• Title/Summary/Keyword: Reaction Furnace

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A Experimental Study of Oxidation Kinetics for a Sub-Bituminous Coal Char (아 역청탄 촤 산화 반응속도론에 관한 실험적 연구)

  • Kang, Ki-Tae;Song, Ju-Hun;Lee, Chuen-Sueng;Chang, Young-June;Jeon, Chung-Hwan
    • Journal of Energy Engineering
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    • v.18 no.4
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    • pp.239-246
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    • 2009
  • A fundamental investigation has been conducted on the combustion of single particle of a sub-bituminous coal char burning at different temperatures and residence times. The lab-scale test setup consisted of a drop tube furnace where gas temperatures varied from $900^{\circ}C$ to $1400^{\circ}C$. A calibrated two color pyrometer, mounted on the top of the furnace, provided temperature profiles of luminous particle during a char oxidation. An amount of char mass reacted during the reaction is measured with thermogravimetry analyzer by using an ash tracer method. As a result, mass and area reactivity as well as reaction rate coefficients are determined for the char burning at atmospheric pressure condition.

Recovery of manganese compounds from electric arc furnace dust by Aluminothermy Process (테르밋 반응을 이용한 페로망간 전기로 분진의 재활용에 관한 연구)

  • Ha, Tae-Young;Jo, Young-Min;Park, Young-Koo;Kim, Youn-Che
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.23-30
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    • 2015
  • The properties of dust collected from electric arc furnace of ferro manganese production units was investigated, and also the metallic manganese was recovered from the dust by aluminothermy process. The ferromanganese dust collected from electric arc furnace contained about 15% of manganese oxide ($Mn_3O_4$) and 9% of carbon as the contaminant, and have a 5um of 50% median diameter and irregular particle shape. The carbon contaminant in the dust could be reduced until about 0.1~0.5% level by roasting in the air at a temperature of 600~900C for 60minutes. The recovery of manganese could not be carried out using only ferromanganese dust from electric arc furnace by aluminothermy process, but the ferromanganese which contained manganese of about 92% and iron of about 5% could be obtained from the mixture of ferromanganese dusts from electric arc furnace and converter. The best mixing condition of dust fixed at electric arc furnace dust / converter dust ratio of 1:9 and 2:8, and the mixing rato of 3:7 or more could not separated the metal and slag from the reactant after aluminothermy reaction.

Synthesis and Control of Ultrafine Particles by Ion-Injection in Furnace (반응로내 이온주입에 의한 초미세입자의 합성 및 응집제어)

  • Yoon, J.U.;Kim, Y.W.;Ahn, K.H.
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.91-96
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    • 2001
  • Ultrafine particles have been widely used in many high technology industrial areas. The spherical nonagglomerated and uniform nanometer-size $SiO_{2}$ particles are synthesized by the injection of TEOS vapor, ions and reaction gas in furnace. Ions were generated by Corona discharge electrode and these ions charge $SiO_{2}$ particles. As a result, spherical, nonagglomerated and ultrafine particles are generated in various conditions, it's morphology, charging portion and size distribution are examined by using TEM, ESP and SMPS. As the applied voltage of electrode changes from 0 kV to 5.0 kV, it is observed that the mean diameter of $SiO_{2}$ particle decreases from 94 nm to 42 nm.

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Numerical Simulation of NO Emission and Combustion Characteristics in Furnace (연소로에서 NO 배출 및 연소특성에 대한 수치해석적 연구)

  • 전영남
    • Journal of Korean Society for Atmospheric Environment
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    • v.12 no.5
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    • pp.577-585
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    • 1996
  • A screening study was performed in order to resolve the flow, combustion and emission characteristics of the gas furmace with co-axial diffusion flane burner. A control-valume based finite-difference method with the power-law scheme was employed for discretization. Numerical procedure for the differential equation was used by SIMPLEST to enclosute rapid converge. A k-.varepsilon. model was incorporated for the closure of turbulence. The mass fraction and mixture fraction were calculated by cinserved scalar method. An equilibrium analysis was employed to determine the concentration of radicals in the product stream and conserbation equations were them solved for N amd NO by Zelovich reaction scheme. The method was exercised in a simple one-dimensional case first, to determine the effects of air ratio, temperature and residence time on NO formation and applied to a furnace with co-axial diffusion flame burner.

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Corona ion Assisted Nano-Particle Morphology Control in an Atmospheric Pressure Furnace Reactor (대기압 반응로 내 코로나 이온을 이용한 나노입자 형상의 제어)

  • An, Gang-Ho;Yun, Jin-Uk;Kim, Yeong-Won
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.26 no.5
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    • pp.710-715
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    • 2002
  • The spherical nonagglomerated and uniform nanometer-size SiO$_2$particles are synthesized by the injection of TEOS vapor, irons and reaction gas in a furnace. Ions are generated by corona discharge and these ions charge SiO$_2$particles. As a result, spherical, nonagglomerated and ultrafine particles are generated in various conditions. Their morphology, charging portion and size distribution are examined by using TEM, ESP and SMPS. As the applied voltage of electrode changes from 0 to 5.0 kV, it is observed that the melon diameter of SiO$_2$particle decreases from 94 nm to 42 nm.

Fining of Flint Glass Melts Containing Blast Furnace Slag

  • Kim, Ki-Dong
    • Journal of the Korean Ceramic Society
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    • v.44 no.11
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    • pp.618-621
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    • 2007
  • In this study, flint glass batches with blast furnace slag (BFS) were prepared and the contribution of the BFS to the fining of melts was studied through investigations of the melting and fining characteristics. Additionally, a sulfur redox reaction for BFS-doped melts was examined by square wave voltammetry (SWV). The results of the melting & fining test showed that BFS improved the fining of the melts. In a voltammogram of BFS-doped melts, two reduction peaks were shown at high frequencies while only one peak appeared at low frequencies. The peaks were located at a potential that was similar to those of melts fined by sulfate. From those results it was concluded that sulfide ($S^{2-}$) in BFS has effects in glass melts that are identical to those of sulfate ($SO_4^{2-}$).

