• Title/Summary/Keyword: Porous Substrate

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EFFECT OF COATING COMPOSITION IN DOUBLE COATING ON THE PENETRATION OF FINE PARTICLES INTO SUBSTRATE

  • Kim, Byeong-Soo;Douglas W. Bousfield
    • Journal of the Korean Graphic Arts Communication Society
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    • v.18 no.1
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    • pp.1-11
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    • 2000
  • The influence of the first coating layer on the properties of the second coating layer is reported. For various model coating composition, ratios of first and second coating weights are used to generate coating layers. The void volume, pore size distribution and light scatter coefficient of the coatings are measured. In some cases, the fine material from the second layer seems to penetrate the first layer to reduce the void fraction of the total system. Rapid setting coating, for example thin layers on porous first layer tends to generate porous coating layers.

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Dynamic response of size-dependent porous functionally graded beams under thermal and moving load using a numerical approach

  • Fenjan, Raad M.;Ahmed, Ridha A.;Faleh, Nadhim M.;Hani, Fatima Masood
    • Structural Monitoring and Maintenance
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    • v.7 no.2
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    • pp.69-84
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    • 2020
  • Based on differential quadrature method (DQM) and nonlocal strain gradient theory (NSGT), forced vibrations of a porous functionally graded (FG) scale-dependent beam in thermal environments have been investigated in this study. The nanobeam is assumed to be in contact with a moving point load. NSGT contains nonlocal stress field impacts together with the microstructure-dependent strains gradient impacts. The nano-size beam is constructed by functionally graded materials (FGMs) containing even and un-even pore dispersions within the material texture. The gradual material characteristics based upon pore effects have been characterized using refined power-law functions. Dynamical deflections of the nano-size beam have been calculated using DQM and Laplace transform technique. The prominence of temperature rise, nonlocal factor, strain gradient factor, travelling load speed, pore factor/distribution and elastic substrate on forced vibrational behaviors of nano-size beams have been explored.

Influences of Electrochemical Vapor Deposition Conditions on Growth Rate ad Characteristics of YSZ Thin films(II) (YSZ 박막의 성장속도와 특성에 미치는 전기화학증착의 조건의 영향(II))

  • 박동원;전치훈;김대룡
    • Journal of the Korean Ceramic Society
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    • v.33 no.3
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    • pp.355-361
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    • 1996
  • Yttria stabilized zirconia (YSZ) thin films were prepared by the electrochemical vapor deposition (EVD) method on the porous Al2O3 substrates. Y2O3 mol% of thin film was linearly increased with yttrium mole fraction of vapor phase. As yttrium mole fraction(Zyc13=0.18) increased dense and faceted thin films were enhanced. However as the yttrium mole fraction (Zyc13=0.04) decreased porous thin films with monoclinnic phase prevailed. With increasing pressure difference of substrate sides penetration depth decreased porosity and amount of monoclinic phase in the films increased.

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Investigating dynamic stability of metal foam nanoplates under periodic in-plane loads via a three-unknown plate theory

  • Fenjan, Raad M.;Ahmed, Ridha A.;Faleh, Nadhim M.
    • Advances in aircraft and spacecraft science
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    • v.6 no.4
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    • pp.297-314
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    • 2019
  • Dynamic stability of a porous metal foam nano-dimension plate on elastic substrate exposed to bi-axial time-dependent forces has been studied via a novel 3-variable plate theory. Various pore contents based on uniform and non-uniform models have been introduced. The presented plate model contains smaller number of field variables with shear deformation verification. Hamilton's principle will be utilized to deduce the governing equations. Next, the equations have been defined in the context of Mathieu-Hill equation. Correctness of presented methodology has been verified by comparison of derived results with previous data. Impacts of static and dynamical force coefficients, non-local coefficient, foundation coefficients, pore distributions and boundary edges on stability regions of metal foam nanoscale plates will be studied.

Study on Corrosion Resistance Performance of Zn Coating Applied by Arc Thermal and Plasma Arc Spray Process in Artificial Ocean Water (인공해양환경에서 Arc Thermal and Plasma Arc Spray 공법이 적용된 Zn 코팅 강재의 내식성능 평가에 관한 연구)

  • Jannat, Adnin Raihana;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.06a
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    • pp.83-84
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    • 2020
  • In present study, we have deposited the Zinc coating using arc thermal spray and plasma arc spray processes onto the steel substrate and durability of the deposited coating was evaluated. The bond adhesion result shows that plasma arc sprayed Zn coating exhibited higher in its value compared to arc thermal spray. SEM shows that Zn coating deposited by plasma arc process is more compact, less porous and adherent compare to arc spray process. The corrosion resistance properties are evaluated in artificial ocean water solution with exposure periods. EIS results show that total impedance at 0.01 Hz of plasma arc sprayed coating is higher than arc thermal spray owing to the compact and less porous morphology. It is concluded that plasma arc sprayed Zn coating is better than arc thermal spray process.

