• Title/Summary/Keyword: Porous particle

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Eco-friendly Self-cooling System of Porous Onggi Ceramic Plate by Evaporation of Absorbed Water

  • Katsuki, Hiroaki;Choi, Eun-Kyong;Lee, Won-Jun;Kim, Ung-Soo;Hwang, Kwang-Taek;Cho, Woo-Seok
    • Journal of the Korean Ceramic Society
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    • v.55 no.2
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    • pp.153-159
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    • 2018
  • Porous ceramic plates were prepared from Onggi clay and bamboo charcoal powder at 1100 and $1200^{\circ}C$ and their porous properties and water absorption, and the cooling effect of porous plates, were investigated to produce eco-friendly porous ceramics for a self-cooling system that relies on the evaporation of absorbed water. Porous properties were dependent on the particle size of charcoal powder pore forming additive and the firing temperature; properties were also found to be dependent on the total pore volume, average pore size and porosity, which had values of $0.103-0.243cm^3/g$, 0.81 - 2.56 mm and 20.9 - 38.2%, respectively, at $1100^{\circ}C$ and $0.04-0.18cm^3/g$, 0.33 - 2.03 mm and 10.8 - 30.9%, respectively, at $1200^{\circ}C$. Cooling temperature difference of flowing air parallel to surface of porous ceramic plates fired with two kinds of charcoal powder at $1100^{\circ}C$ was $3.5-3.6^{\circ}C$ at $26^{\circ}C$ and 60% of relative humidity in a closed box. Cooling temperature difference was dependent on the number of porous plates and the distance between porous plates. A simple and eco-friendly cooling system using porous ceramic plates fired from Onggi clay and charcoal powder was proposed.

Combustion Characteristics of Immobilized Alcohols in Porous Material (다공성 물질에 함침시킨 알콜의 연소특성)

  • 우인성;황명환
    • Journal of the Korean Society of Safety
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    • v.9 no.1
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    • pp.76-82
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    • 1994
  • Combustion phenomena(characteristics) of organic solvents including various alcohols Immobilized on ceramic balls were studied. Experiments were performed by burning methyl, ethyl, and propyl alcohol immobilized on sands (particle size 0.35mm) and coramic balls(particle size 1~5mm) to measure mass burning rate, height burning rate and combustion temperature. The longer time from ignition to extinguishment was resualted from the larger particle size of ceramic balls and the smaller size of ceramic balls exhibited the higher mass burning rate. Of alcohols tested the relative magnitude of facilitation of combustion was methyl >ethyl >propyl. Combustion temperatare of alcohols, without regard to the types of alcohols, was not increased with smaller ceramic balls(up to 3mm of particle size). However, with larger ceramic balls, combustion temperatare of alcohols was increased by 40~5$0^{\circ}C$ and the highest combustion temperatare was obtained with sands(particle size 0.35mm). Also, second rising was occurred at the combustion time of I5-20min. and this second rising time was increased with the smaller particle. These results will be able to be used for petrochemical industries using particles to evaluate the danger of fire and explosion.

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In situ viscoelastic properties of insoluble and porous polysaccharide biopolymer dextran produced by Leuconostoc mesenteroides using particle-tracking microrheology

  • Jeon, Min-Kyung;Kwon, Tae-Hyuk;Park, Jin-Sung;Shin, Jennifer H.
    • Geomechanics and Engineering
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    • v.12 no.5
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    • pp.849-862
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    • 2017
  • With growing interests in using bacterial biopolymers in geotechnical practices, identifying mechanical properties of soft gel-like biopolymers is important in predicting their efficacy in soil modification and treatment. As one of the promising candidates, dextran was found to be produced by Leuconostoc mesenteroides. The model bacteria utilize sucrose as working material and synthesize both soluble and insoluble dextran which forms a complex and inhomogeneous polymer network. However, the traditional rheometer has a limitation to capture in situ properties of inherently porous and inhomogeneous biopolymers. Therefore, we used the particle tracking microrheology to characterize the material properties of the dextran polymer. TEM images revealed a range of pore size mostly less than $20{\mu}m$, showing large pores > $2{\mu}m$ and small pores within the solid matrix whose sizes are less than $1{\mu}m$. Microrheology data showed two distinct regimes in the bacterial dextran, purely viscous pore region of soluble dextran and viscoelastic region of the solid part of insoluble dextran matrix. Diffusive beads represented the soluble dextran dissolved in an aqueous phase, of which viscosity was three times higher than the growth medium viscosity. The local properties of the insoluble dextran were extracted from the results of the minimally moving beads embedded in the dextran matrix or trapped in small pores. At high frequency (${\omega}>0.2Hz$), the insoluble dextran showed the elastic behavior with the storage modulus of ~0.1 Pa. As frequency decreased, the insoluble dextran matrix exhibited the viscoelastic behavior with the decreasing storage modulus in the range of ${\sim}0.1-10^{-3}Pa$ and the increasing loss modulus in the range of ${\sim}10^{-4}-1\;Pa$. The obtained results provide a compilation of frequency-dependent rheological or viscoelastic properties of soft gel-like porous biopolymers at the particular conditions where soil bacteria produce bacterial biopolymers in subsurface.

