• Title/Summary/Keyword: Primary decomposition

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Hydrogen Production by Catalytic Decomposition of Methane over Rubber-Grade Carbon Blacks (고무용 카본블랙 촉매를 이용하는 메탄분해에 의한 수소 생산)

  • Yoon Ki June;Ryu Bo Hyun;Lee Sang Yup;Han Gui Yong
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.06a
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    • pp.223-226
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    • 2005
  • For $CO_2-free$ hydrogen production and better utilization of the produced carbon, catalytic decomposition of methane over rubber-grade carbon blacks manufactured from coal tar was carried out. The catalytic activities of several domestic carbon blacks were compared. A pelletized carbon black exhibited considerably lower activity and activation energy than the fluffy( loose) carbon black of the same grade. This difference is considered due to the binder that was added during pelletization. For pelletized carbon blacks, a tendency was observed that the activity per unit mass of catalyst increased with the specific surface area of the carbon black. Another tendency was also observed that the activation energy increased with the primary particle size or decrease of the specific surface area.

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Intercalation of Primary Diamines in the Layered Perovskite Oxides, $HSr_2Nb_3o_{10}$

  • 홍영식;김시중
    • Bulletin of the Korean Chemical Society
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    • v.17 no.8
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    • pp.730-735
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    • 1996
  • The layered perovskite oxide, KSr2Nb3O10, was synthesized. The interlayer potassium cations were readily exchanged by protons in hydrochloric acid solution to give the protonation compound, HSr2Nb3O10·0.5H2O. The intercalation compounds, [NH3(CH2)nNH3]xSr2Nb3O10, were also obtained by acid-base reactions between the protonation compound and organic bases, 1,n-alkyldiamines. The interlayer distances in the intercalation compounds were linearly increased with the increase of the number of carbon (Δc/Δn=1.05 Å) in 1,n-alkyldiamines. The intercalated alkyldiammonium ions formed a paraffin-like monolayer with average tilting angle (θ) of ca. 56°. The intercalation reactions occurred stoichiometrically. The thermal decomposition process of the intercalation compounds showed distinct three steps due to the desorption of hydrated water, the decomposition of organic moiety, and the decomposition of Sr-related compounds.

The Properties on Fuzzy Submachines of a Fuzzy Finite State Machine

  • Hwang, Seok-Yoon
    • Journal of the Korean Institute of Intelligent Systems
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    • v.13 no.6
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    • pp.749-753
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    • 2003
  • In this paper we introduce the concepts on retrievability, separability and connectedness of fuzzy submachines, which generalize those of crisp submachines. And also we generalize crisp primary submachines to those with fuzziness, from which we obtain the decomposition theorem of fuzzy submachines.

Efficient Primary-Ambient Decomposition Algorithm for Audio Upmix (오디오 업믹스를 위한 효율적인 Primary-Ambient 분리 알고리즘)

  • Baek, Yong-Hyun;Lee, Keun-Sang;Jeon, Se-Woon;Lee, Seokpil;Park, Young-Choel
    • Proceedings of the Korean Society of Broadcast Engineers Conference
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    • 2012.07a
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    • pp.160-163
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    • 2012
  • 업믹스(Upmix) 기술은 홈시어터와 같은 다채널 스피커 재생 환경에서 콘텐츠의 대부분을 차지하는 스테레오 음원을 다채널 환경에 재생하기 위한 채널 포맷 변환 기술을 말한다. 업믹스를 위한 전처리 단계로서 특정 방향으로 패닝된 주(primary)성분과 잔향 및 배경음과 같은 Ambient 성분을 분리하는 과정이 필요하다. Primary와 Ambient를 분리하기 위한 방법으로 채널 간의 상관도, 적응 필터 및 주성분 분석법(principal component analysis, PCA)이 널리 이용되고 있다. 이에 본 논문에서는 비교적 정확하게 Primary와 Ambient를 분리한다고 알려진 주성분 분석법을 이용하여 신호를 분리해 내고 이 때 주성분 분석법이 가지는 문제점을 해결한 향상된 Primary-Ambient 분리 알고리즘을 제안하였다. 제안된 알고리즘은 분리 성능이 Primary 성분이 패닝된 각도에 영향을 받지 않으며 또한 Primary 성분에 섞인 잔여 Ambient를 제거함으로써 기존의 주성분 분석법 보다 더 정확하게 Primary와 Ambient를 분리 할 수 있고 상관성이 없는 Ambient 특성을 좀 더 정확하게 반영한다.

