• Title/Summary/Keyword: Reaction gas ratio

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액체로켓용 터빈시스템 설계

  • Choi, Chang-Ho;Kim, Jin-Han;Yang, Soo-Seok;Lee, Dae-Sung
    • Aerospace Engineering and Technology
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    • v.1 no.1
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    • pp.163-172
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    • 2002
  • The turbine system composed of a nozzle and a rotor is used to drive turbopumps while gas passes through the nozzle, potential energy is converted to kinematic energy, which forces the rotor blades to spin. In this study, an aerodynamic design of a turbine system is investigated using compressible fluid dynamic theories with some pre-determined design requirements (i.e.,pressure ratio, rotational speed, required power etc.) obtained from a liquid rocket engine (L.R.E.) system design. For simplicity of a turbine system, impulse-type rotor blades for open type L.R.E. have been chosen. Usually, the open-type turbine system requires low mass flow rate compared to the close-type system. In this study, a partial admission nozzle is adopted to maximize the efficiency of the close-type turbine system. A design methodology of the a turbine system has been introduced. Especially, a partial admission nozzle has been designed by means of simple empirical correlations between efficiency and configuration of the nozzle. Finally, a turbine system design for a 10 ton thrust level of L.R.E is presented.

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Synthesis of $H_2$-Permselective Silica Films by Chemical Vapor Deposition (화학증착(CVD)에 의한 선택적 수소 투과성 실리카막의 제조)

  • 남석우;하호용;홍성안
    • Membrane Journal
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    • v.2 no.1
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    • pp.21-32
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    • 1992
  • Hydrogen-permselective silica membranes were synthesized within tim walls of porous Vycor tubes by chemical vapor depostion of $SiO_2$. Film deposition was carried out using $SiCl_4$ hydrolysis either in the oppm shag reactants or in the one-sided geometry. At temperatures above $600^{\circ}C$ the permeation rate of hydrogen thorough the silica films varied between 0.01 and $025cm^3(STP)/cm^2-min-atm$ depending on the reaction geometry and the $H_2 : N_2$ permeation ratio was about 1000. Permeation rates of both $H_2$ and $N_2$ increased with increasing temperature. The silica membranes produced by one-sided deposition have higher hydrogen permmeation rates than those produced by the opposing reactants geometry although the membranes formed in an opposing reactants geometry were relatively stable during the heat treatment or after exposure to ambient air. These membranes can be applied to high temperature gas separations or membrane reactors once the film deposition process is optimized to get high permeability as well as good stability.

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Etching characteristic of SBT thin film by using Ar/$CHF_3$ Plasma (Ar/$CHF_3$ 플라즈마를 이용한 SBT 박막에 대한 식각특성 연구)

  • 서정우;이원재;유병곤;장의구;김창일
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.41-43
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    • 1999
  • Among the feffoelectric thin films that have been widely investigated for ferroelectric random access memory (FRAM) applications, SrBi$_2$Ta$_2$$O_{9}$ thin film is appropriate to memory capacitor materials for its excellent fatigue endurance. However, very few studies on etch properties of SBT thin film have been reported although dry etching is an area that demands a great deal of attention in the very large scale integrations. In this study, the a SrBi$_2$Ta$_2$$O_{9}$ thin films were etched by using magnetically enhanced inductively coupled Ar/CHF$_3$ plasma. Etch properties, such as etch rate, selectivity, and etched profile, were measured according to gas mixing ratio of CHF$_3$(Ar$_{7}$+CHF$_3$) and the other process conditions were fixed at RF power of 600 W, dc bias voltage of 150 V, chamber pressure of 10 mTorr. Maximum etch rate of SBT thin films was 1750 A77in, under CHF$_3$(Ar+CHF$_3$) of 0.1. The selectivities of SBT to Pt and PR were 1.35 and 0.94 respectively. The chemical reaction of etched surface were investigated by X-ray photoelectron spectroscopy (XPS) analysis. The Sr and Ta atoms of SBT film react with fluorine and then Sr-F and Ta-F were removed by the physical sputtering of Ar ion. The surface of etched SBT film with CHF$_3$(Ar+CHF$_3$) of 0.1 was analyzed by secondary ion mass spectrometer (SIMS). Scanning electron microscopy (SEM) was used for examination of etched profile of SBT film under CHF$_3$(Ar+CHF$_3$) of 0.1 was about 85˚.85˚.˚.

