• Elastomers and Composites
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• v.55 no.4
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• pp.277-280
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• 2020

In this study, mesoporous hollow silica spheres were synthesized using a polystyrene core and cetyltriammonium chloride (CTACl) as a pore template, and a low-cost water glass instead of expensive tetraethyl orthosilicate (TEOS) as a precursor. In addition, the material was synthesized by varying the concentration of polystyrene. Later, the polystyrene core and CTACl were removed by firing in a high-temperature heat-treatment process. The synthesized product was analyzed by various methods, such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffractometry (XRD), and N2-sorption analysis. It was confirmed that the hollow silica sphere had a hexagonal structure with a Brunauer-Emmett-Teller (BET) specific area of 1623 ㎡/g.

• Korean Journal of Optics and Photonics
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• v.18 no.4
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• pp.286-291
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• 2007

We theoretically investigated the far-field radiation pattern of epi-signal from a polystyrene sphere in coherent anti-Stokes Raman scattering (CARS) microscopy with an objective lens of high numerical aperture. We calculated the field distribution of the incident laser beams under the tight-focusing condition and the far-field radiation pattern through coherent addition of radiation from the nonlinear polarizations (Hertzian dipoles) as the origin of CARS signal generation. The epi-radiation patterns for polystyrene spheres of different diameters are calculated, and the pattern of a sphere is also compared with that of a shell fer a diameter of 1100 nm. We finally show how the radiation pattern of the polystyrene sphere changes as the center of the sphere shifts from the focus of the beam.

• Journal of Adhesion and Interface
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• v.15 no.2
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• pp.63-68
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• 2014

Hollow mesoporous carbon nitride material with sphere shape was synthesized using polystyrene sphere as template and cyanamide as nitrogen and carbon atom sources via thermal treatment process. The process of the silica removal is not necessary because silica as template is not in use for the synthesis of hollow mesoporous carbon nitride material and any solvents are also not in use. The size of polystyrene spheres was about 170 nm. Hollow diameter and wall thickness were 82 nm and 13 nm, respectively, in hollow mesoporous carbon nitride sphere. Surface area, mesopore size and pore volume of hollow mesoporous carbon nitride material was $188m^2g^{-1}$, 3.8 nm and $0.35cm^3g^{-1}$, respectively. The wall in hollow sphere has graphitic structure. Hollow mesoporous carbon nitride material has potential applications in the area of fuel cell, catalysis, photocatalysis, electroemmision device, etc.

• Korean Journal of Optics and Photonics
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• v.9 no.4
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• pp.258-263
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• 1998

Quasi-elastic light scattering is utilized to measure the mean diameter of the 0.3 $\mu\textrm{m}$-dimeter polystyrene sphere. The mean diameter of the polystyrene sphere is required to be known within the uncertainty of a few per centages. The systematic error has been considerably reduced by improving the system for the angle alignment and temperature measurement of cell. NIST SRM 1691 (0.269$\pm$0.007 $\mu\textrm{m}$: TEM; 0.275$\pm$0.007 $\mu\textrm{m}$: QELS) is measured to be 0.273 $\mu\textrm{m}$$\pm$0.006 $\mu\textrm{m}$ in mean diameter. Detailed description is given of the improved method and the resultant uncertainty, and the comparison of results with NIST is followed.

• Fire Science and Engineering
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• v.25 no.6
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• pp.89-97
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• 2011

This study is for evaluating the fire resistance performance (1~2 h) of the RC Structure void slab using the Lightweight Hollow Sphere, which can reduce the unnecessary dynamic part of removing the central concrete. For this experiment, we set up depth of concrete cover, live load, and span length as the factors. The result comes out with all the slabs under those conditions can ensure the goal fire resistance performance (120 min). And among these factors, the resisting capability changes more sensitively with the live load rather than the thickness of cover. And the shorter span length could assure the better the fire resistance performance. The result observing the character in high temperature of the Lightweight Hollow Sphere which does not used as existing RC structure slab, a delay section in temperature change is occurred due to the Glass Transition in $100^{\circ}C$. And heat transfer by conduction does not occur at lightweight hollow sphere because the polystyrene in EPS (Expanded Polystyrene) melts point in $185^{\circ}C$. Therefore temperature at lightweight hollow sphere is lower than the concrete and rebar.

