• 한국염색가공학회지
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• 제20권6호
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• pp.8-17
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• 2008

Poly (vinyl acetate) (PVAc) was used as a precursor of PVA/PVAc (skin/core) bicomponent. In order to investigate the possibility of PVA particles for electrical applications, PVA/PVAc particles were produced with an emulsifier, SDS (Sodium Dodecyl Sulfate) and an initiator, V-50 (2,2'-azobis(2-amidinopropane)digydrochloride). In this study, we investigated the electrical property of PVA/PVAc (skin/core) particles. The hydroxyl group of the PVA/PVAc (skin./core) was confirmed by the analysis of PVAc and PVA/PVAc (skin/core) using Fourier Transform Infrared Spectroscopy (FT-IR). The zeta-potential of the PVA/PVAc (skin/core) and PVAc has similarity; however, charge control agent (CCA) treated PVA/PVAc (skin/core) particles has lower zeta-potential than untreated PVA/PVAc particles. The zeta-potential (negative values) of the PVA/PVAc (skin/core) were enhanced in proportion to the increased concentration of CCA.

• 한국입자에어로졸학회지
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• 제14권3호
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• pp.49-63
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• 2018

During the last decade, electrospray (ES) techniques have been used as potential methods for preparing of core-shell materials. Depending on the architecture of nozzle and design of devices, the ES techniques includes monoaxial, coaxial, multiple coaxial nozzle ES and microfluidic ES devices. ES operates based on a basic principle, in which a spray of monodisperse droplets is formed by dispensing an electrically conductive liquid through a capillary charged to a sufficiently high potential. In review of many recent research papers, we take a closer look at ES techniques and their applications for fabrication of core-shell materials. Several advantages of ES technique compared with other methods were emphasized and it may be regarded as a potential tool for fabrication of core-shell materials current and near future.

• 대한화학회지
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• 제14권3호
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• pp.229-235
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• 1970

Electrodeposition of lead peroxide on the graphite core was studied. The results are following; 1) At more noble potential than 1.6V vs. S.C.E. and lower temperature than $40^{\circ}C$, $PbO_2$ deposited current efficiency is increased but deposited layer falls off easily from graphite core. 2) Oxygen overvoltage of $PbO_2$ deposited layer on the graphite core is largely with increasing $PbO_2$ depositing anodic potential and with lowlying electrolytic temperature. 3) To obtain the $PbO_2$ deposited layer without falling off from the graphite core, it is necessary to change the electrolytic conditions, anodic potential and electrolytic temperature, in four stages successively.

• 지질공학
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• 제26권2호
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• pp.207-221
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• 2016

최근 국내 필댐 및 저수지의 노후화가 급속도로 진행되고 있으며, 이에 따른 제체의 손상이나 붕괴사고가 잇따르고 있다. 그러나 필댐의 핵심적인 차수기능을 담당하는 코어층에 대한 열화와 잠재 위해성 분류에 대한 연구는 거의 미진한 실정이다. 본 연구에서는 노후화가 진행 중인 13개 기존 코어형 필댐에 대해(준공 후 경과년수 9-52년, 댐 높이 22-67 m), 무수보링에 의한 코어층 시추 지반조사와 표준관입시험, 2D 및 3D 전기비저항탐사, 물성·역학시험을 수행하여 공학적 기반의 잠재적 위해성 유형을 국내 최초로 분류, 제시하였다. 중심코어층에 대한 무수보링 시추 지반조사 결과, 코어재 잠재 위해성 유형을 국부적 포화대, 신속한 공내수 유입, 조립질 혼재 코어재, 상대적 저 강성의 네 종류로 분류하였다. 코어형 필댐의 잠재 위해성 유형 중국부적 포화대 유형은 코어존 내 유로의 성장 및 발달에 의한 내적침식의 가능성이 존재하므로 가장 위험한 위해성으로 분류 되었으며, 코어재의 열화 등급에 따라 적절한 차수능 회복을 위한 보수보강이 필요한 것으로 판단되었다. 그 외 세 가지 위해성 유형은 즉각적인 조치보다는 지속적인 모니터링과 정기 검사의 강화가 필요할 것으로 검토되었다. 본 연구대상 댐의 분석 결과, 준공 후 경과년수와 댐 코어재의 열화 양상과는 상관성이 크게 없는 것으로 나타났다. 본 연구 결과는 코어형 필댐의 노후화에 따른 댐의 안전관리와 성능개선에 있어 유용한 자료로 활용 가능할 것으로 판단된다.

