• KCI Concrete Journal
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• 제13권2호
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• pp.58-66
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• 2001

Recently, polymer-modified mortar has been studied for proposed use on industrial floors as top coat with thin thickness, typically 5~15mm. The purpose of this study is to evaluate basic properties of self-leveling materials using polymer dispersions as kinds of SBR, PAE, St/BA with thin coat (under 3mm). Superplasticizer and thickener have been included in the mixes to reduce bleeding and drying shrinkage as well as to facilitate the workability required. The self-leveling materials using four types of polymer dispersion are prepared with polymer-cement ratio which respectively range from 50% and 75%, and tested for basic characteristics such as unit weight, air content, flow, consistency change and adhesion in tension. From the test results, the self-leveling materials using PAE emulsion at curing age of 28days are almost equal to those of conventional floor using urethane and epoxy resin. The adhesion in tension of self-leveling mortars using SBR latex and PAE emulsion at curing age of 3days is over 17 kgf/cm$^2$(1.67MPa). Consistency change is strongly dependent on the type of polymer dispersion. It is concluded that the self-leveling materials using polymer dispersions can be used in the same manner as conventional floor using thermosetting resin in practical applications, in the selection of polymer dispersions.

• 한국세라믹학회지
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• 제42권3호
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• pp.198-204
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• 2005

본 연구에서는 규불화염, 가용성 실리카, 방향족계 고분자 축합물 그리고 잠열특성을 지닌 질산염계 무기화합물로 구성된 규불화염계 수화열 저감제를 시멘트 모르타르의 수화열 및 건조수축에 미치는 영향을 조사하였다. 규불화염계 수화열 저감제의 첨가로 시멘트 모르타르의 단열상승온도 및 건조수축에 의한 길이변화가 저감되는 특성을 나타내었다. 또한, 규불화염계 수화열 저감제가 첨가된 판상형 시멘트 모르타르 시험체의 균열 패턴을 측정한 결과, 수화열 저감과 건조수축에 의해 길이변화가 저감되는 복합적 효과를 통해 시멘트 모르타르의 균열저감성이 개선되는 것을 확인하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.252-255
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• 2003

Recently, there is a growing trend in the United States toward replacing latex additives in polymer-modified cement mortars with redispersible polymer powders. This movement is relatively new in the U.S. but is further advanced in Europe due to the more extensive use of cement and concrete in residential construction. Hitherto, in Korea - there is a very diminutive movement towards this growing trend. Thus, there is limited availability of data on redispersible polymer powders. This study investigates the effectiveness of redispersible polymer powder on improvement of the mechanical properties of modified mortar. It was concluded from the results of the experiments that the size of the dispersed polymer particles, variations in glass transition points (Tg), and variations in minimum film formation temperature (MFT) influenced the strength development of the modified mortars, and optimum strength in modified mortars using redispersible powders can be achieved when the Tg which accounts for the degree of powder flexibility is considered.

• 한국도로학회논문집
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• 제13권2호
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• pp.85-93
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• 2011

본 연구에서는 고로슬래그 미분말 및 플라이애시와 같은 광물질 혼화재를 사용한 친환경 고성능 3성분계 시멘트 콘크리트 교면 포장의 성능을 평가하기 위하여 실험을 하였다. 광물질 혼화재의 혼입률 변화에 따른 3성분계 시멘트 콘크리트의 최적배합을 찾기 위하여 압축강도 및 휨강도 시험을 하였으며 최적배합을 사용하여 내구성 시험인 염소이온 침투저항성, 동결융해, 박리 저항성, 균열 저항성 및 알칼리골재반응 시험으로 친환경 고성능 3성분계 시멘트 콘크리트 교면 표장의 내구성 평가 및 신 구 콘크리트의 부착력을 평가하기 위하여 부착강도 시험을 하였다. 시험결과, 시멘트 70%, 고로슬래그 미분말15% 및 플라이애시 15%의 배합 바인더에서 압축강도 및 휨강도가 우수하게 나타났으며 이를 최적배합으로 도출하였다. 실내 및 시험시공에서 최적 배합을 사용한 실험결과는 염소이온 침투 저항성, 동결융해 저항성, 표면박리 저항성, 알칼리골재 반응 억제 및 내마모성이 우수하게 나타났다. 또한, 특수 제작된 Polymer Cement Mortar(Brooming)를 사용한 신 구 콘크리트의 부착력에서도 우수한 성능을 나타냈다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1997년도 가을 학술발표회 논문집
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• pp.375-380
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• 1997

The purpose of this study is to examine the properties of polymer-modified mortars using asphalt emulsion. The polymer-modified mortars using asphalt emulsion with various asphalt-cement ratios are prepared, and tested for flexural and compressive strengths, water absorption and permeability, carbonation, Cl ion penetration and chemical resistance. From the test results, the flexural and compressive strengths, water absorption and permeability, carbonation and Cl ion penetration depths of polymer-modified mortars using asphalt emulsion tend to be decreased with increasing asphalt-cement ratio, and chemical resistance is improved. It is evident that polymer-modified mortars using asphalt emulsion having an excellent properties as a waterproof and finish materials can be produced.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.537-540
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• 2005

