• Title/Summary/Keyword: Pure Co

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CO Gas Sensing Characterstics and Electrical Properties of $SnO_2-TiO_2$ Composite Ceramics ($SnO_2-TiO_2$ 세라믹 복합체의 일산화탄소 감응특성 및 전기적 성질)

  • 갬태원;최우성;정승우
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.6
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    • pp.453-457
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    • 1998
  • In order to improve CO gas sensitivity, $TiO_2$added $SnO_2$ composite ceramics were prepared. Using XRD and SEM, the phases and micro structures of these ceramics were investigated. The resistances as a function of gas atmosphere were measured by High Voltage Measure/Source Unit. The maximum 100 ppm CO gas sensitivities of $SnO_2-TiO_2$composites were 2.5 times larger than that of pure $SnO_2$ composite and showed the obvious temperature dependence of sensitivities in 500, 100 ppm CO gas atmospheres.

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Extra-fine Ni Powder for Diamond Tool Binder Applications

  • Stephenson, Thomas F.;Korotkin, Maria;Metcalfe, Shawn
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.883-884
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    • 2006
  • A new extra-fine grade Ni powder (XF Ni) has demonstrated increased sintering activity in Co-Fe-Ni binders for diamond tool applications. XF Ni has the advantage of significantly lower cost than XF Co. Up to 30% of XF Co was substituted with XF Ni while maintaining comparable apparent hardness and transverse rupture strength to pure Co binders. Ni substantially increased the diffusion of Fe. Diamond tool producers can take advantage of the improved sintering properties of XF Ni powder to substantially lower material costs.

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Physicochemical Properties of MnO2 Catalyst Prepared via Hydrothermal Process and its Application for CO Oxidation (수열방법으로 합성된 이산화망간의 물리화학적 특성과 일산화탄소 산화반응)

  • Lee, Young-Ho;Jeon, Su A;Park, Sang-Jun;Youn, Hyun Ki;Shin, Chae-Ho
    • Clean Technology
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    • v.21 no.4
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    • pp.248-256
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    • 2015
  • MnO2 was prepared by a hydrothermal process method in the range of 120-200 ℃ and 0.5-5 h, calcined at 300 ℃ after induction of precipitation using KMnO4 and MnCl2・4H2O, and its catalytic activity was compared for CO oxidation. The catalysts were characterized using by X-ray diffraction, N2-sorption, scanning electron microscopy, and temperature programmed reduction of H2 or CO. The crystalline structure of pure α-MnO2 or hybrid α/β-MnO2 was controlled by the preparation conditions. The pure α-MnO2 showed better catalytic activity and thermal stability than hybrid α/β-MnO2. Especially, α-MnO2 prepared at 150 ℃ for 1 h has the highest specific surface area 214 m2 g-1, reducibility and labile lattice oxygen species analyzed by H2, CO-TPR, respectively. It also showed the best CO oxidation activity in both conditions of temperature programmed and isothermal reaction. The results came from the physicochemical properties of catalysts like the crystalline structure, specific surface area, reducibility and lattice oxygen species, and which are correlated with catalytic performance.

Synthesis and Characterization of WS2 Nanoparticles by Chemical Vapor Condensation (화학기상응축공정에 의한 WS2 나노입자의 합성 및 특성평가)

  • Lee, Dong-Won;Kim, Ju-Hyeong;Tolochko, O.;Yun, Jung-Yeul;Kim, Byung-Kee
    • Journal of Powder Materials
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    • v.15 no.4
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    • pp.314-319
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    • 2008
  • Nano-sized tungsten disulfide ($WS_2$) powders were synthesized by chemical vapor condensation (CVC) process using tungsten carbonyl ($W(CO)_6$) as precursor and vaporized pure sulfur. Prior to the synthesis of tungsten disulfide nanoparticles, the pure tungsten nanoparticles were produced by same route to define the optimum synthesis parameters, which were then successfully applied to synthesize tungsten disulfide. The influence of experimental parameters on the phase and chemical composition as well as mean size of the particles for the produced pure tungsten and tungsten disulfide nanoparticles, were investigated.

