• Title/Summary/Keyword: Polymer Binder

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Electromagnetic Wave Absorption Properties of Fe73Si16B7Nb3Cu1-Based Nanocrystalline Soft Magnetic Powder Composite Mixed with Charcoal Powder (나노결정 Fe73Si16B7Nb3Cu1 연자성분말과 숯분말 혼합 복합성형체의 전자파흡수 특성)

  • Kim, Sun-I;Kim, Mi-Rae;Sohn, Keun-Yong;Park, Won-Wook
    • Journal of Powder Materials
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    • v.16 no.4
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    • pp.291-295
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    • 2009
  • The electromagnetic wave absorption sheets were fabricated by mixing of $Fe_{73}Si_{16}B_7Nb_3Cu_1$ nanocrystalline soft magnetic powder, charcoal powder and polymer based binder. The complex permittivity, complex permeability, and scattering parameter have been measured using a network analyzer in the frequency range of 10 MHz$\sim$10 GHz. The results showed that complex permittivity of sheets was largely dependent on the frequency and the amount of charcoal powder : The permittivity was improved up to 100 MHz, however the value was decreased above 1 GHz. The power loss of electromagnetic wave absorption data showed almost the same tendency as the results of complex permittivity. However, the complex permeability was not largely affected by the frequency, and the values were decreased with the addition of charcoal powder. Based on the results, it can be summarized that the addition of charcoal powder was very effective to improve the EM wave absorption in the frequency range of 10 MHz$\sim$1 GHz.

Electrochemical Study of Electrode Material of Ni-MH Battery for HEV and PEMFC Fuel Cell (HEV 및 PEMFC 연료전지용 니켈수소 전지의 전극재료에 대한 전기화학적 평가)

  • Kim, Ho-Sung
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.2
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    • pp.24-28
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    • 2006
  • Electrochemical hydrogenation/dehydrogenation properties were studied for a single particle of a Mm-based(Mm : misch metal) hydrogen storage alloy($MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3}$) for the anode of Ni-MH batteries. A carbon fiber microelectrode was manipulated to make electrical contact with an alloy particle, and the cyclic voltammetry and the galvanostatic charge/discharge experiments were performed. A single particle of the alloy showed the discharge capacity of 280[mAh/g], the value being 90[%] of the theoretical capacity. Data were compared with that of the composite film consisting of the alloy particles and a polymer binder, which is more practical form for Ni-MH batteries. Additionally, pulverization of the alloy particles are directly observed. Compared with the conventional composite film electrodes, the single particle measurements using the microelectrode gave more detailed, true information about the hydrogen storage alloy.

Development of Pressure Sensitive Paint(PSP) technique for low-speed flows and its application (아음속 저속 유동용 Pressure Sensitive Paint의 개발과 응용)

  • Kang, Jong-Hoon;Lee, Sang-Joon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.32 no.4
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    • pp.12-17
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    • 2004
  • The PSP technique has been used to measure pressure distribution on model surfaces ins high-speed flows. The objective of this study is to develop a PSP technique which can be applied to low-speed aerodynamic flows. Four different PSP formulations including two porphyrins (PtOEP and PtTFPP) and two polymers (Poly(TMSP) and RTV-118) were tested and the performance of each combination was evaluated. In a static calibration, the luminescent intensity of the PSP coatings was measured from 0kPa to 11kPa with 0.5, 1, 2kPa increments. Among 4 PSP formulations tested, the combination of PtOEP and RTV-118 shows the best performance. The developed PSP technique was applied to an oblique impinging jet to measure the pressure field distribution on the impinging plate.

