• 한국건축시공학회지
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• 제8권5호
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• pp.85-91
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• 2008

Prepacked concrete has recently been used in the special constructions fields such as underwater concrete work, heavy-weight concrete work, underground structure work, partial repair works for damaged reinforced concrete structures. and polymer-modified mortars have been employed as grouting mortars for the prepacked concrete. The purpose of this study is to recommend the optimum mix design of polymer-modified grouting mortars for prepacked concrete. Polymer-modified mortars using SBR and EVA emulsions as admixture of grouting mortars for prepacked concrete are prepared with various mix proportions such as sand-binder ratio, fly ash replacement ratio, polymer-binder ratio. and tested for flowability, viscosity of grouting mortars, bleeding ratio, expansion ratio, flexural and compressive strengths of grouting mortars and compressive and tensile strengths of prepacked concretes. From the test results, it is apparent that polymer-modified mortars can be produced as grouting mortars when proper mix design is chosen. We can design the mix proportions of high strength mortars for prepacked concrete according to the control of mix design factors such as type of polymer, polymer-binder ratio, sand-binder ratio and fly ash replacement ratio. Water-binder ratio of plain mortars for a constant flowability value are in the ranges of 43% to 50%. SBR-modified mortar has a little water-binder ratios compared to those of plain mortar, however, EVA-modified mortar needs a high water-binder ratio due to a high viscosity of polymer dispersion. The expansion and bleeding ratios of grouting mortars are also controlled in the proper value ranges. Polymer-modified grouting mortars have good flexural. compressive and tensile strengths, are not affected with various properties with increasing fly ash replacement to cement and binder-sand ratio. In this study, SBR-modified grouting mortar with a polymer-binder ratio of 10% or less, a fly ash replacement of 10% to cement and a sand-binder ratio of 1.5 is recommended as a grouting mortar for prepacked concrete.

• International Journal of Concrete Structures and Materials
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• 제10권2호
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• pp.249-256
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• 2016

This paper deals with the effects of silica fume content and polymer-binder ratio on the properties of ultrarapid-hardening polymer-modified mortar using silica fume and ethylene-vinyl acetate redispersible polymer powder instead of styrene-butadiene rubber latex to shorten the hardening time. The ultrarapid-hardening polymer-modified mortar was prepared with various silica fume contents and polymer-binder ratios, and tested flexural strength, compressive strength, water absorption, carbonation depth and chloride ion penetration depth. As results, the flexural, compressive and adhesion strengths of the ultrarapid-hardening polymer-modified mortar tended to increase as increasing polymer-binder ratio, and reached the maximums at 4 % of silica fume content. The water absorption, carbonation and chloride ion penetration resistance were improved according to silica fume content and polymer-binder ratio.

• 폴리머
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• 제35권1호
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• pp.87-93
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• 2011

본 연구에서는 LCD 컬러필터 레지스트용 fluorene 단위 구조를 가지는 다기능 바인더 고분자를 개발하여 카본블랙 기반 감광성 레지스트(CBR)를 제조하고 블랙 매트릭스(BM)에 적용하였다. 다기능 바인더 고분자를 얻기 위해 bisphcnol fluorene epoxy acrylate를 함유한 불포화 폴리에스터(BFEA-polyester)를 합성하였으며 이는 $^1H$ NMR, GPC 및 FTIR을 이용하여 분석하였다. 합성된 BFEA-polyester 바인더 고분자를 상업용 아크릴 바인더와 비교 평가하기 위하여 각각 CBR 제조 후 BM 리소그래피 테스트를 수행하였다. 그 결과, 본 연구에서 합성된 BFEA-polyester 바인더 고분자는 적합한 광경화 반응성과 알칼리 용해성을 가질 뿐만 아니라 기존 아크릴 바인더보다 더 우수한 공정 마진, 패턴 특성 및 유리 가판에 대한 접착력을 나타내었다.

• 한국재난정보학회 논문집
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• 제6권1호
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• pp.10-24
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• 2010

In this paper, warm asphalt binder was proposed as a substitute for the polymer-modified asphalt binder to get higher viscosity than that of the polymer-modified at the same temperature. Performance grade test and rotational viscosity of warm asphalt binder were conducted to evaluate the property variations due to the addition of admixture. Research results showed that the viscosity of warm asphalt binder at $100^{\circ}C$ was similar to that of the conventional asphalt binder. The performance and durability of warm asphalt binder were also comparable to those of the polymer-modified. It is considered that the active applications of warm asphalt binder can reduce environmental damages due to less diffusions of carbon dioxide compared to the conventional.

