• 제목/요약/키워드: RED-II

검색결과 658건 처리시간 0.035초

Synthesis, chemically and electrochemically polymerization of N-substituted pyrrole containing azo chromophore and its copolymerization with pyrrole

  • Hosseini, Seyed Hossein
    • Advances in materials Research
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    • 제1권4호
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    • pp.299-310
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    • 2012
  • This article describes the synthesis of a novel N-substituted pyrrole monomer containing an azobenzene group. The 2-[N-ethyl-N-[4-[(4-nitrophenyl) azo]-phenyl] amino] ethyl-3-chloropropionate (RedII) compound was synthesized via reaction of 4-nitro-4'-[N-ethyl-N-(2-hydroxyethyl)-amino] azobenzene (RedI) and 3-chloropropionic acid. RedII was reacted with the potassium salt of pyrrole then 2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate (Py-RedII) was prepared. Chemical polymerization of Py-RedII and copolymerization of Py-RedII with pyrrole carried out using $FeCl_3$. Poly (2-[N-ethyl-N-[4-[(nitro phenyl) azo] phenyl] amino] ethyl-N-pyrrolyl propionate) (PPy-RedII) was characterized by UV, IR, $^1HNMR$, $^{13}CNMR$ spectroscopies. Electropolymerization of Py-RedII and electroco-polymerization of Py-RedII and pyrrole were studied using conventional three electrodes system, Ag/AgCl reference electrode, platinum counter electrode and GC disk working electrode. Scanning electron microscopy (SEM), thermogravimetry analysis (TGA) and differential scanning calorimetry (DSC) were used for thermal and rheological studies. The TGA curve of PPy-RedII demonstrated a high thermal stability up to 200°C and its DSC thermogram showed two endothermic peaks at 88 and $122^{\circ}C$. The glass transition temperature of the polymer was found to be above the room temperature. Electrical conductivities of PPy-RedII and it's copolymer with pyrrole (PPy-RedII-co-Py) were studied by the four-probe method and produced conductivities of $7.5{\times}10^{-4}$ and $6.5{\times}10^{-3}Scm^{-1}$, respectively.

Rigid External Distraction (RED) II system을 이용한 중안면부 골 신장술시의 고려사항 (Considerations in Midface Distraction Osteogenesis Using RED (Rigid External Distraction) II System for Successful Treatment)

  • 양일형;백승학;남동석
    • 대한구순구개열학회지
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    • 제7권2호
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    • pp.107-121
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    • 2004
  • Midface and maxillary distraction osteogenesis (DO) can be an alternative treatement modality for the craniofacial syndrome patients and cleft lip and palate patients. Rigid External Distraction (RED) II system has more advantages in the force vector control than the other types of distraction systems. Despite of increasing popularity of RED system there is few report on the failure factors. Some considerations should be pointed out in using RED II system for successful treatment; the rigidity of intraoral splint, complete separation of bony segment, and the cooperation of patients. Orthodontists, surgeons, and patients have the same amount of responsibility for the successful midface and maxillary DO using RED II system from the beginning to the end of the treatment.

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화재 시 가연성 물질의 연기 위험성 평가 (Assessment of Smoke Risk of Combustible Materials in Fire)

  • 정영진;진의
    • 공업화학
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    • 제31권3호
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    • pp.277-283
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    • 2020
  • 본 연구는 건자재용 목재의 연기 유해성평가에 대하여 연기성능지수-II (SPI-II), 연기성장지수-II (SGI-II)를 중심으로 조사하였다. 시험편은 삼나무, 가문비나무, 나왕, 적송을 사용하였다. 연기 특성은 시험편 목재에 대하여 콘칼로리미터(ISO 5660-1) 장비를 이용하여 조사하였다. 연소반응 후 측정된 연기성능지수-II는 적송을 기준으로 1.31~2.15배 증가하였다. 연기성능지수-II에 의한 화재위험성은 가문비나무, 나왕, 삼나무, 적송의 순서로 증가하였다. 연기성장지수-II는 삼나무를 기준으로 1.18~2.55배 증가하였다. 연기성장지수-II에 의한 화재위험성은 삼나무, 가문비나무, 나왕, 적송의 순서로 높아졌다. CO 평균농도는 59~133 ppm이었으며 이 결과는 미국직업안전위생관리국(occupational safety and health administration, OSHA)의 허용기준(permissible exposure limits, PEL)인 50 ppm 보다 높게 나타났다. 결론적으로 적송과 같이 휘발성 유기물질을 다랑 함유한 목재는 연기성능지수-II가 낮고, 연기성장지수-II가 높으므로 화재로 인한 연기유해성이 높은 것으로 이해된다.

