• Title/Summary/Keyword: Pure lead

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Characteristics of Lead Accumulation in Lead-Tolerant Pseudomonas aeruginosa (납 내성균의 균체내 납 축적 특성)

  • Cho, Ju-Sik;Lee, Hong-Jae;Heo, Jong-Soo
    • Korean Journal of Environmental Agriculture
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    • v.15 no.3
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    • pp.306-315
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    • 1996
  • This study was performed to develop the biological treatment technology of wastewater polluted with heavy metals. The lead-tolerant microorganism, Pseudomonas aeruginosa which possessed the ability to accumulate lead, was isolated from the industrial wastewater polluted with various heavy metals. The characteristics of lead accumulation in the cells and the recovery of the lead there from were investigated. Removal rate of lead from the solution containing 100mg/l of lead by the lead-tolerant microorganism was more than 97% at 48 hours after inoculation with the microorganism. A large number of the electron-dense granules were found mainly on the cell wall and cell membrane fractions, when determined by transmission electron microscopy. Energy dispersive X-ray spectroscopy revealed that the electron-dense granules were lead complex with the substances binding heavy metals. The lead accumulated into cells was not desorbed by distilled water, but more than 87% of the lead accumulated was desorbed by 0.1M-EDTA. The residues of the cells after combustion at $550^{\circ}C$ amounted to about 30% of the dry weight of the cells. EDS analysis showed that the residues were relatively pure lead compounds containing more than 86% of lead.

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Thermal Stability of the Mechanical and Thermal Conductive Properties on Cu-STS-Cu Clad Metal for LED Package Lead Frame (LED 리드프레임 패키징용 Cu/STS/Cu 클래드 메탈의 기계 및 열전도 특성의 온도 안정성 연구)

  • Kim, Young-Sung;Kim, Il-Gwon
    • Journal of Welding and Joining
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    • v.31 no.5
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    • pp.77-81
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    • 2013
  • We have investigated thermal stability of the mechanical and thermal conductive properties of Cu/STS/Cu 3 layered clad metal lead frame material for a LED device package at different temperatures ranging from RT to $200^{\circ}C$. The fabricated Cu/STS/Cu clad metal has a good thermal stability for the mechanical tensile strength and thermal conductivity of the over 50 $Kg/mm^2$ to the $150^{\circ}C$ and 270 $W/m{\cdot}K$ to the $200^{\circ}C$, respectively. This clad metal lead frame material at a high temperature of $150^{\circ}C$ shows a reinforced mechanical tensile strength by 1.5 times to conventional pure copper lead frame materials and also a comparable thermal conductivity to typical copper alloy lead frame materials.

A Numerical Study on Aerodynamic Characteristics for Cyclic Motion Profile of Flapping Airfoil (Flapping Airfoil의 2차원 운동궤적에 따른 공력특성연구)

  • Jeong, Won-Hyeong;An, Jon;Lee, Gyeong-Tae
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.3
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    • pp.6-13
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    • 2006
  • Aerodynamic characteristics for two-dimensional cyclic motion profile of flapping airfoil in low Reynolds number flows are investigated. Plunging motion and lead-lag motion in the two dimensional space with different plunging and lead-lag amplitudes are combined to cyclic motion profile and the flow around the airfoil is simulated. Present result shows that the improved aerodynamic efficiencies for a given flapping airfoil by adding periodic lead-lag motion of airfoil rather than the pure plunging case. The thrust coefficient and lift coefficient are compared with each cycle during the flapping period and aerodynamic characteristics are obtained on upstroke motion and downstroke motion.

Imitation, Technology, and Firm Performance: The Korean Firms Case in China

  • Kim, Woo-Hyoung;Chen, Bo;Hwang, Jin-Soo
    • Journal of Korea Trade
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    • v.25 no.4
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    • pp.128-145
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    • 2021
  • Purpose - The main purpose of this study is thus to investigate the contingent effect of imitation strategies on firm performance in transition economies such as China, focusing on pure and creative imitation. Design/methodology - We conducted a survey targeting department heads of each company who have more than 10 years work experiences. We assessed that the ability to gain trust and to access information from high-ranking informants would be greater if the firms were from the same country - Korea - as the lead researcher. A total of 200 highly reliable samples were obtained, which could effectively explain the nine variables set in the study. Relevant hypotheses were tested using a hierarchical linear model (HLM). Findings - The findings suggest that SMEs' technology level also had a positive impact on performance. Firms with better technology had a positive impact on performance, irrespective of pure or creative imitation. This reflects the cases where many Korean SMEs entering China without high technology level lose their competitiveness due to Chinese firms' technology catch-up within a short period of time. Originality/value - SMEs that lack technology and know-how need to focus on pure imitation strategies. It is possible that SMEs can perform creative imitation, but it seems difficult under the current circumstances. Therefore, SMEs with limitations in technology and know-how should maintain their competitive advantage for a while, by maintaining their pure imitation strategy.

