• Title/Summary/Keyword: Process Modification

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Change of Antioxidant Activities in Carrots (Daucus carota var. sativa) with Enzyme Treatment (효소처리 가공이 당근(Daucus carota var. sativa)의 항산화 활성 변화에 미치는 영향)

  • Yoo, Jin-Kyoun;Lee, Jin-Hee;Cho, Hyung-Yong;Kim, Jung-Gook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.2
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    • pp.262-267
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    • 2013
  • The purpose of this research is to minimize the loss of nutrients in carrots (Daucus carota var. sativa). A protopectinase was used to enzymatically macerated and separate cells without damage. The enzyme modification group's collection rate was 81% (residue rate 19%), while the grinding process group's collection rate was 56% (residue rate 44%)-an over 20% of collection rate difference. Thus we predicted a big difference in transference number after the process and wastage. In comparing ingredient changes in the enzyme modification group versus the grinding process group, the content of ${\beta}$-carotene (the carrot's main ingredient) showed a change in protection factor (PF) ($2.2{\pm}0.2$ PF, $1.4{\pm}0.4$ PF, respectively), total polyphenol content ($89{\pm}3.42{\mu}g/g$, $64{\pm}4.16{\mu}g/g$, respectively), and total flavonoid content ($68{\pm}2.73{\mu}g/g$, $41{\pm}3.26{\mu}g/g$, respectively). Thus we confirmed that nutrient destruction, due to cell membrane preservation, occurred less often in the enzyme modification process than the mechanical grinding process group. We also measured DPPH radical scavenging activity, hydroxyl radical scavenging activity, and nitrite scavenging activity. DPPH radical scavenging activity was $87{\pm}0.29%$ and $74{\pm}1.56%$ in the enzymatic modification group compared to the mechanical grinding process group, respectively. Hydroxyl radical scavenging activity was $44{\pm}0.49%$ and $32{\pm}0.48%$ in the enzymatic modification group compared to the mechanical grinding process group, respectively. Nitrite scavenging activity was $59{\pm}0.53%$ and $46{\pm}0.62%$ in the enzymatic modification group compared to the mechanical grinding process group, respectively. Our results show that cell membrane preservation, via the protopectinase enzyme process, decreases the loss of nutrients and still preserves inherent antioxidants.

Modification of Dielectric Surface in Organic Thin-Film Transistor with Organic Molecule

  • Kim, Jong-Moo;Lee, Joo-Won;Kim, Young-Min;Park, Jung-Soo;Kim, Jai-Kyeong;Ju, Byeong-Kwon;Oh, Myung-Hwan;Kim, Jong-Seung;Jang, Jin
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1030-1033
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    • 2004
  • We herewith report for the effect of dielectric surface modification on the electrical characteristics of organic thin-film transistors (OTFTs). The kist-jm-1 as an organic molecule for the surface modification is deposited onto the surface of zirconium oxide ($ZrO_2$) gate dielectric layer. The OTFTs are elaborated on the flexible plastic substrates through 4-level mask process to yield a simple fabrication process. In this work, we also have examined the dependence of electrical performance on the interface surface state of gate dielectric/pentacene, which may be modified by chemical properties in the gate dielectric surface.

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Surface modification for block copolymer nanolithographyon gold surface

  • Hwang, In-Chan;Bang, Seong-Hwan;Lee, Byeong-Ju;LeeHan, Bo-Ram;Kim, Hyeong-Jun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.33.2-33.2
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    • 2009
  • Block copolymer lithography has attracted great attention for emerging nanolithography since nanoscaleperiodic patterns can be easily obtained through self-assembly process without conventional top-down patterning process. Since the morphologies of self-assembled block copolymer patterns are strongly dependent on surface energy of a substrate, suitable surface modification is required. Until now, the surface modification has been studied by using random copolymer or self-assembled mono layers (SAMs). However, the research on surface modifications has been limited within several substrates such as Si-based materials. In present study, we investigated the formation of block copolymer on Au substrate by $O_2$ plasma treatment with the SAM of 3-(p-methoxy-phenyl)propyltrichloro-silane [MPTS, $CH_3OPh(CH_2)_3SiCl_3$]. After $O_2$ plasma treatment, the chemical bonding states of the surface were analyzed by X-ray photoelectron spectroscopy (XPS). The static contact angle measurement was performed to study the effects of $O_2$ plasma treatment on the formation of MPTS monolayer. The block copolymer nanotemplates formed on Au surface were analyzed by scanning electron microscopy. The results showed that the ordering of self-assembled block copolymer pattern and the formation of cylindrical nano hole arrays were enhanced dramatically by oxygen plasma treatment. Thus, the oxidation of gold surface by $O_2$ plasma treatment enables the MPTS to form the monolayer assembly leading to surface neutralization of gold substrates.