홍삼에탄올추출물의 염증유발인자에 대한 억제효과 (Red Ginseng Ethanol Extract Suppressed Ag I/II-induced Up-expression of Inflammatory Mediators in RAW 264.7 Macrophages)

  • 최경민;황승미;임지예;고은실;박종혁;문정혜;이민정;장지은;차정단
    • 한국미생물·생명공학회지
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    • 제43권2호
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    • pp.158-163
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    • 2015
  • 본 연구에서, 우리는 S. mutans Ag I/II 재조합단백질에 의해 유도되어진 염증유발 단백질의 발현에 홍삼 40% 에탄올 추출물의 효과를 알아보고자 하였다. 홍삼에탄올추출물은 Ag I/II 재조합단백질에 의해 유도되어진 염증유발물질들의 mRNA와 단백질의 발현을 억제하였다. 더불어 홍삼에탄올 추출물은 NF-κΒ p65가 핵내로 이용하는 것이 억제하였다. 결론적으로 홍삼 40%에탄올추출물은 NF-κB의 활성에 의해 NO 생성과 iNOS 발현이 조절되어지는 것으로 생각되어지며, 염증유발 관련 유전자들의 낮은 발현을 유도하는 것으로 관찰되어졌다.

Gas Liquid Chromatography에 의한 인삼(人蔘) 제품(製品) 중의 지방산(脂肪酸) 분석(分析) (Gas Liquid Chromatographic Analysis of Fatty Acids in Ginseng Products)

  • 윤태헌;김을상
    • 한국식품과학회지
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    • 제11권3호
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    • pp.182-187
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    • 1979
  • 시판되고 있는 홍삼(紅蔘)과 백삼(白蔘), 홍삼(紅蔘) 엑기스와 백삼(白蔘) 엑기스를 구입하여 ethyl ether로 추출한 다음 지방질(脂肪質)의 총(總) 지방산(脂肪酸) 조성(組成)을 GLC로 분석 확인하였고 각 peak면적은 integrator로 계산하였다. 1. 홍삼(紅蔘)과 백삼(白蔘) II의 조(粗) 지방질(脂肪質) 함량은 각각 0.86%와 0.82%로 비슷하였고 백삼(白蔘) I의 조(粗) 지방질(脂肪質)은 0.54%였다. 엑기스에서는 홍삼(紅蔘) 엑기스와 백삼(白蔘) 엑기스 I에서 다같이 약 1.1%정도였는데 다만 백삼(白蔘)엑기스 II에서만 0.40%로서 함량이 가장 적었다. 2. 홍삼(紅蔘)과 백삼(白蔘)에서 $C_{10:0}$을 제외한 $C_{6:0}$에서 $C_{24:1}$까지 분리된 총 22개의 peak중 16개의 우수 지방산(脂肪酸)을 확인하였으며 홍삼(紅蔘)과 백삼(白蔘)의 주지방산(主脂肪酸)은 linoleic acid로서 홍삼(紅蔘)이 63.33%, 백삼(白蔘) I 45.55%, 백삼(白蔘) II 41.06%였다. 그 다음으로 많은 지방산(脂肪酸)은 palmitic acid로서 홍삼(紅蔘)은 11.30%였고 백삼(白蔘) I과 II는 이보다 다소 많았다. 3. 홍삼(紅蔘) 엑기스에서는 linoleic acid가 15.93% palmitic acid가 15.71%로서 이 두 지방산(脂肪酸)이 주(主) 지방산(脂肪酸)을 이루고 있었고 백삼(白蔘) 엑기스 I에서도 linoleic acid가 21.94%, palmitic acid가 19.15%로서 역시 이 두 지방산(脂肪酸)이 주(主) 지방산(脂肪酸)을 이루고 있었다. 그러나 백삼(白蔘)엑기스 II에서는 16.13%인 palmitic acid가 주(主) 지방산(脂肪酸)을 구성하고 있었다.

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홍삼의 법제유황 처리가 당뇨쥐의 혈중지질 및 대사지표물질에 미치는 영향 (Effect of Red Ginseng with Processed Sulfur Extracts on Serum Lipids Concentration and Metabolic Variables in Diabetic Rats)

  • 한현정;김혜자;정명수;조화은;최윤희;이기남
    • 대한본초학회지
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    • 제24권1호
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    • pp.89-98
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    • 2009
  • Objectives : The purpose of this study was to evaluate effects of processed sulfur with red ginseng on streptozotocin(STZ) induced diabetic rats for expansion of processed sulfur internal application. Methods : We prepared red ginseng with non processed sulfur extracts(GS), red ginseng with processed sulfur I extracts(GPS I) and red ginseng with processed sulfur II extracts(GPS II). In the present study, we examined about contents of crdue saponin, antioxidant activity, $\alpha$-glucosidase inhibitory activity, and effects of STZ induced diabetic rats. Results : Contents of crude saponin increased by processed sulfur, and GPS II was shown highest contents in crude saponin and sulfur compared with another groups. Electron donating ability of GPS II was shown highest activity compared with GS and GPS I, SOD-like activity showed same tendency as electron donating ability at 1 $mg/m\ell$ concentration. Inhibitory activity of $\alpha$-glucosidase was approximately same level in acarbose and GPS II. Blood glucose level of GPS II group was decreased 18.34% compared with DC(diabetes control) group and maintained stability range in glucose level. but GS and GPS I showed high level compared to GPS II. Serum triglycerides concentration also showed lowest level in GPS II. The activity of ALT, AST and ALP was shown high level in diabetic induced groups, and lowest level in GPS II. Creatinine was shown non-significantly difference in each groups and GPS II was shown lowest level in BUN. Conclusions : These results suggested that processed sulfur with red ginseng have improvement effects on diabetes and internal application of processed sulfur with red ginseng have no specific toxicity in liver and kidney.

