• Title/Summary/Keyword: Porous

검색결과 5,337건 처리시간 0.033초

다공성 실리콘의 산화로부터 얻은 다공성 실리카의 산화에 대한 분석 (Analysis on Oxidation of Porous Silica Obtained from Thermal Oxidation of Porous Silicon)

  • 고영대
    • 통합자연과학논문집
    • /
    • 제3권3호
    • /
    • pp.153-156
    • /
    • 2010
  • Oxidation behaviors of porous silicon were investigated by the measurement of area of $SiO_2$ vibrational peaks in FT-IR spectra during thermal oxidation of porous silicon at corresponding temperatures. Visible photoluminescent porous silicon samples were obtained from an electrochemical etch of n-type silicon of resistivity between 1-10 ${\Omega}/cm$. The etching solution was prepared by adding an equal volume of pure ethanol to an aqueous solution of HF. The porous silicon was illuminated with a 300 W tungsten lamp for the duration of etch. Etching was carried out as a two-electrode galvanostatic procedure at applied current density of 200 $mA/cm^2$ for 5 min. The porosity of samples prepared was about 80%. After formation of porous silicon, the samples were thermally oxidized at $100^{\circ}C$, $200^{\circ}C$, $300^{\circ}C$, and $400^{\circ}C$, respectively. The growth rate of $SiO_2$ layer of porous silicon was investigated by using FT-IR spectroscopy. The effect of oxidation of porous silicon was presented.

다공성실리콘의 탄화를 이용한 PL의 열적안정성 증진 (Enhancement of Thermal Stability in Photoluminescence by Carbonization of Porous silicon)

  • 최두진;서영제;전희준;박홍이;이덕희
    • 한국세라믹학회지
    • /
    • 제34권5호
    • /
    • pp.467-472
    • /
    • 1997
  • Porous silicon was prepared by an anodic etching. The pore size was about 10 nm at an etching time of 20 sec and a current density of 20 mA/$\textrm{cm}^2$. The porous layer was composed of an micro-porous layer (0.6 ${\mu}{\textrm}{m}$) and a macro-porous layer (10 ${\mu}{\textrm}{m}$). Room temperature PL with maximum peak 6700$\AA$ appeared. The peak disappeared by an oxidation reaction when the porous silicon was heated to 100~20$0^{\circ}C$ in atmosphere. In order to avoid the oxidation a heat treatment was done in H2 atmosphere. The micro-pore and Si column, which formed quantum well, were collapsed by the high temperature. The PL maximum peak of heated sample was gradually red-shifted and showed about 300$\AA$ red-shift at 50$0^{\circ}C$. The intensity of PL was maintained to high temperatures in lower pressures. The porous Si was carbonized in C2H2+H2 gas in order to increase thermal stability. The carbonization of the porous Si prevented red-shift of the maximum PL peak caused by sintering effect at high temperatures, and the carbonized porous Si showed Pl signal at higher temperatures by above 20$0^{\circ}C$ than the sample in H2 atmosphere.

  • PDF

A Review of Porous Media Theory from Woltmans Work to Biots Work

  • Park, Taehyo;Jung, Sochan
    • 한국지반환경공학회 논문집
    • /
    • 제4권2호
    • /
    • pp.93-104
    • /
    • 2003
  • Porous media consist of physically and chemically different materials and have an extremely complicated behavior due to the different material properties of each of its constituents. In addition, the internal structure of porous materials has generally a complex geometry that makes the description of its mechanical behavior quite complex. Thus, classical continuum mechanics cannot explain the behavior of materials with pore spaces, such as concrete, soils and organic materials in waste landfill. For these reasons, porous media theory has been developed in the nineteenth century. Biot had the greatest influence on the development of porous media theory. Biot's work has been referred by many authors in the literature. Development of numerous fundamental equations in porous media theory were made possible due to Biot's work. His contributions made the greatest influence on porous media theory. Therefore, it is highly advantageous to review Biot's publications. This work presents a review of Biot's work. It shows how porous media theory has been developing so far and provides a chance to discuss the contribution of his work to the modern porous media theory.

  • PDF

Solid volume fraction이 20% 인 다공성 실린더 주위의 유동 해석 (NUMERICAL SIMULATION OF FLOW PAST A POROUS CYLINDER WITH 20% SOLID VOLUME FRACTION)

  • 장경식
    • 한국전산유체공학회지
    • /
    • 제17권3호
    • /
    • pp.87-92
    • /
    • 2012
  • The presence of a layer of vegetation which is relevant in river engineering or coastal engineering can modify the overall flow resistance, turbulent characteristics of flow. The patch of vegetation can be modelled and studied in a simple porous cylinder by previous researchers. Fully three dimensional Large Eddy Simulation is conducted in flow past a porous cylinder with a solid volume fraction (SVF) 0f 20%. The porous cylinder of diameter D contains 89 smaller cylinders which diameter is 0.048D in a regular staggered way. Reynolds number based on porous cylinder diameter D and the bulk velocity is 10,000. The large scale shedding is qualitatively similar to the one observed in the non-porous case (SVF=100%). The difference in the dynamics of the separated shear layer and the streamwise flow penetrating through the porous cylinder are compared with those in the non-porous cylinder. In particular, the wake billows form a larger distance from the back of the porous cylinder.

