• 제목/요약/키워드: Polarity ratio

검색결과 108건 처리시간 0.023초

아민계 추출제에 의한 아크릴산의 추출 평형 (Extraction Equilibria of Acrylic Acid with Amine Extractants)

  • 이용화;이준;홍연기
    • 청정기술
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    • 제20권2호
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    • pp.103-107
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    • 2014
  • 각종 고분자 화합물과 섬유산업에 응용되어왔던 아크릴산은 지금까지 화석원료를 이용하여 생산되어 왔다. 그러나 최근 화석원료의 가격 불안정성과 화석연료 유래 제품의 전주기에 걸친 온실가스 배출로 인해 재생 가능한 바이오매스로부터 아크릴산을 생산하는 공정에 관심이 높아지고 있다. 재생 가능한 탄소원으로부터 경제적으로 아크릴산을 생산하기 위해서는 효율적인 분리공정 개발이 필수적이다. 본 연구에서는 수용액 내의 아크릴산을 추출하기 위해 3차 아민추출제인 TOA를 사용하여 반응추출을 실시하였다. 각종 변수들이 추출능에 미치는 영향을 알아보고자 희석제의 극성과 TOA의 농도, 수용상에서 아크릴산의 농도에 변화를 주며 실험을 진행하였다. 아크릴산의 추출능은 TOA의 농도와, 알콜의 극성에 비례하였으며 최대 추출능은 95% 이상인 것으로 나타났다. 추출 후 산과 아민의 복합체의 형성을 확인하기 위해 적외선분광법을 실시하였고, 적외선분광법을 바탕으로 평형모델 식을 세워 추출평형 데이터를 해석하였다. 적외선분광법을 통하여 TOA의 농도가 높아질수록 (1, 1) 복합체의 비율이 증가하는 반면 아크릴산 이합체의 비율이 감소하는 것을 확인하였으며 이를 바탕으로 수립된 평형모델은 평형데이터를 잘 모사하였다.

Alkanolamine계 수용액을 이용한 이산화탄소 흡수에 관한 연구 (A Study on the Absorption of $CO_2$Using Alkanolamine Solution)

  • 이성남;송호철;현재휴;박진원
    • 한국대기환경학회지
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    • 제17권5호
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    • pp.407-414
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    • 2001
  • In this study, the absorption kinetics of $CO_2$onto a mixture of AMP (2-amino-2-methyl-1-propanol) MEA (monoethanolamine) water were investigated at 30 and 4$0^{\circ}C$ using a packed absorption tower. Solubility and absorption rate of $CO_2$into alkanolamine solutions and optimal condition of $CO_2$absorption process were investigated. The experimental conditions are as follows; temperature of 30 and 4$0^{\circ}C$, gas flow rate of 3ι/min for the absorption tower, and liquid flow rate of 0.1ι/min. Feed gas was a mixture of 85% $N_2$and 15% $CO_2$. The experimental results showed that AMP had greater solubilities and faster absorption rates than MEA and DEA. In addition, MEA had the fastest initial reaction rate. To improve the properties of AMP which have low initial reaction rate and high cost, AMP was used with MEA. The mixing ratio was also changed in constant total molarity of 1,2,3 and 4. The experimental results can be summarized as follows: (1) in solubility experiment, the addition of MEA in constant total polarity decreased the solubility of $CO_2$in AMP/MEA mixture. (2) from 0 to about 0.3 in mixing ratio, the solubility of $CO_2$in AMP/MEA mixture had little differences compared with the sum of solubility of AMP only and solubility of MEA only . (3) mixing ratio of 0.3 was found to be an optimal point with the fastest $CO_2$absorption rate.

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자속구속형 초전도 전류제한기의 용량증대를 위한 동작특성 (Operating Characteristics of Capacity Increase in a Flux-Lock Type Superconducting Fault Current Limiter)

  • 남긍현;최효상;박형민;조용선;이나영;한태희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 춘계학술대회 논문집 전기기기 및 에너지변환시스템부문
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    • pp.200-202
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    • 2006
  • We investigated the operating characteristics of a flux-lock type superconducting fault current limiters according to the number of the serial connection each the superconducting element at the additive polarity winding of a transformer. This SFCL consists of two coils wound in parallel on the same iron core, and the secondary coil is connected to the elements in series. Operating characteristics can be controlled by adjusting the inductances and the winding directions of the coils. It turns ratio between the primary and the secondary coils is 63:21. The analysis of voltage, current, and resistance in serial connection each element was performed to increase the applied voltage of flux-lock type SFCL. When the applied voltage was 200/$\sqrt{3}[V_{rms}]$ with three elements connected in seres, the peak value of the line current increased up to 26,24[A]. On the other hands, resistive SFCL increased up to 36.35[A], under the same conditions. This enabled the flux-lock type SFCL to be easy to increase the capacity of power system.

