• 제목/요약/키워드: Powder dispersion

검색결과 366건 처리시간 0.027초

P3HT:PCBM 층 내 분산 가능한 금속 나노입자의 제조 및 이를 포함한 고분자 태양전지 소자의 특성에 관한 연구 (Synthesis of Highly Dispersible Metal Nanoparticles in P3HT:PCBM Layers and Their Effects on the Performance of Polymer Solar Cells)

  • 김민지;최규채;김영국;김양도;백연경
    • 한국분말재료학회지
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    • 제21권3호
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    • pp.179-184
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    • 2014
  • In this study, we prepare polymer solar cells incorporating organic ligand-modified Ag nanoparticles (O-AgNPs) highly dispersed in the P3HT:PCBM layer. Ag nanoparticles decorated with water-dispersible ligands (WAgNPs) were also utilized as a control sample. The existence of the ligands on the Ag surface was confirmed by FT-IR spectra. Metal nanoparticles with different surface chemistries exhibited different dispersion tendencies. O-AgNPs were highly dispersed even at high concentrations, whereas W-AgNPs exhibited significant aggregation in the polymer layer. Both dispersion and blending concentration of the Ag nanoparticles in P3HT:PCBM matrix had critical effects on the device performance as well as light absorption. The significant changes in short-circuit current density ($J_{SC}$) of the solar cells seemed to be related to the change in the polymer morphology according to the concentration of AgNPs introduced. These findings suggested the importance of uniform dispersion of plasmonic metal nanoparticles and their blending concentration conditions in order to boost the solar cell performance.

Retention and Drainage Characteristics with Inverse Emulsion Type C-PAM

  • Son, Dong-Jin;Kim, Bong-Yong
    • 펄프종이기술
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    • 제38권5호
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    • pp.24-30
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    • 2006
  • This study was performed to characterize inverse emulsion type cationic polyacrylamide (PAM) and to compare with powder and salt dispersion type PAMs as a retention and drainage aid. Salt dispersion type PAM has defects of high amount of salt which increases conductivity of white water, low active polymer contents and relatively worse retention and drainage properties than others because of its low molecular weight. Powder type PAM has benefit of high active polymer contents and good retention and drainage properties, but defects of low dissolution speed and insoluble particle generation were observed. However, inverse emulsion type showed the best retention and drainage aids among them by controlling molecular weight and morphology easily and it had relatively higher active polymer contents and better solubility.

흰쥐에 경구 투여시 히드록시프로필-베타-시클로덱스트린과 니트렌디핀 고체분산에 의한 생체이용률 증가 (Enhancement of Nitrendipine Bioavailability in Rats by its Solid Dispersion with $Hydroxypropyl-{\beta}-Cyclodextrin$ after Oral Administration)

  • 용철순
    • Journal of Pharmaceutical Investigation
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    • 제27권4호
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    • pp.295-301
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    • 1997
  • Nitrendipine, a slightly soluble calcium channel blocking agent forms a solid dispersion system with $hydroxypropyl-{\beta}-cyclodextrin$, which exhibits better dissolution characteristics than the uncomplexed drug. The dissolution rate of nitrendipine was markedly increased in solid dispersion system in pharmacopeial disintegration media at pH 1.2 and pH 6.8. Four different dosage forms of nitrendipine were administered to rats: (a) nitrendipine in the solution of PEG 400; (b) nitrendipine solid dispersion system with $hydroxypropyl-{\beta}-cyclodextrin$ in a molar ratio of 1:2 by solvent evaporation method and administered in capsule form; (c) physical mixture of nitrendipine with $hydroxypropyl-{\beta}-cyclodextrin$ in a molar ratio of 1:2 and administered in capsule form; (d) nitrendipine alone administered in capsule form. Relative bioavailability after the oral administration of various dosage forms to rats with a dose of 10 mg/kg equivalent to nitrendipine was compared with that of nitrendipine in the solution of PEG 400. The AUC of solid dispersion was significantly bigger than that of nitrendipine powder. $T_{max}$ of solid dispersion was significantly shorter and $C_{max}$ was higher than that of nitrendipine powder. These results indicate that the bioavailability of nitrendipine could be improved markedly by inclusion complexation. An interesting correlation also appears to exist between the in vitro dissolution data and the area under the plasma concentration-time curves.

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Synthesis and Dispersion Stabilization of Indium Tin Oxide Nanopowders by Coprecipitation and Sol-Gel Method for Transparent and Conductive Films

  • Cho, Young-Sang;Hong, Jeong-Jin;Kim, Young Kuk;Chung, Kook Chae;Choi, Chul Jin
    • 대한금속재료학회지
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    • 제48권9호
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    • pp.831-841
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    • 2010
  • Indium tin oxide (ITO) nanopowders were synthesized by coprecipitation and the sol-gel method to prepare a stable dispersion of ITO nano-colloid for antistatic coating of a display panel. The colloidal dispersions were prepared by attrition process with a vibratory milling apparatus using a suitable dispersant in organic solvent. The ITO coating solution was spin-coated on a glass panel followed by the deposition of partially hydrolyzed alkyl silicate as an over-coat layer. The double-layered coating films were characterized by measuring the sheet resistance and reflectance spectrum for antistatic and antireflective properties.

