• Proceedings of the Korean Society of Precision Engineering Conference
• /
• 2000.11a
• /
• pp.409-412
• /
• 2000

Much research efforts have been made on the structure and properties of metals deformed to severe plastic deformation (SPD). Being deformed to SPD, ultra-fine grains (UFG) are usually formed, and UFG structure exhibits fundamental differences in original physical properties. One method often used to obtain SPD is equal channel angular pressing (ECAP). In order for this technique to be exploited, it is important to understand the deformation behavior during the ECAP processing with respect to friction. The finite element method (FEM) has been used to investigate this issue.

• Journal of the Korean Ceramic Society
• /
• v.25 no.1
• /
• pp.1-6
• /
• 1988

The IR edge absorption of the important pure components of ZrF4-based glasses, including two previously uncharacterized components(ZrF4 and AlF3), has been measured. Values of the glass IR edge absorption coefficients have been calculated from these results, assuming additivity, and are compared with experimental glass absorption coefficients. The calculated ${\alpha}$ values are about a factor of two lower than the experimental values for ZrF4-based glasses, and the ZrF4 makes the largest contribution to the calculated ${\alpha}$ value.

• Bulletin of the Korean Chemical Society
• /
• v.32 no.9
• /
• pp.3317-3322
• /
• 2011

This study examines the photoelectric conversion efficiency of dye-sensitized solar cells (DSSCs) when nanometer-sized Zr (0.1, 0.5, and 1.0 mol %)-$TiO_2$ prepared using a solvothermal method is utilized as the working electrode material. The particle sizes observe in the transmission electron microscopy (TEM) images are < 30 nm in all samples. The absorption band is slightly broadened at the tail for the 0.1 mol % Zr-$TiO_2$, and the intensity of the photoluminescence (PL) curves of the Zr-incorporated $TiO_2$ is significantly smaller than that of the pure $TiO_2$. Compared to that using pure $TiO_2$, the energy conversion efficiency is enhanced considerably by the application of Zr-$TiO_2$ in the DSSCs to approximately 6.17% for 0.5 mol % Zr-$TiO_2$ with the N719 dye (10.0 ${\mu}m$ film thickness and 5.0 mm ${\times}$ 5.0 mm cell area) under 100 mW/$cm^2$ of simulated sunlight.

• The Journal of Korean Academy of Prosthodontics
• /
• v.36 no.5
• /
• pp.701-720
• /
• 1998

Research advances in dental implantology have led to the development of several different types of materials and it is anticipated that continued research will lead to advanced dental implant materials. Currently used pure titanium has relatively low hardness and strength which may limit its ability to resist functional loads as a dental implant. Ti-6Al-4V also has potential problems such as corrosion resistance. osseointegration properties and neurologic disorder due to aluminium and vanadium, known as highly toxic elements, contained in Ti-6Al-4V. Newly developed titanium based alloys(Ti-20Zr-3Nb-3Ta-0.2Pd-1In, Ti-20Zr-3Nb-3Ta-0.2Pd) which do not contain toxic metallic components were designed by the Korea Institute of Science and Technology (KIST) with alloy design techniques using Zr, Nb, Ta, Pd, and In which are known as non-toxic elements. Biocompatibility and osseointegration properties of these newly designed alloys were evaluated after implantation in rabbit femur for 3 months. The conclusions were as follows : 1. Mechanical properties of the new designed Ti based alloys(Ti-20Zr-3Nb-3Ta-0.2Pd-1In, Ti-20Zr-3Nb-3Ta-0.2Pd) demonstrated close hardness and tensile strength values to Ti-6Al-4V. 2. New desinged experimental alloys showed stable corrosion resistance similar to the pure Ti but better than Ti-6Al-4V. However, the corrosion rate was higher for the new alloys. 3. Cell culture test showed that the new alloys have similar cell response compared with pure Ti and Ti-6Al-4V with no cell adverse reaction. 4. New designed alloys showed similar bone-metal contact ratio and osseointegration properties compared to pure Ti and Ti-6Al-4V after 3 months implantation in rabbit femur. 5. Four different surface treatments of the metals did not show any statistical difference of the cell growth and bone-metal contact ratio.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.30 no.7 s.250
• /
• pp.765-772
• /
• 2006

Much research efforts have been made on the equal channel angular pressing (ECAP) which produces ultra-fine grains. Along with the experiments, the finite element method has been widely employed to investigate the deformation behavior of specimen during ECAP and the effect of process parameters of ECAP. In this paper, sectional shape change has been investigated during ECAP with the pure-Zr, Zr-702 by using three-dimensional finite element analysis. The results have been compared with experimental results.

