• Title/Summary/Keyword: Production of Alternative Materials

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Comparison of Ethanol Fermentation by Saccharomyces cerevisiae CHY1077 and Zymomonas mobilis CHZ2501 from Starch Feedstocks (전분 기질에 대한 Saccharomyces cerevisiae CHY1077과 Zymomonas mobilis CHZ2501의 에탄올 발효 비교)

  • Choi, Giwook;Kang, Hyunwoo;Kim, Youngran;Chung, Bongwoo
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.977-982
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    • 2008
  • The production of ethanol by microbial fermentation as an alternative energy source has been of interest because of increasing oil price. Saccharomyces cerevisiae and Zymomonas mobilis are two of the most widely used ethanol producers. In this study, characteristics of ethanol fermentation by Saccharomyces cerevisiae CHY1077 and Zymomonas mobilis CHZ2501 was compared. Brown rice, naked barley, and cassava were selected as representatives of the starch-based raw materials commercially available for ethanol production. The volumetric ethanol productivities by Saccharomyces cerevisiae from brown rice, naked barley and cassava were $0.68g/l{\cdot}h$, $1.03g/l{\cdot}h$ and $1.28g/l{\cdot}h$ respectively. But for the Zymomonas mobilis, $2.19g/l{\cdot}h$(brown rice), $2.60g/l{\cdot}h$(naked barley) and $3.12g/l{\cdot}h$(cassava) were obtained. Zymomonas mobilis was more efficient strain for ethanol production than S. cerevisiae.

Volatile Fatty Acid Production from Saccharina japonica Extracts by Anaerobic Fermentation: Evaluation of Various Environmental Parameters for VFAs Productivity (혐기성 발효에 의한 다시마 추출물로부터 휘발성 유기산 제조: 휘발성 유기산 생산성에 대한 환경적 영향인자 평가)

  • Choi, Jae Hyung;Song, Min Kyung;Chun, Byung Soo;Lee, Chul Woo;Woo, Hee Chul
    • Clean Technology
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    • v.19 no.2
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    • pp.148-155
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    • 2013
  • Volatile fatty acids (VFAs) production from marine brown algae, Saccharina japonica, was investigated in anaerobic dark fermentation. In order to evaluate the VFAs productivity, various experimental parameters (i.e., physicochemical pre-treatment, microorganism inoculation ratio, substrate concentration, and pH) were evaluated. According to the physicochemical pre-treatment methods, the maximum concentrations of VFAs were obtained in the order of sulfuric acid, subcritical water and subcritical water with lipid-extraction. Also, we investigated the operating parameters such as microorganism inoculation ratio (MV/M = 10 to 30), the substrate concentration (18.0 to 72.0 g/L) and pH (6.0 to 7.0) in sulfuric acid pre-treatment method. When the substrate concentrations were 18.0, 36.0, 54.0 and 72.0 g/L at $35^{\circ}C$, microorganism inoculation ratio 15, pH 7.0 for 372 hours, the maximum concentrations of VFAs were respectively 9.8, 13.9, 18.6 and 22.3 g/L. The change in VFAs concentrations was detected that acetic- and propionic acids increased according to increasing pH, while the butyric acid increased with decreasing pH. The VFAs obtained from concentration and separation process may be used as basic chemistry materials and bio-fuel, and they will expect to produce alternative energy of fossil fuel.

Manufacture of Wood Veneer-Bamboo Zephyr Composite Board - I. Properties of Bamboo Zephyr and Composite Board Made from Moso, Giant Timber and Hachiku Bamboo -

  • Roh, Jeang Kwan;Kim, Jae Kyung;Kim, Sa Ick;Ra, Jong Bum;Kim, Yu Jung;Park, Sang Jin
    • Journal of the Korean Wood Science and Technology
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    • v.32 no.3
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    • pp.42-51
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    • 2004
  • Wood veneer-bamboo zephyr composite board (WBCB) was manufactured to evaluate the properties of bamboo as alternative raw materials for the manufacture of composite panels. Bamboo zephyr was prepared using Moso bamboo (Phyllostachys pubesens Mazel. et Z), Giant timber bamboo (Phyllostachys bambusoides Sieb. et Zucc), and Hachiku bamboo (Phyllostachys nigra var. henosos Stapf). The effect of age and species of bamboo on zephyr production was investigated in terms of the pass number of bamboo split through the rollers, and the width increasing rate of bamboo split. Five-ply WBCBs were produced with Keruing veneers as face and back layers, leading to three layers of bamboo zephyr sheets as core layer. Each layer was placed so that its grain direction was at right angles to that of the adjacent layer and the layers were bonded together with phenol-formaldehyde (PF) resin.The pass number of bamboo split was increased with an increase of the thickness of culm wall. At the same thickness, Moso bamboo showed no effect of the age of bamboo on the pass number. The pass number of split of Giant timber bamboo was lower than that of Moso bamboo. No significant effect of bamboo species and age on the width of zephyr produced was observed. The width of zephyr obtained could be expressed as a function of diameter multiplied by thickness of culm wall. The physical and mechanical properties of WBCB manufactured in all given conditions did not show any significant differences, and they were above the requirement of Korean Standard (KS).

