• Journal of Energy Engineering
• /
• v.7 no.1
• /
• pp.146-156
• /
• 1998

Fly ash produced in coal combustion is a fine-grained material consisting mostly of spherical, glassy, and porous particles. A physical, morphological, and chemical characteristic of fly ash has been analyzed. This study may contribute to the data base of domestic fly ash, the improvement of combustion efficiency, ash recycling and ash collection in the electrostatic precipitator. The physical property of fly ash is determined using a particle counter for the measurement of ash size distribution and gravimeter. Morphological characteristic of fly ash is performed using a scanning electron micrograph and an optical microscope. The chemical components of fly ash are determined using an inductively coupled plasma emission spectrometry (ICP). The distribution of fly ash size was ranged from 15 to 25 $\mu$m in mass median diameter. Exposure conditions of flue gas temperature and duration within the combustion zone of the boiler played an important role on the morphological properties of the fly ash such as shape, relative opacity, coloration, cenosphere and plerosphere. The spherical fly ash might be generated at the condition of complete combustion. The size of fly ash was found to be increased the with particle-particle interaction of agglomeration and coagulation. Fly ash consisted of $SiO_2\;Al_2O_3\;and\;Fe_2O_3$ with 85% and carbon with 3~10% of total mass.

• Journal of the Korean Recycled Construction Resources Institute
• /
• v.1 no.1
• /
• pp.49-57
• /
• 2013

Recently, recycling of industrial by-products and CO2 reduction have been important issues in the world. In this reason, applications and reuse of Fly ash as a binder for concrete, which is generated in thermoelectric power plant, have been one of the effective recycle methods. In order for Fly ash to be applied to concrete, Korean Standard(KS) has selected and managed quality such as $SiO_2$, fineness, specific gravity, ignition loss and activity index. However, there is a limits for activity index, whose test period required is at least 28 days or 91 days. Activity index is the critical indication standard to determine mechanical strength of concrete that contained Fly ash. To complement the disadvantage of test method, this research provided "API test method", which quickly measure Pozzolanic reaction of Fly ash can be considered as a alternative of activity index. Then, the adaptable API test method need to be investigated through comparative analysis with the test result of API, activity index and K-value. The test method can make evaluation of Fly ash quality faster and more accurate. As a result, most Fly ash produced in Korea has not been satisfied in the KS quality standard except water content and specific gravity, and especially fluidized bed boiler ash has its characteristics. Also, API, activity index and K-value have superior interrelationship. The interrelationship between API and activity index and K-value gets increased as the material age gets higher, so API test can be considered as very useful test method for Pozzolanic reaction evaluation of Fly ash.

• Journal of Energy Engineering
• /
• v.24 no.4
• /
• pp.89-96
• /
• 2015

Recently, much research has been put into finding the causes and solutions of slagging/fouling problems that occur at the end of the boiler. This slagging/fouling, caused by low-rank coal's ash, disturbs the thermal power and greatly reduces efficiency. In environmental aspects, such as NOx pollution, governments have been implementing restrictions on the quantity of emission gases that can be released into the atmosphere. To solve these problems, research on Ash Free Coal (AFC), which eliminates ash from low-rank coal, is in progress. AFC has advantages over similar high-rank coals because it increases the heating value of the low grade coal, reduces the contaminants that are emitted, and decreases slagging/fouling problems. In this study, using a DTF, the changes of NOx emissions, unburned carbon, and the characteristics of ash deposition were identified. KCH raw coal, AFC extracted from KCH, residue coal, Glencore, and Mixed Coal (Glencore 85wt% and residue coal 15wt%) were studied. Results showed that AFC had a significantly lower emission of NOx compared to that of the raw coal and residue coal. Also, the residue coal showed a higher reactivity compared to raw coal. And finally, In the case of the residue coal and mixed coal, they showed a lower ash deposition than that of low-rank coal.

