiazolidine (1,3-티아졸리딘 술폭시드의 입체구조에 관한 연구)

  • Ma He-Duck;Park Shin-Ja;Han Hoh-Gyu
    • Journal of the Korean Chemical Society
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    • 제37권1호
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    • pp.119-130
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    • 1993
  • The stereochemistry of 1,3-thiazolidine sulfoxides 1 in which 3 chiral centres are present in a molecule was elucidated by deuterium exchange and trapping reactions. 3-Acetoxy-1,3-thiazolidines 5 was oxidized to 6 and 8, corresponding $\alpha$-cis 10, $\alpha$-trans 11, $\beta$ -cis 12, and $\beta$ -trans 13 isomers were separated from their diasteromeric mixtures. Sulfoxide 10 was isomerized to more thermodynamically stable isomer 13 under neutral conditions in refluxing benzene or toluene. The methyl hydrogens of 2-methyl group in the sulfoxide 13 and those of the sulfoxide 11 were deuterated by the deuterium incorporation reactions. The intermediate sulfenic acids 25 and 26 derived from the sulfoxides 10 and 12 via sigmatropic rearrangement were trapped by 2-mercaptobenzothiazole (2-MBT) to give disufides 27 and 28 respectively. However, the sulfoxides 11 and 13 were transformed to ring expansion product dihydro-1,4-thiazine 29 under the same reaction conditions. In the presence of acid catalyst, the sulfoxides 10, 11, and 12 were converted to dihydro-1,4-thiazine 29 through the sulfoxide 13 quantitatively. The mechanisms of isomerization of sulfoxides and the formation of 29 were also discussed.

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The Base-Catalysed Carbonato or Oxalato Ring Opening of $cis-{\beta}-$$[Co(3,2,3-tet)(CO_3 or C_2O_4)]^+$ (3,2,3-tet=4,7-diazadecane-1,10-diamine) (염기성 촉매에 의한 $cis-{\beta}-$$[Co(3,2,3-tet)(CO_3 or C_2O_4)]^+$ (3,2,3-tet=4,7-diazadecane-1,10-diamine)에 대한 Carbonato 혹은 Oxalato 리간드의 고리열림 반응)

  • Yoon, Doo Cheon;Oh, Chang Eon;Kim, Bok Jo;Doh, Myung Ki
    • Journal of the Korean Chemical Society
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    • 제40권7호
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    • pp.501-508
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    • 1996
  • The base-catalysed carbonato or oxalato ring opening of cis-${\beta}-[Co(3,2,3,-tet))CO_3\;or\;C_2O_4)]^+$(3,2,3-tet=4,7-diazadecane-1,10-diamine, $C_2O_4$=oxalate) has been investigated in aqueous solution and in mixed aqueous-organic solvent. The rearrangement of 3,2,3-tet and carbonato or oxalato ring opening of cis-${\beta}-[Co(3,2,3,-tet))CO_3\;or\;C_2O_4)]^+$ occurred via the dissociation of one of the two coordinating carbonato or oxalato oxygen atoms. The resulting product was cis-${\alpha}-[Co(3,2,3-tet)(OH)(OCO_2\;or\;OC_2O_3)_3].$ It has been suggested that the base-catalysed reaction of cis-${\beta}-[Co(3,2,3,-tet))CO_3\;or\;C_2O_4)]^+$ takes place via the Dcb(dissociative conjugated base) mechanism. The other oxygen atom of carbonato or oxalato was dissociated continuously to give cis-${\alpha}-[Co(3,2,3-tet)(OH)_2]^+.$ Cis-${\alpha}-[Co(3,2,3-tet)(OH)_2]^+$ was isomerized to cis-${\beta}-[Co(3,2,3-tet)(OH)_2]^+.$

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Two-Dimensional Magnetotelluric Interpretation by Finite-Element Method (유한요소법에 의한 MT 법의 2차원 해석)

  • Kim, Hee-Joon;Choi, Ji-Hyang;Han, Nu-Ree;Lee, Seong-Kon;Song, Yoon-Ho
    • Geophysics and Geophysical Exploration
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    • 제11권2호
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    • pp.85-92
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    • 2008
  • Magnetotelluric (MT) methods are widely applied as an effective exploration technique to geothermal surveys. Two-dimensional (2-D) analysis is frequently used to investigate a complicated subsurface structure in a geothermal region. A 2-D finite-element method (FEM) is usually applied to the MT analysis, but we must pay attention to the accuracy of so-called auxiliary fields. Rodi (1976) proposed an algorithm of improving the accuracy of auxiliary fields, and named it as the MOM method. Because it introduces zeros into the diagonal elements of coefficient matrix of the FEM total equation, a pivoting procedure applied to the symmetrical band matrix makes the numerical solution far less efficient. The MOM method was devised mainly for the inversion analysis, in which partial derivatives of both electric and magnetic fields with respect to model parameters are required. In the case of forward modeling, however, we do not have to resort to the MOM method; there is no need of modifying the coefficient matrix, and the auxiliary fields can be elicited from the regular FEM solution. The computational efficiency of the MOM method, however, can be greatly improved through a sophisticated rearrangement of the total equation.