• 한국세라믹학회지
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• 제36권1호
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• pp.50-54
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• 1999

양이온 결손 La0.970Mn0.970O3의 x-ray photoemission spectroscopy를 온도를 함수로 측정하였다. 온도의 변화에 따라서 Mn 2p와 3d core level의 화학적 변동 및 이동이 관측되었다. 즉 Mn 2p 3/2와 1/2 및 La 3d core 스펙트럼은 온도의 증가와 함께 저 결합 에너지 측으로 이동이 관측되었다. 이러한 XPS 관측 결과는 Mn3+의 localization의 강도 변화에 의한 것으로 사료되며, Mn3+에 의한 Jahn-Teller효과 이외에도 conventional random potential 효과 역시 La0.790Mn0.970O3의 전도 carrier의 localization에 기여하는 것으로 사료된다.

• Steel and Composite Structures
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• 제20권3호
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• pp.513-543
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• 2016

Third order shear deformation theory is used to evaluate electro-elastic solution of a sandwich plate with considering functionally graded (FG) core and composite face sheets made of piezoelectric layers. The plate is resting on the Pasternak foundation and subjected to normal pressure. Short circuited condition is applied on the top and bottom of piezoelectric layers. The governing differential equations of the system can be derived using Hamilton's principle and Maxwell's equation. The Navier's type solution for a sandwich rectangular thick plate with all edges simply supported is used. The numerical results are presented in terms of varying the parameters of the problem such as two elastic foundation parameters, thickness ratio ($h_p/2h$), and power law index on the dimensionless deflection, critical buckling load, electric potential function, and the natural frequency of sandwich rectangular thick plate. The results show that the dimensionless natural frequency and critical buckling load diminish with an increase in the power law index, and vice versa for dimensionless deflection and electrical potential function, because of the sandwich thick plate with considering FG core becomes more flexible; while these results are reverse for thickness ratio.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.803-808
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• 2012

We have implemented two-component spin-orbit relativistic effective core potential (SOREP) methods in an all-electron relativistic program DIRAC. This extends the capacity of the two-component SOREP method to many ground and excited state calculations in a single program. As the test cases, geometries and energies of the small halogen molecules were studied. Several two-component methods are compared by using spin-orbit and scalar relativistic effective core potentials. For the $I_2$ molecule, excitation energies of low-lying excited states agree well with those from corresponding all-electron methods. Efficiencies in SOREP calculations enhanced by using symmetries are also discussed briefly.

• Journal of Magnetics
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• 제12권3호
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• pp.113-117
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• 2007

Here we report a theoretical description of ferromagnetic vortex dynamics. Based on Thiele's formulation of the Landau-Lifshitz-Gilbert equation, the motion of the vortex core could be described by a function of the vortex core position. Under a parabolic potential generated in the circular magnetic patterns, the vortex core showed a circular rotation-namely the gyrotropic motion, which could be described by a 2-dimensional simple harmonic oscillator. The gyrotropic frequency and apparent damping constant were predicted and compared with the values obtained micromagnetic calculation.

• Journal of Pharmaceutical Investigation
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• 제39권3호
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• pp.201-205
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• 2009

Triglyceride solid lipid with medium chain fatty acid, tricaprin (TC), was used as a core matrix of lipid nanoparticles (LN) to solubilize water-insoluble paclitaxel and enhance the stability of nanoparticles by immobilization of incorporated drug in the solid core during storage at low temperature. In the present study, TC-LN containing paclitaxel was prepared by hot melt homogenization method using TC as a core lipid and phospholipids as stabilizers. The particle size of TC-LN containing paclitaxel was less than 200 nm and its zeta potential was around -40 mV. Calorimetric analysis showed TC core could be solidified by freezing and thawing in the manufacturing process in which the hot dispersion should be prepared at elevated temperature and subsequently cooled to obtain solid lipid nanoparticles. The melting transition of TC core was observed at $27.5^{\circ}C$, which was lower than melting point of TC bulk. The particle size of TC-LN remained unchanged when kept at $4^{\circ}C$. Paclitaxel containing TC-LN showed comparable anticancer activity to the Cremophore ELbased paclitaxel formulation against human ovarian (OVCAR-3) and breast (MCF-7) cancer cell lines. Thus, lipid nanoparticles with medium chain solid lipid may have a potential as alternative delivery system for parenteral administration of paclitaxel.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2007년도 춘계학술대회A
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• pp.130-135
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• 2007

The mechanical characteristics of three types of core with two-dimensional isotropic patterns-triangular, hexagonal and starcell-were studied in applications to sandwich structures. The Young's modulus and shear modulus were calculated for the three core types in the direction normal to the faces. The compressive buckling strength and shear buckling strength were calculated by modeling each cell wall of the core as a plate under compressive or shear load. To verify this model, tests were conducted on scaled specimens to measures the compressive buckling strength of each core. The bending flexibilities of the three cores were also studied. Compliances for the three cores were measured using biaxial flexural tests. The three isotropic core patterns exhibited distinct characteristics. In the direction normal to the faces, all three cores had the same stiffness. However, the starcell core exhibited high flexibility compared to the other cores, indicating potential for application to curved sandwich structures.