• Title/Summary/Keyword: Polymer dispersion liquid crystal

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Effect of droplet size on electro-optical switching properties of polymer dispersed liquid crystals (폴리머 분산 액정의 전기 광학적 스위칭 특성에 대한 액정방울 크기의 효과)

  • Kim, In-Tae;Yu, Yeon-Serk
    • Korean Journal of Optics and Photonics
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    • v.17 no.1
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    • pp.23-30
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    • 2006
  • Effects of liquid-crystal droplets size on electro-optical properties of the polymer dispersed liquid crystals are investigated experimentally The liquid crystal droplets size was varied by controlling the Laser power for phase separation and LC/oligomer composition ratio. Electro-optical switching voltage is dependent on the LC/oligomer composition ratio and liquid crystal droplet size. The experimental results showed droplet size will be small and saturation voltage is increased but rise time will be short at high power illumination laser light for phase separation.

Control of Wavelength Dispersion of Birefringence by Miscible Polymer Blends

  • Ougizawa, Toshiaki;Kuboyamaima, Keiichi
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.365-365
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    • 2006
  • The wavelength dispersion of birefringence (or retardation) is very important property for optical use of polymer films. Birefringence free film and retardation film have been widely used for applications such as liquid crystal display (LCD). In this study, miscible polymer blends which consist of polymers of positive and negative birefringence were found. By operating composition and orientation of molecules in the transparent blend films, the behavior of wavelength dispersion of birefringence (retardation) was controlled. The applicability to wideband birefringence free film and quarter wave (retardation) film was discussed.

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Preparation and Dielectric Properties of LCP and BaTiO3 Composites (LCP(Liquid Crystal Polymer)와 BaTiO3복합체의 제조 및 유전특성)

  • 윤기현;이승주;양병덕;김종희
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1183-1188
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    • 2003
  • LCP (Liquid Crystal Polymer)/BT(BaTiO$_3$) composite was prepared by mixing LCP varnish and BT slurry. And the effect of the composition of LCP/BT composites and the size of BT powder on dielectric properties of LCP/BT composite were investigated. The dispersion properties of BT slurries were also studied as a function of volume fraction of dispersant, GLYMO (3-glycidyloxypropyltrimethoxysilane) added to various sized BT powders. The quantity of optimum dispersant in BT slurry decreased with an increase of BT powder size because of the decrease of specific surface area of BT powder. LCP/BT composite sheet was prepared by tape-casting method with mixing BT slurry and LCP varnish. The dielectric constant of the composites increased from 34.3 to 44.1 and their dielectric loss increased from 0.05 to 0.063 as the size of BT powder increased from 100 nm to 500 nm.

Dielectric and Optical Study of Polymer Nematic Liquid Crystal Composite

  • Manohar, S.;Shukla, S.N.;Chandel, V.S.;Shukla, J.P.;Manohar, R.
    • Transactions on Electrical and Electronic Materials
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    • v.14 no.3
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    • pp.111-115
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    • 2013
  • The dielectric anisotropy and dispersion of the real and imaginary part of the permittivity of commercially important nematic mixture E-24 and its polymer composite were investigated in the frequency range from 1 kHz to 10 MHz, and temperature range $14^{\circ}C$ to $55^{\circ}C$. The percentage optical transmittance and density have also been measured for both the systems. The results have been explained by assuming molecular rotation about the long molecular axis, under a hindering nematic potential. The dielectric anisotropy ${\Delta}{\varepsilon}$ is positive, and the mean dielectric permittivity falls with rising temperature. ${\Delta}{\varepsilon}$ is also used to determine the order parameter with varying temperature.

Liquid crystal alignment and pretilt angle generation using oblique UV light irradiation on polymer surface (경사진 자외선조사를 이용한 셀의 프리틸트각의 입사각도 의존성)

  • 서대식;한정민;박두석;박태규;황율연
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.267-270
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    • 1998
  • In this study, we investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with oblique non-polarized ultraviolet (UV) light irradiation on polyimide (PI) surfaces. It was found that the monodomain alignment of the NLC is obtained in a cell with an angle of incidence of 70∼85$^{\circ}$on PI surface. We consider that the monodomain alignment of NLC is attributed to anisotropic dispersion force effect due to Photo-depolymerization of polymer on PI surfaces. Also, pretilt angle of NLC is generated about 3$^{\circ}$ with an angle of incidence of 70∼75$^{\circ}$. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecules and the polymer surfaces.