자동차 흡기 소음 저감을 위한 다공질 관의 적용 (The Application of a Porous Duct for Reducing the Intake Noise of Vehicle)

  • 이장명;한성수
    • 소음진동
    • /
    • 제11권1호
    • /
    • pp.29-35
    • /
    • 2001
  • Recently, the porous duct is becoming one of Possible ways to reduce the intake noise of an automobile instead of using resonators. In this article, acoustic characteristic of the porous duct is investigated theoretically and experimently. Futhermore, 4-pole parameter of the porous duct is introduced to predict transmission loss of it for various case. Acoustic efficiency of the porous duct is shown with experimental result using a car.

  • PDF

다공성 소결금속의 단조한계해석 (ANALYSIS OF FORGING LIMIT FOR SINTERED POROUS METALS)

  • 한흥남;오규환;이동녕
    • 한국소성가공학회:학술대회논문집
    • /
    • 한국소성가공학회 1995년도 제2회 단조심포지엄 단조기술의 진보
    • /
    • pp.64-73
    • /
    • 1995
  • The forging limit curves of sintered porous metals have been calculated, in terms of the two principal strains, by the Lee-Kuhn initial imperfection model. The various yield functions for porous metal have been applied to the initial imperfection model. When the value of initial imperfection ratio equals the value of initial relative density of the sintered porous metals, the calculation values are in good agreement with the measured data. The slopes of the forging limit curves are about 0.5 as in the case of non-porous metals.

Estimation of Oil Quantity in Porous Bearing

  • kohno, Hajime
    • 한국분말야금학회:학술대회논문집
    • /
    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
    • /
    • pp.594-595
    • /
    • 2006
  • Porous bearings are lubricated the oil that is contained in porous metal. Then they are always used with no oil supply, because of that, widely used electric motors. But, if oil flow out less than the limit, troubles often happen. This report shows that attempt of estimating oil quantity in porous bearing by using calculation that based Reynols' equation and Darcy's law, aimed of developing long life bearing. And comparing with experimental and calculation result, we show possibility of estimating rest oil quantity in porous bearing at steadry state by calculation.

  • PDF

발포알루미늄 다공핀의 열유동특성 (Flow and Heat Transfer Characteristics of Aluminum Foam Porous Fins)

  • 김서영;백진욱;강병하
    • 설비공학논문집
    • /
    • 제12권5호
    • /
    • pp.511-518
    • /
    • 2000
  • The present experimental study investigates the impact of porous fins on the pressure drop and heat transfer characteristics in plate-fin heat exchangers. Systematic experiments have been carried out in a simplified model of a plate-porous fin heat exchanger at a controlled test environment. Comparison of performance between the porous fins and the conventional louvered fins has been made. The experimental results indicate that friction and heat transfer rate are significantly affected by permeability as well as porosity of the porous fin. The porous fins used in the present study show a similar air-side performance to the louvered fin. The correlations of friction and modified j-factor are also given for the design of the plate-porous fin heat exchanger.

  • PDF

Magadiite 주형을 이용한 다공성 흑연제조에 미치는 Co와 Ni 촉매 효과 (Effect of Co and Ni Catalyst on the Preparation of Porous Graphite Using Magadiite Template)

  • 최석현;권오윤
    • 한국재료학회지
    • /
    • 제28권3호
    • /
    • pp.189-194
    • /
    • 2018
  • Porous graphites were synthesized by removing the template in HF after cabothermal conversion for 3 h at $900^{\circ}C$, accompanied by intercalations of pyrolyzed fuel oil (PFO) in the interlayer of Co or Ni loaded magadiite. The X-ray powder diffraction pattern of the porous graphites exhibited 00l reflections corresponding to a basal spacing of 0.7 nm. The particle morphology of the porous graphites was composed of carbon plates intergrown to form spherical nodules resembling rosettes like a magadiite template. TEM shows that the cross section of the porous graphites is composed of layers with very regular spaces. In particular, crystallization of the porous graphite was dependent on the content of Co or Ni loaded in the interlayer. The porous graphite had a surface area of $328-477m^2/g$. This indicates that metals such as Co and Ni act as catalysts that accelerate graphite formation.

A systematic approach for the development of porous concrete based on axiomatic design theory

  • Tran, X.H.;Tawie, R.;Lee, H.K.
    • Computers and Concrete
    • /
    • 제6권6호
    • /
    • pp.491-503
    • /
    • 2009
  • This paper presents a design framework developed using axiomatic design (AD) theory that can be applied in the design process of porous concrete. The main contribution of this paper is the definition of an AD framework based on the needs and functional requirements of porous concrete. The framework shows how AD theory can be used to provide guidelines for proportioning and manufacturing porous concrete. The advantage of the AD approach is that it systemizes the way to decouple design parameters and makes designers to think rationally between what we want to achieve and how we propose to satisfy the functional requirements of porous concrete. In this paper, test results of laboratory-size porous concrete specimens under compression were analyzed to evaluate the performance of the porous concrete based on the desired functional requirements.