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Perfluorinated Sulfonic Acid based Composite Membranes for Vanadium Redox Flow Battery (바나듐 레독스 흐름 전지를 위한 과불소화 술폰산 복합막)

  • Cho, Kook-Jin;Park, Jin-Soo
    • Journal of the Korean Electrochemical Society
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    • v.19 no.1
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    • pp.21-27
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    • 2016
  • Vanadium redox flow batteries (VRFBs) using the electrolytes containing various vanadium ions in sulfuric acid as supporting solution are one of the energy storage devices in alternatively charging and discharging operation modes. The positive electrolyte contains $V^{5+}/V^{4+}$ and the negative electrolyte $V^{2+}/V^{3+}$ depending on the operation mode. To prevent the mixing of two solutions, proton exchange membranes are mainly used in VRFBs. Nafion 117 could be the most promising candidate due to the strong oxidative property of $V^{5+}$ ion, but causes high crossover of electroactive species to result in a decrease in coulombic efficiency. In this study, the composite membranes using Nafion ionomer and porous polyethylene substrate were prepared to keep good chemical stability and to decrease the cost of membranes, and were compared to the properties and performance of the commercially available electrolyte membrane, Nafion 117. As a result, the water uptake and ionic conductivity of the composite membranes increased as the thickness of the composite membranes increased, but those of Nafion 117 slightly decreased. The permeability of vanadium ions for the composite membranes significantly decreased compared to that for Nafion 117. In a single cell test for the composite membranes, the voltage efficiency decreased and the coulombic efficiency increased, finally resulting in the similar energy efficiency. In conclusion, the less cost of the composite membranes by decreasing 6.4 wt.% of the amount of perfluorinated sulfonic acid polymer due to the introduction of porous substrate and lower vanadium ion permeability to decrease self-discharge were achieved than Nafion 117.

The Permeation Characteristics of $O_{2}/N_{2}$ Gas for Composite Membrane Prepared by Plasma Polymerization (플라즈마 종합에 의해 제조된 복합막에 대한 $O_{2}/N_{2}$의 기체투과 특성)

  • 현상원;정일현
    • Journal of environmental and Sanitary engineering
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    • v.13 no.2
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    • pp.147-155
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    • 1998
  • In this study, we prepared non-porous plasma membrane for having high permeability and selectivity and this membrane was deposited on the $Al_{2}O_{3}$ membrane by using $CHF_{3}$ & $SiH_{4}$ monomer. Also, we investigated for the permeation characteristics of the plasma polymer membrane by Ar plasma treatment. When the position of substrate was near cathode, the selectivity was increased with Ar plasma treatment time and rf-power. The pore size of $Al_{2}O_{3}$ membrane had an effect on the permeability and the position of substrate affected selectivity.

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Effect of Slurry Property on Preparation of Zirconia Film in Electrophoretic Deposition (전착법에서 용액특성이 지르코니아 막형성에 미치는 영향)

  • 김상우;이병호;손용배;송휴섭
    • Journal of the Korean Ceramic Society
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    • v.36 no.9
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    • pp.991-996
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    • 1999
  • Effect of solution property on the weight varation and microstructural change of film was studied by electrophoretic deposition in order to obtain a homogeneous and dense zirconia film. As a result of weight kinetics of film which obtained in alcohol or aqueous solution having different polarity experimental data showed large deviation from theoretical ones calculated by Zhang's kinetic model. It had been shown that the weight affecting factors was largely dependent on properties other than dielectric constant and viscosity of solvent zeta potential appiled field and time. In initial stage a main factor of the drastic weight increase was the capillary drag of porous substrate. The cause of weight decrease with time in aqueous solution after 300 s was attributed to the defect of film by sagging and electrolytic reaction. The electrolyte film which prepared in alcohol solution with good wetting for substrate had better homogeneous and dense microstructure than one in aqueous solution with high surface tension.

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Nanocomposite Ni-CGO Synthesized by the Citric Method as a Substrate for Thin-film IT-SOFC

  • Wang, Zhenwei;Liu, Yu;Hashimoto, Shin-ichi;Mori, Masashi
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.782-787
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    • 2008
  • Ni-ceria cermets have been extensively investigated as candidates for the anode in intermediate-temperature solid oxide fuel cells. We have used the citric method to synthesize nanocomposite powders consisting of NiO (Ni metal content: $40{\sim}60%$ by volume) highly dispersed in $Ce_{0.9}Gd_{0.1}O_{1.95}$ (CGO). The microstructure characteristics and sintering behaviors of the nanocomposites were investigated. No impurity phases were observed and the shrinkage of these substrates matched well with that of a CGO electrolyte with a specific surface area of $11\;m^2/g$. Densification of the CGO electrolyte layer to $<5\;{\mu}m$ thickness was achieved by co-firing the laminated electrolyte with the porous NiO-CGO substrate at $1400^{\circ}C$ for 6 h.

Bioactivity of Calcium Phosphate Ceramic Coatings on Metallic Implants

  • Kim, Cheol-Sang;Ducheyne, P.
    • Journal of Biomedical Engineering Research
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    • v.11 no.1
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    • pp.5-12
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    • 1990
  • Calcium phosphate ceramics have been applied intensively to orthopaedic and dental implants by virtue of their osteoconductive nature. In an attempt to enhance the bone implant intergrity and Eta utility, these ceramics are deposited onto the porous surface of metallic implants. The coating procedure and the ensuing phase transformations of the ceramic alter the mechanical properties and surface chemistry of the ceramic layers as well as those of the substrate. These structural and compositional differences are directly related to the interaction mechanisms at the surface-active ceramicbone interface. Material and processing induced influences on dissolution, electrokinetic behavior, ceramic-metallic substrate interface and boRe growth enhancement are presented.

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