Irregular Waves-Induced Seabed Dynamic Responses around Submerged Breakwater (불규칙파동장하 잠제 주변지반의 동적거동에 관한 수치해석)

  • Lee, Kwang-Ho;Ryu, Heung-Won;Kim, Dong-Wook;Kim, Do-Sam;Kim, Tae-Hyung
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • 제28권4호
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    • pp.177-190
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    • 2016
  • In case of the seabed around and under gravity structures such as submerged breakwater is exposed to a large wave action long period, the excess pore pressure will be generated significantly due to pore volume change associated with rearrangement soil grains. This effect will lead a seabed liquefaction around and under structures as a result from decrease in the effective stress. Under the seabed liquefaction occurred and developed, the possibility of structure failure will be increased eventually. Lee et al.(2016) studied for regular waves, and this study considered for irregular waves with the same numerical analysis method used for regular waves. Under the condition of the irregular wave field, the time and spatial series of the deformation of submerged breakwater, the pore water pressure (oscillatory and residual components) and pore water pressure ratio in the seabed were estimated and their results were compared with those of the regular wave field to evaluate the liquefaction potential on the seabed quantitatively. Although present results are based on a limited number of numerical simulations, one of the study's most important findings is that a more safe design can be obtainable when analyzing case with a regular wave condition corresponding to a significant wave of irregular wave.

Theoretical Studies of the Gas-Phase Identity Nucleophilic Substitution Reactions of Cyclopentadienyl Halides

  • Lee, Ik-Choon;Li, Hong-Guang;Kim, Chang-Kon;Lee, Bon-Su;Kim, Chan-Kyung;Lee, Hai-Whang
    • Bulletin of the Korean Chemical Society
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    • 제24권5호
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    • pp.583-592
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    • 2003
  • The gas phase identity nucleophilic substitution reactions of halide anions (X = F, Cl, Br) with cyclopentadienyl halides (1) are investigated at the B3LYP/6-311+G**, MP2/6-311+G** and G2(+)MP2 levels involving five reaction pathways: σ-attack $S_N2$, β-$S_N$2'-syn, β-$S_N$2'-anti, γ-$S_N$2'-syn and γ-$S_N$2'-anti paths. In addition, the halide exchange reactions at the saturated analogue, cyclopentyl halides (2), and the monohapto circumambulatory halide rearrangements in 1 are also studied at the same three levels of theory. In the σ-attack $S_N2$ transition state for 1 weak positive charge develops in the ring with X = F while negative charge develops with X = Cl and Br leading to a higher energy barrier with X = F but to lower energy barriers with X = Cl and Br than for the corresponding reactions of 2. The π-attack β-$S_N$2' transition states are stabilized by the strong $n_C-{\pi}^{*}_{C=C}$ charge transfer interactions, whereas the π-attack γ-$S_N$2' transition states are stabilized by the strong $n_C-{\sigma}^{*}_{C-X}$ interactions. For all types of reaction paths, the energy barriers are lower with X = F than Cl and Br due to the greater bond energy gain in the partial C-X bond formation with X = F. The β-$S_N$2' paths are favored over the γ-$S_N$2' paths only with X = F and the reverse holds with X = Cl and Br. The σ-attack $S_N2$ reaction provides the lowest energy barrier with X = Cl and Br, but that with X = F is the highest energy barrier path. Activation energies for the circumambulatory rearrangement processes are much higher (by more than 18 kcal $mol^{-1}$) than those for the corresponding $S_N2$ reaction path. Overall the gas-phase halide exchanges are predicted to proceed by the σ-attack $S_N2$ path with X = Cl and Br but by the β-$S_N$2'-anti path with X = F. The barriers to the gas-phase halide exchanges increase in the order X = F < Br < Cl, which is the same as that found for the gas-phase identity methyl transfer reactions.