• 한국도로학회논문집
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• 제14권4호
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• pp.51-61
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• 2012

PURPOSES : This study deals with the working life of polymer concrete, which is typically used as a repair or overlay material for portland cement concrete pavements. METHODS : In the scope of this study, laboratory testing was conducted on fresh MMA modified UP polymer concrete, which uses an MMA monomer for viscosity adjustment and strength improvement of UP resin. The experimental variables were temperature (-20 to $+20^{\circ}C$) and binder components (MMA, MEKPO, and DMA). RESULTS : The result showed that the optimum binder ratios for polymer concrete production were 12, 11, and 10 wt.% when the MMA contents were 20, 30, and 40 wt.%, respectively. The working life of polymer concrete depending on temperature and binder components could be expressed by a logarithmic functional formula. The coefficient of variation for each binder component was the highest for DMA content while the lowest for MEKPO content. Also, the contents of each binder component for ensuring the working life of 60 minutes were proposed. CONCLUSIONS : Ultimately, the present study derived a linear regression equation estimating 60 minutes working life based on the setting times of each binder component.

• 한국응용과학기술학회지
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• 제40권6호
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• pp.1191-1200
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• 2023

The lithium ion battery has applied to various fields of energy storage systems such as electric vehicle and potable electronic devices in terms of high energy density and long-life cycle. Despite of various research on the electrode and electrolyte materials, there is a lack of research for investigating of the binding materials to replace polymer based binder. In this study, we have investigated petroleum pitch/polymer composite with various ratios between petroleum pitch and polymer in order to optimize the electrochemical and physical performance of the lithium-ion battery based on petroleum pitch/polymer composite binder. The electrochemical and physical performances of the petroleum pitch/polymer composite binder based lithium-ion battery were evaluated by using a charge/discharge test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and universal testing machine (UTM). As a result, the petroleum pitch(MP-50)/polymer(PVDF) composite (5:5 wt % ratio) binder based lithium-ion battery showed 1.29 gf mm^-1 of adhesion strength with 144 mAh g^-1 of specific dis-charge capacity and 93.1 % of initial coulombic efficiency(ICE) value.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1998년도 가을 학술발표논문집(II)
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• pp.350-355
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• 1998

Preplaced aggregate concrete in the building fields has recently been used in the partial repair works for damaged reinforced concrete structures, and polymer-modified mortars have been employed as grouting mortars for the preplaced aggregate concrete. The objective of this study is to clear the properties of polymer-modified grouting mortars. Polymer-modified mortars using a polystyrene acrylic(St/Ac) emulsion as grouting mortars for preplaced aggregate concrete are prepared with various mix proportions, and tested for flexural and compressive strengths, adhesion in tension. The flexural strength of emulsion-modified grouting mortars does not give much variation with increasing fly ash replacement for cement and sand-binder ratio. With increasing polymer-binder ratio, the flexural strength and adhesion in tension of St/Ac emulsion-modified grouting mortars increases, become nearly constant or reaches a maximum at a polymer-binder ratio of 5%. From the test results, St/Ac emulsion-modified grouting mortar with a polymer-binder ratio of 5%, a fly ash replacement of 10% for cement and sand-binder ratio of 1.0 is recommended as a grouting mortar for preplaced aggregate concrete.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.1029-1034
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• 2001

The effects of binder content and silica sand content on the freezing and thawing resistance of lightweight polymer concrete are examined. As a result, the mass loss and pulse velocity of lightweight polymer concrete decrease with increasing binder content and silica sand content. The relative dynamic modulus and durability factor of lightweight polymer concrete reaches minimum at a silica sand content of 50% and a binder content of 28%, and is inclined to increase with increasing binder content and silica sand content.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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• pp.360-361
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• 2008

A new kind of SBM co-polymer binder as styrene, n-butyl acrylate, and methacrylic acid (SBM) monodisperse co-polymer binder materials basted on $TiO_2$ pastes was synthesized and this $TiO_2$ pastes were applied of dye-sensitized solar cells (DSSCs). The SBM co-polymer binder was prepared by soap-free emulsion copolymerization using a PEG-EEM macromonomer. The photoanodes were characterized by morphology investigated from field emission scanning electron microscopy (FE-SEM). The photoelectrochemical properties of the thin films and the performance of DSSCs were measured by photovoltaic-current density. DSSC based on the emulsion co-polymer binder was obtained conversion efficiency of 7.1% under irradiation of AM 1.5($100mWcm^{-2}$).

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.925-928
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• 2006

The effects of polymer-binder ratio, antifoamer content and shrinkage-reducing agent content on the air content and strengths of high-fluidity polymer-modified pastes are examined. As a result, the air content of the polymer-modified pastes tends to decrease with increasing polymer-binder ratio and antifoamer content. Irrespective of the antifoamer content, the flexural and tensile strengths of the high-fluidity polymer-modified pastes tends to increase with increasing polymer-binder ratio, and tend to decrease with increasing shrinkage-reducing agent content. However, the compressive strength of the polymer-modified pastes decreases with increasing polymer-binder ratio and shrinkage-reducing agent content.