• Title/Summary/Keyword: Rare earth material

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Electrical properties of the ZnO varistors with the amount of rare-earth metal oxide addition (희토류 금속 산화물 첨가에 따른 ZnO varistor의 전기적 특성)

  • Cho, Hyun-Moo;Lee, Jong-Deok;Park, Sang-Man
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.336-337
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    • 2005
  • ZnO varistor ceramics were fabricated as a function of the amount of $Y_2O_3$ addition and sintered at $1250^{\circ}C$ for 2 hour. The average grain size was decreased from 14.2 ${\mu}m$ to 8.3 ${\mu}m$ with the amount of $Y_2O_3$ addition, and varistor voltage was increased from 433 V to 563 V with $Y_2O_3$ addition. Nonlinear coefficient a of all specimens were increased with the amount of $Y_2O_3$ more than 67, in case of $Y_2O_3$ 0.01wt% addition showed the excellent results of 87. And leakage current was less than $1{\mu}A$ at 82% of varistor voltage. The clamping voltage ratio of the specimens added 0.01wt% $Y_2O_3$ was 1.41 at 25A [8/20${\mu}s$]. At the specimen 0.01wt% $Y_2O_3$ addition. endurance of surge current and deviation of varistor voltage were 5700A/$cm^2$ and $\Delta$-2.86%, respectively.

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Photoluminescence properties of oxy-fluoride glass-ceramics of La2O3-CaF2-Al2O3-SiO2 system (La2O3-CaF2-Al2O3-SiO2 계 oxy-fluoride 결정화 유리의 광 발광 특성)

  • Ha, Taewan;Kang, Seunggu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.2
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    • pp.84-88
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    • 2021
  • The change of the photoluminescence properties of La2O3-CaF2-Al2O3-SiO2 glass-ceramics doped with rare earth material, that is used as laser and optical sensors, was analyzed according to heat treatment temperature. The heat treatment conditions for fabricating glass-ceramics were obtained through non-isothermal thermal analysis, and X-ray diffraction analysis was performed to determine the degree of crystal growth and kinds of crystal phases generated according to the heat treatment temperature. Using Scherrer's equation, it was predicted that crystals with a size of 25~40 nm would be generated inside the glass-ceramics. Photoluminescence (PL) analysis showed that the specimens heat-treated at 660℃ to 670℃ for 1 hour had the highest PL intensity. Also, from the CIE color coordinate analysis, all glass-ceramics specimens emitted red-orange light regardless of the heat treatment condition.

Synthesis of Yttria Stabilized Zirconia Powder with Rare Earth Using Oxalate Method (옥살산법을 이용하여 희토류를 첨가한 안정화 지르코니아 분말 합성)

  • Nam, Jeong Sic;Lee, Ji-Sun;Lee, Young-Jin;Jeon, Dae-Woo;Kim, Sun-Woog;Ra, Yong-Ho;Kim, Sae-Hoon;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.32 no.2
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    • pp.174-177
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    • 2019
  • The traditional yttria-stabilized zirconia (YSZ) used in thermal barrier coatings has a limited operating temperature owing to densification and volume changes at high temperatures. A $(La_{1-x}Y_x)_2Zr_2O_7$ sintered compound was prepared by the co-precipitation and oxalate methods, by adding lanthanum zirconate to yttria. The thermal properties and crystallinity obtained by the two different methods were compared. Both methods yielded pyrochlore structures, and the oxalate method confirmed phases at low temperatures. The thermal conductivity of the sintered bulk prepared by co-precipitation was 0.93 W/mK, while that prepared by the oxalate method was 0.85 W/mK. These values are superior to that of 4YSZ at $1,000^{\circ}C$, which is widely used in industries.