Numerical modeless of the damage, around inclusion in the orthopedic cement PMMA

  • Mohamed, Cherfi;Smail, Benbarek;Bouiadjra, Bachir;Serier, B.
    • Structural Engineering and Mechanics
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    • v.57 no.4
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    • pp.717-731
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    • 2016
  • In orthopedic surgery and more especially in total arthroplastie of hip, the fixing of the implants generally takes place essentially by means of constituted surgical polymer cement. The damage of this materiel led to the fatal rupture and thus loosening of the prosthesis in total hip, the effect of over loading as the case of tripping of the patient during walking is one of the parameters that led to the damage of this binder. From this phenomenon we supposed that a remain of bone is included in the cement implantation. The object of this work is to study the effect of this bony inclusion in the zones where the outside conditions (loads and geometric shapes) can provoke the fracture of the cement and therefore the aseptic lousing of the prosthesis. In this study it was assumed the presence of two bones -type inclusions in this material, one after we analyzed the effect of interaction between these two inclusions damage of damage to this material. One have modeled the damage in the cement around this bone inclusion and estimate the crack length from the damaged cement zone in the acetabulum using the finite element method, for every position of the implant under the extreme effort undergone by the prosthesis. We noted that the most intense stress position is around the sharp corner of the bone fragment and the higher level of damage leads directly the fracture of the total prosthesis of the hip.

Fluorescent Pattern Generation on the Fluorescent Photopolymer with 2-beam Coupling Method (2-beam Coupling 방법을 이용한 광 고분자 형광 패턴 형성)

  • Kim, Yoon-Jung;Kim, Jeong-Hun;Sim, Bo-Yeon;Lee, Myeong-Kyu;Kim, Eun-Kyoung
    • Korean Journal of Optics and Photonics
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    • v.21 no.1
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    • pp.6-11
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    • 2010
  • Fluorescent photopolymer film was prepared with composition containing acrylate monomer, binder, a visible light sensitive photo initiator, and fluorescent anthracene polymer. A fluorescent grating pattern was inscribed on the photopolymer film using a 2-beam coupling method. A 514 nm laser was coupled to generate a beam-interference pattern. A highly fluorescent diffractive line pattern was formed on the fluorescent photopolymer within 30 sec. of exposure. The fluorescence intensity was highly enhanced in the patterned area, possibly due to the change in the environment of the fluorescent polymers by the photo-polymerization of monomers. Under a photo-mask, a gap electrode pattern was formed of fluorescent gratings with a sub-micron scale, which was matched well to the calculated value ($2.5\;{\mu}m$ and $0.6\;{\mu}m$) based on the refractive index of the photopolymer and beam incident angle ($3.4^{\circ}$, $15^{\circ}$) to the photopolymer surface.

Free-standing Three Dimensional Graphene Incorporated with Gold Nanoparticles as Novel Binder-free Electrochemical Sensor for Enhanced Glucose Detection

  • Bui, Quoc Bao;Nguyen, Dang Mao;Nguyen, Thi Mai Loan;Lee, Ku Kwac;Kim, Hong Gun;Ko, Sang Cheol;Jeong, Hun
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.229-237
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    • 2018
  • The electrochemical sensing performance of metal-graphene hybrid based sensor may be significantly decreased due to the dissolution and aggregation of metal catalyst during operation. For the first time, we developed a novel large-area high quality three dimensional graphene foam-incorporated gold nanoparticles (3D-GF@Au) via chemical vapor deposition method and employed as free-standing electrocatalysis for non-enzymatic electrochemical glucose detection. 3D-GF@Au based sensor is capable to detect glucose with a wide linear detection range of $2.5{\mu}M$ to 11.6 mM, remarkable low detection limit of $1{\mu}M$, high selectivity, and good stability. This was resulted from enhanced electrochemical active sites and charge transfer possibility due to the stable and uniform distribution of Au NPs along with the enhanced interactions between Au and GF. The obtained results indicated that 3D-GF@Au hybrid can be expected as a high quality candidate for non-enzymatic glucose sensor application.

Wedge Splitting Test and Fracture Energy on Particulate Reinforced Composites (입자강화 복합재료의 쐐기분열시험 및 파괴에너지 평가)

  • Na, Seong Hyeon;Kim, Jae Hoon;Choi, Hoon Seok;Park, Jae Beom;Kim, Shin Hoe;Jung, Gyoo Dong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.3
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    • pp.253-258
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    • 2016
  • The effect of temperature on the fracture energy, crack propagation, and crack tip opening displacement (CTOD) was determined for particulate reinforced composites using the wedge splitting test. The materials that were used consisted of a polymer binder, an oxidizing agent, and aluminum particles. The test rate of the wedge splitting specimen was 50 mm/min, the temperature conditions were $50^{\circ}C$, room temperature, $-40^{\circ}C$, and $-60^{\circ}C$. The fracture energy, calculated from splitting load-crack mouth opening displacement(CMOD) curves, increased with decreasing temperature from $50^{\circ}C$ to $-40^{\circ}C$. In addition, the strength of the particulate reinforced composites increased sharply at $-60^{\circ}C$, and the composites evidenced brittle fracture due to the glass transition temperature. The strain fields near the crack tip were analyzed using digital image correlation.

