• Title/Summary/Keyword: Reaction Furnace

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An Experimental Study on Alkali-Silica Reaction of Alkali-Activated Ground Granulated Blast Furnace Slag Mortars (알칼리 활성 고로슬래그 미분말 모르터의 알칼리-실리카 반응에 관한 실험적 연구)

  • Kim, Young-Soo;Moon, Dong-Il;Lee, Dong-Woon
    • Journal of the Korea Institute of Building Construction
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    • v.11 no.4
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    • pp.345-352
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    • 2011
  • The purpose of this study was to investigate the expansion of alkali-activated mortar based on ground granulated blast furnace slag containing reactive aggregate due to alkali-silica reaction. In addition, this study was particularly concerned with the behavior of these alkaline materials in the presence of reactive aggregates. The experimental program included expansion measurement of the mortar bar specimens, as well as the determination of the morphology and composition of the alkali-silica reaction products by using scanning electron microscopy(SEM), and energy dispersive x-ray(EDX). The experiment showed that while alkali-activated ground granulated blast furnace slag mortars showed expansion due to the alkali-silica reaction, the expansion was 0.1% at Curing Day 14, showing that it is safe. After the accelerated test, SEM and BEM analysis showed the presence of alkali-silica gel and rim around the aggregate and cement paste. According to the EDX, the reaction products decreased markedly as alkali-activated ground granulated blast furnace slag was used. In addition, for the substitutive materials of mineral admixture, a further study on improving the quality of alkali-activated ground granulated blast furnace slag is needed to assure of the durability properties of concrete.

Prediction of Transient Slab Heating Characteristics in a Walking Beam Type of Reheating Furnace

  • Han Sang-Heon;Baek Seung-Wook
    • 한국전산유체공학회:학술대회논문집
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    • 2006.05a
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    • pp.405-407
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    • 2006
  • A full-scale simulation of steel mill reheating furnace was performed by using parallel computing technology. Turbulent flow as well as chemical reaction is considered and solved in a coupled manner while radiation is also calculated. The movement of slab is taken into account so that a more precise observation of its heating characteristics becomes possible through this numerical analysis.

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Effect of Curing Temperature on Geopolymeric Polycondensation of Blast Furnace Slag (고로슬래그의 지오폴리머 축중합반응에 미치는 양생온도의 영향)

  • Jeon, Chang-Seob;Song, Tae-Woong
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.610-616
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    • 2011
  • The effect of curing temperature on basic geopolymeric reactivity and hardening behaviour of blast furnace slag were investigated using the mixture of pulverized slag and several alkaline solutions of relatively high concentration. For the pastes prepared at several different temperatures between 20$^{\circ}C$ and 90$^{\circ}C$, setting time and heat of reaction were examined while mineralogical and morphological examinations were performed for the hardened paste after curing period at same temperature. The geopolymeric reaction of slag was revealed to be accelerated strongly according to the curing temperature regardless of the sort and concentration of the alkaline solution. The increase of concentration of the alkaline solution within 9M and the existence of silicic ion in the solution also promoted the reaction severely. The mineral component and their ratio of the hardened paste were revealed to be influenced by the chemical species and silicic ion contained in alkaline solution rather than by the curing temperature. The higher temperature and longer period of curing stage were effective for the sustained formation of geopolymer and succeed improvement of density and uniformity of morphology of the final hardened body.

Hydraulic Reaction Analysis of C3A in Ordinary Portland Cement with Mineral Additions by Rietveld Method (리트벨트법에 의한 혼합재 첨가 보통 포틀랜드 시멘트 중 C3A 수화반응 해석)

  • Lim, Young-Jin;Lee, Seung-Heun;Cho, Jae-Woo
    • Journal of the Korean Ceramic Society
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    • v.51 no.2
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    • pp.82-87
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    • 2014
  • Due to the revised Korean standard KS L 5201 for Ordinary Portland Cement (OPC), the use of mixed cement has grown from 5% to 10%. This study investigates the hydration behavior of $C_3A$, asit is a cement mixture that is more commonly used than granulated blast furnace slag or limestone alone. Paste samples were prepared with either granulated blast furnace slag or limestone alone. Each sample was compared with the widely used Rietveld method with a cement mixture containing blast furnace slag or limestone. The hydration behavior of $C_3A$ in each OPC sample was assessed and results were analyzed. Granulated blast furnace slag promotes a high initial level of ettringite, but as the days passed, it promotes an increase in monosulfate, leading to cracks and expansion due to the penetration of sulfates in the solution. However, when limestone is added to the mixture, a transformation of ettringite to monosulfate occurs in the presence of the $CaCO_3$ in the limestone. It is considered that this produces hemi-carbonate and mono-carbonate and thus maintains the ettringite level.

