• Title/Summary/Keyword: RED-II

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Synthesis, chemically and electrochemically polymerization of N-substituted pyrrole containing azo chromophore and its copolymerization with pyrrole

  • Hosseini, Seyed Hossein
    • Advances in materials Research
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    • v.1 no.4
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    • pp.299-310
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    • 2012
  • This article describes the synthesis of a novel N-substituted pyrrole monomer containing an azobenzene group. The 2-[N-ethyl-N-[4-[(4-nitrophenyl) azo]-phenyl] amino] ethyl-3-chloropropionate (RedII) compound was synthesized via reaction of 4-nitro-4'-[N-ethyl-N-(2-hydroxyethyl)-amino] azobenzene (RedI) and 3-chloropropionic acid. RedII was reacted with the potassium salt of pyrrole then 2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate (Py-RedII) was prepared. Chemical polymerization of Py-RedII and copolymerization of Py-RedII with pyrrole carried out using $FeCl_3$. Poly (2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate) (PPy-RedII) was characterized by UV, IR, $^1HNMR$, $^{13}CNMR$ spectroscopies. Electropolymerization of Py-RedII and electroco-polymerization of Py-RedII and pyrrole were studied using conventional three electrodes system, Ag/AgCl reference electrode, platinum counter electrode and GC disk working electrode. Scanning electron microscopy (SEM), thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC) were used for thermal and rheological studies. The TGA curve of PPy-RedII demonstrated a high thermal stability up to 200°C and its DSC thermogram showed two endothermic peaks at 88 and $122^{\circ}C$. The glass transition temperature of the polymer was found to be above the room temperature. Electrical conductivities of PPy-RedII and it's copolymer with pyrrole (PPy-RedII-co-Py) were studied by the four-probe method and produced conductivities of $7.5{\times}10^{-4}$ and $6.5{\times}10^{-3}Scm^{-1}$, respectively.

Considerations in Midface Distraction Osteogenesis Using RED (Rigid External Distraction) II System for Successful Treatment (Rigid External Distraction (RED) II system을 이용한 중안면부 골 신장술시의 고려사항)

  • Yang Il-Hyung;Baek Seung-Hak;Nahm Dong-Seok
    • Korean Journal of Cleft Lip And Palate
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    • v.7 no.2
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    • pp.107-121
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    • 2004
  • Midface and maxillary distraction osteogenesis (DO) can be an alternative treatement modality for the craniofacial syndrome patients and cleft lip and palate patients. Rigid External Distraction (RED) II system has more advantages in the force vector control than the other types of distraction systems. Despite of increasing popularity of RED system there is few report on the failure factors. Some considerations should be pointed out in using RED II system for successful treatment; the rigidity of intraoral splint, complete separation of bony segment, and the cooperation of patients. Orthodontists, surgeons, and patients have the same amount of responsibility for the successful midface and maxillary DO using RED II system from the beginning to the end of the treatment.

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Assessment of Smoke Risk of Combustible Materials in Fire (화재 시 가연성 물질의 연기 위험성 평가)

  • Chung, Yeong-Jin;Jin, Eui
    • Applied Chemistry for Engineering
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    • v.31 no.3
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    • pp.277-283
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    • 2020
  • The smoke hazard assessment of building materials focusing on smoke performance index-II (SPI-II) and smoke growth index-II (SGI-II) was investigated. The test species used were Japanese cedar, spruce, lauan, and red pine. The smoke characteristics of wood specimen were investigated using a cone calorimeter (ISO 5660-1). SPI-II was measured after the combustion reaction increased by 1.31~2.15 times based on red pine. The fire risk by SPI-II increased in the order of spruce, lauan, Japanese ceda, and red pine. SGI-II increased by 1.18~2.55 times compared to that of Japnese ceda. The fire risk caused by SGI-II increased in the order of Japanese ceda, spruce, lauan, and red pine. COmean concentrations were ranged from 58 to 133 ppm, which was higher than permissible exposure limits of the occupational safety and health administration (OSHA), 50 ppm. Therefore, woods such as red pine containing various volatile organic substances, were considered to be highly smoke hazardous due to low SPI-II and high SGI-II.