Durability of the polymer-modified mortars using the redispersible SBR and PAE powder-modified mortars were experimentally investigated. Results of a previous study were used to determine the mix proportion that optimized the strength, and the freezing-thawing resistence, the carbonation depth and the chloride intrusion depth of the mortar for various polymer-cement ratios were studied. After 300 freezing-thawing cycles, the rate of weight reduction decreased from 7 to below 2 $\%$ as the polymer-cement ratios increased from 0 to 15 $\%$, and, on the 150 cycle basis, durability index increased from 60 to 98. Carbonation depth decreased from initial value of 5.5 to about 2.5 mm and chloride intrusion depth did from 3.5 to 1.5 mm

• KCI Concrete Journal
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• 제14권1호
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• pp.15-22
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• 2002

Stresses that develop due to differential shrinkage between polymer modified cement mortar (PM) and Portland cement concrete (PCC) in a repaired concrete beam at early ages were investigated. Interface delamination or debonding of the newly cast repair material from the base is often observed in the field when the drying shrinkage of the repair material is relatively large. This study presents results of both experimental and analytical works. In the experimental part of the study, development of the material properties such as compressive strength, elastic modulus, interface bond strength, creep constant, and drying shrinkage was investigated by testing cylinders and beams for a three-week period in a constant-temperature chamber. Development of shrinkage-induced strains in a PM-PCC composite beam was determined. In the analytical part of the study, two analytical solutions were used to compare the experimental results with the analytically predicted values. One analysis method was of an exact type but could not consider the effect of creep. The other analysis method was rather approximate in nature but the creep effect was included. Comparison between the analytical and the experimental results showed that both analytical procedures resulted in stresses that were in fair agreement with the experimentally determined values. It may be important to consider the creep effect to estimate shrinkage-induced stresses at early ages.

• 폴리머
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• 제36권2호
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• pp.216-222
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• 2012

콘크리트 제조 시 잉여수의 지연 흡수를 위하여 가교된 crosslinked poly(styrene-$alt$-maleic anhydride)(PSMA)가 core이고, PSMA가 shell인 마이크로캡슐 흡수제를 침전중합법으로 제조하였다. Shell의 두께를 조절하기 위하여 (core 단량체의 질량)/(shell 단량체의 질량) 비가 1/1, 1/2 및 1/3이 되도록 하여 cPSMA-PSMA를 중합하였다. FTIR spectrometer를 사용하여 시멘트 포화 수용액 내에서 PSMA가 가수 분해 반응이 일어남을 확인하였다. TEM 분석으로 core/shell 단량체 비가 1/2(cPSMA #3)일 때 마이크로캡슐 구조를 잘 형성하는 것을 관찰하였고, 1/1(cPSMA #2)과 1/3(cPSMA #4)은 불완전한 마이크로캡슐 구조임을 관찰하였다. 시멘트 포화 수용액에서 cPSMA #3의 팽윤비는 초기 20분까지 증가한 후 2시간까지는 감소하였으며, 그 후 24시간까지는 다시 증가하였다. 제조된 cPSMA #3을 시멘트 페이스트에 첨가한 후 시간에 따른 점도 측정 결과 1시간까지는 거의 변화가 없었지만, 그 후 급격한 점도 증가가 일어났다. Core로만 구성된 cPSMA #1을 0.5 wt% 첨가한 시멘트 모르타르의 압축강도는 무첨가 시멘트 모르타르에 비해 약 5% 높게 나타났으며, cPSMA #3을 첨가한 모르타르는 약 7% 증가로 가장 높게 나타났다.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2012년도 추계 학술논문 발표대회
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• pp.255-257
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• 2012

Epoxy resin without any hardener can harden in the presence of hydroxide ions in cement mortars and concretes at ambient temperature. The purpose of present study is to examine the hardening properties of hardener-free epoxy-modified mortars by curing conditions. The hardener-free epoxy-modified mortars using diglycidyl ether of A epoxy resin are prepared with various polymer-cement ratios, and subjected to initial moist/dry curing, initial steam(90℃) curing, initial steam/heat(80℃, 100℃) curing.As a result, degree of hardening of epoxy resin in initial moist/dry cured, initial steam cured and initial steam/heat(80℃) cured hardener-free epoxy-modified mortars is decreased with increasing polymer-cement ratio. However, it is markedly improved with additional dry-curing periods. On the other hand, regardless of the polymer-cement ratio and dry curing periods, degree of hardening of hardener-free epoxy-modified mortars with initial steam/heat(100℃) cure is over 95%.

• 자원리싸이클링
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• 제26권6호
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• pp.20-28
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• 2017

피치계 탄소섬유를 함유한 모르타르의 직접인장강도는 평균압축강도의 1/27~1/22에 해당하였다. 동일 양의 PAN계 탄소섬유를 함유한 모르타르의 직접인장강도가 1/15임에 비하여, 낮은 수준으로 나타났다. 이 때, 무보강 기준시편의 직접인장강도는 1/29 수준이었다. 피치계 탄소섬유를 함유한 모르타르의 휨인장강도는 평균압축강도에 비해, 약 1/12 수준으로 나타났고, PAN계 탄소섬유를 함유한 모르타르와 무보강 모르타르는 각각 1/10, 1/13.5의 수준으로 나타났다. 피치계 탄소섬유를 혼입한 모르타르의 인장성능은 무보강 모르타르와 PAN계 탄소섬유를 혼입한 모르타르의 중간 수준으로 나타났다.