• Title/Summary/Keyword: Polymer networks

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The Toughness of Polyurethane and Epoxy Resins IPNs (폴리우레탄-에폭시 IPNs의 강인성)

  • Kim, Jong Seok;Hong, Suk Pyo
    • Applied Chemistry for Engineering
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    • v.9 no.3
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    • pp.445-450
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    • 1998
  • Interpenetrating polymer networks(IPNs) were prepared from castor oil-type polyurethanes(PUs) and epoxy resin. Two types of PU were prepared by using polypropylene ether glycol(PPG) as a chain extending agent and caster oil(CO) as a crosslinking agent. COPU/epoxy simultaneous interpenetrating polymer networks(SINs) based on CO had a better compatibility over the all composition than PPGPU/epoxy SINs based on PPG. The flexural strength of all PPGPU/epoxy SINs was decreased with decreasing entanglement of networks. COPU/epoxy SINs showed the higher fracture toughness and mechanial properties than the PPGPU/epoxy SINs. Fracture surfaces of all of the SINs showed the localized shear deformation and crack deflection rather than generation of stress whitening associated with the cavitation.

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Evaluation of shear capacity of FRP reinforced concrete beams using artificial neural networks

  • Nehdi, M.;El Chabib, H.;Said, A.
    • Smart Structures and Systems
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    • v.2 no.1
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    • pp.81-100
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    • 2006
  • To calculate the shear capacity of concrete beams reinforced with fibre-reinforced polymer (FRP), current shear design provisions use slightly modified versions of existing semi-empirical shear design equations that were primarily derived from experimental data generated on concrete beams having steel reinforcement. However, FRP materials have different mechanical properties and mode of failure than steel, and extending existing shear design equations for steel reinforced beams to cover concrete beams reinforced with FRP is questionable. This paper investigates the feasibility of using artificial neural networks (ANNs) to estimate the nominal shear capacity, Vn of concrete beams reinforced with FRP bars. Experimental data on 150 FRP-reinforced beams were retrieved from published literature. The resulting database was used to evaluate the validity of several existing shear design methods for FRP reinforced beams, namely the ACI 440-03, CSA S806-02, JSCE-97, and ISIS Canada-01. The database was also used to develop an ANN model to predict the shear capacity of FRP reinforced concrete beams. Results show that current guidelines are either inadequate or very conservative in estimating the shear strength of FRP reinforced concrete beams. Based on ANN predictions, modified equations are proposed for the shear design of FRP reinforced concrete beams and proved to be more accurate than existing equations.

3-D Underwater Object Restoration Using Ultrasonic Transducer Fabricated with 1-3 Type Piezoceramic/Polymer Composite and Neural Networks (1-3형 복합압전체로 제작한 초음파 트랜스듀서와 신경회로망을 이용한 3차원 수중 물체복원)

  • Jo, Hyeon-Cheol;Lee, Gi-Seong;Choe, Heon-Il;Sa, Gong-Geon
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.48 no.6
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    • pp.456-461
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    • 1999
  • In this study, the characteristics of Ultrasonic Transducer fabricated with PZT-Polymer 1-3 type piezoelectric ceramic/polymer composite are investigated. 3-D underwater object restoration using the self-made ultrasonic transducer and modified SCL(Simple Competitive Learning) neural network was presented. The ultrasonic transducer was satisfied with the required condition of commerical ultrasonic transducer in underwater. The modified SCL neural network using the acquired object data $16\times16$ low resolution image was used for object restoration of $32\times32$ high resolution image. The experimental results have shown that the ultrasonic transducer fabricated with PZT-Polymer 1-3 type piezoelectric ceramic/polymer composite could be applied for SONAR system.

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Mechanical Property and Thermal Stability of Epoxy Composites Containing Poly(ether sulfone) (폴리에테르설폰이 도입된 에폭시 복합재의 열 안정성 및 기계적 특성)

  • Lee, Si-Eun;Park, Mi-Seon;Jeong, Euigyung;Lee, Man Young;Lee, Min-Kyung;Lee, Young-Seak
    • Polymer(Korea)
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    • v.39 no.3
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    • pp.426-432
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    • 2015
  • Poly(ether sulfone) (PES) embedded diglycidylether of bisphenol-A (DGEBA) epoxy composites were fabricated for improving its mechanical properties and thermal stability. The mechanical properties such as tensile, flexural and impact strength of the composites changed significantly with the introduction of PES. The value of the fracture toughness of this composite also was increased remarkably about 24%. Thermal stability of PES/epoxy composites also improved 12%, which was calculated with integral procedural decomposition temperature (IPDT). From the differential scanning calorimeter (DSC) result, the curing temperature and curing heat decreased according to the increase of PES contents. These were attributed to the good distribution and the formation of the semi-interpenetrating polymer networks (semi-IPNs) composed of the epoxy network and linear PES.