A Numerical Study on Spatial Behavior of Linear Absorbing Solute in Heterogeneous Porous Media (비균질 다공성 매질에서 선형 흡착 용질의 공간적 거동에 대한 수치적 연구)

  • Jeong, Woo Chang;Lee, Chi Hun;Song, Jai Woo
    • Journal of the Korean GEO-environmental Society
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    • v.4 no.3
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    • pp.79-88
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    • 2003
  • This paper presents a numerical study of the spatial behavior of a linear absorbing solute in a heterogeneous porous medium. The spatially correlated log-normal hydraulic conductivity field is generated in a given two-dimensional domain by using the geostatistical method (Turning Bands algorithm). The velocity vector field is calculated by applying the two-dimensional saturated groundwater flow equation to the Galerkin finite element method. The simulation of solute transport is carried out by using the random walk particle tracking model with CD(constant displacement) scheme in which the time interval is automatically adjusted. In this study, the spatial behavior of a solute is analyzed by the longitudinal center-of-mass displacement, longitudinal spatial spread moment and longitudinal plume skewness.

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Preparation of Porous Ceramics Sound Absorbent Material Using Sewage Sludge Slag (하수슬러지 슬래그를 이용한 다공성 세라믹스 흡음재료 제조)

  • 신대용;한상목
    • Journal of the Korean Ceramic Society
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    • v.40 no.3
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    • pp.273-278
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    • 2003
  • The effects of content and particle size of sewage sludge slag on the sound absorption was investigated and the physical$.$mechanical properties of porous ceramics for sound absorbent material was studied. The physical$.$mechanical properties of specimens have depended on sintering temperature and slag content without particle size effect of slag. As water glass content increase and particle size of slag decrease at the same slag content, physical$.$mechanical properties of them have been improved. The bulk density and compressive strength of specimens with the batch composition of 77∼89 wt% of slag content and particles with 1∼3 mm, and sintered at 1,050$^{\circ}C$ for 2 h were 1.48∼1.71 and 86∼163 kgf/$\textrm{cm}^2$, respectively. The specimens with 1∼3 mm and <1 mm of particles size showed good sound absorption property at low frequency and high frequency region. With increasing thickness of specimens, sound absorption properties at low frequency region were increased.

Influence of Particle and Filter Charge on Filtration Property of Air Filter under Particle Loading (입자 및 필터 대전상태에 따른 입자부하조건에서 공기정화 필터의 여과특성)

  • Ji, Sung-Mi;Sohn, Jong-Ryeul;Park, Hyun-Seol
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.6
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    • pp.644-655
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    • 2012
  • As soon as a new air filter is applied to an air purification process, the filter gets loaded with dust particles. Thus, the study on the particle loading characteristics of air filter is very essential in order to understand the real filtration phenomena during filter use. In this study, we investigated the effect of particle and filter charge on the particle loading property of air filter. Charged filter and uncharged filter prepared by discharging the charged filter by isopropyl alcohol were used as test samples, and three types of particle having different charge states were supplied to filters tested. For neutralized particles there was a big difference in areal mass loading rates between charged and uncharged filters due to the very small amount of particle charge, on the other hand the difference was diminished for atomized particle and finally almost vanished for corona charged particles. The pressure drop of filter loaded with corona charged particles was only half of those for neutralized and atomized particles at the same areal mass loading because of the porous structure of particle deposit formed on filter fibers, caused by the space charge effect between particles.

Frost resistance of porous concrete assuming actual environment (實環境を考慮したポーラスコンクリートの耐凍害性の評価(실제 환경을 고려한 다공질 콘크리트의 내동해성(耐凍害性) 평가))

