• Title/Summary/Keyword: Reaction characteristic

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Micromachined DNA Manipulation Device Using Circular Multi-Electrodes (원형 다중전극을 이용한 DNA 조작소자)

  • Moon, Sang-Jun;Yun, Jae-Young;Lee, Seung-S.;Nam, Hong-Kil;Chi, Yeun-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.27 no.7
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    • pp.1071-1075
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    • 2003
  • In this paper, we present a DNA manipulation device in the reaction chamber, which consists of a center electrode and circular outer electrodes of a reaction unit. The charged bio-molecules, DNA, are manipulated by the charge of the electrode in reaction unit. Controlling the induced dynamic electric field between the center electrode and the outer electrodes, concentration / repulsion / manipulation of bio-molecules are enabled at a periphery of electrode. Concentration of the fluorescent DNA at the center electrode is observed by applying +2V. Subsequently, applying -2V, the concentrated DNA is repelled rapidly from the center electrode, which makes dispersion completely in 0.5second. Furthermore, repeated applying +1V/-1V every 5 seconds at each outer electrode, we can circulate the DNA. We also investigate a micro-heater and sensor for DNA manipulation and reaction temperature. The coefficient of heat-resistance and heater temperature characteristic is 0.0043 and 100$^{\circ}C$/sec, respectively.

Characteristic of heat storage/release in chemical heat pump using the calcined dolomite (소성 Dolomite를 이용한 화학열펌프내의 축·방열특성)

  • Hong, Min-Hyuk;Lee, Young-Sei;Choi, Hyun-Kuk;Park, Young-Hea;Kim, Jong-Shik
    • Journal of the Korean Society of Industry Convergence
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    • v.8 no.4
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    • pp.191-196
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    • 2005
  • This study was carried out to investigate the heat storage/release characteristics of the thermochemical reaction of the calcined dolomite with the packed bed shape experimental apparatus for development of chemical heat pump system. In the present study, it was found that MgO of the calcined dolomite was not hydrated during the hydration process under the experimental conditions. Therefore, the MgO of the calcined dolomite can be regard as an inert material. As a result, it was found that all of CaO packed kept the reaction temperature of about $510^{\circ}C$ through the entire part of the bed. The dehydration reaction was incurred first at the wall side area as the supplied heat was transferred through the wall side into the packed bed. As a result of the temperature and concentration spread, the reaction was completed at the wall side progressed into the center.

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A Quantitative Vigilance Measuring Model by Fuzzy Sets Theory in Unlimited Monitoring Task

  • Liu, Cheng-Li;Uang, Shiaw-Tsyr;Su, Kuo-Wei
    • Industrial Engineering and Management Systems
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    • v.4 no.2
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    • pp.176-183
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    • 2005
  • The theory of signal detection has been applied to a wide range of practical situation for a long time, including sonar detection, air traffic control and so on. In general, in this theory, sensitivity parametric index d' and bias parametric index $\beta$ are used to evaluated the performance of vigilance. These indices use observer's response "hit" and "false alarm" to explain and evaluate vigilance, but not considering reaction time. However, the reaction time of detecting should be considered in measuring vigilance in some supervisory tasks such as unlimited monitoring tasks (e.g., supervisors in nuclear plant). There are some researchers have used the segments of reaction time to generate a pair of probabilities of hit and false alarm probabilities and plot the receiver operating characteristic curve. The purpose of this study was to develop a quantitative vigilance-measuring model by fuzzy sets, which combined the concepts of hit, false alarm and reaction time. The model extends two-values logic to multi-values logic by membership functions of fuzzy sets. A simulated experiment of monitoring task in nuclear plant was carried out. Results indicated that the new vigilance-measuring model is more efficient than traditional indices; the characteristics of vigilance would be realized more clearly in unlimited monitoring task.

Influence of Changing Combustor Pressure on Combustion Characteristics and Reaction Zone in the Partially Premixed Flame with $CH_4$, $C_2H_4$ and $C_3H_8$ (부분 예혼합 화염에서 연소실 압력이 연료별($CH_4$, $C_2H_4$, $C_3H_8$) 연소특성과 반응영역에 미치는 영향)