Synthesis of all-inorganic halide perovskite nanocrystal and film fabrication for application in highly efficient optoelectronic device (고효율 광전자 소자 응용을 위한 전 무기 할라이드 페로브스카이트 나노결정 합 성 및 필름 제작)

  • Choi, Seung Hee;Kim, Hyun Bin;Yoo, Jung Hyeon;Kwon, Seok Bin;Jeong, Seong Guk;Song, Young Hyun;Yoon, Dae Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.28 no.3
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    • pp.106-111
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    • 2018
  • Halide perovskite nanocrystals have become attractive for LED applications due to their high color purity and excellent luminescent properties. $CsPbX_3$ (X = I, Br, and Cl) nanocrystals were synthesized by hot-injection method and the emission wavelength was controlled by changing the composition of halide ion. Green- and red-emitting films were fabricated using a polymer binder. The outstanding optical properties of the synthesized nanocrystals and fabricated films were confirmed. The wLED designed by green- and red-emitting perovskite nanocrystal films on blue InGaN LED was characterized.

Preparation of solvent-based eco-friendly stone paper (용제기반 친환경 stone paper의 제조)

  • Seok Ju Jeong;Do Yoon Kam;Eun Ok Choi;Hyun Cho;Byeong Woo Lee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.4
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    • pp.139-144
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    • 2023
  • Stone papers made of inorganic filler and plastic polymer do not use pulp, which is the main raw material of existing papers, so they contribute to the preservation of nature and can be used as more eco-friendly materials when they have biodegradability. Since most stone papers are manufactured by hot extrusion, the amount of ceramic fillers and related physical properties are limited to control manufacturing workability. In this study, the stone paper composition was prepared in a liquid form using solvents, so that there was little limitation on the amount of ceramic filler added and it was also easy to add additives to control biodegradability. They were fabricated from eco-friendly raw materials using waste oyster shells as an inorganic filler and (recyclable) PVC materials as an organic binder. After making a solution using common solvents for PVC, inorganic filler and cellulose to impart biodegradability were mixed and processed into sheets to prepare solvent-based stone papers, and their paper properties were evaluated.

Studies on Multi-step Addition of NMP in (LiNi0.80Co0.15Al0.05) (NCA) Cathode Slurry Preparation and its Rheological, Mechanical Strength and Electrochemical Properties for Li-ion Cells

  • Vasudevarao Pasala;Satyanarayana Maddukuri;V. Sethuraman;Rekha Lankipalli;Devi Gajula;Venkateswarlu Manne
    • Journal of Electrochemical Science and Technology
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    • v.14 no.3
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    • pp.262-271
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    • 2023
  • For electrode stability and the electrochemical performance of the Li-ion cell, it is essential that the active ingredients and unique additives in the polymer binder be well dispersed with the solvent-based slurry. The efficient procedure used to create the slurry affects the rheological characteristics of the electrode slurry. When successively adding different steps of Nmethyl-2-pyrrolidone (NMP) solvent to the cathode composition, it is evenly disseminated. The electrochemical performance of the Li-ion cells and the electrodes made with slurry formed by single step and multiple steps of addition of NMP solvent are examined. To preform rheological properties of cathode electrode slurry on Ni-rich Lithium Nickel-Cobalt-Aluminum Oxide (LiNi0.80Co0.15Al0.05) (NCA). Also, we investigate different step addition of electrode formation and mechanical strength characterization like peel strength. According to the EIS study, a multi-step electrode slurry has lower internal resistance than a single-step electrode slurry, which results in better electrical characteristics and efficiency. Further, microstructure of electrodes is obtained electrochemical performance in the 18650 cylindrical cells with targeted capacity of 1.5 Ah. The slurry of electrodes prepared by single step and multiple steps of addition of NMP solvent and its effect on the fabrication of 1.5 Ah cells. A three-step solvent addition on slurry has been found to be a lower internal resistance than a single-step electrode slurry as confirmed by the EIS analysis, yielding improved electrical properties and efficiency.