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Study on CO2 Decomposition using Ar/CO2 Inductively Coupled Plasma (아르곤/이산화탄소 혼합가스의 유도 결합 플라즈마를 이용한 이산화탄소 분해 연구)

  • Kim, Kyung-Hyun;Kim, Kwan-Yong;Lee, Hyo-Chang;Chung, Chin-Wook
    • KEPCO Journal on Electric Power and Energy
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    • v.1 no.1
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    • pp.135-140
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    • 2015
  • Decomposition of carbon dioxide is studied using $Ar/CO_2$ mixture inductively coupled plasmas (ICP). Argon gas was added to generate plasma which has high electron density. To measure decomposition rate of $CO_2$, optical emission actinometry is used. Changing input power, pressure and mixture ratio, the plasma parameters and the spectrum intensity were measured using single Langmuir probe and spectroscope. The source characteristic of Carbon dioxide ICP observed from the obtained plasma parameters. The decomposition rate is evolved depending on the reaction and discharge mode. This result is analyzed with both the measurement of the plasma parameters and the dissociation mechanism of $CO_2$.

Control the Blow-off Characteristics of Lean Premixed Flames Utilizing a Stratified Flame Concept (성층화된 화염을 이용한 희박 예혼합화염의 날림 특성 제어)

  • Lee, Wonnam;Ahn, Taekook;Nam, Younwoo
    • Journal of the Korean Society of Combustion
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    • v.17 no.4
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    • pp.11-20
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    • 2012
  • The Blow-off characteristics of LPG/air lean pre-mixed flames were experimentally investigated using a double and a multiple concentric coflow burners. Experiments were conducted to understand the effects of recirculation motion, thermal interaction between flames, and stratified flame configuration. Here, the stratified premixed flame is a "new concept" of a flame that sequentially contains fuel rich, stoichiometric, and fuel lean reaction zones in a flame. The blow-off from a lean premixed flame was significantly suppressed with recirculation motion. The recirculation motion by itself, however, was not sufficient to prevent the blow-off when the equivalence ratio became low. The existence of a inner premixed flame could also help to prevent the blow-off of lean premixed flame; however, the blow-off suppression effect was rather diminished by weakened recirculation motion with the presence of inner flame. The inner flame could be separated from an outer flame on a multiple concentric coflow burner, causing recirculation motion as well as thermal interaction between flames to become effective; therefore, the blow-off was further suppressed. The lean premixed flame could be stabilized with a fuel rich premixed flames that was produced with the supply of fuel through an inner nozzle. The penetration of lean premixed gas from outside into the fuel stream produced a lifted rich premixed flame. Chemiluminescence images of OH, CH, and $C_2$ radicals confirmed the structure of a stratified premixed flame. The stable premixed flames could be obtained at the very fuel lean condition by applying the stratified premixed flame concept.

Adsorption Properties of SO$_2$ Using Fibrous Strong-base Anionic ion Exchange Scrubber (강염기성 음이온교환 섬유 스크러버를 이용한 SO$_2$의 흡착특성)

  • 황택성;최재은;강경석
    • Polymer(Korea)
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    • v.26 no.5
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    • pp.661-669
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    • 2002
  • The purpose of this research is to absorb and remove sulfur dioxide existing in the air by using ion exchange non-woven fabric. So we found out very appropriate condition of anionic exchange fabric scrubber by measuring amount of SO$_2$ adsorption under the atmosphere that concentration, velocity, and humidity was 100∼200 ppm, 0.6∼1.0 m/sec, and 30∼90 RH%, respectively. Ion exchange capacity of ion exchanger showed the maximum value, 3.75 meq/g at pH 4, and adsorption equilibrium time was the maximum value, 30 h when gas velocity was 0.6 m/sec, moreover, at 80$\^{C}$, adsorption equilibrium time tended to decrease more than 10 h. When concentration was 200 ppm, while reaction speed between SO$_2$ and ligand of fibrous ion exchanger was getting faster, adsorption break point had a tendency to get faster as well. In addition, when relative humidity in the scrubber was 90%, adsorption efficiency was 7.6%/h that seemed to be 30% higher than 4.6%/h coming from the condition that relative humidity had been 30%, and it was totally absorbed under 5 wt% NaOH solution in 5 minutes.

Development and Launching Test of 10N Class Liquid Propellant Rocket (10뉴턴급 추진력의 액체로켓 개발 및 발사시험)

  • Lee, Jung-Sub;Choi, Won-June;Kim, Min-Ki;Moon, Ki-Hyun;Song, Seong-Hwan;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.375-379
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    • 2008
  • In this paper, a 10N class liquid propellant rocket utilizing a dissolving reaction of hydrogen peroxide is constructed and tested. Through a series of designs, seven orifices with a diameter of 200 ${\mu}m$ and a nozzle with a neck of 2.5mm in diameter and area ratio of 2.56 were made. The platinum coated on Isolite was used for catalyst. 90wt% peroxide pressed at 20 bar by nitrogen gas was used for performance evaluation. The length of the catalyst bed and the load of platinum was taken as the parameters for this experiment. For the catalyst support length of 4cm loaded on 5wt% platinum, satisfactory $c^*$ efficiency and stable thrust was observed. The light weight body of the rocket was composed of aluminum. Rocket rose about 10m with relatively constant velocity in launching test.

