• 제목/요약/키워드: Preferred temperature

검색결과 577건 처리시간 0.025초

루테늄 삽입층에 의한 니켈모노실리사이드의 안정화 (Thermal Stability of Ru-inserted Nickel Monosilicides)

  • 윤기정;송오성
    • 대한금속재료학회지
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    • 제46권3호
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    • pp.159-168
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    • 2008
  • Thermally-evaporated 10 nm-Ni/1 nm-Ru/(30 nm or 70 nm-poly)Si structures were fabricated in order to investigate the thermal stability of Ru-inserted nickel monosilicide. The silicide samples underwent rapid thermal anne aling at $300{\sim}1,100^{\circ}C$ for 40 seconds. Silicides suitable for the salicide process were formed on the top of the single crystal and polycrystalline silicon substrates mimicking actives and gates. The sheet resistance was measured using a four-point probe. High resolution X-ray diffraction and Auger depth profiling were used for phase and chemical composition analysis, respectively. Transmission electron microscope and scanning probe microscope(SPM) were used to determine the cross-sectional structure and surface roughness. The silicide, which formed on single crystal silicon and 30 nm polysilicon substrate, could defer the transformation of $Ni_2Si $i and $NiSi_2 $, and was stable at temperatures up to $1,100^{\circ}C$ and $1,100^{\circ}C$, respectively. Regarding microstructure, the nano-size NiSi preferred phase was observed on single crystalline Si substrate, and agglomerate phase was shown on 30 nm-thick polycrystalline Si substrate, respectively. The silicide, formed on 70 nm polysilicon substrate, showed high resistance at temperatures >$700^{\circ}C$ caused by mixed microstructure. Through SPM analysis, we confirmed that the surface roughness increased abruptly on single crystal Si substrate while not changed on polycrystalline substrate. The Ru-inserted nickel monosilicide could maintain a low resistance in wide temperature range and is considered suitable for the nano-thick silicide process.

열 퍼머넌트 웨이브 시술 시 로드의 열 형성에 따른 모발의 형태적 손상에 관한 연구 (Morphological Damages of Hair by Heat Formation of Rods during Heat Perm)

  • 오수련;임순녀
    • 산업융합연구
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    • 제18권6호
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    • pp.99-105
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    • 2020
  • 일반적으로 모발에 웨이브를 형성시키기 위해서 시술하는 퍼머넌트 웨이브 중에서도 가장 자연스럽고 탄력있는 웨이브를 얻기 위해서 열을 이용한 시술을 선호한다. 이에 본 연구는 퍼머넌트 웨이브 시술시 사용되는 로드의 열 형성도에 따라서 모발에 미치는 표면적인 모발의 손상도를 주사전자현미경을 활용하여 측정하였다. 로드의 열 형성이 웨이브에 미치는 영향력을 알아보기 위해 열 로드에서 전달되는 온도를 측정하고 웨이브를 시술하여 웨이브 된 둥근 모양의 형태대로 모발을 절단한 후 처치를 하였다. 주사전자현미경 관찰에서 뜨거운 열이 직접적으로 닿은 부분은 모발이 끊어진 것을 확인할 수 있었는데 끊어진 면이 매끄러운 현상을 보였다. 본 연구의 결과로는 퍼머넌트 웨이브시에 사용되는 열 로드는 열 전달이 로드 전체에 고르게 전달되는 특성을 가지고 있는 재질을 활용하고 로드의 구조 또한 중요함을 인식하고 미용 업계에서 활발한 연구가 이뤄져야 할 것으로 사료된다.

Evaluation of extraction methods for essential oils in mugwort (Artemisia montana) using gas chromatography-mass spectrometry