Prenatal Diagnosis of a Satellited Chromosome 8p Results from a de novo Cryptic Translocation between Chromosomes 8 and 22 (산전 진단에서 관찰된 8번과 22번 염색체 사이의 미세 전좌에 의한 8번 염색체 단완 위성체)

  • Oh, Ah-Rum;Lee, Bom-Yee;Choi, Ene-Yuong;Ryu, Hyun-Mee;Lee, Seung-Jae;Jung, Ji-Ye;Park, So-Yeon
    • Journal of Genetic Medicine
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    • 제8권2호
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    • pp.135-138
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    • 2011
  • The authors of the present study report the prenatal detection of a chromosomal abnormality with additional satellites on the distal short arm of chromosome 8. A 35-year-old woman was referred for amniocentesis because of her advanced maternal age and positive result for maternal serum screening test. Cytogenetic analysis of cultured amniocytes showed a satellite 8p chromosome. The satellite 8p chromosome was positive for nucleolus organizer region (NOR) staining. The parents' karyotypes were normal. Fluorescence in situ hybridization (FISH) study for metaphases of fetal amniocytes revealed a cryptic translocation of chromosomes 8p and 22p. The fetal karyotype was described as 46,XY,8ps.ish t(8;22)(p23.3;p11.2) (D8S504-;D8S504+)dn. The parents decided to continue the pregnancy and a phenotypically normal boy was born at 38 weeks of gestation. In case of de novo terminal NORs detected prenatally, more accurate cytogenetic and molecular analysis should be performed in order to rule out cryptic chromosomal rearrangement among other chromosomes.

Application of DNA Probe Method for Detection of 2,4-Dichlorophenoxyacetic Acid Degrading Bacteria in Soil (DNA Probes에 의한 토양의 이사디 (2,4-D) 분해세균의 검출)

  • Ka, Jong-Ok
    • Applied Biological Chemistry
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    • 제39권5호
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    • pp.403-408
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    • 1996
  • Total bacterial community DNA, which was extracted from microcosm soil and field soil after 2,4-D amendments, was analyzed on Southern blots, using the tfdA gene probe derived from plasmid pJP4 and the Spa probe from Sphingomonas paucimobilis. Southern blot analyses with total bacterial DNA extracted from soils Inoculated with Pseudomonas cepacia/pJP4 revealed that DNA probe method could detect the 2,4-D degrading bacteria down to $10^5\;cells/g$ dry soil. In the microcosm experiment, there was a good correlation between 2,4-D degradation and banding patterns in hybridization analyses performed after each 2,4-D treatment using the two probes. When bacterial DNA extracted from microcosm soil was hybridized with the Spa probe, a change in the position of hybrid bands was observed over time in a Southern blot, suggesting that population change or possibly genetic rearrangement in 2,4-D degrading microbial populations occurred in this soil. With the Spa probe, one hybrid DNA band was persistently observed throughout the five 2,4-D additions. When bacterial DNA isolated from the field soil was probed with the tfdA and Spa, strong hybridization signal was observed in the 100 ppm-treated subplot, weak signal In the 10 ppm-treated subplot, and no significant signal in the 1 ppm-treated and control subplots. The data show that DNA probe analyses were capable of detecting and discriminating the indigenous 2,4-D degrading microbial populations in soil amended with 2,4-D under laboratory and field conditions.

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Analysis on the Impact of Climate Change on the Survey of Rural Water District and Agricultural Production Infrastructure (농어촌용수 및 농업생산기반시설의 실태조사에 따른 기후변화 영향 분석)

  • Kim, Soo-Jin;Bae, Seung-Jong;Choi, Jin-Yong;Kim, Seong-Pil;Eun, Sang-Kyu;Yoo, Seung-Hwan;Jang, Tae-Il;Goh, Nam-Young;Hwang, Sye-Woon;Kim, Seong-Joon;Park, Tae-Seon;Jeong, Kyung-Hun;Song, Suk-Ho
    • Journal of The Korean Society of Agricultural Engineers
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    • 제60권5호
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    • pp.1-15
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    • 2018
  • This study aims to effective survey on actual condition for impact and vulnerability assessment on climate change in agriculture and rural community (limited to rural water and agricultural infrastructure, Paragraph 3, Article 2 of the Rearrangement of Agricultural and Fishing Villages Act) entrusted to Korea Rural Community Corporation based on the Law (Paragraph 2, Article 47 of the Framework Act on Agriculture, Rural community and Food industry). The results are summarized as follows. The rural water was divided into three categories (abnormal climate, water use, and flood control), and 31 indicators were selected. The reservoirs were divided into four categories, and 20 indicators were selected. The pumping stations were divided into two categories, 7 indicators, and the drainage pump stations were divided into two categories, 5 indicators were chosen. A survey on actual condition of each indicator was conducted and the result of the impact assessment was calculated. The 65 rural water showed values ranged from 0.855 to 1.308. The reservoir ranged from 0.966 to 23.338 as a result of the impact assessment on the 16 indicators. The pumping station was able to calculate the results of the safety inspection and the thorough safety inspection, and the drainage pump station was able to calculate only the result of the safety inspection. It is judged that it will be necessary to secure and analyze data on indicators with no data in the future. The results of this research can be utilized as baseline data that can deal with climate change preemptively.