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Influence of solvent on the nano porous silica aerogels prepared by ambient drying process (상압건조 나노다공성 실리카 에어로젤에 대한 용매의 영향)

  • Ryu, Sung-Wuk;Kim, Sang-Sig;Oh, Young-Jei
    • Journal of Sensor Science and Technology
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    • v.15 no.5
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    • pp.371-377
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    • 2006
  • Nano porous, transparent silica aerogels monoliths were prepared under ambient drying (1 atm, $270^{\circ}C$) condition by the combination of sol-gel process and surface modification with subsequent heat treatment. Three kinds of solvent, n-hexane, n-heptane and xylene, were selected in the point view of low surface tension and vapor pressure in order to restrain a formation of cracks during drying. Crack-free silica aerogels with over 93 % of porosity and below $0.14g/cm^3$ of density were obtained by solvent exchange and surface modification under atmosphere condition. Optimum solvent was confirmed n-heptane among these solvents through estimation of FT-IR, TGA, BET and SEM. Modified silica aerogel exhibited a higher porosity and pore size compare to unmodified aerogels. Hydrophobicity was also controled by C-H and H-OH bonding state in the gel structure and heat treatment over $400^{\circ}C$ effects to the hydrophobicity due to oxidation of C-H radicals.

Structural Dynamics Modification Using Surface Grooving Technique: Application to HDD Cover Model (그루브를 이용한 표면형상변형 동특성 변경법 : HDD 커버에 대한 적용)

  • Park, Mi-You;Park, Youngjin;Park, Youn-sik
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.15 no.3 s.96
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    • pp.341-345
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    • 2005
  • Structural Dynamics Modification (SDM) is a very effective technique to improve structure's dynamic characteristics by adding or removing auxiliary structures, changing material properties and shape of structure. Among those of SDM technique, the method to change shape of structure has been mostly relied on engineer's experience and trial-and-error process which are very time consuming. In order to develop a systematic method to change structure shape, surface grooving technique is studied. In this work, the shape of base structure was modified to improve its dynamic characteristics such as natural frequencies via surface grooving technique. Grooving shape was formed by mergingthe neighboring small embossing elements after analyzing frequency increment sensitivities of all the neighboring emboss elements. For this process, Criterion Factor was introduced and the initial grooving was started from the element having highest strain energy and the grooving is expanded into neighboring element. The range of targeting grooving area to check its frequency variations restricted to their neighboring area to reduce the computation effort. This surface grooving technique was successfully applied to a hard disk drives (HDD) cover model to raise its natural frequency by giving some groove on its surface.

Design Modification of Marine Turning Gear Based on Spur Planetary Gear (스퍼 유성감속기 기반 선박용 터닝기어의 설계 변경)

  • Kim, Kun-Woo;Lee, Jae-Wook;Jang, Jin-Seok;Oh, Joo-Young;Hong, Jong-Hae;Lee, Kang-Jae
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.18 no.12
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    • pp.7-14
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    • 2019
  • A marine turning gear controls the position of the piston-crank mechanism by rotating the flywheel of the marine engine at a low speed, which is the main auxiliary machine that enables the disassembly and maintenance of the engine. In this study, the safety factor for surface durability and tooth bending strength was improved by the design modification of the marine turning gear based on the spur planetary gear. Angular velocity, torque, and efficiency of the turning gear were measured using a reliability evaluation tester, and a multibody dynamics model for analysis corresponding to the test results was developed. Finally, it was confirmed that the design improvements improved the tooth surface damage of the sun gear in the 3rd reduction stage.