  • Kim, Jihwan;Oh, Si-Eun;Choi, Eunjung;Lee, Sung-Hoon;Hwang, In Hyun;Kim, Ju-Young;Lee, Wonwoong
    • 분석과학
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    • 제35권2호
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    • pp.53-59
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    • 2022
  • Mugwort (Artemisia montana), which is a perennial plant mainly distributed throughout Northeast Asian regions, has been used as a preferred source of various foods and traditional medicines in Korea. In particular, as essential oils extracted from mugwort were reported to be biologically active, its steam distillate has been widely used to treat various conditions, such as itching, hemorrhoids, and gynecological inflammation. Therefore, efforts have been devoted to develop effective methods for the collection of bioactive essential oils from mugwort. In this study, five mugwort extracts were obtained using different extraction conditions, namely, 6 % ethanol at room temperature and at 80 ℃, pure ethanol, n-hexane, and an adsorbent resin. To evaluate the five extracts of mugwort, area-under-the-curve values (AUCs), chemical profiles, and major bioactive essential oil contents were investigated using gas chromatography-mass spectrometry (GC-MS). An overall assessment of the volatile components, including essential oils, in the five extracts was conducted using AUCs, and the individual essential oil in each extract was identified. Furthermore, the four major essential oils (1,8-cineole, camphor, borneol, and α-terpineol), which are known to possess anti-microbial and anti-inflammatory activities, were quantified using authentic chemical standards. Based on the evaluation results, pure ethanol was the best extractant out of the five used in this study. This study provides evaluation results for the five different mugwort extracts and would be helpful for developing extraction methods to efficiently collect the bioactive oil components for medical purposes using chemical profiles of the extracts.

Assessing the Formation of Polycyclic Aromatic Hydrocarbons in Grilled Beef Steak and Beef Patty with Different Charcoals by the Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) Method with Gas Chromatography-Mass Spectrometry

  • Ali Samet Babaoglu
    • 한국축산식품학회지
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    • 제43권5호
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    • pp.826-839
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    • 2023
  • This study investigated the effects of different charcoals on the occurrence of 16 polycyclic aromatic hydrocarbons (PAHs) in grilled beef steaks and beef patties. Seven different charcoals were used as follows: from oak wood (C1), from orange wood (C2), from Valonia oak wood (C3), from Marabu wood (C4), extruded charcoal from beech wood (C5), from coconut shells (C6), and from hazelnut shells (C7). The grilling times for each charcoal type were 6 min for the beef patties and 7 min for the beef steaks, until the internal temperature reached at least 74℃. The total concentration of 16 PAHs (PAH16) in beef steaks grilled with C1 (35.75 ㎍/kg) and C7 (36.39 ㎍/kg) was higher than that of C3 (23.80 ㎍/kg) and C6 (24.48 ㎍/kg; p<0.05). The highest amounts of PAH16 (216.40 ㎍/kg) were determined in the beef patty samples grilled using C5 (p<0.05). The summation of benzo[a]anthracene, chrysene, benzo[b]fluoranthene and benzo[a]pyrene, referred to as PAH4, was not detected in any of the beef steaks, whereas it was determined in the beef patties grilled with C2 (7.72 ㎍/kg) and C5 (22.95 ㎍/kg; p<0.05). The PAH16 concentrations of the beef patty samples in each charcoal group were significantly higher compared to the beef steaks (p<0.05). To avoid the formation of high PAH levels, the use of extruded charcoal and hazelnut shell charcoal should therefore be avoided when charcoal grilling beef steaks and beef patties, and low-fat meat products should be preferred.

산화물환원과 압축성형 공정에 의한 Bi2Te2.5Se0.5 화합물의 제조와 열전특성 (Fabrication of Bi2Te2.5Se0.5 by Combining Oxide-reduction and Compressive-forming Process and Its Thermoelectric Properties)

  • 임영수;이길근
    • 한국분말재료학회지
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    • 제31권1호
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    • pp.50-56
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    • 2024
  • We report the effect of plastic deformation on the thermoelectric properties of n-type Bi2Te2.5Se0.5 compounds. N-type Bi2Te2.5Se0.5 powders are synthesized by an oxide-reduction process and consolidated via spark-plasma sintering. To explore the effect of plastic deformation on the thermoelectric properties, the sintered bodies are subjected to uniaxial pressure to induce a controlled amount of compressive strains (-0.2, -0.3, and -0.4). The shaping temperature is set using a thermochemical analyzer, and the plastic deformation effect is assessed without altering the material composition through differential scanning calorimetry. This strategy is crucial because the conventional hot-forging process can often lead to alterations in material composition due to the high volatility of chalcogen elements. With increasing compressive strain, the (00l) planes become aligned in the direction perpendicular to the pressure axis. Furthermore, an increase in the carrier concentration is observed upon compressive plastic deformation, i.e., the donor-like effect of the plastic deformation in n-type Bi2Te2.5Se0.5 compounds. Owing to the increased electrical conductivity through the preferred orientation and the donor-like effect, an improved ZT is achieved in n-type Bi2Te2.5Se0.5 through the compressive-forming process.