Assimilation of Peptides and Amino Acids and Dissimilation of Lactate During Submerged Pure Cultures of Penicillium camembertii and Geotrichum candidum

  • Aziza, M.;Adour, L.;Amrane, A.
    • Journal of Microbiology and Biotechnology
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    • v.18 no.1
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    • pp.124-127
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    • 2008
  • The behavior of Penicillium camembertii and Geotrichum candidum growing in submerged pure cultures on simple (glutamate) or complex (peptones) substrates as nitrogen and carbon sources and lactate as a second carbon source was examined. Similar to the behavior previously recorded on a simple substrate (glutamate), a clear differentiation between the carbon source and the energy source was also shown on peptones and lactate during P. camembertii growth, since throughout growth, lactate was only dissimilated, viz., used for energy supply by oxidation into $CO_2$, whereas peptides and amino acids from peptones were used for carbon (and nitrogen) assimilation. Because of its deaminating activity, G candidum preferred peptides and amino acids to lactate as energy sources, in addition to being assimilated as carbon and nitrogen sources. From this, on peptones and lactate, G candidum grew faster than P. camembertii (0.19 and 0.08 g/l/h, respectively) by assimilating the most readily utilizable peptides and amino acids; however, owing to its lower proteolytic activity, the maximum biomass was lower than that of P. camembertii (3.7 and 5.5 g/l, respectively), for which continuous proteolysis and assimilation of peptides were shown.

Effects of Different Shielding Gases in Laser Welding of Secondary Ni battery with Multi-thin Plates (이차전지용 니켈 다층 박판의 레이저 용접 보호가스의 영향)

  • You, Young-Tae;Lee, Ka-Ram;Kim, Jin-Woo
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.25 no.5
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    • pp.329-337
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    • 2016
  • The demand for the eco-friendly vehicles is skyrocketing because of the increasing $CO_2$ emissions and global warming. In the industrial field, the battery process, a core part of an eco-friendly vehicle, is drawing increased attention; its weight lightening as well as high energy density are becoming increasingly important. In this study, pure Ni plates that were used as the battery pole plate were welded using the laser. The lab joint welding was conducted on ten pure Ni plates at a laser power of 1900 W and a feed speed of 2.8-3.4 m/min. As observed in the experiment, a faster feed speed reduced the bead width, but the laser did not penetrate all ten specimen plates. In addition, pores were trapped when protective gas was used, but they were not trapped when the welding was conducted in atmospheric condition.

Flexural Behavior of High-Strength Concrete Beams Confined with Stirrups in Pure Bending Zone

  • Jang, Il-Young;Park, Hoon-Gyu;Kim, Yong-Gon;Kim, Sung-Soo;Kim, Jong-Hoe
    • International Journal of Concrete Structures and Materials
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    • v.3 no.1
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    • pp.39-45
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    • 2009
  • The purpose of this study is to establish flexural behavior of high-strength concrete beams confined in the pure bending zone with stirrups. The experiment was carried out on full-scale high-strength reinforced concrete beams, of which the compressive strengths were 40 MPa and 70 MPa. The beams were confined with rectangular closed stirrups. Test results are reviewed in terms of flexural capacity and ductility. The effect of web reinforcement ratio, longitudinal reinforcement ratio and shear span to beam depth ratio on ductility are investigated. The analytic method is based on finite element method using fiber-section model, which is known to define the behavior of reinforced concrete structures well up to the ultimate state and is proven to be valid by the verification with the experimental results above. It is found that confinement of concrete compressive regions with closed stirrups does not affect the flexural strength but results in a significantly increased ductility. Moreover, the ductility tends to increase as the quantity of stirrups increases by reducing the spacing of stirrups.