  • NAKAMURA, Takuro;HORIGUCHI, Takashi;SHIMURA, Kazunori;SUGAWARA, Takashi
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2008.11a
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    • pp.227-233
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    • 2008
  • Porous concrete has large continuous voids of 20-30 % by volume, and this concrete is attractive as environmental material in Japan i.e. permeable road pavement, river bank protection with vegetation and green roof system which influence thermal environment. It is necessary to confirm the frost resistance when constructing porous concrete structure in cold region. However applicable test method and evaluation criterion of porous concrete has not defined yet. Therefore, the object of this study is to investigate the frost resistance of porous concrete and this investigation attempts to address this concern by comparing 4 kinds of specified freezing and thawing tests methods (JIS A1148 procedure A/B and RILEM CIF/CDF test) in consideration of actual environment. RILEM freeze-thaw tests are different from JIS A1148 freeze-thaw tests, which are widely adopted for evaluating the frost resistance of conventional concrete in Japan, in water absorption, cooling rate, length of freezing and thawing period, and number of freezing and thawing cycles. RILEM CIF test measures internal damage and is primarily applicable for pure frost attack. CDF test is appropriate for freeze-thaw and de-icing salt attack. JIS A1148 procedure A/B showed extremely low frost resistance of porous concrete if the large continuous voids were filled with water and the ice expansion in the large continuous voids set in during cooling. Frost resistance of porous concrete was improved by mixing coarse aggregate (G7) which particle size is smaller and fine aggregate in JIS freezing and thawing tests. RILEM CIF/CDF test showed that freeze-thaw and de-icing resistance of porous concrete was seems to be superior in that of conventional concrete.

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The Effect of Porous Support and Intermediate Layer on the Silica-zirconia Membranes for Gas Permeation Performance (실리카-지르코니아 분리막 성능에 대한 다공성 지지체와 중간층의 영향)

  • Lee, Hye Ryeon;Seo, Bongkuk
    • Membrane Journal
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    • v.25 no.1
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    • pp.15-26
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    • 2015
  • In this study, porous metal (O.D. = 10 mm, length = 10 mm, 316 L SUS, Mott Corp.) and ${\alpha}$-alumina tube (O.D. = 10 mm, length = 50 mm, Pall, German) support was modified with suspension sols, which were consisted of $3{\sim}4{\mu}m$ and 150 nm size of ${\alpha}$-alumina particle in the water or silica-zirconia colloidal sol. The porous support was fabricated by dip coating method for 5 seconds with suspension of alumina particles. After drying at $100^{\circ}C$ for 1 h, it was calcined at $550^{\circ}C$ for 30 min. It was repeated several times in order to decrease big pore on support. The surface roughness and largest pore size on the porous support was decreased by increasing coating times with $3{\sim}4{\mu}m$ size of ${\alpha}$-alumina particle and alumina coating with 150 nm size of ${\alpha}$-alumina particle served as further smoothening the surface and decreasing the pore size of the substrate. And the silica-zirconia membranes were successfully prepared on the modified porous metal and ${\alpha}$-alumina supports, and showed hydrogen permeance in the range of $1.8-8.4{\times}10^{-4}mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$ and $3.3-5.0{\times}10^{-5}mol{\cdot}m^{-2}{\cdot}s^{-1}{\cdot}Pa^{-1}$, respectively.

Highly-closed/-Open Porous Ceramics with Micro-Beads by Direct Foaming

  • Jang, Woo Young;Seo, Dong Nam;Park, Jung Gyu;Kim, Hyung Tae;Lee, Sung Min;Kim, Suk Young;Kim, Ik Jin
    • Journal of the Korean Ceramic Society
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    • v.53 no.6
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    • pp.604-609
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    • 2016
  • This study reports on wet-foam stability with respect to porous ceramics from a particle-stabilized colloidal suspension that is achieved through the addition of polymethyl methacrylate (PMMA) using a wet process. To stabilize the wet foam, an initial colloidal suspension of $Al_2O_3$ was partially hydrophobized by the surfactant propyl gallate (2 wt.%) and $SiO_2$ was added as a stabilizer. The influence of the PMMA content on the bubble size, pore size, and pore distribution in terms of the contact angle, surface tension, adsorption free energy, and Laplace pressure are described in this paper. The results show a wet-foam stability of more than 83%, which corresponds to a particle free energy of $2.7{\times}10^{-12}J$ and a pressure difference of 61.1 mPa for colloidal particles with 20 wt.% of PMMA beads. It was possible to control the uniform distribution of the open/closed pores by increasing the PMMA content and by adding thick struts, leading to the achievement of a higher-stability wet foam for use in porous ceramics.

The development of encoded porous silicon nanoparticles and application to forensic purpose (코드화 다공성 실리콘 나노입자의 개발 및 법과학적 응용)

  • Shin, Yeo-Ool;Kang, Sanghyuk;Lee, Joonbae;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.22 no.3
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    • pp.247-253
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    • 2009
  • Porous silicon films are electrochemically etched from crystalline silicon wafers in an aqueous solution of hydrofluoric acid(HF). Careful control of etching conditions (current density, etch time, HF concentration) provides films with precise, reproducible physical parameters (morphology, porosity and thickness). The etched pattern could be varied due to (1) current density controls pore size (2) etching time determines depth and (3) complex layered structures can be made using different current profiles (square wave, triangle, sinusoidal etc.). The optical interference spectrum from Fabry-Perot layer has been used for forensic applications, where changes in the optical reflectivity spectrum confirm the identity. We will explore a method of identifying the specific pattern code and can be used for identities of individual code with porous silicon based encoded nanosized smart particles.