• Proceedings of the Optical Society of Korea Conference
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• 1998.08a
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• pp.176-177
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• 1998

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.37 no.2
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• pp.188-194
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• 2024

This paper introduces an optimized oxygen (O₂) plasma surface treatment technique to enhance sphere lithography on hydrophobic photoresist surfaces. The focus is on semiconductor manufacturing, particularly the creation of finer structures beyond the capabilities of traditional photolithography. The key breakthrough is a method that makes substrate surfaces hydrophilic without altering photoresist patterns. This is achieved by meticulously controlling the O₂ plasma treatment duration. The result is the consistent formation of nano and microscale patterns across large areas. From an academic perspective, the study deepens our understanding of surface treatments in pattern formation. Industrially, it heralds significant progress in semiconductor and precision manufacturing sectors, promising enhanced capabilities and efficiency.

• Korean Journal of Materials Research
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• v.20 no.10
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• pp.550-554
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• 2010

This work presents a fabrication procedure to make large-area, size-tunable, periodically different shape metal arrays using nanosphere lithography (NSL) combined with ashing and annealing. A polystyrene (PS, 580 ${\mu}m$) monolayer, which was used as a mask, was obtained with a mixed solution of PS in methanol by multi-step spin coating. The mask morphology was changed by oxygen RIE (Reactive Ion Etching) ashing and temperature processing by microwave heating. The Au or Pt deposition resulted in size tunable nano patterns with different morphologies such as hole and dots. These processes allow outstanding control of the size and morphology of the particles. Various sizes of hole patterns were obtained by reducing the size of the PS sphere through the ashing process, and by increasing the size of the PS sphere through annealing treatment, which resulted in tcontrolling the size of the metallic nanoparticles from 30 nm to 230 nm.

• Korean Journal of Materials Research
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• v.27 no.12
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• pp.658-663
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• 2017

Urchin-structured zinc oxide(ZnO) nanorod(NR) gas sensors were successfully demonstrated on a polyimide(PI) substrate, using single wall carbon nanotubes(SWCNTs) as the electrode. The ZnO NRs were grown with ZnO shells arranged at regular intervals to form a network structure with maximized surface area. The high surface area and numerous junctions of the NR network structure was the key to excellent gas sensing performance. Moreover, the SWCNTs formed a junction barrier with the ZnO which further improved sensor characteristics. The fabricated urchin-structured ZnO NR gas sensors exhibited superior performance upon $NO_2$ exposure with a stable response of 110, fast rise and decay times of 38 and 24 sec, respectively. Comparative analyses revealed that the high performance of the sensors was due to a combination of high surface area, numerous active junction points, and the use of the SWCNTs electrode. Furthermore, the urchin-structured ZnO NR gas sensors showed sustainable mechanical stability. Although degradation of the devices progressed during repeated flexibility tests, the sensors were still operational even after 10000 cycles of a bending test with a radius of curvature of 5 mm.

• Polymer(Korea)
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• v.33 no.1
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• pp.33-38
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• 2009

Monodisperse polystyrene and its copolymer beads containing amine function were prepared for the electroless silver plating using reduction of silver alkylcarbamate complex in organic solvent. Soap-free emulsion polymerization was adopted for the polymerization of styrene, divinylbenzene (DVB), and 2-(N,N-dimethylamino) ethyl methacrylate (DAEMA) in the presence of poly (vinyl alcohol) in a water/methanol solvent. The resulting poly (styrene/DVB/DAEMA), containing 30/0$\sim$1.5/0$\sim$3 wt% in monomer composition, were found to be a sphere-type particle with diameter of 1 ${\mu}m$. Silver Ag-coated polystyrene beads were prepared by in sito reduction of a silver 2-ethylhexylcarbamate (Ag-EHCB) complex solution with hydrazine without pretreatment of polystyrene beads. Robust Ag/polystyrene beads were analyzed by SEM, UV -visible spectrometer and XRD.