Potential use of local waste scoria as an aggregate and SWOT analysis for constructing structural lightweight concrete

  • Islam, A.B.M. Saiful;Walid, Walid;Al-Kutti, A.;Nasir, Muhammad;Kazmi, Zaheer Abbas;Sodangi, Mahmoud
    • Advances in materials Research
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    • v.11 no.2
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    • pp.147-164
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    • 2022
  • This study aims to investigate the influence of scoria aggregate (SA) and silica fume (SF) as a replacement of conventional aggregate and ordinary Portland cement (OPC), respectively. Three types of concrete were prepared namely normal weight concrete (NWC) using limestone aggregate (LSA) and OPC (control specimen), lightweight concrete (LWC) using SA and OPC, and LWC using SA and partial SF (SLWC). The representative workability and compressive strength properties of the developed concrete were evaluated, and the results were correlated with non-destructive ultrasonic pulse velocity and Schmidt hammer tests. The LWC and SLWC yielded compressive strength of around 30 MPa and 33 MPa (i.e., 78-86% of control specimens), respectively. The findings indicate that scoria can be beneficially utilized in the development of structural lightweight concrete. Present renewable sources of aggregate will preserve the natural resources for next generation. The newly produced eco-friendly construction material is intended to break price barriers in all markets and draw attraction of incorporating scoria based light weight construction in Saudi Arabia and GCC countries. Findings of the SWOT analysis indicate that high logistics costs for distributing the aggregates across different regions in Saudi Arabia and clients' resistant to change are among the major obstacles to the commercialized production and utilization of lightweight concrete as green construction material. The findings further revealed that huge scoria deposits in Saudi Arabia, and the potential decrease in density self-weight of structural elements are the major drivers and enablers for promoting the adoption of lightweight concrete as alternative green construction material in the construction sector.

Scale-Up of Polymerization Process of Biodegradable Polymer Poly(lactic acid) Synthesis Using Direct Polycondensation Method

  • Pivsa-Art, Sommai;Niamlang, Sumonman;Pivsa-Art, Weraporn;Santipatee, Nutchapon;Wongborh, Tossamon;Pavasupree, Sorapong;Ishimoto, Kiyoaki;Ohara, Hitomi
    • International Journal of Advanced Culture Technology
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    • v.3 no.2
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    • pp.100-109
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    • 2015
  • Environmental problems from petroleum-based plastic wastes have been rapidly increasing in recent years. The alternative solution is focus on the development of environmental friendly plastic derived from renewable resource. Poly(lactic acid) (PLA) is a biodegradable polymer synthesized from biomass having potential to replace the petroleum-based non-degradable polymers utilizations. PLA can be synthesized by two methods: (1) ring-opening of lactide intermediate and (2) direct polycondensation of lactic acid processes. The latter process has advantages on high yields and high purity of polymer products, materials handling and ease of process treatments. The polymerization process of PLA synthesis has been widely studied in a laboratory scale. However, the mass scale production using direct polycondensation of lactic acid has not been reported. We have investigated the kinetics and scale-up process of direct polycondensation method to produce PLA in a pilot scale. The order of reaction is 2 and activation energy of lactic acid to lactic acid oligomers is 61.58 kJ/mol. The pre-polymer was further polymerized in a solid state polymerization (SSP) process. The synthesized PLA from both the laboratory and pilot scales show the comparable properties such as melting temperature and molecular weight. The appearance of synthesized PLA is yellow-white solid powder.

Effects of Crushed Shells on the Physical Properties of Cement Mortar (분쇄패각이 시멘트 모르터의 물성에 미치는 영향)

  • Kim, Ji-Hyun;Chung, Chul-Woo;Lee, Jae-Yong
    • Journal of the Korea Institute of Building Construction
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    • v.14 no.1
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    • pp.94-101
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    • 2014
  • Approximately 240,000 tons of waste shells are produced annually in the south and west coast of South Korea. Some of these waste shells (oyster, cockle) are recycled as seeding collector and fertilizer, but most are dumped illegally near the coast. One of the alternative solutions that can economically utilize a large amount of these waste shells is to apply them to the production of construction materials. In this research, the basic physical properties of waste shells such as oyster, cockle, clam, manila clam were investigated, and were used to prepare cement mortar with a 25% replacement ratio of sand. According to the results, the 28 day compressive strength of cement mortar with cockle and manila clam shells was similar to that of plain cement mortar. The compressive strength decreased by about 18% when clam was used. However, the cement mortar with oyster shell showed about a 35% reduction in 28-day compressive strength, and two times the absorption capacity of plain cement mortar. The reduction in compressive strength and the increase in absorption capacity were mostly associated with the porous nature of the oyster shell.