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Effect of the Diisocyanate Type on the Hydrolysis Behavior of Polyurethane

  • Dong-Eun Kim;Seung-Ho Kang;Sang-Ho Lee
    • Elastomers and Composites
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    • v.58 no.3
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    • pp.121-127
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    • 2023
  • The effect of diisocyanate type on the decomposition temperature of polyurethane (PU) hydrolysis was investigated in a subcritical water medium up to 250℃. PU samples were prepared using different types of diisocyanate: two aromatic diisocyanates (4,4'-methylene diphenyl diisocyanate (MDI) and methyl phenylene diisocyanate (TDI)), one unbranched aliphatic diisocyanate (hexamethylene diisocyanate (HDI)), and two cyclic aliphatic diisocyanates (4,4'-methylene dicyclohexyl diisocyanate (H12MDI) and isophorone diisocyanate (IPDI)). The pressure had no effect on hydrolysis in the range of 70-250 bar. The decomposition temperature of the PU samples increased in the following order: TDI-PU (199℃) < H12MDI ≈ IPDI ≈ HDI (218-220℃) < MDI-PU (237℃). This order of increase in temperature is related to the electron-donating ability of the group to connected to the nitrogen of the urethane unit. When the temperature of the (PU + water) mixture reached the specific decomposition temperature, the PU samples hydrolyzed completely within 5 min into primary amine and 1,4-butanediol. The hydrolysis products from MDI-PU and H12MDI-PU were separated into a liquid phase rich in (BD + water) and a solid low phase rich in amine, whereas the products from TDI-, IPDI-, and HDI-PU existed in a single aqueous phase.

Decomposition of primary tar influenced by char particle types and reaction time during biomass gasification (바이오매스 가스화시 촤 입자 종류 및 반응시간에 따른 일차타르의 분해 특성)

  • Park, Jinje;Lee, Yongwoon;Ryu, Changkook
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.33-36
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    • 2014
  • Gasification of biomass produces syngas containing CO, $H_2$ and/or $CH_4$, which can then be converted into energy or value-added fuels. One of key issues for efficient gasification is to minimize tar concentration in the syngas for use in a final conversion device such as gas engine. This study investigated the decomposition of primary tar by catalytic cracking using char as catalyst, of which the feature can be integrated into a fixed bed gasifier design. The pyrolysis vapor containing tar from pyrolysis of wood at $500^{\circ}C$ was passed through a reactor filled with or without char at $800^{\circ}C$ for a residence time of 1, 3 or 5 sec. Then, the condensable vapor (water and tar) and gases were analyzed for the yields and elemental composition. Four types of char particles with different microscopic surface area and pore size distribution: wood, paddy straw, palm kernel shell and activated carbon. The results were analyzed for the mass and carbon yields of tar and the composition of product gases to conclude the effects of char types and residence time.

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ON THE 2-ABSORBING SUBMODULES AND ZERO-DIVISOR GRAPH OF EQUIVALENCE CLASSES OF ZERO DIVISORS