  • Son, Je-Ha;Kim, Jong-Ryul;Choi, Gyung-Min;Kim, Duck-Jool
    • Journal of the Korean Society of Combustion
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    • v.16 no.3
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    • pp.33-40
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    • 2011
  • Combustion experiments were conducted at three different fuels ($CH_4$, $C_2H_4$ and $C_3H_8$) to investigate the effects of combustor pressure (30 ~ -30 kPa) on combustion charateristics and reaction zone structure. Regardless of the fuels, emission index of CO (EICO) increased with decreasing combustor pressure, and EICO of $C_2H_4$ was mostly affected by changing combustor pressure at subatmospheric pressure. In order to observe reaction zone, $OH^*$, $CH^*$ and ${C_2}^*$ chemiluminescence intensity were measured. The sequence of the chemiluminescence intensity peak position was affected by chemical characteristics of fuels rather than changing combustor pressure. The emission zone thickness of $C_2H_4$ and $C_3H_8$, defined by the full width at half maximum (FWHM) of $CH^*$ intensity profile, were increased with decreasing combustor pressure. however, the thickness of $C_2H_4$ exhibited the opposite tendency due to the characteristics of the fuel as the bond structure.

Computational Modeling of Cyclic Voltammetry on Multi-electron Electrode Reaction using Diffusion Model (확산모델을 이용한 다중전자 전극반응에 대한 순환전위법의 전산모델링)

  • Cho, Ha-Na;Yoon, Do-Young
    • Journal of the Korean Electrochemical Society
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    • v.15 no.3
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    • pp.165-171
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    • 2012
  • Here is implemented MATLAB program to analyze the characteristic curves of cyclic voltammetry which involves the multi-electron electrode reaction considered as key processes in electrochemical systems. For the electrochemical mass-transfer system, Fick's concentration equation subject to semi-infinite diffusion model for the boundary condition was discretized and solved by the explicit finite difference method. The resulting concentration values were converted into currents at each node by using Butler-Volmer equation. Based on the good agreement between the present numerical solution and the existing experimental results, effects of kinetic constants and CV scan rates on the reaction mechanism in multi-electron transfer processes were investigated effectively.

Synthesis of Nanocrystalline BaTiO3 Powder by the Combination of High Energy Ball Milling of BaCO3-TiO2 Mixture and Solid-State Reaction (고에너지 볼밀링된 BaCO3와 TiO2 혼합분말의 고상반응에 의한 나노결정 BaTiO3 분말 합성)

  • Ryu, Sung-Soo
    • Journal of Powder Materials
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    • v.19 no.4
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    • pp.310-316
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    • 2012
  • Nanocrystalline $BaTiO_3$ powder could be synthesized by solid-state reaction using the mixture which was prepared by a high energy milling process in a bead mill for $BaCO_3$ and nanocrystalline $TiO_2$ powders mixture. Effect of the milling time on the powder characteristic of the synthesized $BaTiO_3$ powder was investigated. Nanocrystalline $BaTiO_3$ with a particle size of 50 nm was obtained at $800^{\circ}C$. High tetragonal $BaTiO_3$ powder with a tetragonality(=c/a) of 1.009 and a specific surface area of $7.6m^2/g$ was acquired after heat-treatment at $950^{\circ}C$ for 2 h. High energy ball milling was effective in decreasing the reaction temperature and increasing the tetragonality.

A Study for Characteristic and Manufacturing of Porous Ni/AC4C and Ni-Cr/AC4C Composites (다공질 Ni 및 Ni-Cr으로 강화한 AC4C 복합재료의 제조 및 특성연구)

  • Kim, Young-Hyun;Kim, Eok-Soo;Yeo, In-Dong;Lee, Kwang-Hak
    • Journal of Korea Foundry Society
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    • v.20 no.1
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    • pp.21-28
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    • 2000
  • Ni and Ni-Cr porous metals which are estimated to be easy to fabricate by squeeze casting are used as strengtheners for composite materials. As a matrix material, Al-7%wtSi-0.3 wt%Mg(AC4C) has been used. In case of Ni/AC4C and Ni-Cr/AC4C composite, $750^{\circ}C$ melt temperature and minimum 25 MPa squeezing pressure are needed to produce sound composite materials. The observation of interfacial reaction zone at various heat treatment condition showed that solutionizing temperature of above 520^{\circ}C$, the interfacial reaction zone increased proportionally with increasing heat treatment tim and reaction products formed by interfacial reaction are mainly composed of $Al_3Ni$ and $Al_3Ni_2$ phases. The tensile strength of Ni/AC4C and Ni-Cr/AC4C composite is lower than the matrix metal and this can be explained by the brittle intermetallic compounds formed at the interface of Ni and Ni-Cr reinforcements. But the properies of hardness, wear resistance and thermal expansion are better than the matrix due to the strengthening effect of Ni-Cr porous metals.