Mixed rare earth $(Nd_{1/3}Eu_{1/3}Gd_{1/3})Ba_2Cu_3O_{7-d}$ thin films by PLD (PLD법에 의한 혼합된 희토류계$(Nd_{1/3}Eu_{1/3}Gd_{1/3})Ba_2Cu_3O_{7-x}$ 고온 초전도 박막)

  • Ko, Rock-Kil;Bae, Sung-Hwan;Jung, Myung-Jin;Jang, Se-Hoon;Song, Kyu-Jeong;Park, Chan;Sohn, Myung-Hwan;Kang, Suk-Ill;Oh, Sang-Soo;Ha, Dong-Woo;Ha, Hong-Soo;Kim, Ho-Sup;Kim, Young-Cheol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.05a
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    • pp.3-3
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    • 2009
  • In order to investigate the possibility of using mixed rare earth $(Nd_{1/3}Eu_{1/3}Gd_{1/3})Ba_2Cu_3O_{7-x}$ (NEG123) as the superconducting layer of the HTS coated conductor, the NEG123 thin film was deposited epitaxialy on LAO(100) single crystal and IBAD_YSZ metal templates by pulsed laser deposition. Systematic studies were carried out to investigate the influences of deposition parameters of PLD on the micro structure, texture and superconducting properties of NEG-123 coated conductor. Deposition at oxygen partial pressure of 600 mTorr was needed to routinely obtain high quality NEG123 films with $J_c$'s (77K) over 2 MA/$cm^2$ and Tc's over 90K (${\Delta}T{\sim}2\;K$). We verified from magnetization study that the NEG123 has an improved in-field Jc as the field increases at temperatures between 10 K and 77 K compared with Gd123. The $J_c$ (77K, self field) and the value of onset $T_c$ of NEG123 thin film on LAO substrate was $4.0MA/cm^2$ and 92K, respectively. This is the first report, to the best of our knowledge, of coated conductors with NEG123 film as the superconducting layer which have Ic and Jc over 40 A/cm-width and 1.6 MA/$cm^2$ at 77K, self field. This study shows the possibility of using NEG123 film as the superconducting layer of the HTS coated conductor which can be used in high magnetic field power electric devices.

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Recent Research Trend of the $Sm_2Fe_{17}N_X$ Magnetic Materials (최근 $Sm_2Fe_{17}N_X$ 자성재료의 연구동향)

  • 정전헌일;족립금야
    • Electrical & Electronic Materials
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    • v.8 no.6
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    • pp.811-815
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    • 1995
  • 회토류계 영구자석은 종래의 Ferrite계나 Alnico계와 비교해서 대단히 강하여, 전기전자부품의 소형화에 크게 기여하고 있다. 최근에는, 전자기기산업 이외의 분야에 있어서도 그의 응용이 확대되어가고 있는 추세로 자성재료의 생산액은 매년 증가하고 있다. 회토류계 영구자석재료의 연구는 1960년대에 시작되어 Sm $Co_{5}$, Sm$_{2}$ $Co_{17}$ 화합물의 등장을 거쳐 현재는 1982년데 Sagawa 및 Croat가 독자적으로 발견한 Nd$_{2}$ Fe$_{14}$B 자석이 주류로 되고 있다. 그렇지만 이 화합물에는 다른 영구자석에 비하여 큐리온도가 낮은 결점이 있어서, 아직도 새로운 화합물의 탐색이 계속되고 있다. 그 중에서도, 1990년대에 Coey에 의해서 최초로 학회지에 보고되어진 Sm$_{2}$Fe$_{17}$N$_{x}$는, Nd$_{2}$Fe$_{14}$B와 같은 정도의 이론 최대에너지급, Sm $Co_{5}$에 대등한 거대한 이방성자장, 750K에 달하는 큐리온도등의 우수한 성질을 갖고 있어 Nd$_{2}$Fe$_{14}$B를 극복하는 자성재료로서 큰 기대가 되어진다. 되어진다.진다.

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Structural and temperature coefficient of resistance characteristics of colossal magnetoresistance Mn oxides prepared by RF sputtering

  • Choi, Sun-Gyu;Ha, Tae-Jung;Reddy, A.Sivasankar;Yu, Byoung-Gon;Park, Hyung-Ho
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.361-361
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    • 2007
  • A lot of efforts have been paid to develop infrared imaging systems in last decades. Bolometer has a wide range of applications from military to commercial, such as military night vision, medical imaging system and so on. Bolometer is a resistive sensor that detects temperature changes through resistance change. To improve detecting ability, bolometer should have a good resistive film which has high temperature coefficient of resistance (TCR) value. Colossal magnetoresistance (CMR) $L_{1-x}A_xMnO_3$ (where L and A are trivalent rare-earth ions and divalent alkaline earth ions, respectively.) are received attention to apply bolometer resistive film because it has a high TCR property which was discovered in the metal to semiconductor phase transition temperature region. In this work, CMR films were deposited on various substrates in relative low substrate temperature by RF magnetron sputtering. The influence of deposition parameters such as substrate temperature, gas partial pressure, and so on have been studied. The structural and TCR properties of the films were also investigated for applying to microbolometer.