Red Ginseng Ethanol Extract Suppressed Ag I/II-induced Up-expression of Inflammatory Mediators in RAW 264.7 Macrophages (홍삼에탄올추출물의 염증유발인자에 대한 억제효과)

  • Choi, Kyung-Min;Hwang, Seung-Mi;Lim, Ji-Ye;Ko, Eun-Sil;Park, Jong-Hyuk;Moon, Jung-Hye;Lee, Min-Jung;Jang, Ji-Eun;Cha, Jeong-Dan
    • Microbiology and Biotechnology Letters
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    • v.43 no.2
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    • pp.158-163
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    • 2015
  • In this study, we investigated the effects of 40% ethanol extract of Red Ginseng (RGE) on the productions of inflammatory proteins in Antigen I/II (Ag I/II)-N, a recombinant protein isolated from Streptococcus mutans -stimulated in RAW 264.7 cells. RGE inhibited the expression of Ag I/II-N-induced pro-inflammatory mediators, both mRNA and protein synthesis levels, without any cytotoxic effects. Moreover, RGE significantly inhibited Ag I/II-N induced NF-κB translocation into the nucleus by preventing the degradation of inhibitor κB-α. In conclusion, RGE down regulates the expression of pro-inflammatory genes involved in the synthesis of NO and iNOS in Ag I/II-N-stimulated RAW 264.7 cells by suppressing NF-κB activity.

Gas Liquid Chromatographic Analysis of Fatty Acids in Ginseng Products (Gas Liquid Chromatography에 의한 인삼(人蔘) 제품(製品) 중의 지방산(脂肪酸) 분석(分析))

  • Yoon, Tai-Heon;Kim, Eul-Sang
    • Korean Journal of Food Science and Technology
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    • v.11 no.3
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    • pp.182-187
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    • 1979
  • Six commercial ginseng products, red ginseng, white ginseng I and II, red ginseng extract, white ginseng extract I and II were extracted with ethyl ether. Total fatty acid composition of the extracted free lipids was analyzed by gas liquid chromatography and digital integrator was used to measure the area of each peak. Crude lipid contents of red and white ginsengs were similiar. Those of red ginseng extract, white ginseng extract I and II were 1.10, 1.13 and 0.40%, respectively. It was found that 22 kinds of fatty acids existed in red and white ginsengs. Among them, 16 kinds of even numbered fatty acids were identified. Linoleic acid in red and white ginsengs was the most abundant. The contents of that in red ginseng, white ginseng I and II were 63.33, 45.55 and 41.06%, respectively. The next most abundant acid was palmitic acid, the contents of which were 11.30, 14.4 and 18.10% for red ginseng, white ginseng I and II, respectively. Major fatty acids for red ginseng extract and white ginseng extract I were linoleic and palmitic acids in the same order of magnitude. Linoleic and palmitic acids for red ginseng extract were 15.93 and 15.71 %, respectively, while linoleic and palmitic acids for white ginseng extract I were 21.94 and 19.15%, respectively. However, white ginseng extract II contained only 9.21% of linoleic acid and 16.13% of palmitic acid which was the major fatty acid.

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Effect of Red Ginseng with Processed Sulfur Extracts on Serum Lipids Concentration and Metabolic Variables in Diabetic Rats (홍삼의 법제유황 처리가 당뇨쥐의 혈중지질 및 대사지표물질에 미치는 영향)

  • Han, Hyun-Jung;Kim, Hae-Ja;Chong, Myong-Soo;Cho, Hwa-Eun;Choi, Yun-Hee;Lee, Ki-Nam
    • The Korea Journal of Herbology
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    • v.24 no.1
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    • pp.89-98
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    • 2009
  • Objectives : The purpose of this study was to evaluate effects of processed sulfur with red ginseng on streptozotocin(STZ) induced diabetic rats for expansion of processed sulfur internal application. Methods : We prepared red ginseng with non processed sulfur extracts(GS), red ginseng with processed sulfur I extracts(GPS I) and red ginseng with processed sulfur II extracts(GPS II). In the present study, we examined about contents of crdue saponin, antioxidant activity, $\alpha$-glucosidase inhibitory activity, and effects of STZ induced diabetic rats. Results : Contents of crude saponin increased by processed sulfur, and GPS II was shown highest contents in crude saponin and sulfur compared with another groups. Electron donating ability of GPS II was shown highest activity compared with GS and GPS I, SOD-like activity showed same tendency as electron donating ability at 1 $mg/m\ell$ concentration. Inhibitory activity of $\alpha$-glucosidase was approximately same level in acarbose and GPS II. Blood glucose level of GPS II group was decreased 18.34% compared with DC(diabetes control) group and maintained stability range in glucose level. but GS and GPS I showed high level compared to GPS II. Serum triglycerides concentration also showed lowest level in GPS II. The activity of ALT, AST and ALP was shown high level in diabetic induced groups, and lowest level in GPS II. Creatinine was shown non-significantly difference in each groups and GPS II was shown lowest level in BUN. Conclusions : These results suggested that processed sulfur with red ginseng have improvement effects on diabetes and internal application of processed sulfur with red ginseng have no specific toxicity in liver and kidney.