A comparative experimental study on the mechanical properties of cast-in-place and precast concrete-frozen soil interfaces

  • Guo Zheng;Ke Xue;Jian Hu;Mingli Zhang;Desheng Li;Ping Yang;Jun Xie
    • Geomechanics and Engineering
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    • 제36권2호
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    • pp.145-156
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    • 2024
  • The mechanical properties of the concrete-frozen soil interface play a significant role in the stability and service performance of construction projects in cold regions. Current research mainly focuses on the precast concrete-frozen soil interface, with limited consideration for the more realistic cast-in-place concrete-frozen soil interface. The two construction methods result in completely different contact surface morphologies and exhibit significant differences in mechanical properties. Therefore, this study selects silty clay as the research object and conducts direct shear tests on the concrete-frozen soil interface under conditions of initial water content ranging from 12% to 24%, normal stress from 50 kPa to 300 kPa, and freezing temperature of -3℃. The results indicate that (1) both interface shear stress-displacement curves can be divided into three stages: rapid growth of shear stress, softening of shear stress after peak, and residual stability; (2) the peak strength of both interfaces increases initially and then decreases with an increase in water content, while residual strength is relatively less affected by water content; (3) peak strength and residual strength are linearly positively correlated with normal stress, and the strength of ice bonding is less affected by normal stress; (4) the mechanical properties of the cast-in-place concrete-frozen soil interface are significantly better than those of the precast concrete-frozen soil interface. However, when the water content is high, the former's mechanical performance deteriorates much more than the latter, leading to severe strength loss. Therefore, in practical engineering, cast-in-place concrete construction is preferred in cases of higher negative temperatures and lower water content, while precast concrete construction is considered in cases of lower negative temperatures and higher water content. This study provides reference for the construction of frozen soil-structure interface in cold regions and basic data support for improving the stability and service performance of cold region engineering.

MCFC 발전시스템용 촉매연소기의 연소 특성에 관한 실험적 연구 (An Experimental Study on the Combustion Characteristics of a Catalytic Combustor for an MCFC Power Generation System)

  • 홍동진;안국영;김만영
    • 대한기계학회논문집B
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    • 제36권4호
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    • pp.405-412
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    • 2012
  • MCFC 발전시스템에서 연소기는 연료극의 배가스 중에 포함된 미반응 가스를 연료로 사용하여 공기극에 $H_2O$$CO_2$ 농도가 높은 고온의 혼합가스를 공급하는 역할을 한다. 하지만 이러한 배가스는 가연한계 이하로 내려가게 되어 통상적인 연소방식에 의한 완전연소가 어렵기 때문에 이를 해결하기 위하여 촉매연소기를 사용한다. 완전연소 및 이에 다른 공해물질의 저감 특성에 따라 최근 촉매연소는 환경친화적인 연소방식으로 주목받고 있다. 따라서 본 연구에서는 MCFC 발전시스템의 BOP 시스템에 적용되는 촉매연소기에 대한 실험연구를 수행하였다. 본문에서는 실험장치를 설명한 후 촉매연소 시스템의 설계변수, 즉, $H_2$ 연료 첨가에 따른 연료조성, 유입가스의 온도, 과잉 공기비, 촉매의 종류, 그리고 시동 스케줄에 따른 촉매연소 특성을 고찰하였다.

갈색날개매미충(Ricania sp.) 성충의 광 선호성과 성충포획장치의 유인효과 (Responses of Ricania sp. (Hemiptera: Ricaniidae) to light and Attraction to Capturing Device)

  • 최덕수;김효정;오상아;이진희;마경철
    • 한국유기농업학회지
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    • 제28권3호
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    • pp.405-415
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    • 2020
  • 갈색날개매미충(Ricania sp.)을 효과적으로 방제하기 위하여 성충의 광에 대한 반응을 조사하여 유인력이 우수한 광을 이용하여 성충 포획장치를 개발하였다. 갈색날개매미충 성충에 대하여 주광색, 녹색 등 6종의 광원간 선호도를 조사한 결과 주광색 97 > 검정색 79 = 빨강색 79 = 파랑색 79 > 초록색 24 > 노랑색 13으로 주광색을 가장 선호하였다. 갈색날개매미충이 가장 선호하는 주광색등과 행동습성을 이용한 성충포획장치를 개발하였다. 포획장치는 주광색 컴팩트램프 2개(30 W, 20 W), 황색판, 포집수반으로 구성되었으며, 하루에 약 700마리가 포획되었다. 야간기온이 높으면 성충이 활발하게 활동하기 때문에 포획장치의 포획량은 많았으나 기온이 23℃ 이하로 낮아지면 포획량이 현저하게 줄었다. 갈색날개매미충 성충은 19시부터 23시까지 3시간 동안 85% 이상이 포획되었다. 따라서 갈색날개매미충 방제를 위한 성충 포획장치는 야간기온이 23℃ 이상인 7월 중순부터 8월 하순에 이용하며 19시부터 23시까지 점등하면 효율적일 것으로 판단된다.