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Low Temperature Bonding of Copper with Interlayers Coated by Sputtering(Part 1) (스퍼터링 코팅층을 중간재로 사용한 동(Cu)의 저온 접합(제1보))

  • Kim, Dae-Hun
    • 연구논문집
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    • s.24
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    • pp.63-79
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    • 1994
  • This article reports a experimental study of the method to achieve a bond joint at lower temperature in a short time. DC magnetron sputtering of Sn, Sn/Pb, Sn/In and Sn/Cu on copper substrate was provided as an interlayer for Cu to Cu bonding under the air environment. Various examination was conducted and investigated on the effect of experimental parameters such as coating materials, coating time(or coating thickness), bonding temperature and bonding time etc. Bonding was performed at the temperature of $210^\circC-320^\circC$ for 0sec and interfacial reaction between the coated layer and copper substrate was examined using optical, scanning electron microscope and x-ray diffractometer. From the obtained results, it was found that intermetallic compounds layer consisted of $\eta-phase(Cu_6Sn_5)$ and $\beta-phase(Cu_3Sn)$ was formed at the joint interface for almost all coating materials. But the dominant phase formed in the preetched Cu substrate coated with Sn was $\beta-phase$. A characteristic morphology looks like a reaction ring, which was believed as the strong interconnecting regions between two substrates, was found to be formed on the reaction surface of copper substrates. The morphologies and compositions of the intermetallics, which depends on the regions of the reaction surface, was appeared as greatly different. Based on above results, the new bonding process to make the joint at lower temperature for short time can be admitted as a feasible process.

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The Effect of Seepage Forces on the Ground Reaction Curve of Tunnel (침투력이 터널의 지반반응곡선에 미치는 영향)

  • Lee Seok-Won;Jung Jong-Won;Nam Seok-Woo;Lee In-Mo
    • Journal of the Korean Geotechnical Society
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    • v.21 no.3
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    • pp.87-98
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    • 2005
  • When a tunnel is excavated below groundwater table, the groundwater flows into the excavated wall of tunnel and seepage forces are acting on the tunnel wall. The ground reaction curve is defined as the relationship between internal pressure and radial displacement of tunnel wall. Therefore, the ground reaction curve is significantly affected by seepage forces. In this study, the theoretical solutions of ground reaction curves were derived for both the dry condition and the seepage forces. The theoretical solutions derived were validated by numerical analysis. The ground reaction curves with the support characteristic curve were also analyzed in various conditions of groundwater table. Finally, the theoretical solutions of the ground reaction curve derived in this study can be utilized easily to determine the appropriate time of support systems, the stiffness of support system and so forth for the reasonable design.

Catalytic Reactions of Ethanol and Acetaldehyde Over $TiO_2$-supported Gold Catalysts

  • Kim, Jeong-Jin;Kim, Yu-Gwon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.264-264
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    • 2012
  • As an environment-friendly alternative energy resource, ethanol may be used to obtain hydrogen, a clean energy source. Thus, studies on catalytic reactions involving ethanol have been studied to understand the underlying principles in the reaction mechanism using various oxide-supported catalysts. Among them, Au-based catalysts have shown a superior activity in producing hydrogen gas. In the present study, Au/$TiO_2$ catalysts were prepared by deposition-precipitation method to understand their catalytic activities toward ethanol and acetaldehyde with increasing gold loading, especially at the very low Au loading regime. A commercially available $TiO_2$ (Degussa P-25) was employed and the Au loading was varied to 0, 0.1, 0.5, and 1.0 wt% respectively. The catalysts showed characteristic x-ray diffraction (XRD) features at $2{\theta}=78.5^{\circ}$ that could be assigned to the presence of gold nanoparticles. Its reactivity measurements were performed under a constant flow of ethanol and acetaldehyde at a flow rate of ${\sim}0.6{\mu}mol/sec$ and the substrate temperature was slowly raised at a rate of 0.2 K/sec. We observed that the overall reactivity of the catalysts increased with increasing Au loading along with selectivity favoring dehydrogenation to product hydrogen gas. In addition, we disclosed various reaction channels involving competitive reaction paths such as dehydrogenation, dehydration, and condensation. In addition, subsequent reactions of acetaldehyde obtained from dehydrogenation of ethanol, were found to occur and produce butene, crotonaldehyde, furan, and benzene. Based on the results, we proposed overall reaction pathways of such reaction channels.

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