Effect of Chelation with Calcium Disodium EDTA on Haemato-biochemical and Trace Mineral Profile in Blood from Lead Exposed Calves

  • Patra, R.C.;Swarup, D.
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.8
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    • pp.1130-1134
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    • 2005
  • An experiment was performed using 20 calves of about one-month old to investigate the effect of chelation therapy with calcium disodium ethylenediaminetetraacetate ($CaNa_2$EDTA) alone or along with antioxidant $\alpha$-tocopherol in lead loaded calves on blood trace minerals, erythrocytic sulfahydryl groups and some haematobiochemical parameters. Fifteen calves were given lead orally at a daily dose of 7.5 mg of 99% pure lead acetate/kg body weight for 28 days. Then the lead was withdrawn on day 28 and the calves were randomly divided into three groups. Each group of five animals was either treated with $CaNa_2$EDTA alone at the dose rate of 110 mg/kg body weight in two divided doses for 4 days or along with $\alpha$-tocopherol at the dose rate of 100 mg/kg body weight orally daily for 7 days, keeping the remaining five calves as lead-exposed untreated controls. Blood samples were collected at the end of the lead exposure (day 0) and thereafter on day 2, 4, 7 and 10 from the start of the chelation treatment. The treatment with EDTA alone led to slow but non-significant improvement in blood copper level, but incorporation of antioxidant $\alpha$-tocopherol in chelation therapy resulted in its significant decline, as recorded on day 7-post treatment. Withdrawal of lead or treatment with $CaNa_2$EDTA alone or along with $\alpha$-tocopherol enhanced the erythrocytic thiol contents and the levels of T-SH and P-SH became statistically (p<0.05) comparable to those of lead-exposed controls by day 7 and 4, respectively. There was no significant (p>0.05) change in serum urea, creatinine, total protein and albumin levels between the treatment groups. It is concluded from the present investigation that treatment with $CaNa_2$EDTA at the present dose rate is safe to be used for chelation in lead loaded calves.

Colloidal Synthesis of Octahedral Shaped PbSe Nanocrystals from Lead Oleate and Se : Temperature Effect

  • Gokarna, Anisha;Jun, Ki-Won;Khanna, P.K.;Baeg, Jin-Ook;Seok, Sang-Il
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1803-1806
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    • 2005
  • Formation of octahedral shaped PbSe quantum dots at higher synthesis temperature is being reported in this paper. The synthesis includes the reaction between lead oleate and trioctylphosphine selenide under inert gas conditions to produce PbSe. TEM, SEM, XRD and EDS were used to characterize the samples. The SEM exhibited the formation of spherical shaped nanocrystals at temperature below 140 ${^{\circ}C}$ and octahedral shaped nanoparticles at higher temperatures. Moreover, the TEM also showed the well resolved (111) lattice fringes proving that the nanocrystals were crystalline in nature. Synthesis of highly pure PbSe nanocrystals was another interesting aspect of this research.

Characteristics of Microwelded BLU CCFL Electrode in Terms of Glass Beading Heat Treatment Temperature (미세 용접된 BLU CCFL 전극의 유리비딩 열처리 온도에 따른 접합부 특성)

  • Kim, Gwang-Soo;Kim, Sang-Duck;Kwon, Hyuk-Dong
    • Journal of Welding and Joining
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    • v.27 no.4
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    • pp.73-78
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    • 2009
  • Characterization of the microweld CCFL electrode for the TFT-LCD backlight unit was carried out in terms of the glass beading heat treatment conditions. We evaluate the weld zone and parent metal of the microweld CCFL electrodes that were exposed to simulated glass beading heat treatment. The CCFL electrode was composed of the cup made with pure Ni, the pin made with pure Mo and the lead wire made with Ni-Mn alloy. Each part of the electrode was assembled together by micro spot welding process and then the assembled electrodes were exposed to simulated glass beading temperatures of $700^{\circ}C,\;750^{\circ}C$ and $800^{\circ}C$. The microstructures of the microweld CCFL electrode were observed by using optical microscope, scanning electron microscope and EDS. Micro-tensile and microhardness test were also carried out. The results indicated that the grain coarsening in the HAZs(heat affected zones) for both the cup-pin weld and pin-lead wire were exhibited and the grain coarsening of the HAZ for the cup and the lead wire was more obvious than the HAZ of the pin. The micro-tensile test revealed that the fracture occurred at the cup-pin weld zone for all test conditions. The fracture surface could be classified into two parts such as pin portion and cup portion including weld nugget. The failure was seemed to be initiated from the boundary between nugget and pin through the weld joint. The result of the microhardness measurement exhibited that the relatively low hardness value, about 105HV was recorded at the HAZ of the cup. This value was about 50% less than that of the original value of the cup. The reduction of the microhardness was considered as the cause of the grain coarsening due to welding process. It was also appeared that there was no change in electric resistance for the standard electrodes and heat treated electrodes.

