• 제목/요약/키워드: Process Decomposition

검색결과 1,263건 처리시간 0.024초

A Comparative Study on Litter Decomposition of Emergent Macrophytes in the Littoral Zone of Reservoir

  • 조강현;공학양
    • Animal cells and systems
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    • 제2권3호
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    • pp.333-339
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    • 1998
  • Litter decomposition is a key process in energy flow and nutrient cycling in the freshwater littoral zone, and is regulated by physicochemical properties of litters. Using a litterbag method, we compared the decomposition rates of 16 different litter types from 10 plant species of the emergent macrophytes for one year in the littoral zone of the Paltangho Reservoir, Korea. The regression analysis fitted to the various decomposition models showed that mass loss of the litters with time best fitted an asymptotic function. The litters of the emergent macrophytes were composed of two compartments, labile and refractory. The macrophytic litters showed a great variety in decomposition dynamics depending on sources of litters. The labile compartment of the initial litter mass was in a wide range between 18% and 99%, and their decomposition rates varied from 0.0037 to 0.0131 day-1. The decomposition processes of the emergent macrophytes were determined by the relative amounts of the labile and refractory compartments and by the decomposition rate of the habile one in the littoral zone.

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Effect of $H_2O_2$ and Metals on The Sonochemical Decomposition of Humic Substances in Wastewater Effluent

  • Jung, Oh-Jun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제10권S_3호
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    • pp.127-137
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    • 2001
  • The sonochemical Process has been applied as a treatment method and was investigated its effect on the decomposition of humic substances(HS). The reaction kinetics and mechanisms in the Process of sonochemical treatment for humic substances(HS) in wastewater have also been discussed. It was observed that the metal ions such as Fe(II) and Mn(II) showed catalytic effects, while Al(III), Ca(II), and Mg(II) had inhibitory effects on the decomposition of humic substances in sonochemical reaction with hydrogen peroxide. Experimental results also showed factors such as hydrogen peroxide dose affected the formation of disinfection by-products. Two trihalomethanes, chloroform and dichlorobromomethane were formed as major disinfection by-products during chlorination. The mechanism of radical reaction is controlled by an oxidation process. The radicals are so reactive that most of them are consumed by HS radicals and hydroxyl radicals can be acted on organic solutes by hydroxyl addition, hydrogen abstraction, and electron transfer. The depolymerization and the radical reaction of HS radicals appear to occur simultaneously. The final steps of the reaction are the conversion of organic acids to carbon dioxide.

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사용빈도와 의미투명도가 복합명사의 분리처리에 미치는 효과 (Effects of word frequency and semantic transparency on decomposition processes of compound nouns)

  • 이태연
    • 인지과학
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    • 제18권4호
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    • pp.371-398
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    • 2007
  • 이 연구는 의미점화과제와 반복점화과제를 사용하여 사용빈도와 의미투명성이 복합명사의 분리처리 양상에 어떤 영향을 미치는지를 알아보았다. 실험 1에서는 사용빈도에 따라 복합명사의 분리처리 양상이 달라지는지를 검토하였다. 의미점화효과가 복합명사 연상어 조건에서 자극제시시차나 사용빈도와 무관하게 관찰되었으며, 반복점화효과는 부분조건과 전체조건에서 모두 관찰되었지만 부분조건에서 더 큰 반복점화효과를 보였다. 이 결과는 복합명사가 하위 형태소로 분리되어 처리되는 경로와 복합명사 전체로 처리되는 경로가 함께 존재할 가능성을 보여준다. 실험 2에서는 의미투명도에 따라 복합명사의 분리처리 양상이 달라지는지를 검토하였다. 의미점화효과가 복합명사 연상어 조건에서 자극제시시차나 의미투명도에 무관하게 관찰되었으며, 반복점화과제에서도 실험 1b와 유사한 결과를 보였다. 실험 1과 2의 결과는 어휘수준에서 분리처리경로와 전체처리경로를 통해 활성화된 의미가 개념 수준에서 이루어지는 상호작용과정을 통해 복합명사의 의미를 결정함을 시사한다.

