• Title/Summary/Keyword: Rate of Substitution

Search Result 547, Processing Time 0.033 seconds

Remaining Strength of Fireproof Mortar using the Oyster Shell as a Fine Aggregate (굴 패각을 잔골재로 활용한 내화모르타르의 잔존강도 특성)

  • Jung, Ui-In;Kim, Bong-Joo
    • Journal of the Korea Institute of Building Construction
    • /
    • v.17 no.5
    • /
    • pp.411-418
    • /
    • 2017
  • This study classified oyster shells that produced as a industrial waste into 3 distribution by washing, drying and processing them. Mortar specimens with a constant ratio by using this to substitute fine aggregates were made, and the specimens were heated under the heating conditions of $300^{\circ}C$, $600^{\circ}C$ and $900^{\circ}C$ based on the 28-day age. On the age of 28 days, the plain flexural strength was found to be 9.2MPa, and in O 0.15, it was shown to be 4.4~7.9MPa depending on the substitution rate. It was found to be 4.4~7.7MPa in O 1.2~2.5 depending on the substitution rate, and last but not least, it was shown to be 6.1~8.8MPa in case of O 2.5~5.0 depending on the substitution rate. In case of the compressive strength of the 28-day age, it showed the difference of 23.6~43.2MPa in O 0.15 depending on the substitution rate, and 20.4~45.1MPa in O 1.2~2.5 depending on the substitution rate, and last but not least, 17.1~40.4MPa in case of O 2.5~5.0. As a result of measuring the residual strength through heating, in case of substituting fine aggregates less than O 0.15 by 100%, it showed the lowest strength reduction ratio, and it is expected that the heat-resisting property could be achieved through processing and proper mixing of oyster shells through these results.

Implementation of morphologica analyzer and spelling corrector for charcter recognition post-processing (문자 인식 후처리를 위한 형태소 분석기와 문자 교정기의 구현)

  • 이영화;김규성;김영훈;이상조
    • Journal of the Korean Institute of Telematics and Electronics C
    • /
    • v.34C no.5
    • /
    • pp.82-92
    • /
    • 1997
  • In this paper, we propose post-rpocessing method that corrects a misrecognized character by generated a characater recognizer using morphological analyzer and spelling corrector. The proposed post-processing consists of sthree phases : First, our method pass through morhological analyzer which only outputted necessary information for spelling correcting, doesn't analyze a bundle of phrases, and detects the location of misrecognized character. Second, tagging the generated candidate character using the information of character substitution table and grapheme substitution/separating table. Then we retry analysis after the misrecognition character has been substituted. Finally we select table, we investigate misrecognized charcters in CORPUS. Reliability analysis used to frequency of randomly selected about 100,000 words in CORPUS. A korean character recognizer demonstrates 93% correction rate without a post-processing. The entire recognition rate of our system with a post-processing exceeds 97% correction rate.

  • PDF

XRD Analysis of Portland Limestone Cement Paste (포틀랜드 석회석 시멘트에 관한 XRD 분석)

  • Bang, Mi-Jin;Shin, Ki-Su;Park, Ki-Bong
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 2018.05a
    • /
    • pp.189-190
    • /
    • 2018
  • This study produced Portland limestone cement at the rate of limestone substitution by grinding limestone and clinker together, and it conducted an XRD analysis to determine the sign language response structure as a basic study on Portland Limestone Cement. As a result of the XRD analysis, the higher the substitution rate of limestone, the more likely it is that the detection rate of ettringite is decreased. Additionally, we could see that the production volume of Mono-carbonate was increasing.