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Nonlinear Properties of ZnO Varistors Doped with Rare earth Oxides (희토류 산화물이 첨가된 ZnO 바리스터의 비직선 특성)

  • Park, Jong-Ah;Lee, Hong-Hee;Kim, Myung-Jun;Ryu, Jung-Sun;Nahm, Choon-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07b
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    • pp.747-750
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    • 2003
  • The microstructure and nonlinear properties of ZPCMR-based varistors were investigated with various additives. The density of varistors were gradually decreased for the same R in order of NiO, MgO, and $Cr_2O_3$, respectively. The ZPCR-based varistors were not affected by NiO and MgO additives in nonlinear properties, whereas greatly affected by $Cr_2O_3$. Among the ZPCCR-based varistors, ZPCCD varistor exhibited the highest nonlinear properties, in which the nonlinear exponent is in the range of $40.5{\sim}67.4$ and the leakage current is in the range of $1.2{\sim}2.7{\mu}A$.

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Eutectic Nanocomposites for Thermophotovoltaic Application

  • Han, Young-Hwan;Lee, Jae-Hyung;Kakegawa, Kazuyuki
    • Transactions on Electrical and Electronic Materials
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    • v.11 no.6
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    • pp.249-252
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    • 2010
  • The ground amorphous powder was consolidated into a dense sintered body with a typical ultrafine $Al_2O_3-GdAlO_3$ eutectic structure by spark plasma sintering (SPS). Sintered material with ultrafine and dense eutectic structure was obtained by an appropriate combination of rapid quenching and SPS at lower temperature and more quickly than by conventional sintering. The $Al_2O_3$-based rare earth eutectic ceramics for solar cell emitters are believed to have a higher efficiency and the $Al_2O_3$ based eutectic ceramics with ultrafine grains will be one of the promising materials showing excellent selective emitter characteristics.

The Influence of Re2O3(RDy, Er) on the Electromagnetic Properties of Mn-Zn Ferrite (Re2O3(RDy, Er)가 Mn-Zn ferrite의 전자기적 특성에 미치는 영향)

  • 백승철;최우성
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.2
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    • pp.178-183
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    • 2002
  • The effects of Dy$_2$O$_3$and Er$_2$O$_3$addition on the electromagnetic properties of Mn-Zn ferrite were investigated in the doping concentration range from 0.05 wt% to 0.25 wt%. All samples were prepared by standard fabrication of ferrite ceramics. The XRD patterns of sample were observed spinel and secondary phase. The densities of sample were showed nearly constant values. As the increased additive, electrical resistivity, initial permeability and real component of the series complex permeability increased with setting limits each other. Excess doped with Dy$_2$O$_3$ and Er$_2$O$_3$, those values decreased. The maximum electrical resistivity was observed with 0.15 we% and initial permeability was observed with 0.05 wt%. Magnetic loss decreased with additive and then increased in proportion to increased.

The fabrication of europium complex electroluminescence using BCP as hole blocking layer

  • Liang, Yujun;Zhang, Hongjie;Kim, Beung-Kwon;Jung, Young-Ho;Park, Jo-Yong;Myung, Kwang-Shik;Khatkar, S.P.;Han, Sang-Do
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.11a
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    • pp.578-580
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    • 2002
  • A bright and highly monochromatic red organic electroluminescent device based on a poly(N-vinylcarbazole) host was made. The device structure consists of poly(N-vinylcarbazole) dispersed with a europium complex as an emitting layer and a hole blocking layer of 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline (BCP). The EL cell exhibited just characteristic emission of europium ion.

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