• 한국전기화학회:학술대회논문집
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• 2002.11a
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• pp.57-65
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• 2002

The presence of tetragonal phase at the surface of $LiMn_2O_4$ pinicle due to a Jahn-Teller offset was previously reported to be one of the causes for capacity fading observed during cycling of $Li//Li_xMn_2O_4$ in 4V range. Further, it is reported that a Jahn-Teller effect in 4V range may be suppressed by substitution of Mn ions with Li ions or other transition metal ions. However, the direct evidence of the suppression of a Jahn-Teller effect in 4V range by substitution of Mn ions with other metal ions has not been reported. The dissolution and formation of surface film at the surface of $LiMn_2O_4$ electrodes also reportedly affect the capacity fading or rate capability. This study reports on the evidence of the onset and suppression of a Jahn-Teller effect in 4V range and the dissolution and formation of surface film at the surface of $LiMn_2O_4$ thin film electrodes using in situ bending beam method (BBM) in situ electrochemical quartz crystal microbalance (EQCM).

• Transactions of the Korean Society of Automotive Engineers
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• v.17 no.2
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• pp.171-179
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• 2009

An object of this study is to confirm application characteristics of the vortex tube apparatus for substitution of the intercooler in a common-rail diesel engine. The turbo pressure, the intake air mass flow rate and the charging air cooling ratio of the intercooler were measured in an experimental engine. The vortex tube apparatus was made after confirmation of the geometric phenomena in fundamental experiments. The vortex tube designed with fundamental data was applied to a conventional common-rail diesel engine instead of the intercooler. Its application characteristics, engine performances and emissions were investigated. From this experimental results, we suggested the vortex tube can be applied to a conventional common-rail diesel engine throughout extra complement. We can also expect the higher cooling effect, if we consider the application of the vortex tube in supercharging diesel engine without the intercooler.

• Journal of Fisheries and Marine Sciences Education
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• v.20 no.1
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• pp.78-89
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• 2008

This study is intended to analyse the economic sensitivity of imported fishery products due to decrease in or elimination of tariff rates through the progress of free trade. Forty-seven species of fishes were selected for this study on the basis of the HS Code. The substitution and price effects were calculated using the price elasticities of both domestic and imported demands for fishery products under the assumption of 5% decrease in a tariff rate. Seven main economic variables were extracted from the fishery industry which can mediate the substitution and price effects. A multiple regression analysis was conducted to obtain the influence weights of these main economic variables on both effects. The order of sensitivity of the fishes was calculated using these weights. The 47 fish species were classified into four groups according to their sensitivity based on the means and the standard deviations of their total scores on seven main economic considerations. Nine fish species such as squids, hair tails, shellfishes, and crabs belonged to the hyper-sensitive group, whereas 15 fishes such as eels, sea breams, and sea weeds belonged to the sensitive group. Twelve species including common sea basses, cods, and abalones were among the less-sensitive group, and 11 species including skate rays and mud fishes comprised the non-sensitive group.

• Proceedings of the Microbiological Society of Korea Conference
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• 2006.05a
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• pp.129-131
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• 2006

Through molecular phylogenetic analysis using the nef gene sequences of HIV-l isolated from Korean registered in the NCBI GenBank together with 41 reference strains and 94 foreign isolates, we verified that most (${\sim}80%$) of Korean isolates belonged to subtype B and 78% of subtype B were clustered together exclusively of foreign isolates, and this cluster was named Korean clade subtype B ($K_cB$). Similarity study suggested that the $K_cB$ cluster was more homogeneous than and clearly distinctive from the non-Korean subtype B ($NK_cB$). Comparison of the consensus amino acid sequences of the $K_cB\;or\;NK_cB$ revealed characteristic $K_cB$ signature amino acid pattern comprised of 13 amino acid residues. The $K_cB$ signature amino acid residues were critical in separating the $K_cB$ ftom the $NK_cB$, since substitution of the $NK_cB$ sequences with $K_cB$ signature amino acids relocated them to the Koran clade, and vice versa. Synonymous and nonsynonymous substitution rate study suggested positive selection event for the $K_cB$.