  • PDF

The Effect of Solvation and Polarizability on the $\alpha$-Effect: Nucleophilic Substitution Reactions of p-Nitrophenyl Benzoate with Various Anionic Nucleophiles

  • Um Ik-Hwan
    • Bulletin of the Korean Chemical Society
    • /
    • v.13 no.6
    • /
    • pp.632-636
    • /
    • 1992
  • Second-order rate constants have been determined spectrophotometrically for nucleophilic substitution reactions of p-nitrophenyl benzoate with various anionic nucleophiles including 6 ${\alpha}$ -effect nucleophiles. The logarithmic second-order rate constants for the aryloxides give a good Bronsted correlation with the respective basicity while the ones for p-chlorothiophenoxide and hydroxide exhibit significantly positive and negative deviations, respectivity, from the Bronsted linear line. The deviations are attributed to a solvation effect rather than a change in the reaction mechanism. The ${\alpha}$-effect nucleophiles except highly basic ones demonstrate significantly higher nucleophilicity (the ${\alpha}$ -effect) than would be predicted from the respective basicity. The effect of solvation and polarizability appears to be important for the ${\alpha}$-effect as well as for the reaction rate.

Study on the Effect of Fineness and Substitution Rate of Natural Zeolites on Chemical Reaction and Physical Properties of Cement Mortar (천연 제올라이트의 분말도와 치환율이 시멘트모르타르의 화학반응 및 물리적 특성에 미치는 영향에 관한 연구)

  • Yoon, Chang-Bok;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
    • /
    • v.24 no.3
    • /
    • pp.96-103
    • /
    • 2020
  • As a basic study for the application of natural zeolite as a concrete admixture, the compressive strength, activity factor, Ca(OH)2 quantitative analysis and XRD experiments were investigated. It is thought that SiO2, which is abundant in natural zeolite, affects the strength development by reacting with the hydration product of cement in all specimens in which natural zeolite was added according to powder level and substitution rate. As the substitution rate increases, the compressive strength decreases, which is considered to be due to the decrease in the amount of C3S and C2S minerals in the clinker, which affects the strength expression compared to the cement content of the reference mortar. The XRD crystal structure did not show a significant difference from the reference mortar, and it was confirmed that the Z2-10 (Blaine: 15,600㎠ / g) specimen with 10% substitution of natural zeolite was the best among the experimental levels. Substitution amount for use as concrete admixture is 10% substitution is most ideally seen.

A Study on Properties of Sound Absorbing Materials with Characteristics of Exhaust-gas Purge (배기가스를 정화하는 흡음재의 특성에 관한 연구)

  • 이승한;황보광수;장석수
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 2001.05a
    • /
    • pp.935-940
    • /
    • 2001
  • This study search for absorbing sound and exhaust-gas which aims to manufacture continuous void by using clay and foam, the surface of materials is covered with $TiO_{2}$ powder as heat treatment. According to the results of the experiment, the increase of thickness of manufactured sound absorbing materials caused the increase of absorption rate in the range of low and middle sound and thus it can be an important factor of improving absorption rate. Sound absorbing materials could satisfy 70% of the average of sound absorption ratio in 7cm thickness. Also, the manufactured sound absorbing materials is covered with $TiO_{2}$ showed an excellency in the clarification of exhaust-gas under ultraviolet rays treatment when 70% of removal rate and about 10% of generation rate of $NO_{2}$ is settled by the flow of 2 $\ell$/min NO gas. Especially, manufactured sound absorbing materials could improve compressive strength of continuos porous concrete. in the case of 7% bubble addition, when the substitution rate of coagulator was 30% and 20%, compressive strength was 45kgf/$cm^{2}$ and 65kgf/$cm^{2}$ respectively. As the substitution rate of coagulator reducing, compressive strength increased after preforming burnt clay.

  • PDF

Nucleophilic Substitution Reaction of Dansyl Chloride with Substituted Anilines$^1$

  • Han, Sung-Bin;Sung, Dae-Dong;Lee, Ik-Choon
    • Bulletin of the Korean Chemical Society
    • /
    • v.6 no.3
    • /
    • pp.162-164
    • /
    • 1985
  • Nucleophilic substitution reaction of dansyl chloride with anilines in various solvents have been investigated. The Bronsted ${\beta}$ and Hammett ${\rho}_N$ values indicated that the bond formation is advanced more than the bond breaking at the transition state. Solvatochromic correlations also predicted the importance of bond formation at the TS, showing a greater contribution of polarity (${\pi}^{\ast}$) compared to hydrogen bond donor acidity (${\alpha}$). The effect of solvent on rate was found to violate the reactivity-selectivity principle.