• Plant Journal
• /
• v.12 no.1
• /
• pp.29-36
• /
• 2016

It is becoming increasingly important to make use of alternative energy source. because It is not able to rely on only fossil fuel for the recent increasing demand of energy consumption. With this situation, lots of studies for utilizing low grade energy such as industrial waste heat, solar energy, and geothermal energy have been conducted. The aim of this study is to predict the operation characteristics of working fluid by using performance analysis program (ThermoFlex) through the system analysis which is not mixing district return water but using ORC(Organic Rankine Cycle, hereinafter ORC) as a downstream cycle when accumulating district heating (hereinafter DH). In this study, We conducted the performance analysis for the case which has the district heating water temperature($120^{\circ}C$) and Flow rate of $163m^3/h$ (including District Heating return water flow), and examined several working fluid which is proper to this temperature. The case using R245fa (which is the best-case) showed 269.2kW power output, 6.37% efficiency. Additionally, Cut down on fuel was expected because of the boiler inlet temperature increase by being Formed $57.3{\sim}85^{\circ}C$ in a temperature of district heating return water, depending on a pressure change of a condenser in ORC system.

• Membrane Journal
• /
• v.15 no.4
• /
• pp.310-319
• /
• 2005

This paper describes the preliminary study on the development of multi-stage membrane demonstration plant for removal of carbon dioxide from flue gas stream being emitted from LNG boiler in thermal power generation plant. The prerequisite requirement is to design and develop the membrane process producing a $99\%\;CO_2$ with $90\%$ recovery from LNG flue gas of 1,000 $Nm^3$/day. Asymmetric polyethersulfone hollow fiber membranes and membrane modules developed in this laboratory[1] were used in this study. Using the permeation data for the hollow fiber membranes, modelling on the membrane module and multi-stage membrane process was done to meet the requirement condition of the process design. The effects of the operating pressure of feed and permeate side and feed concentration on $CO_2$ purity and recovery were investigated experimentally with the developed hollow fiber modules. These experimental results matched well with theoretical modelling results.

• Journal of Energy Engineering
• /
• v.23 no.2
• /
• pp.42-48
• /
• 2014

Soot and tar which were derived from combustion or pyrolysis processes in Puverized Coal(PC) furnace or boiler have been significantly dealing in a radiative heat transfer and an additional source of NOx. Furthermore, the increasing for the use of a coal with low caloric value gives rise to a lot of tar-soot yield and LOI in a recycled ash for using cement materials. So, the ash with higher tar-soot yield and LOI can not recycle due to decreased strength of concrete. In this study, tar-soot yields and flame structures were investigated using the LFR for a blending combustion with bituminous coal and sub-bituminous coal. Also, The investigation were conducted as each single coals and blending ratio. The coals are used in a doestic power plant. In the experimental results, sub-bituminous coal with high volatile contents shows longer soot cloud length than bituminous coal, but overall flame length was shorter than bituminous coal. Tar-soot yields of sub-bituminous coal is lower than those of bituminous coal. Combustion characteristics are different between single coal and blended coal. Therefore, finding an optimal coal blending ratio according to coal rank effects on tar-soot yields.

• Clean Technology
• /
• v.24 no.4
• /
• pp.339-347
• /
• 2018

In order to cope with environmental problems and climate change caused by fossil fuels, renewable energy supply is increasing year by year. Currently, waste energy accounts for 60% of renewable energy production. However, waste has a lower calorific value than fossil fuels and contains various harmful substances, which causes serious problems when applied to power generation boilers. In particular, the chlorine in the waste fuel increases slagging and fouling of boiler heat exchangers, leading to a reduction in thermal efficiency and the main cause of high temperature corrosion, lowering facility operation rate and increasing operating cost. In this study, the high temperature corrosion experiments of superheater materials (ASME SA213/ASTM A213 T2, T12 and T22 alloy steel) by alkali chlorides were conducted, and their corrosion characteristics were analyzed by the weight loss method and SEM-EDS. Experiments show that the higher the temperature and chloride content, the more corrosion occurs, and KCl further corrodes the materials compared to NaCl under the same condition. In addition, the higher the chromium content of the material, the better the corrosion resistance to the alkali chlorides.