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Studies on decomposition behavior of oxalic acid waste by UVC photo-Fenton advanced oxidation process

  • Kim, Jin-Hee;Lee, Hyun-Kyu;Park, Yoon-Ji;Lee, Sae-Binna;Choi, Sang-June;Oh, Wonzin;Kim, Hak-Soo;Kim, Cho-Rong;Kim, Ki-Chul;Seo, Bum-Chul
    • Nuclear Engineering and Technology
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    • 제51권8호
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    • pp.1957-1963
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    • 2019
  • A UVC photo-Fenton advanced oxidation process (AOP) was studied to develop a process for the decomposition of oxalic acid waste generated in the chemical decontamination of nuclear power plants. The oxalate decomposition behavior was investigated by using a UVC photo-Fenton reactor system with a recirculation tank. The effects of the three operational variables-UVC irradiation, H2O2 and Fenton reagent-on the oxalate decomposition behavior were experimentally studied, and the behavior of the decomposition product, CO2, was observed. UVC irradiation of oxalate resulted in vigorous CO2 bubbling, and the irradiation dose was thought to be a rate-determining variable. Based on the above results, the oxalate decomposition kinetics were investigated from the viewpoint of radical formation, propagation, and termination reactions. The proposed UVC irradiation density model, expressed by the first-order reaction of oxalate with the same amount of H2O2 consumption, satisfactorily predicted the oxalate decomposition behavior, irrespective of the circulate rate in the reactor system within the experimental range.

분해가 고려된 쓰레기 매립지의 장기 침하 거동 (Long -Term Settlement Behavior of Landfills with Consideration of Refuse Decomposition)

  • 박현일;이승래;고광훈
    • 한국지반공학회지:지반
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    • 제14권1호
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    • pp.5-14
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    • 1998
  • 쓰레기 매립지의 장기 침하 메카니즘은 일반적인 홀의 거동과는 달리 생물학적인 분해에 의해서 크게 영향을 받는다. 본 논문에서는 쓰레기 매립지의 장기 침하량(역학적 이차침하량과 분해에 의한 이차침하량)을 예측하기 위하여 두 식이 사용되었다. 역학적 이차침하는 변형률-대수 시간에서 선형적인 관계를 갖는다고 가정하였다. 분해에 의한 침하를 평가하기 위하여, 분해 가능한 쓰레기 고형물의 용액화에 관련된 일차반응기작으로 모사되는 가수분해 과정을 고려한 모델을 숙성된 (aged) 쓰레기로 충진된 Lysimeter 침하자료에 적용하였다. 본 연구에서는 분해과정 가운데 쓰레기 고형물의 용액화로 말미암아 유발되는 침하를 효과적으로 모사할 수 있는 간단한 수학적 모델을 제안하고자 하였다.

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Parallel Process System and its Application to Steam Generator Structural Analysis

  • Chang Yoon-Suk;Ko Han-Ok;Choi Jae-Boong;Kim Young-Jin
    • Journal of Mechanical Science and Technology
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    • 제19권11호
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    • pp.2007-2015
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    • 2005
  • A large-scale analysis to evaluate complex material and structural behaviors is one of interesting topic in diverse engineering and scientific fields. Also, the utilization of massively parallel processors has been a recent trend of high performance computing. The objective of this paper is to introduce a parallel process system which consists of general purpose finite element analysis solver as well as parallelized PC cluster. The later was constructed using eight processing elements and the former was developed adopting both hierarchical domain decomposition method and balancing domain decomposition method. Then, to verify the efficiency of the established system, it was applied for structural analysis of steam generator in nuclear power plant. Since the prototypal evaluation results agreed well to the corresponding reference solutions it is believed that, after reinforcement of PC cluster by increasing number of processing elements, the promising parallel process system can be utilized as a useful tool for advanced structural integrity evaluation.

고분자물질 바닥재의 열적특성에 관한 연구 (A Study on Thermal Characteristics on Polymeric Floorings)

  • 이내우;김남석;문병수
    • 한국안전학회지
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    • 제21권6호
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    • pp.38-45
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    • 2006
  • Polymeric floorings mainly consisted of PVC are easily decomposed by many kinds of hot environmental factors, then generate hazardous asphyxiate gases and/or toxic gases etc. Therefore the mechanism of decomposition and quantitative toxic indices of products are very important for preventing safety and health disasters, especially in case of confined area. So we have investigated decomposition kinetics, numbers of process involved, toxicity indices of product and so on, using DSC, TGA, FT-IR and Pyrolyzer-GC/MS. The thermal decomposition process of polymeric floorings can be mainly divided by dehydrochlorinated reaction and polyene decomposition step, and activation energies of those are approximately $53.93{\sim}62.42kcal/mol$. Especially lethal concentration($LC_{50}$), fractional effective dose (FED) are calculated by measuring the amount of decomposition product. The values on $LC_{50}$ of sample G are ranged $2,003{\sim}2,019(mg/m^{3})$ in case of sample K and H are $1,877,\;1,998(g/m^{3})$ respectively. Even if the results are estimated by calculation method without animal test and/or clinical demonstration, these values could be very useful data for occupational health, hygiene and safety control.