저온균일침전법으로 제조된 TiO2 분말의 아크릴레진에서의 분산특성 및 광분해 효과 (Dispersion Properties and Photocatalytic Activities of TiO2 Powders Obtained by Homogeneous Precipitation Process at Low Temperature in a Acrylic Resin)

  • 우승희;김흥회;이창규
    • 한국분말재료학회지
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    • 제11권6호
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    • pp.503-509
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    • 2004
  • Dispersion stabilities and photocatalytic activities of rutile $TiO_{2}$ powders with unique nano-structure synthesized by homogeneous precipitation process at low temperature(HPPLT) have been investigated in the acrylic resin containing fluorostyrene in the range of 0~0.16 mole. Isoelectric point of $TiO_{2}$ in the acrylic resin placed in the neutral region whereas that of $TiO_{2}$ in the water placed in the acidic region, indicating that zeta potential and agglomeration of $TiO_{2}$ powder is strongly dependent on the pH and the type of solvent. To prepare an adhesion, an acrylic resin containing fluorostyrene was synthesized by a radical polymerization. The adhesion of coating layer was increased with increasing fluorostyrene's contents without changing the dispersion stabilities and degrading photocatalytic properties.

$Si_3$$N_4$ 분말의 분산과 소결에 관한 연구 (A Study on Dispersion and Sintering of $Si_3$$N_4$ Powder)

  • 임대영
    • 자연과학논문집
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    • 제5권2호
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    • pp.75-80
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    • 1992
  • $Si_3$$N_4$$-5^w$/$oA1_2$$O_3$$-5^w$/$oY_2$$O_3$ 분말의 분산이 소성후 미세구조에 미치는 영향을 조사하였다. 분산은 pH를 변화시켜 가면서 행하였고, 분산상태를 직접 전자 현미경으로 관찰 하였다. 각시편을 $1750^{\circ}C$에서 1시간 소성하여 치밀도를 조사하였으며 그결과 pH5, pH10에서 분산시킨 분말이 가장 치밀하게 소결되었다.

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Dispersion of Alloy 625 Nanoparticles in Ethanol

  • Lee, Eun-Hee;Lee, Min-Ku;Rhee, Chang-Kyu
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.673-674
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    • 2006
  • The influence of several experimental parameters on the formation of stable Alloy 625 nanoparticles dispersion in ethanol was investigated. Several analyzing methods were applied, like transmission profiles measured by Turbiscan, transmission electron microscopy, X-ray diffraction, gas chromatography, and particle size analyzer. The correlation among the increase of particle sizes, caused by nanoparticle coalescence and collision, concentration of dispersant and time was presented and discussed. The optimum conditions for the formation of stable dispersion are evaluated.

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물리화학적 처리를 통한 극성 용매 내 나노다이아몬드의 탈응집 및 분산성 향상 연구 (Deaggregation and Ultradispersion of Detonation Nanodiamonds in Polar Solvent Using Physicochemical Treatments)

  • 김창규;이경자;이창규
    • 한국분말재료학회지
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    • 제20권6호
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    • pp.479-486
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    • 2013
  • In the present work, physicochemical treatments were introduced for de-aggregation and stable dispersion of detonation nanodiamonds (DND) in polar solvents. The DNDs in water exhibited a particle size of 138 nm and high dispersion stability without particular treatment. However, the DNDs in ethanol were severely aggregated to several micrometers in size and showed poor dispersion stability with time. To break down aggregates of DNDs and enhance the dispersion stability of them in ethanol, mechanical force and chemical surfactant were introduced as functions of zirconia ball size, kind of surfactant and amount of surfactant added. From the analyses of average particle size and Turbiscan results, it was suggested that the size of DNDs in ethanol can be reduced by only mechanical force; however, the DNDs were re-aggregated due to high surface activity. The long-term dispersion stability can be achieved by applying mechanical force to break down the aggregates of DNDs and by preventing re-aggregation of them using proper surfactant.

A study on the mechanically equivalent surrogate plate of U-Mo dispersion fuel using tungsten

  • Kim, Hyun-Jung;Yim, Jeong-Sik;Jeong, Yong-Jin;Lee, Kang-Hee
    • Nuclear Engineering and Technology
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    • 제51권2호
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    • pp.495-500
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    • 2019
  • When a new fuel is developed, various mechanical properties are absolutely necessary for a safety analysis of the fuel for the licensing and prediction of its mechanical behavior during operation and accident conditions. In this paper, a mechanically equivalent surrogate plate of U-Mo dispersion fuel is presented using tungsten, substitute material of U-Mo particle. A surrogate plate, composed of tungsten/aluminum dispersion meat and aluminum alloy cladding, is manufactured with the same fabrication process with that of fuel plate except that a tungsten powder is used instead of U-Mo powder. A modal test showed that the surrogate plate and fuel plate have similar dynamic characteristics, and a tensile test demonstrated the similarity of the material property up to the yield strength range. The conducted tests proved that the surrogate tungsten plate has equivalent mechanical behaviors with that of a fuel plate, which leads to the acceptable use of a surrogate fuel assembly using tungsten/aluminum dispersion meat in various mechanical tests. The surrogate fuel assembly can be utilized for various out-of-pile characteristic tests, which are necessary for the licensing achievement of a research reactor that uses U-Mo dispersion fuel as a driver.