• Clean Technology
• /
• v.27 no.2
• /
• pp.190-197
• /
• 2021

Kraft lignin is a by-product of the pulp and paper industry, obtained as a black liquor after the extraction of cellulose from wood through the Kraft pulping process. Right now, kraft lignin is utilized as a low-grade boiler fuel to provide heat and power but can be converted into high-calorific biofuels or high-value chemicals once the efficient catalytic depolymerization process is developed. In this work, the multi-functional catalyst of Ru-Mg-Al-oxide, which contains hydrogenation metals, acid, and base sites for the effective depolymerization of kraft lignin are prepared, and its lignin depolymerization efficiency is evaluated. In order to understand the role of different active sites in the lignin depolymerization, the three different catalysts of MgO, Mg-Al-oxide, and Ru-Mg-Al-oxide were synthesized, and their lignin depolymerization activity was compared in terms of the yield and the average molecular weight of bio-oil, as well as the yield of phenolic monomers contained in the bio-oil. Among the catalysts tested, the Ru-Mg-Al-oxide catalyst exhibited the highest yield of bio-oil and phenolic monomers due to the synergy between active sites. Furthermore, in order to maximize the extent of lignin depolymerization over the Ru-Mg-Al-oxide, the effects of reaction conditions (i.e., temperature, time, and catalyst loading amount) on the lignin depolymerization were investigated. Overall, the highest bio-oil yield of 72% and the 3.5 times higher yield of phenolic monomers than that without a catalyst were successfully achieved at 350 ℃ and 10% catalyst loading after 4 h reaction time.

• Resources Recycling
• /
• v.29 no.6
• /
• pp.125-132
• /
• 2020

Enrichment possibilities for recovering rare earth elements contained in coal bottom ash generated from domestic circulating fluidized bed combustion (CFBC) were identified. The transport characteristics of the REEs according to the separation and removal of major minerals were evaluated using sieving and leaching process. The main minerals of bottom ash were identified as anhydrite, magnetite, and quartz, and this was confirmed as a 30% of REE content of the world's average coal ash REE value (404 ppm) as a result of the difference in the combustion characteristics of power plants (REE contents in starting material: 123 ppm). More than 90% of the REEs contained in the bottom ash were found to move mainly with magnetite, and less than 10% of the components were found to move with the quartz. Therefore, In order to recover rare earth elements from coal bottom ashes generated from CFBC boiler, it is necessary to select the main rare elements such as magnetite and develop a pretreatment and concentration process.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
• /
• v.15 no.4
• /
• pp.223-229
• /
• 2022

In this paper, the ignition trans used in boilers was studied. Regardless of the change in the ignition rod length and the ignition rod gap, the output frequency was measured between 59.5 and 61.3 Hz, and it was found that the low frequency circuit operated normally. When the ignition rod gap changed by 2 to 10 mm, the ignition rod length was measured from 2.8A to 3.45A at 30cm. The ignition rod length was measured from 9.37 A to 14.5 A at 500 cm and from 13.2 A to 32.6 A at 1000 cm. As the ignition rod length and the ignition rod gap increased, the current increased. As a result of measuring the secondary coil output voltage. The ignition rod length was measured from AC 0.84 kV to AC 1.75 kV at 30 cm, AC 1.17 kV to AC 1.944 at 500 cm, and AC 1.4 kV to AC 7.18 kV at 1000 cm. As the ignition rod length and the ignition rod gap increased, the output voltage of the secondary coil also increased. As a result of measuring the output voltage of the ignition trans, the ignition rod length was measured from DC 1.11 kV to DC 1.57 kV at 30cm, DC 2.49 kV to DC 3.72 kV at 500cm, and DC 3.78 kV to DC 9.42 kV at 1000cm, and the power voltage increased as the ignition rod length and interval increased.