• Journal of the Korean Society for Precision Engineering
• /
• v.18 no.6
• /
• pp.182-187
• /
• 2001

Much research efforts have been made on the equal-channel angular pressing(ECAP)that produces ultra-fine grain size materials. Recently many materials have been tested for ECAP process, and in this paper pure-Zirconium is considered due to its applicability to nuclear reactors. Among many process parameters of ECAP, frictional effects on the deformation behavior of materials and on the stress distribution of die have been investigated. The finite element method has been employed in order to investigate this issue, and experiments have also been made to verify the numerical results.

• Proceedings of the Korean Nuclear Society Conference
• /
• 2002.10a
• /
• pp.221.2-221
• /
• 2002

• Journal of the Korean Applied Science and Technology
• /
• v.20 no.4
• /
• pp.358-365
• /
• 2003

Zirconium nitride powders were synthesized at a relatively lower temperature using methane as a reducing agent in the nitridation of zircoia. $ZrO_2$ powder was prepared by a sol-gel technique. The resulting sol-gel was centrifuged, and the gel was washed with deionized water. Anhydrous ammonia was used as the nitrogen source and methane was used as the reducing agent. Conversion diagrams show the equilibrium solid phase as a function of reagent concentrations for a specific temperature and gas pressure for the reagent system $NH_3-ZrO_2-CH_4$. The reagent concentration ranges within which pure ZrN is formed increase with increasing reaction temperature. Low pressure with an excess of hydrogen decreases the reaction temperature at which pure ZrN is formed. Low pressure together with the introduction of excess hydrogen into the reaction system increases Zr and N conversion efficiency and retards C deposition.

• Journal of Technologic Dentistry
• /
• v.33 no.4
• /
• pp.263-270
• /
• 2011

Purpose: The grindability of binary Ti-X%Zr(X=10,20,40) alloys in order to develop a Ti alloy with better machinability than unalloyed titanium has been evaluated. Methods: Experimental Ti-Zr alloys were made in an argon-arc melting furnace. Slabs of experimental alloys were ground using a SiC abrasive wheel on an electric handpiece at circumferential speeds(12000,18000,25000 or 30000rpm) by applying a force(200gr). Grinding rate was evaluated by measuring the amount of metal volume removed after grinding for 1 minute and the volume ratio of metal removed compared to the wheel material lost, which was calculated from the diameter loss (grinding ratio). Experimental datas were compared to those for cp Ti(commercially pure titanium) and Ti-6%Al-4%V alloy were used controls. Results: It was observed that the grindability of Ti-Zr alloys increased with an increase in the Zr concentration. More, they are higher than cp Ti, particularly the Ti-20%Zr alloy exhibited the highest grindability at all circumferential speeds. There was significant difference in the grinding rate and grinding ratio between Ti-20%Zr alloy and cp Ti at any speed(p<0.05). Conclusion: By alloying with Zr, the Ti exhibited better grindability at all circumferential speeds. the Ti-20%Zr alloy has a great potential for use as a dental machining alloy.

• Journal of the Korean Ceramic Society
• /
• v.16 no.4
• /
• pp.213-224
• /
• 1979

The present work was undertaken: (1) to determine if CaO-partially stabilized $ZrO_2$ prepared by Hot Petroleum Drying Method would show better ionic conductor as an oxygen sensor in molten metals than that prepared by Oxide Wet Mixing Method and than CaO-fully stabilized $ZrO_2$, and (2) to understand the nature of conduction mechanism of CaO-partially stabilized $ZrO_2$ by a comparison of measured electrical conductivity data with theory on defect structure of pure monoclinic $ZrO_2$ and fully stabilized cubic $ZrO_2$. The DC electrical conductivity was measured by 3-probe technique and the AC electrical conductivity by 2-probe technique as a function of temperature in the range 973-1373 K and oxygen partial pressure in the range 10-1-10-25Mpa. The results of the experiments were as follows: 1. CaO-partially stabilized $ZrO_2$ prepared by Hot petroleum Drying Method showed at T=1094-1285 K and $Po_2$=10-7-10-25 MPa a nearly ionic conduction with 4 times higher conductivity than that prepared by Oxide Wet Mixing Method. 2. High-oxygen pressure conductivity tends toward a Po_2^{+1/5}-Po_2^{+1/6}$dependence. An analysis of possible defect structures suggests that CaO-partially stabilized $ZrO_2$ has an anti-Frenkel defect in which singly or doubly ionized oxygen interstitials and defect electrons predominate at T=1094-1285 K and $Po_2$=10-1-10-7MPa. 3. The activation energy for pure electron hole-conduction and ionic conduction of CaO-partially stabilized $ZrO_2$ was found to be 130 KJ/mol at T=973-1373 K, $Po_2$=2, 127 10-2 MPa(air) and 153KJ/mol at T=1094-1285 K respectively.