A closer look at the structure and gamma-ray shielding properties of newly designed boro -tellurite glasses reinforced by bismuth (III) oxide

  • Hammam Abdurabu Thabit;Abd Khamim Ismail;N.N. Yusof;M.I. Sayyed;K.G. Mahmoud;I. Abdullahi;S. Hashim
    • Nuclear Engineering and Technology
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    • v.55 no.5
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    • pp.1734-1741
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    • 2023
  • This work presents the synthesis and preparation of a new glass system described by the equation of (70-x) B2O3-5TeO2 -20SrCO3-5ZnO -xBi2O3, x = 0, 1, 5, 10, and 15 mol. %, using the melt quenching technique at a melting temperature of 1100 ℃. The photon-shielding characteristics mainly the linear attenuation coefficient (LAC) of the prepared glass samples were evaluated using Monte Carlo (MC) simulation N-particle transport code (MCNP-5) at gamma-ray energy extended from 59 keV to 1408 keV emitted by the radioisotopes Am-241, Ba-133, Cs-137, Co-60, Na-22, and Eu-152. Furthermore, we observed that the Bi2O3 content of the glasses had a significantly stronger impact on the LAC at 59 and 356 keV. The study of the lead equivalent thickness shows that the performance of fabricated glass sample with 15 mol.% of Bi2O3 is four times less than the performance of pure lead at low gamma photon energy while it is enhanced and became two times lower the perforce of pure lead at high energy. Therefore, the fabricated glasses special sample with 15 mol.% of Bi2O3 has good shielding properties in low, intermediate, and high energy intervals.

Biosorption Model and Factors for Removing Lead to Aureobasdium pullulans being Imperfect Fungus (불완전 균류 Aureobasdium pullulans으로 납을 제거하기 위한 인자들과 흡착모델)

  • Suh, Jung-Ho;Suh, Myung-Gyo;Chung, Kyung-Tae;Lee, Yong-Hee
    • Journal of Life Science
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    • v.16 no.6
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    • pp.877-883
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    • 2006
  • An alternative method to remove and recover heavy metals is biosorption based on metal-sequestering properties of natural or biological origin. In this study, the effects of factors such as temperature, pH, initial concentration of lead, and initial amount of biomass on biosorption of lead using Aureobasdium pullulans were investigated. A. pullulans has an excellent selectivity to remove lead than other heavy metals such as cadmium, chromium, nickel in pure and mixed solution. The optimum temperature of biosorption with A. pullulans was $40^{\circ}C$ and the amount of removal increased at high pH. The higher initial lead concentration or the lower cell dry weight, the higher amount of lead was adsorbed. The adsorption isotherm of lead was accorded with Freundlich model. The adsorption capacity and initial adsorption rate of living A. pullulans were about twice higher than that of dead one.

Nanoparticle Effect on Durability of Carbon fiber/Epoxy Composites in Saline Water Environment (염수환경에서 탄소섬유/에폭시 복합재료의 내구성에 미치는 나노입자의 영향)

  • Kim, Bu-Ahn;Moon, Chang-Kwon
    • Journal of Ocean Engineering and Technology
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    • v.28 no.1
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    • pp.64-68
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    • 2014
  • This study was conducted to investigate the durability of carbon fiber/epoxy composites (CFRP) in a saline water environment. The carbon fiber/epoxy composites were modified to use nanoparticles such as carbon nanotubes and titanum oxide. These hybrid composites were exposed to a saline water environment for a certain period. The weight gain according to the immersion time, a quasi-static tensile test, and micro-graphic characterization were used to investigate the samples exposed to the saline water environment. The weight gains increased with increasing immersion time. The weight gains of the hybrid composites were lower than that for pure CFRP throughout the entire immersion time. The tensile strengths decreased with increasing immersion time. The tensile strengths of the hybrid composites were higher than that of the pure CFRP throughout the entire immersion time. The pure CFRP was observed to be more degraded than the hybrid composites in the saline water environment. Therefore, it was concluded that the addition of nanoparticles to CFRP could lead to improved durability in a saline water environment.