Enhanced Spectral Hole Substitution for Improving Speech Quality in Low Bit-Rate Audio Coding

  • Lee, Chang-Heon;Kang, Hong-Goo
    • The Journal of the Acoustical Society of Korea
    • /
    • v.29 no.3E
    • /
    • pp.131-139
    • /
    • 2010
  • This paper proposes a novel spectral hole substitution technique for low bit-rate audio coding. The spectral holes frequently occurring in relatively weak energy bands due to zero bit quantization result in severe quality degradation, especially for harmonic signals such as speech vowels. The enhanced aacPlus (EAAC) audio codec artificially adjusts the minimum signal-to-mask ratio (SMR) to reduce the number of spectral holes, but it still produces noisy sound. The proposed method selectively predicts the spectral shapes of hole bands using either intra-band correlation, i.e. harmonically related coefficients nearby or inter-band correlation, i.e. previous frames. For the bands that have low prediction gain, only the energy term is quantized and spectral shapes are replaced by pseudo random values in the decoding stage. To minimize perceptual distortion caused by spectral mismatching, the criterion of the just noticeable level difference (JNLD) and spectral similarity between original and predicted shapes are adopted for quantizing the energy term. Simulation results show that the proposed method implemented into the EAAC baseline coder significantly improves speech quality at low bit-rates while keeping equivalent quality for mixed and music contents.

An Experimental Study on the Flow Characteristics of Mortar using the Blast-Furnace Slag Sand (서냉슬래그 모르터의 FLOW특성에 관한 연구)

  • 임남기;이종균;김성식;김종락;정상진
    • Proceedings of the Korea Concrete Institute Conference
    • /
    • 1998.10c
    • /
    • pp.54-59
    • /
    • 1998
  • This experimental Study presents the flow properties of mortar Using the Blast-furnace Slag Sand. It gives following result. The substitution rate is inversely proportional to flow. But W/C ratio is directly proportional to flow. Consequently Flow characteristics of the Blast-furnace mortar is simillar to the river sand mortar.

  • PDF

A Study on the Properties of Recycled Concrete Using Recycled Fine Aggregates with different Removal formulas of Powder In Aggregate (미분 제거방식이 다른 2종의 재생 잔골재가 콘크리트외 특성에 미치는 영향)

  • Lee Mun-Hwan;Lee Sea-Hyun;Shim Jong-Woo
    • Journal of the Korea Concrete Institute
    • /
    • v.17 no.1 s.85
    • /
    • pp.95-104
    • /
    • 2005
  • The research conducted to study the potential practicability of recycled aggregate concrete by analyzing the characteristics of concretes made of recycled quality aggregates produced by wet and dry process has found the following results. The air content of recycled aggregate concrete increased with increase of the substitut on rate due to mortar included while producing recycled aggregates. However, the concretes with aggregate produced by dry process had relatively low rate of increase in air content. The slump showed generally decreasing trend as the substitution rate of recycled aggregate increased regardless of the wet or dry process. It was assumed that the mortar particles remained in recycled aggregate absorbed the surplus hydration in concrete and decreased fluidity The compressive strength generally decreased as the substitution rate of recycled aggregate increased, however there was an increasing trend as well due to decreasing effect of water-cement ratio when the substitution rate of recycled aggregate reached 25, 50% after mix. This phenomena also appeared in early age, which meant that recycled aggregate concrete should not be retarded in setting when applied in the field. The tensile strength also reached the maximum when wet or dry recycled aggregate replaced with 25%. To conclude, recycled aggregates for concrete produced by wet or dry process are expected to demonstrate essential characteristics of concrete without significant decline in physical or dynamic quality when the substitution rate is below 25% although there are variations subject to water-cement ratio. However, slight differences are expected due to types of recycled aggregate and physical quality.