Characterization of Three Extracellular β-Glucosidases Produced by a Fungal Isolate Aspergillus sp. YDJ14 and Their Hydrolyzing Activity for a Flavone Glycoside

  • Oh, Jong Min;Lee, Jae Pil;Baek, Seung Cheol;Jo, Yang Do;Kim, Hoon
    • Journal of Microbiology and Biotechnology
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    • 제28권5호
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    • pp.757-764
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    • 2018
  • A cellulolytic fungus, YDJ14, was isolated from compost and identified as an Aspergillus sp. strain. Three extracellular ${\beta}$-glucosidases, BGL-A1, BGL-A2, and BGL-A3, were separated using ultrafiltration, ammonium sulfate fractionation, and High-Q chromatography. The molecular masses of the three enzymes were estimated to be 100, 45, and 40 kDa, respectively, by SDS-PAGE. The optimum pH and temperature of BGL-A3 were 5.0 and $50^{\circ}C$, respectively, whereas the optimum pH and temperature of BGL-A1 and BGL-A2 were identical (4.0 and $60^{\circ}C$, respectively). The half-life of BGL-A3 at $70^{\circ}C$ (2.8 min) was shorter than that of BGL-A1 and BGL-A2 (12.1 and 8.8 min, respectively). All three enzymes preferred p-nitrophenyl-${\beta}$-$\text\tiny{D}$-glucopyranoside (pNPG) and hardly hydrolyzed cellobiose, suggesting that these enzymes were aryl ${\beta}$-glucosidases. The $K_m$ of BGL-A3 (1.26 mM) for pNPG was much higher than that of BGL-A1 and BGL-A2 (0.25 and 0.27 mM, respectively). These results suggested that BGL-A1 and BGL-A2 were similar in their enzymatic properties, whereas BGL-A3 differed from the two enzymes. When tilianin (a flavone glycoside of acacetin) was reacted with the three enzymes, the inhibitory activity for monoamine oxidase, a target in the treatment of neurological disorders, was similar to that shown by acacetin. We conclude that these enzymes may be useful in the hydrolysis of flavone glycosides to improve their inhibitory activities.

KrF Pulsed Laser Ablation 법으로 제조한 $Nd_xFe_{90.98-x}B_{9.02}$ 박막의 자기특성 (Magnetic Properties of $Nd_xFe_{90.98-x}B_{9.02}$ Thin Films Grown by a KrF Pulsed Laser Ablation Method)

  • 김상원;양충진
    • 한국자기학회지
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    • 제7권6호
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    • pp.299-307
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    • 1997
  • KrF 엑시머 Laser Ablation 법으로 (100)Si 기판위에 NdFeB 박막을 제조하였다. N $d_{x}$F $e_{90.98-x}$ $B_{9.02}$(x=17.51 ~ 27.51) 조성의 타겟을 사용하고, 레이저광에너지밀도를 2.75 ~ 5.99 J/c $m_{2}$, 기판온도를 620 ~ 700 .deg. C로 하여 제공정 조건이 박막의 자기특성, 결정배향성 및 미세조직에 미치는 영향을 조사한 결과, 증착상태의 시편에서 우선결정배향성은 관찰되지 않았으나 4 .pi. $M_{s}$ .approximately equal. 7 kG, 4 .pi. $M_{r}$ .approximately equal. 4 kG 및 $H_{c}$ = 300 ~ 1000 Oe인 자기특성이 얻어졌다. 증착 속도는 에너지밀도의 증가에 따라 직선적으로 증가 하였으며, 기판온도 증가에 따라서는 현저한 변화가 관찰되지 않았다. 3 J/c $m_{2}$의 에너지밀도가 최적의 조건이었으며, Nd량의 증가에 따라 4 .pi. $M_{s}$ 의 현저한 감소없이 4 .pi. $M_{r}$$H_{c}$가 증가하는 경향이 확인되었다.되었다.다.

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