Comparative Study on Cytochrome Oxidase of Rat Muscle Tissues (쥐 근조직의 Cytochrome Oxidase에 대한 비교 연구)

  • Song, Eun-Sook
    • The Korean Journal of Zoology
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    • v.29 no.1
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    • pp.70-74
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    • 1986
  • Cytochrome oxidase activities have been compared from crude sumibitochondrial preparations of rat skeletal muscle tissues. Fast red (type $II_A$) preparation has highest cytochrome oxidase activity, slow red (type I) next, and fast white (type $II_B$) the lowest. Differences of electrophoretic mobilities have been detected by heme staining. Migration of heme band is in the order of slow red>fast red>fast white from fastest to slowest. Results of immunoelectrophoresis have substantiated the above finding.

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Antitoxic Effect of Korean Red Ginseng Extract on Serum Protein of Mouse Treated with Methyl Mercury (생쥐의 혈청 단백질에 미치는 메틸수은 독성에 대한 홍삼 추출물의 해독 효과)

  • Chung, Hee-Won
    • The Korean Journal of Ecology
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    • v.9 no.4
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    • pp.193-200
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    • 1986
  • In order to investigate the antiotoxic effect of red ginseng extract on serum protein of mouse treated with methyl mercury playing a role as toxic contaminant in ecosystem, variations of the serum protein contents, electrophoretic patterns, and blood components were studied. Mice were divided into 3 groups: Control, group I treated only with methyl mercury, and group II treated together with methyl mercury and red ginseng extract. The total serum protein content of the control group was 5.8g/dl and those of groups I and II were slightly decreased as compared with the control. The control group showed 11 serum protein fractions and groups I and II showed 10 fractions except prealbumin. The amounts of albumin, ${\alpha}_1-$, ${\alpha}_2-$ globulin fractions were decreased and those $\beta$-, $\gamma$-globulin fractions were increased in groups I and II. The amount of each serum protein fraction in group II showed approximately the same level as the control. The hematocrit value and the number of white blood cells of groups I and II were increased, whereas the number of red blood cells showed the decrease as compared with the control.

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Study on the Use of Orchargrass-Red Clover mixture II. Effect of seed rate of orchargrass-red clover on herbage yield and quality (Orchargrass-Red Clover 혼파이용에 관한 연구 II. Orchargrass-Red Clover 파종비율이 목초의 수량과 품질에 미치는 영향)

  • 이인덕;이형석
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.12 no.4
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    • pp.211-217
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    • 1992
  • This experiment was conducted over a 3-year period (1990-1992) to evaluate the production and quality of orchardgrass (Potomac)-red clover (Kenland) mixture when orchardgrass + red clover mixture was sown at seed rates of 20+0. 18+2, 16+4, 14+6 and 12+8 kg/ha. Total herbage dry matter, crude protein and digestible organic matter production and organic matter intake were markedly affected by increasing rcd clover seed rate, those increased with increasing red clovcr seed rate due to the cnhancernent of red clover percentage of total herbagc in all 3-year. but significant differences occured between the orchardgrass alone and orchardgrass-red clover mixture with a seed rate of 4,6 and 8 kg/ha red clover (P<0.01). But on the other hand increasing red clover seed rate increased red clover percentage in total herbage, the mean red clover percentage of total herbage at the last cutting ranged from 54 to 65% in first year. 58 to 60% in second year, and 62 to 69% in third year, particularly it was observed that red clover was sown at seed rates of 6 and 8 kg/ha for red clover sown dominated strongly as the cutting times were progressed. Considering the maintenance of good botanical composition balance and the enhancement of production and quality of herbage, the optimized seed rate for orchardgrass-red clover mixtures, 16 kg/ha orchardgrass and 4 kg/ha red clover seems to be considered adequate.

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