The Effect of Hybrid Reburning on NOx Reduction in Oxygen-Enriched LPG Flame (산소부화 LPG 화염에서 혼합형 재연소 방법에 의한 NOx 저감 효과)

  • Lee, Chang-Yeop;Baek, Seung-Wook
    • Journal of the Korean Society of Combustion
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    • v.12 no.4
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    • pp.14-21
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    • 2007
  • In order to enhance combustion efficiency, oxygen-enriched combustion is used by increasing the oxygen ratio in the oxidizer. However, since the flame temperature increases, NOx formation in the furnace seriously increases for low oxygen enrichment ratio. In this case, reburning is a useful technology for reducing nitric oxide. In this research, experimental studies have been conducted to evaluate the hybrid effects of reburning/selective non-catalytic reaction (SNCR) and reburning/air staging on NOx formation and also to examine heat transfer characteristics in various oxygen-enriched LPG flames. Experiments were performed in flames stabilized by a co-flow swirl burner, which were mounted at the bottom of the furnace. Tests were conducted using LPG gas as main fuel and also as reburn fuel. The paper reported data on flue gas emissions, temperature distribution in furnace and various heat fluxes at the wall for a wide range of experimental conditions. Overall temperature in the furnace, heat fluxes to the wall and NOx generation were observed to increase by low level oxygen-enriched combustion, but due to its hybrid effects of reburning, SNCR and Air staging, NOx concentration in the exhaust have decreased considerably.

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A Study on the Effect of Initial Strength of Cement Paste Containing Fly Ash or Blast Furnace Slag on CO2 Curing Period (플라이 애쉬 및 고로슬래그 혼입 시멘트 페이스트의 CO2 양생 기간에 따른 초기강도의 영향에 대한 연구)

  • Han, Jae-Do;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.11a
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    • pp.83-84
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    • 2018
  • As the concentration of greenhouse gases in the atmosphere increases, the reduction of CO2 is gaining worldwide attention. In the construction industry, cement replacement materials such as fly ash and blast furnace slag were investigated to reduce CO2 emissions in cement production process. Precast concrete is used in the field after manufacturing in the factory in the form of pipes and bricks because of shortening construction period and cutting construction cost. According to the results of previous research, it is known that early CO2 curing in concrete using OPC or fly ash has an initial strength enhancement effect and can be used for precast concrete production. Therefore, the purpose of this study is to evaluate the strength improvement effect by confirming the initial strength improvement effect when blast furnace slag is mixed.

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An Experimental Study on the Characteristics of Microporous Structure Formation by Curing Condition of Cement and Blast Furnace Slag Composite (시멘트 및 고로슬래그 경화체의 양생환경에 따른 미세 공극구조 형성 특성에 관한 실험적 연구)

  • Park, Cheol;Jung, Yeon-Sik;Seo, Chee-Ho
    • Journal of the Architectural Institute of Korea Structure & Construction
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    • v.33 no.12
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    • pp.63-70
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    • 2017
  • When industrial by-products like slag and fly ash are using in concrete with cement, it improves strength and durability against external deterioration factors by densifying the structure through potential hydraulic and pozzolanic reaction. But it has been pointed out that high dependence on the quality variation and the curing condition using a admixure material for concrete. In this study, the characteristics of internal micropore structure according to curing condition were analyzed for pastes and mortar specimens under using blast furnace slag powder. As a result, the variation of compressive strength and the internal microstructure were observed according to curing conditions by binder type. Particularly, using blast furnace slag powder, decrease in compressive strength were clearly observed in indoor and carbonation curing compared with water curing. The pore structure analysis also clearly observed the decrease of the gel pore existing in the CSH hydrate layer and the increase of the capillary pore in indoor and carbonation curing compared with water curing condition.

Process Technology of the Direct Separation and Recovery of Iron and Zinc Metals Contained in High Temperature EAF Exhaust Gas

  • Furukawa, Takeshi;Sasamoto, Hirohiko;Isozaki, Shinichi;Tanno, Fumio
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.393-397
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    • 2001
  • The innovatory process, that is the direct separation and recovery of the iron and zinc metals contained in the high temperature exhaust gas generated from the electric arc furnace fer the inn scrap melting and/or the dust treatment, has been proposed. This proposed process consists of the moving coke bed filter that is directly connected to the electric furnace, and the following heavy metal condenser. The exhaust gas passes through the filter and the condenser right after exhausting from the electric furnace. The moving coke bed filter is being controlled at about 1000℃ and collects iron and slag components contained in the high temperature exhaust gas. Heavy metals such as zinc and lead pass through the filter as vapor. Based on the thermodynamic considerations, the iron oxide and the zinc oxide are reduced in the filter. The solution loss reaction rate is comparatively low at about 1000℃ in the coke bed filter by the analysis using the mathematical simulation model. The heavy metal condenser is installed in the position after the coke bed filter, and rapidly cools the gas from about 1000℃ to 450℃ by a full of the cooling medium like the solid ceramic ball in addition to the cooling from the wall. The zinc and lead vapor condense and separate f개m the gas in a liquid state. The investigation of the characteristics of the exhaust gas of the commercial electric arc furnace, the fundamental experiments of the laboratory scale and the bench scale ensured the formation of this proposed process. A small-scale pilot plant examination is carrying out at present to confirm the formation of the process. It is certain that the dust generation of the electric arc furnace is extremely decreased, and it can save the energy consumption of usual dust treatment processes by the realization of this process.

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