A Study of the Strength and Durability Properties on Recycled Aggregate Concrete and Blain of Blast Furnace Slag (고로슬래그의 분말도 및 순환골재 치환율에 따른 콘크리트의 강도 및 내구적 특성에 관한 연구)

  • Lim, Myung-Kwan;Park, Moo-Young;Jung, Sang-Jin
    • Journal of the Korea Institute of Building Construction
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    • v.7 no.4
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    • pp.101-108
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    • 2007
  • Furnace slag powder used currently in Korea needs to add special functions in response to the increase of large-scale projects. In addition, it is advantageous in that it has a lower hydration heat emission rate than ordinary Portland cement and improves properties such as the inhibition of alkali aggregate reaction, watertightness, salt proofness, seawater resistance and chemical resistance. However, furnace slag powder is not self -hardening, and requires activators such as alkali for hydration. Accordingly, if recycled fine aggregate, from which calcium hydroxide is generated, and furnace slag, which requires alkali stimulation, are used together they play mutually complementary roles, so we expect to use the mixture as a resource-recycling construction material. Thus the present study purposed to examine the properties and characteristics of furnace slag powder and recycled aggregate, to manufacture recycled fine aggregate concrete using furnace slag and analyze its performance based on the results of an experiment, to provide materials on concrete using furnace slag as a cement additive and recycled fine aggregate as a substitute of aggregate, and ultimately to provide basic materials on the manufacturing of resource-recycled construction materials using binder and fine aggregate as recycled resources.

A Study on the Hydration Property of Mortar with Balst Furnace Slag using Water Eluted from Recycled Coarse Aggregates (순환골재 용출수를 활용한 고로슬래그 미분말 혼입 모르터의 강도특성)

  • Shin, Sang-Yeop;Jeong, Euy-Chang;Kim, Young-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2012.11a
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    • pp.81-82
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    • 2012
  • The purpose of this study is the hydration properties of motar using Blast-Furnace Slag(BFS) with water elured from recycled coarse aggregate. The results of the experiment show that the water eluted from recycled coarse aggregate mixed with blast furnace slag has comparatively higher hydration activity than the mortar not mixed with one in early-age mortar causing the calcium hydroxide in the recycled coarse aggregate to work on as a stimulus to the hydration of ground granulated blast furnace slag. BFS mixed with the eluting water the hydration reaction was a promotion.

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Surface Reaction between Phosphate bonded $SiO_2$ Investment and Ti-Zr-(Cu) based Alloys for Dental castings (인산염계 $SiO_2$ 주형재와 치과주조용 Ti-Zr-(Cu)계 합금의 계면반응)

  • Joo, Kyu-Ji
    • Journal of Technologic Dentistry
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    • v.27 no.1
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    • pp.57-63
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    • 2005
  • Experimental Ti-13%Zr and Ti-13%Zr-5%Cu alloys were made in an argon-arc melting furnace. The grade 2 CP Ti was used to control. To investigate the surface reaction layers produced by the reaction with mold materials and the influence of the reaction layers on the hardness of castings, A phosphate bonded $SiO_2$ base investment was used as mold material, and microstructure observation and hardness test were performed. The surface reaction layers of Ti-13%Zr and Ti-13%Zr-5%Cu alloys were thinner than that of CP Ti had a clearly multiple structure. A difference of the hardness between surface and inner of the Ti-13%Zr and Ti-13%Zr-5%Cu alloys became less than that of CP Ti. From the results, it was found that the Ti-Zr-(Cu) based alloys were possible to cast with $SiO_2$ base investment without the great changes of mechanical properties of the castings.

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Hydration Properties of Ordinary Portland Cement Using Mixture of Limestone and Blast Furnace Slag as Minor Inorganic Additives (소량 혼합재로서 석회석과 고로슬래그를 복합 사용한 보통 포틀랜드 시멘트의 수화특성)

  • Lee, Seung-Heun;Lim, Young-Jin;Cho, Jae-Woo
    • Journal of the Korea Concrete Institute
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    • v.27 no.1
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    • pp.3-9
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    • 2015
  • In this study, hydration properties of ordinary Portland cement were examined, shown from a limestone and blast furnace slag alone or their mixture up to 10% as a minor mineral additives. As of setting time, it was identified that final setting became faster as the amount of limestone mixture increased, which showed limestone accelerated early hydration faster than blast furnace slag. This is because limestone did accelerate the hydration of alite. At the age of 3 days, limestone 5%-blast furnace slag 5% mixture had the highest compressive strength of mortar. It is because hydration acceleration of alite by limestone, and $Ca(OH)_2$ that was additionally formed by hydration acceleration of alite reacted with blast furnace slag, and as a result, additionally created C-S-H hydrate. Regarding the hydration properties by the age of 7 and 28 days, limestone 3%-blast furnace slag 7% of composited mixture showed the largest compressive strength, and in comparison with the 3 days in curing age. This period is when hydration reaction of blast furnace slag is active and the amount of hydrate depends on the amount of blast furnace slag mixture more than that of the limestone mixture. And in order to vitalize hydration reaction of blast furnace slag the amount of $Ca(OH)_2$ created has to increase, and thus, a small amount of limestone is necessary that can accelerate the hydration of alite. Therefore, after the age of 7 days, the fact that there were a large amount of blast furnace slag mixture and small amount of limestone mixture was effective to the strength development of ordinary Portland cement.

Global analysis of heat transfer in Si CZ furnace with specular and diffuse surfaces

  • Hahn, S.H.;Tsukada, T.;Hozawa, M.;Maruyama, S.;Imaishi, N.
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1998.06a
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    • pp.45-48
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    • 1998
  • For the single crystal growth of silicon, a global analysis of heat transfer in a CZ furnace was carried out using the finite element method, where the radiative heat transfer between the surfaces that possess both specular and/or diffuse reflectance components was taken into account, and then the effect of the specular reflection of the crystal and/or melt on the CZ crystal growth was numerically investigated.

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