Characterization of Nanostructure and Electronic Properties of Catalytically Grown Carbon Nanofiber (촉매법으로 제조한 나노탄소섬유의 미세구조 및 전기적 특성 제어 연구)

  • 김명수;우원준;송희석;임연수;이재춘
    • Journal of the Korean Ceramic Society
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    • v.37 no.4
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    • pp.345-353
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    • 2000
  • Carbon nanofibers were prepared from the decomposition of various carbon-containing gases over pure Ni, pure Fe and their alloys with Cu. They yields, properties, and structure of carbon nanofibers obtained from the various reaction conditions were analyzed. Type of reacting gas, reaction temperature and catalyst composition were changed as the reaction variable. With Ni-Cu catalysts, the maximum yields of carbon nanofibers were obtained at temperatures between 550 and 650$^{\circ}C$ according to the reacting gas mixtures of C2H2-H2, C2H4-H2 and C3H8-H2, and the surface areas of the carbon nanofibers produced were 20∼350㎡/g. In the case of CO-H2 mixture, the rapid deposition of carbon nanofibers occurred with Fe-Cu catalyst and the maximum yield were obtained around 550$^{\circ}C$ with the range of surface areas of 140∼170㎡/g. The electrical resistivity of carbon nanofiber regarded as the key property of filler for the application of electromagnetic interference shielding was very sensitive to the type of reactant gas and the catalyst composition ranging 0.07∼1.5Ωcm at a pressure of 10000 psi, and the resistivity of carbon nanofibers produced over pure nickel catalyst were lower than those over alloy catalysts. SEM observation showed that the carbon nanofibers produced had the diameters ranging 20∼300 nm and the straight structure of carbon nanofibers changed into the twisted or helical conformation by the variation of reacting gas and catalyst composition.

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$High-J_c\;NdBa_2Cu_3O_{7-{\delta}}$ thin films on $SrTiO_3$(100) substrates prepared by the PLD process

  • Wee, Sung-Hun;Moon, Seung-Hyun;Yoo, Sang-Im
    • Progress in Superconductivity and Cryogenics
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    • v.11 no.2
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    • pp.1-6
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    • 2009
  • We report a successful fabrication of $high-J_c\;NdBa_2Cu_3O_{7-{\delta}}$ (NdBCO) films on $SrTiO_3$(STO) (100) substrates by pulsed laser deposition (PLD) in a relatively wide processing window. Under various oxygen pressures controlled by either 1%$O_2$/Ar mixture gas or pure $O_2$ gas, strongly c-axis oriented NdBCO films were grown at the substrate temperature $(T_s)\;of\;800^{\circ}C$ in 800 mTorr with 1%$O_2$/Ar gas and also in 400 and 800 mTorr with pure $O_2$ gas. These samples exhibited $T_c$ values over 90K and $J_c$ values of $2.8-3.5MA/cm^2$ at 77K in self-field (77K, sf). On the other hand, $J_c$ values over $1A/cm^2$ were obtained at the temperature regions of $700-830^{\circ}C$ in 800 mTorr with 1%$O_2$/Ar gas at those of $750-830^{\circ}C$ in 800 mTorr with pure $O_2$ gas. Unlike previous reports, resent results support that the PLD processing window for high-Jc NdBCO films is not narrow.

Separation of Electronic Grade Highly Pure Carbon Dioxide Using Combined Process of Membrane, LNG Cold Heat Assisted Cryogenic Distillation (분리막 공정과 LNG 냉열 및 심냉 증류를 이용한 전자급 고순도 이산화탄소의 분리)

  • YOUNGSOO KO;KYUNGRYONG JANG;JUNGHOON KIM;YOUNGJOO JO;JUNGHO CHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.35 no.1
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    • pp.90-96
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    • 2024
  • In this paper, a new technology to obtain electronic grade, highly pure carbon dioxide by using membrane and liquefied natural gas (LNG) cold heat assisted cryogenic distillation has been proposed. PRO/II with PROVISION release 2023.1 from AVEVA company was used, and Peng-Robinson equation of the state model with Twu's alpha function to predict pure component vapor pressure versus temperature more accurately was selected for the modeling of the membrane and cryogenic distillation process. Advantage of using membrane separation instead of selecting absorber-stripper configuration for the concentration of carbon dioxide was the reduction of carbon dioxide capture cost.