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A Study on Alignment of Nematic Liquid Crystal by Using Slanted Non-polarized Ultraviolet Light Irradiation on Polyimide Film (폴리이미드막표면위에 경사진 자외선 조사를 이용한 네마틱 액정의 배향에 관한 연구)

  • 서대식;황율연;이보호
    • Electrical & Electronic Materials
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    • v.10 no.5
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    • pp.461-466
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    • 1997
  • In this paper, we developed the new non-rubbing liquid crystal (LC) alignment techniques in the cell with slanted non-polarized ultraviolet (UV) light irradiation on polyimide (PI) film. It is shown that the uniform alignment for nematic (N) LC is obtained by using slanted non-polarized UV light irradiation on PI surface. We successfully obtained that the pretilt angle of NLC is generated about 3.3 degree in the cell with slanted non-polarized UV light irradiation with 70 degree on PI surface, for the first time. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecular and the PI, which is broken the polymer by slanted non-polarized UV irradiation. Therefore, we concluded that the uniform LC alignment is attributed to anisotropic dispersion force due to photo depolymerization with slanted non-polarized UV light irradiation on PI surface.

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Generation of High Pretilt Angle in a Cell with Oblique non-polarized UV Light Irradiation on Polyimide Surface (폴리이미드막표면위에 경사진 자외선 조사를 이용한 액정셀에서의 고프리틸트각의 발생)

  • 서대식;한정민
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.6
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    • pp.481-485
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    • 1998
  • We investigated the generation of high pretilt angle for nematic liquid crystal (NLC) in a cell with obilique non-polarized ultraviolet (UV) light irradiation on mixtured polyimide surface. It was found that the monodomain alignment of NLC is obtained with an angle of incidence of 75∼85 degrees on PI surface. We consider that the monodomain alignment of NLC is attributed to anisotropic dispersion force effect to photo-depolymerization of polymer. We successfully observed that the pretilt angle of NLC is generated above 5 degree with an angle of incidence of 75∼85 degrees. It is considered that the pretilt angle generation NLC is attributed to interaction between the LC molecules and the polymer surfaces.

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Liquid crystal alignment and pretilt angle generation in the cell using linearly polarized UV light Irradiation on polymer surface (고분자막에 직선편광된 자외선 조사를 이용한 셀의 액정배향과 프리틸트각의 발생)

  • 서대식;이정호;이창훈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.259-262
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    • 1998
  • The liquid crystal (LC) alignment and pretilt angle generation using photo-alignment method were investigated in this study. We obtained that the monodomain alignment of nematic(N) LC increases with increasing irradiation time in a cell with linearly polarized ultraviolet (LPUV) light irradiation on polyimide (Pl) surfaces. We consider that the monodomain alignment is able to be anisotropic dispersion force due to photo-depolymerization of polymer with LPUV light irradiation on Pl surface. Also, we observed that the uniform alignment of NLC is obtained in a cell with normally LPUV light irradiated on Pl surface at 30 min. and then oblique LPUV is secondly irradiated on Pl surfaces rotated by 90$^{\circ}$. The pretilt angle of NLC is generated about 1.5$^{\circ}$ with oblique angle 60$^{\circ}$.

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Generation of high pretilt angle in nematic liquid crystal by using photo-alignment techniques on polyimide surfaces (광배향 기술을 이용한 액정의 고프리틸트각 발생)

  • 한정민;황율연;이창훈;서대식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.11a
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    • pp.198-201
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    • 1997
  • We investigated the generation of pretilt angle for nematic liquid crystal (NLC) in a cell with slanted non-polarized ultraviolet (UV) light irradiation on mixtured polyimide (PI) surfaces. It was found that the monodomain alignment of NLC is obtained in a cell with an angle of incidence of 75∼85 degrees on PI surface. We consider that the monodomain alignment of NLC is attributed to anisotropic dispersion force effect due to photo-depolymerization of polymer on Pl surfaces. We successfully observed that the pretilt angle of NLC is generated above 5 degree with an angle of incidence of 75∼85 degree. It is considered that the pretilt angle generation in NLC is attributed to interaction between the LC molecules and the Polymer surfaces.

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Electro-optical Properties of Polymer Dispersed Liquid Crysta Displays (고분자 분상형 액정표시소자의 전기광학적 특성 연구)

  • 박우상;고영부;박세근
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.10
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    • pp.885-890
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    • 1998
  • The electro-optical properties of polymer dispersed liquid crystals (PDLCs) depend on dispersion structures and nematic alignment which can be controlled by taking proper liquid crystal/polymer mixtures and process conditions. To achieve excellent electro-optical properties such as low driving voltage, good contrast ratio and negligible hysteresis, we have developed optimization procedure. Under the optimized conditions, PDLC of low threshold voltage less than 3.1 V, high contrast ratio more than 150 and negligible hysteresis were obtained.

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