Polymer-based Large Core Optical Splitter for Multimode Optical Networks (멀티모드 광네트워크용 폴리머기반 대구경 광분배기)

  • An, Jong Bae;Lee, Woo-Jin;Hwang, Sung Hwan;Kim, Gye Won;Kim, Myoung Jin;Jung, Eun Joo;Moon, Jong Ha;Kim, Jin Hyeok;Rho, Byung Sup
    • Korean Journal of Optics and Photonics
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    • v.24 no.4
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    • pp.184-188
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    • 2013
  • Two types of polymer-based optical splitters with $200{\mu}m$ large core are presented for optical multimode networks, such as smart home networks, intelligent automotive networks, etc. Optical splitters that have 1:1 symmetric and 9:1 asymmetric structure were fabricated by a ultra violet(UV)-imprint technology using a deep etched Si(silicon) master by the Bosch process. In this paper, we successfully fabricated the symmetric and asymmetric optical splitters with suitable optical network applications.

Study on Nanocomposite Thermoplastic Elastomer Gels

  • Paglicawan Marissa A.;Balasubramanian Maridass;Kim, Jin-Kuk
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.370-370
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    • 2006
  • Thermoplastic elastomer gels, which has molecular networks composed of a microphase-separated multiblock copolymer swollen to a large extent by a low volatility mid-block selective solvent such as white oil have various applications. In this particular study, the effect of several network-forming nanoscale fillers such as two different graphite particles and carbon nanotube on the properties of TPE gels prepared from a microphaseordered poly[styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS) triblock copolymer with an EB compatible white oil was studied. The linear viscoelastic behavior, sol-gel transition, x-ray diffraction and mechanical properties were discussed. The properties of thermoplastic elastomer gels hybrid with graphite prepared by mixing Poly(styrene-b-ethylene-co-butylene)-b-styrene) with paraffin oil and different amount of expandable graphite were found to increase the mechanical properties at only lower graphite concentration but tends to decrease when paraffin oil/SEBS ratio is lower. The gelation temperature is the same for all TPE gels with different amounts of graphite. Both storage (G') modulus loss (G") modulus of TPE gels slightly increase with addition of graphite.

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Cross-linkable and water-soluble phospholipid polymer as artificial extracellular matrix

  • Maeta, Eri;Ishihara, Kazuhiko
    • Biomaterials and Biomechanics in Bioengineering
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    • v.1 no.3
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    • pp.163-174
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    • 2014
  • The objective of this study is to prepare an artificial extracellular matrix (ECM) for cell culture by using polymer hydrogels. The polymer used is a cytocompatible water-soluble phospholipid polymer: poly[2-methacryloyloxyethyl phosphorylcholine (MPC)-n-butyl methacrylate-p-nitrophenyloxycarbonyl poly(ethylene oxide) methacrylate (MEONP)] (PMBN). The hydrogels are prepared using a cross-linking reaction between PMBN and diamine compounds, which can easily react to the MEONP moiety under mild conditions. The most favorable diamine is the bis(3-aminopropyl) poly(ethylene oxide) (APEO). The effects of cross-linking density and the chemical structure of cross-linking molecules on the mechanical properties of the hydrogel are evaluated. The storage modulus of the hydrogel is tailored by tuning the PMBN concentration and the MEONP/amino group ratio. The porous structure of the hydrogel networks depends not only on these parameters but also on the reaction temperature. We prepare a hydrogel with $40-50{\mu}m$ diameter pores and more than 90 wt% swelling. The permeation of proteins through the hydrogel increases dramatically with an increase in pore size. To induce cell adhesion, the cell-attaching oligopeptide, RGDS, is immobilized onto the hydrogel using MEONP residue. Bovine pulmonary artery endothelial cells (BPAECs) are cultured on the hydrogel matrix and are able to migrate into the artificial matrix. Hence, the RGDS-modified PMBN hydrogel matrix with cross-linked APEO functions as an artificial ECM for growing cells for applications in tissue engineering.