분해탈기법에 의한 염색폐수 중의 고농도 질소 제거에 관한 연구 (Removal of High Strength Nitrogen in Dyeing Wastewater by Decomposition-Air Stripping Process)

  • 조병락
    • 한국산업융합학회 논문집
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    • 제5권3호
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    • pp.213-218
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    • 2002
  • Total nitrogen is a major pollutant which mostly causes eutrophication and red tide. Wastewater effluent from printing of cotton-viscose rayon containing high concentrations of total nitrogen can not be effectively treated with a typical biological treatment process. This paper provides a new treatment process and experimental results for the removal of high strength nitrogen from dyeing wastewater. The optimum conditions of air stripping for the removal of total nitrogen include around pH 12, temperature $60^{\circ}C$ with 60 minutes of stripping time. In case of a filtration-air stripping process, an initial level ($500mg/{\ell}$) of total nitrogen was significantly reduced to below $60mg/{\ell}$. Deconite was synthesised for further decomposition of organic nitrogen. Thus, a filtration-decomposition-air stripping process was possibly achieved, by which a high level ($900mg/{\ell}$) of total nitrogen was effectively removed to below $60mg/{\ell}$ P. Finally, a continuous new process for the removal of total nitrogen is proposed and confirmed, based on batch experimental results, and its process validity is further discussed throughout.

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페놀 분해를 위한 오존 나노기포 공정에서 초음파 조사의 영향 (Effect of Ultrasonic Irradiation on Ozone Nanobubble Process for Phenol Degradation)

  • 이상빈;박재우
    • 한국지반환경공학회 논문집
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    • 제23권3호
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    • pp.23-29
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    • 2022
  • 본 연구에서는 오존의 용해효율 개선과 자가분해 촉진을 위해 나노기포와 초음파 캐비테이션을 동시에 적용한 오존 나노기포 공정을 조사하였다. 공정의 유기물 분해효율을 파악하기 위해 200mm × 200mm × 300mm 규모의 반응기를 제작하여 다양한 조건에서 페놀 분해 실험을 진행하였다. 나노기포의 사용은 60분 반응에서 페놀 분해 효율을 일반적인 폭기 방식에 비해 2.07배 증가시켰으며, 용존 오존의 최대 용해농도를 크게 증가시켜 오존의 용해효율 개선에 효과적이었다. 초음파 조사는 나노기포와 함께 사용될 때 페놀 분해 효율을 36% 증가시켰으며 오존의 자가 분해 촉진으로 용존 오존은 낮게 나타났다. 초음파 출력이 강할수록 페놀 분해 효율도 증가하였으며, 실험에서 사용한 28kHz, 132kHz, 580kHz 중 132kHz의 주파수에서 페놀의 분해 효율이 가장 높게 나타났다. 오존 나노공정은 기존 오존 공정과 같이 높은 pH에서 더 좋은 분해효율을 보였으나 중성에서도 60분 반응 후 페놀 100% 분해를 달성하여 pH에 의한 영향이 적은 것으로 나타났다. 이는 초음파에 의한 오존 자가분해 촉진에 의한 것으로 판단된다. 초음파 조사에 의한 기포 특성 변화를 확인하기 위해 Zetasizer를 이용하여 기포의 크기와 제타 전위 분석을 진행하였으며 초음파 조사가 기포의 평균 크기를 11% 감소시키고 기포 표면의 음전하를 강화하여 오존 나노기포의 물질전달과 수산화 라디칼 생성 효율에 긍정적인 효과를 끼치는 것을 확인하였다.

모델링에 의한 퇴비화 시설의 운전성에 관한 연구 (Operability of Composting Facilities by Modeling)

  • 유영석;김이태;지재성
    • 유기물자원화
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    • 제3권2호
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    • pp.59-68
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    • 1995
  • 퇴비화 시설은 공기량과 수분 조절만으로 운전되기 때문에 2개의 운전인자의 영향을 분석하기 위하여 수분을 첨가하는 경우와 첨가하지 않는 경우에 대하여 공기량을 변화시켜 모델링하였다. 또한 최적의 퇴비화 환경이 조성될지라도 발열량 및 분해속도에 따라 퇴비화 시설의 운전온도를 달리하여야 하므로, 고속분해 단계와 완속분해 단계의 운전온도를 변화시켜 모델링함으로써 퇴비화 공정에 대한 영향을 분석하였다. 한편 모델은 미국 Roger T. Haug Inc 에서 개발한 "The Library of Compost Engineering Software" 를 사용하였다. 결과적으로 적정 함수율의 퇴비화 시설 운전이 공기량 변화에 대하여 운전온도의 변화가 민감하며, 수분이 부족한 경우에 비하여 오히려 적은 공기량으로 높은 반응율을 달성하게 된다. 완속분해 단계의 효과적인 운전이 전 공정의 분해율을 높일 수 있으므로 완속분해 물질의 분해에 촛점을 맞추어 단계별 운전온도를 설정하여야 함을 알 수 있었다.

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