쥐 근조직의 Cytochrome Oxidase에 대한 비교 연구 (Comparative Study on Cytochrome Oxidase of Rat Muscle Tissues)

  • Song, Eun-Sook
    • 한국동물학회지
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    • 제29권1호
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    • pp.70-74
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    • 1986
  • 쥐 골격근의 크루드 미토콘드리아에 있는 시토크롬 옥시다제의 활성을 비교 하였다. 붉은색의 빠른 트윗치 근육은 가장 높은 효소 활성을 나타냈고, 흰색의 빠른 트읫치 근육은 가장 낮았으며, 붉은 색이며 느린 트윗치 근육은 그 중간이었다. 위 세가지 타입의 근육에서 힘 염색한 결과 시토크롬 옥시다제의 전기영동상의 이동성이 다르게 나타났다. 이동성의 순서는 타입 I > 타입 $II_A$ > 타입 $II_B$이었다. 면역학적 전기영동의 결과는 위의 결과를 뒷받침 하였다.

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생쥐의 혈청 단백질에 미치는 메틸수은 독성에 대한 홍삼 추출물의 해독 효과 (Antitoxic Effect of Korean Red Ginseng Extract on Serum Protein of Mouse Treated with Methyl Mercury)

  • Chung, Hee-Won
    • The Korean Journal of Ecology
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    • 제9권4호
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    • pp.193-200
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    • 1986
  • In order to investigate the antiotoxic effect of red ginseng extract on serum protein of mouse treated with methyl mercury playing a role as toxic contaminant in ecosystem, variations of the serum protein contents, electrophoretic patterns, and blood components were studied. Mice were divided into 3 groups: Control, group I treated only with methyl mercury, and group II treated together with methyl mercury and red ginseng extract. The total serum protein content of the control group was 5.8g/dl and those of groups I and II were slightly decreased as compared with the control. The control group showed 11 serum protein fractions and groups I and II showed 10 fractions except prealbumin. The amounts of albumin, ${\alpha}_1-$, ${\alpha}_2-$ globulin fractions were decreased and those $\beta$-, $\gamma$-globulin fractions were increased in groups I and II. The amount of each serum protein fraction in group II showed approximately the same level as the control. The hematocrit value and the number of white blood cells of groups I and II were increased, whereas the number of red blood cells showed the decrease as compared with the control.

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Orchargrass-Red Clover 혼파이용에 관한 연구 II. Orchargrass-Red Clover 파종비율이 목초의 수량과 품질에 미치는 영향 (Study on the Use of Orchargrass-Red Clover mixture II. Effect of seed rate of orchargrass-red clover on herbage yield and quality)

  • 이인덕;이형석
    • 한국초지조사료학회지
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    • 제12권4호
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    • pp.211-217
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    • 1992
  • This experiment was conducted over a 3-year period (1990-1992) to evaluate the production and quality of orchardgrass (Potomac)-red clover (Kenland) mixture when orchardgrass + red clover mixture was sown at seed rates of 20+0. 18+2, 16+4, 14+6 and 12+8 kg/ha. Total herbage dry matter, crude protein and digestible organic matter production and organic matter intake were markedly affected by increasing rcd clover seed rate, those increased with increasing red clovcr seed rate due to the cnhancernent of red clover percentage of total herbagc in all 3-year. but significant differences occured between the orchardgrass alone and orchardgrass-red clover mixture with a seed rate of 4,6 and 8 kg/ha red clover (P<0.01). But on the other hand increasing red clover seed rate increased red clover percentage in total herbage, the mean red clover percentage of total herbage at the last cutting ranged from 54 to 65% in first year. 58 to 60% in second year, and 62 to 69% in third year, particularly it was observed that red clover was sown at seed rates of 6 and 8 kg/ha for red clover sown dominated strongly as the cutting times were progressed. Considering the maintenance of good botanical composition balance and the enhancement of production and quality of herbage, the optimized seed rate for orchardgrass-red clover mixtures, 16 kg/ha orchardgrass and 4 kg/ha red clover seems to be considered adequate.

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