Effect of Fiber Addition for Improving the Properties of Lightweight Foamed Concrete (경량 기포콘크리트의 성능향상에 대한 섬유혼입의 영향)

  • Lee, Kyung-Ho;Yang, Keun-Hyeok
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.4
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    • pp.383-389
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    • 2015
  • The objective of this study is to develop mixture proportioning approach of crack controlled lightweight foamed concrete without using high-pressure steam curing processes, as an alternative to autoclaved lightweight concrete blocks (class 0.6 specified in KS). To control thermal cracks owing to hydration heat of cementitious materials, 30% ground granulated blast-furnace slag (GGBS) was used as a partial replacement of ordinary portland cement (OPC). Furthermore, polyvinyl alcohol (PVA) and polyamid (PA) fibers were added to improve the crack resistance of foamed concrete. The use of 30% GGBS reduced the peak value of hydration production rate measured from isothermal tests by 28% and the peak temperature of foamed concrete measured from semi-adiabatic hydration tests by 9%. Considering the compressive strength development, internal void structure, and flexural strength of the lightweight foamed concrete, the optimum addition amount of PVA or PA fibers could be recommended to be $0.6kg/m^3$, although PA fiber slightly preferred to PVA fiber in enhancing the flexural strength of foamed concrete.

Dissolution Kinetics of Thiourea in Triglycol Solution (트리글리콜용액에서 싸이오우레아 용해 반응속도론)

  • Li, Hua;Guo, Feng;Hu, Guoqin;Zhao, Lei;Zhang, Yadong
    • Journal of the Korean Chemical Society
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    • v.54 no.1
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    • pp.88-92
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    • 2010
  • Isopropyl mercaptan is an important pharmaceutical intermediate and chemical material. And thiourea and triglycol are the main materials for the synthesis of isopropyl mercaptan. Therefore the dissolution of thiourea in triglycol solution is very important for the production of isopropyl mercaptan. The aims of this study are to examine the dissolution kinetics of thiourea in triglycol solution, and to present an alternative process for producing isopropyl mercaptan. In order to investigate the dissolution kinetics of thiourea in triglycol solution, the concentrations of solution and reaction temperature were selected as experimental parameters. It was determined that the dissolution rate of thiourea increased with the increase in solution concentration and temperature. An empirical equation was used in fitting the data. Statistical analysis indicated small errors and the results should be reliable.

Experimental Comparative Analysis of Terrestrial Lidar Data and Cadastral Data for the Calculation of the Slope Area of Highland Agriculture Region (고랭지 농업지역의 경지면적 산출을 위한 지상라이다 데이터와 지적성과의 실험적 비교 분석)

  • Lee, Ho-Hyun;Lee, Jung-Il;Oh, Min-Kyun;Lee, Kyung-Do
    • Journal of Cadastre & Land InformatiX
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    • v.46 no.2
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    • pp.137-153
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    • 2016
  • The price of agricultural products has changed from year to year, the m ajor c ause o f price fluctuation is the imbalance of supply and demand. Materials which are mainly used in korean cabbage production volume is the forecast model, using the cadastral result, slope calculation is impossible to achieved. For this reason, this implies the drastic decrease of prices and the prediction of supply and demand of field crops that is cultivated in a highland slope area, this situation is being repeated. Therefore, the target area of this research is the slopes of high land, by using 2D and 3D Lidar data for the analysis of the cultivated area. Experiment was carried out in the same area to compare the data differences. The rate of change in the area of slope is quantitatively increasing presented by the regression model. An alternative methodology that can improve the reliability of the calculated slope area using 2D is through cadastral map.

The Role of Cover Material in Soil Water Retention and Growth of Tropaeolum majus and Fragaria spp. by Vertical Farming using Hanging Baskets in Urban Agriculture (도시농업을 위한 저관리 용기형 수직녹화에서 피복재가 토양수분 및 한련화와 딸기의 식물생장에 미치는 영향)

  • Ju, Jin-Hee;Yang, Ji;Park, Ju-Young;Yoon, Yong-Han
    • Journal of Environmental Science International
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    • v.27 no.5
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    • pp.291-297
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    • 2018
  • Vertical farming systems offer many advantages in urban spaces. They have also been proposed as an engineering solution to increase the productivity per unit area of cultivated land by extending crop production in the vertical dimension. However, soil water retention is a major constraint affecting the plant environment. This study analyzed the effects of growth environment of Tropaeolum majus and Fragaria spp., on the vertical farming system, by using four different types of cover material types including sphagnum moss (Control), a shading net (S.N.), multi-layered fabric (M.L.F.), and non-woven fabric (N.W.F.). The volumetric soil moisture contents and plant characteristics were investigated from May to September 2014. Plant materials were individually cultivated in hanging baskets measuring $30{\times}17{\times}17cm$, filled with a mixture of soil and perlite, and placed at 1.5m height. Each treatment was performed in quadruplicate and consisted of five plants, amounting to a total of 20 plants. The analysis indicated that different covers were associated with multiple functions and soil water retention improvements may have a positive impact on the vertical farming system. The difference in soil water retention increased in the following order: M.L.F. > Control > N.W.F. > S.N.. Furthermore, the differences in plant height and survival rate increased in the following order: M.L.F. > Control > N.W.F. > S.N. Therefore, M.L.F yielded satisfactory good response for the vertical farming system of cover materials. Our results clearly demonstrate that vertical spaces represent an attractive alternative to urban farming and suggest that further increases in yield may be achieved via different cover materials in vertical farming using hanging baskets.