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Study on Manufacture of High Purity TiCl4 and Synthesis of High Purity Ti Powders (고순도 TiCl4 제조 및 이를 활용한 고순도 Ti 분말 제조 공정 연구)

  • Lee, Jieun;Yoon, Jin-Ho;Lee, Chan Gi
    • Journal of Powder Materials
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    • v.26 no.4
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    • pp.282-289
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    • 2019
  • Ti has received considerable attention for aerospace, vehicle, and semiconductor industry applications because of its acid-resistant nature, low density, and high mechanical strength. A common precursor used for preparing Ti materials is $TiCl_4$. To prepare high-purity $TiCl_4$, a process based on the removal of $VOCl_3$ has been widely applied. However, $VOCl_3$ removal by distillation and condensation is difficult because of the similar physical properties of $TiCl_4$ and $VOCl_3$. To circumvent this problem, in this study, we have developed a process for $VOCl_3$ removal using Cu powder and mineral oil as purifying agents. The effects of reaction time and temperature, and ratio of purifying agents on the $VOCl_3$ removal efficiency are investigated by chemical and structural measurements. Clear $TiCl_4$ is obtained after the removal of $VOCl_3$. Notably, complete removal of $VOCl_3$ is achieved with 2.0 wt% of mineral oil. Moreover, the refined $TiCl_4$ is used as a precursor for the synthesis of Ti powder. Ti powder is fabricated by a thermal reduction process at $1,100^{\circ}C$ using an $H_2-Ar$ gas mixture. The average size of the Ti powder particles is in the range of $1-3{\mu}m$.

Effects of short-term fasting on in vivo rumen microbiota and in vitro rumen fermentation characteristics

  • Kim, Jong Nam;Song, Jaeyong;Kim, Eun Joong;Chang, Jongsoo;Kim, Chang-Hyun;Seo, Seongwon;Chang, Moon Baek;Bae, Gui-Seck
    • Asian-Australasian Journal of Animal Sciences
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    • v.32 no.6
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    • pp.776-782
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    • 2019
  • Objective: Fasting may lead to changes in the microbiota and activity in the rumen. In the present study, the effects of fasting on rumen microbiota and the impact of fasting on in vitro rumen fermentation were evaluated using molecular culture-independent methods. Methods: Three ruminally cannulated Holstein steers were fed rice straw and concentrates. The ruminal fluids were obtained from the same steers 2 h after the morning feeding (control) and 24 h after fasting (fasting). The ruminal fluid was filtrated through four layers of muslin, collected for a culture-independent microbial analysis, and used to determine the in vitro rumen fermentation characteristics. Total DNA was extracted from both control and fasting ruminal fluids. The rumen microbiota was assessed using denaturing gradient gel electrophoresis (DGGE) and quantitative polymerase chain reaction. Microbial activity was evaluated in control and fasting steers at various intervals using in vitro batch culture with rice straw and concentrate at a ratio of 60:40. Results: Fasting for 24 h slightly affected the microbiota structure in the rumen as determined by DGGE. Additionally, several microorganisms, including Anaerovibrio lipolytica, Eubacterium ruminantium, Prevotella albensis, Prevotella ruminicola, and Ruminobacter amylophilus, decreased in number after fasting. In addition, using the ruminal fluid as the inoculum after 24 h of fasting, the fermentation characteristics differed from those obtained using non-fasted ruminal fluid. Compared with the control, the fasting showed higher total gas production, ammonia, and microbial protein production (p<0.05). No significant differences, however, was observed in pH and dry matter digestibility. Conclusion: When in vitro techniques are used to evaluate feed, the use of the ruminal fluid from fasted animals should be used with caution.

Enhancement of Desulfurization System Efficiency in 1,000 MW Coal-Fired Power Plants (1,000 MW 석탄화력발전소 대기환경오염물질 제거효율 향상을 위한 탈황설비 성능개선)

  • Lee, Young-Su;Moon, Seung-Jae
    • Plant Journal
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    • v.17 no.2
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    • pp.32-41
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    • 2021
  • Recently, air environmental issues such as fine dust have rapidly emerged as national issues, and intensive environmental regulations are being applied to coal-fired power plants. This study introduces the case of improving the performance of desulfurization facilities for removing sulfur oxides and dust, which are the main air pollutant emitters of coal-fired power plants, and conducted four case studies to improve the performance of 1,000 MW power plants currently in operation and carried out construction. Liquid ratio was increased by remodeling the absorption tower of desulfurization facilities, and vaporization reaction was promoted by increasing the flow rate of oxidized air. In addition, the gas heater leakage rate was improved to improve the efficiency of final desulfurization facilities. It is expected that performance improvement work considering harmony with existing facilities will satisfy the regulations(25ppm of sulfur oxides, 5mg/Sm3) that will be applied from 2023, and can be referred to other thermal power plants for review and application.