  • Shiroyeh Payrovi;Yasaman Sadatrasul
    • Communications of the Korean Mathematical Society
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    • v.38 no.1
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    • pp.39-46
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    • 2023
  • Let R be a commutative ring, M be a Noetherian R-module, and N a 2-absorbing submodule of M such that r(N :R M) = 𝖕 is a prime ideal of R. The main result of the paper states that if N = Q1 ∩ ⋯ ∩ Qn with r(Qi :R M) = 𝖕i, for i = 1, . . . , n, is a minimal primary decomposition of N, then the following statements are true. (i) 𝖕 = 𝖕k for some 1 ≤ k ≤ n. (ii) For each j = 1, . . . , n there exists mj ∈ M such that 𝖕j = (N :R mj). (iii) For each i, j = 1, . . . , n either 𝖕i ⊆ 𝖕j or 𝖕j ⊆ 𝖕i. Let ΓE(M) denote the zero-divisor graph of equivalence classes of zero divisors of M. It is shown that {Q1∩ ⋯ ∩Qn-1, Q1∩ ⋯ ∩Qn-2, . . . , Q1} is an independent subset of V (ΓE(M)), whenever the zero submodule of M is a 2-absorbing submodule and Q1 ∩ ⋯ ∩ Qn = 0 is its minimal primary decomposition. Furthermore, it is proved that ΓE(M)[(0 :R M)], the induced subgraph of ΓE(M) by (0 :R M), is complete.

Decomposition of Rice Straw and Compost in an Acid Sulfate Soil under Aerobic and Anaerobic Conditions (특이산성토양(特異酸性土壤)에 있어서 볏짚 및 퇴비(堆肥)의 분해(分解)에 관(關)한 연구(硏究))

  • Lee, Sang Kyu;Yoo, Ick Dong;Parr, James F.
    • Korean Journal of Soil Science and Fertilizer
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    • v.8 no.4
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    • pp.171-176
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    • 1975
  • The rate and extent of decomposition of rice straw and compost in an acid sulfate soil amended with urea and lime and incubated under aerobic and anaerobic(flooded) conditions were investigated in the laboratory. Results are summarized as follows: 1. The rate of compost(alone) decomposition in a flooded soil was more than twice as high as all other treatments, which included rice straw+urea, rice straw+lime, rice straw (alone), and compost+lime. Lime appeared to suppress the decomposition of compost in a flooded soil but actually enhanced its decomposition under aerobic conditions. 2. Compost decomposition in both anaerobic and aerobic environments was characterized by single maximum peak rates of $CO_2$ evolution that were reached soon after the start of incubation. 3. Both urea and lime greatly increased the rate and extent of rice straw decomposition in the soil when incubated aerobically, although urea had a greater effect than did liming. Decomposition rates were characterized by the appearance of two maximum peak rates, a greater primary peak and a smaller secondary peak. 4. The percent decomposition of rice straw in soil incubated aerobically was approximately half (10.8%) that of compost(23.1%). However, percent decomposition of these substrates in soil amended with lime was essentially the same; i.e., rice straw+lime (29.4%) and compost+lime(31.6%). 5. There is a need to investigate the possible interaction between the addition of lime (pH) and supplemental nitrogen applied to acid sulfate soils and how this interaction might affect the decomposition of organic wastes and residues.

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Oscillating Boundary Layer Flow and Low Frequency Instability in Hybrid Rocket Combustion (하이브리드 로켓 연소에서의 경계층 진동 변화와 저주파수 연소불안정)

  • Kim, Jina;Lee, Changjin
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.47 no.10
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    • pp.720-727
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    • 2019
  • Resonating thermal lags of solid fuel with heat transfer oscillations generated by boundary layer oscillation is the primary mechanism of the occurrence of the LFI (Low Frequency Combustion Instability) in hybrid rocket combustion. This study was experimentally attempted to confirm that how the boundary layer was perturbed and led to the LFI. Special attention was also made on oxidizer swirl injection to investigate the contribution to combustion stabilization. Also the overall behavior of fluctuating boundary layer flow and the occurrence of the LFI was monitored as swirl intensity increased. Fluctuating boundary layer was successfully monitored by the captured image and POD (Proper Orthogonal Decomposition) analysis. In the results, oscillating boundary layer became stabilized as the swirl intensity increases. And the coupling strength between high frequency p', q' diminished and periodical amplification of RI (Rayleigh Index) with similar frequency band of thermal lag was also decreased. Thus, results confirmed that oscillating axial boundary layer triggered by periodic coupling of high frequency p', q' is the primary mechanism to excite thermal resonance with thermal lag characteristics of solid fuel.