The Synthesis of Hydrophobic Silica Aerogel in the Macroporous Ceramic Structure by Ambient Drying Process (상압 건조 공정을 이용한 다공성 세라믹스 구조체 내부에 소수성 실리카 에어로겔의 합성)

  • Hong, Sun-Wook;Song, In-Hyuck;Park, Young-Jo;Yun, Hui-Suk;Hahn, Yoo-Dong;Hwang, Ki-Young;Rhee, Young-Woo
    • Journal of Powder Materials
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    • v.18 no.3
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    • pp.269-276
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    • 2011
  • The synthesis behavior of nanoporous silica aerogel in the macroporous ceramic structure was observed using TEOS as a source material and glycerol as a dry control chemical additive (DCCA). Silica aerogel in the macroporous ceramic structure was synthesized via sono-gel process using hexamethyldiazane (HMDS) as a modification agent and n-hexane as a main solvent. The wet gel with a modified surface was dried at $105^{\circ}C$ under ambient pressure. The addition of glycerol appears to give the wet gel a more homogeneous microstructure. However, glycerol also retarded the rate of surface modification and solvent exchange. Silica aerogel completely filled the macroporous ceramic structure without defect in the condition of surface modification (20% HMDS/nhexane at 36hr).

Structural dynamics modification using non-matching substructure synthesis. (비부합 결합을 이용한 구조물 변경법)

  • 정의일;박윤식
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2002.05a
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    • pp.666-671
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    • 2002
  • For a large structure, substructure based SDM(structural dynamics modification) method is very effective to raise its dynamic characteristics. Dividing into smaller substructures has a major advantage in the aspect of computation especially for getting sensitivities, which are in the core of SDM process. But quite often, non-matching nodes problem occurs in the process of synthesizing substructures. The reason is that, in general, each substructure is modelled separately, then later combined together to form a entire structure model under interface constraint conditions. Without solving the non-matching nodes problem, the substructure based SDM can not be processed. In this work, virtual node concept is introduced. Lagrange multipliers are used to enforce the interface compatibility constraint. The governing equation of whole structure is derived using hybrid variational principle. The eigenvalues of whole structure are calculated using determinant search method. The number of degrees of freedom of the eigenvalue problem can be drastically reduced to just the number of interface degree of freedom. Thus, the eigenvalue sensitivities can be easily calculated, and further SDM can be efficiently performed. Some numerical problems are tested to show the effectiveness of handling non-matching nodes.

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Adhesion of Cu on Polycarbonate with the Condition of Surface Modification and DC-Bias Sputtering Deposition (폴리카보네이트에서의 표면개질 조건과 DC-Bias Sputtering 증착에 따른 Cu 밀착성)

  • 배길상;엄준선;이인선;김상호;고영배;김동원
    • Journal of the Korean institute of surface engineering
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    • v.37 no.1
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    • pp.5-12
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    • 2004
  • The enhancement of adhesion for Cu film on polycarbonate (PC) surface with the $Ar/O_2$ gas plasma treatment and dc-bias sputtering was studied. The plasma treatment with this reactive mixture changes the chemical property of PC surface into hydrophllic one, which is shown by the variation of contact angle with surface modification. The micro surface roughness that also gives the high adhesive environment is increased by the $Ar/O_2$ gas plasma treatment. These results were observed distinctly from the atomic force microscopy (AFM). The negative substrate dc-bias effect for the Cu adhesion on PC was also investifated. Accelerated $Ar^{+}$ lons in sheath area of anode bombard the bare surface of PC during initial stage of dc bias sputtering. PC substrate. therefore, has severe roughen and hydrophilic surface due to the physical etching process with more activated functional group. As dc-bias sputtering process proceeds, morphology of Cu film shows better step coverage and dense layer. The results of peel test show the evidence of superiority of bias sputtering for the adhesion between metal Cu and PC.C.

Surface Modification Studies by Atomic Force Microscopy for Ar-Plasma Treated Polyethylene

  • Seo, Eun-Deock
    • Macromolecular Research
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    • v.10 no.5
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    • pp.291-295
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    • 2002
  • Atomic force microscopy(AFM) was used to study the polyethylene(PE) surfaces grafted and immobilized with acrylic acid by Ar plasma treatment. The topographical images and parameters including RMS roughness and Rp-v value provided an appropriate means to characterize the surfaces. The plasma grafting and immobilization method were a useful tool for the preparation of surfaces with carboxyl group. However, the plasma immobilization method turned out to have a limitation to use as a means of preparation of PE surface with specific functionalities, due to ablation effect during the Ar plasma treatment process.