• Bulletin of the Korean Chemical Society
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• v.25 no.2
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• pp.203-206
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• 2004

The kinetics of reactions between Z-aryl thiophene-2-carbodithioates and X-pyridines in acetonitrile at 60.0 $^{\circ}C$ have been investigated. The Bronsted plots obtained for the pyridinolysis of aryl thiophene-2-carbodithioates are curved, with the center of curvature at $pK_a$ ~ 5.2 ($pK_a^{\circ}$). The Bronsted plots for these nucleophilic reactions show a change in slope from a large ( ${\beta}_X{\cong}$0.78-0.87) to a small ( ${\beta}_X{\cong}$0.33-0.35) value, which can be attributed to a change in the rate-determining step from breakdown to formation of a zwitterionic tetrahedral intermediate in the reaction path as the basicity of the pyridine nucleophile increases. A clear-cut change in the crossinteraction constants, ${\rho}_{XZ}$, from +0.92 to -0.23 supports the proposed mechanistic change. The breakpoint at $pK_a$ = 5.2 for R = thiophene ring in the present work is in agreement with those for the pyridinolysis of R = Me and 2-furyl, and attests to the insignificant effects of acyl group, R, on the breakpoint.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.43 no.2 s.344
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• pp.13-17
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• 2006

Pentacene channel for organic thin film transistor was deposited on the SiOC film by thermal evaporation. The growth of pentacene is related with the Diels-Alder reaction and the nucleophilic reaction by the thermal induction. The surface is an important factor to control the recursive Diels-Alder reaction for growing of pentacene on SiOC far The terminal C=C double bond of pentacene molecule was broken easily as a result of attack of the nucleophilic reagents on the surface of SiOC film. The nucleophilic reaction can be accelerated by increasing temperature on surface, and it maks pentacene to grow hardly on the SiOC film with a flow rate ratio of $O_2/(BTMSM+O_2)=0.5$ due to its inorganic property. The nucleophlic reaction mechanism is $SN_2(bimolecular nucleophilic substitution)$ type.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2022.04a
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• pp.17-18
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• 2022

Carbon dioxide emissions in the construction sector account for 38% of all industries, and environmental destruction is occurring due to indiscriminate use of natural resources. The purpose of this study is to develop by-product aggregate Non-Sintered Cement(NSC) that can replace sand used as natural aggregate and Portland cement. Therefore, Ground Granulated Blast Furnace Slag, Type C Fly Ash and Type F Fly Ash are used to replace cement, and water granulated ferro-nickel slag(FNS) is used to replace aggregate. The flow, compressive strength and flexural strength of the formulation using sand as an aggregate and the formulation replacing 100% FNS were compared. As a result of the experiment, the formulation using FNS had higher overall strength than the formulation using sand, and as the substitution rate of Type C fly ash increased, the strength was the best. Formulation using FNS is more fluid than using sand. Through this study, we show the possibility of 100% substitution of FNS and its applicability to secondary concrete products of by-product aggregate NSC.

• The Journal of the Acoustical Society of Korea
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• v.21 no.2
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• pp.160-166
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• 2002

In this paper, we implement a new vocabulary-independent speech recognition system that uses CV, VCCV, VC recognition unit. Since these recognition units are extracted in the trowel region of syllable, the segmentation is easy and robust. And in the case of not existing VCCV unit, the units are replaced by combining VC and CV semi-syllable model. Clustering of vowel group and applying combination rule to the substitution model in the case of not existing of VCCV model lead to 5.2% recognition performance improvement from 90.4% (Model A) to 95.6% (Model C) in the first candidate. The recognition results that is 98.8% recognition rate in the second candidate confirm the effectiveness of the proposed method.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.37 no.6B
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• pp.453-463
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• 2012

The Effect of asymmetric interconnection charge is different between where the retail price of incumbent is regulated and that of incumbent is not regulated. When the retail price of incumbent is not regulated, the brand loyalty and the relative magnitude of each marginal cost determine the effect of consumer surplus. However, when the retail price of incombent is regulated, network substitution effect also plays a important role to the consumer surplus. The higher the brand loyalty, the lower the network substitution effect, or the higher the marginal cost of the entrant, the social welfare through the asymmetric interconnection charge is more increased. In the other cases, the consumer surplus might be decreased.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.287-288
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• 2012

In this study, Analyzed the effect of the change in RFA and RCA substitution rate on the concrete containing BS bonding materials but no cement. The findings are as follows. First, the fresh concrete has less slump value and air contents as more RFA and RCA is used. In case of hardened concrete, as more RFA and RCA are used, the higher the compressive strength of concrete becomes. Especially, the compressive strength of concrete which used recycled aggregates only is found to be 2.2 times as high as that of concrete using natural fine and coarse aggregates only. But if the concrete is to be used as the structural concrete having the compressive strength of 13.8 MPa, the alkaline materials and some cement are required to be added.