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Fault Plane Solutions for the Recent Earthquakes in the Central Region of South Korea

  • Hoe, Seo-Yun;Kyung, Jai-Bok
    • 한국지구과학회지
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    • 제29권5호
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    • pp.437-445
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    • 2008
  • We analyzed fault plane solutions of the recent twenty-two earthquakes which occurred from 2004 to 2006 in the central part of the Korean Peninsula by using P- and S-wave polarities along with SH/P amplitude ratios. The fault plane solution shows that strike-slip fault is dominant here, especially for the events with local magnitude equal to or greater than 3.0. However, some events with local magnitude less than 3.0 show normal fault or strike-slip fault with normal components. In the case of strike-slip fault, its orientation is almost in the direction of NNE-SSW to NE-SW almost parallel to the general trend of faults, while the compressional axis of the stress field trends ENE to E-W. The result is almost consistent with the stress field in and around the Korean peninsula, as reported previously. We cannot give any appropriate explanations to the normal faulting events along the western offshore and inland areas whether it is related to the local stress changes or tectonically unidentified extensional structures. Thus, an extension of investigations is desirable to clarify the cause of such phenomena.

삼상 분리형 자속커플링 전류제한기의 2차 권선의 턴 수 및 결선 방향에 따른 전류제한 특성 (Current Limiting Characteristics of Separated Three-phase Flux-coupling Type SFCL according to Winding Number of Coil 2 and Winding Direction)

  • 김용진;두호익;두승규;김민주;이동혁;한병성
    • 한국전기전자재료학회논문지
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    • 제22권8호
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    • pp.694-697
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    • 2009
  • The separated three-phase flux-coupling type superconducting fault current limiter(SFCL) is composed of a series transformer and superconducting unit of the YBCO coated conductor. The primary and secondary coils in the transformer were wound in series each other through an iron core and the YBCO coated conductor was connected with secondary coil in parallel. In this paper, we investigated the current limiting characteristics through winding number of coil 2 and winding direction in the flux-coupling type SFCL. Through the analysis, it was shown that additive polarity condition and lower winding number of coil 2 have advantaged from the point of view of fault current limiting and burned of YBCO coated conductor.

Design And Implementation of a Novel Sustain Driver for Plasma Display Panel

  • Agarwal Pankaj;Kim Woo-Sup;Cho Bo-Hyung
    • 전력전자학회:학술대회논문집
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    • 전력전자학회 2006년도 전력전자학술대회 논문집
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    • pp.403-405
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    • 2006
  • Over the years, plasma display panel (PDP) manufacturers have impressed the flat panel display industry with yet another new product essentially having the merits of a larger screen size. Since larger size implies higher power ratings, voltage/current ratings of the power devices used have become a rising concern. Another important concern is the brightness of PDP, one way of increasing which is by operating the PDP at higher frequencies. In order to address the above issues, a transformer coupled sustain-driver for AC-PDP is proposed During the transition time, the two windings of the transformer greatly boost up the displacement current flowing through the panel capacitance and hence enable a fast inversion of the voltage polarity with practical values of resonant inductance. In the proposed topology, the resonant inductance can be increased by a factor of $(n+1)^2$ as compared to prior approaches. Increased inductance results in lower current stresses. Moreover, high frequency operation is possible by using higher value of n (turn ratio of the transformer). The operational principle and design procedure of the proposed circuit are presented with theoretical analysis. The validity of the proposed sustain driver is established through simulation and experimental results using a 42-in PDP

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영지의 항산화성 물질에 관한 연구 (Studies on Antioxidative Substances of Ganoderma lucidum)

  • 정동옥
    • 한국식품과학회지
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    • 제24권5호
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    • pp.497-503
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    • 1992
  • 영지 추출액의 항산화 활성을 thiocyanate method, TBA method, weighing method를 이용하여 검색한 결과 n-hexane 추출물, methanol 추출물에서 항산화활성이 나타났으며 그 중에서 n-hexane 추출물의 fraction V와 methanol 추출물의 methanol 불용성 fraction II에서 강한 활성을 나타내었다. 이들 항산화 활성을 나타내는 fraction 5와 fraction II를 rat의 간 균질액을 이용한 항산화 활성 검색에서 과산화 지질 생성억제를 TBA값으로 나타내어 inhibition ratio(I.R.)를 산출하였으며 그 결과 n-hexane 추출물의 fraction V는 l5%, methanol 추출물의 methanol 불용성 fraction II는 54.6%의 억제율을 나타내었다 이는 rat의 간 mitochondria에서 과산화지질 생성 억제율이 영지의 물 추출물은 16%, acetone 추출물은 23%인 것에 비하여 약간 높았으나, microsome에서 과산화지질 생성 억제율이 물 추출물은 44%, acetone 추출물은 75%인 것에 비하여 다소 낮은 활성을 보여주었다.

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강인한 고스트제거기준신호 포획방법 (A Robust Method of Capturing Ghost Canceling Reference)

  • 권성재;정창진
    • 한국산업정보학회:학술대회논문집
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    • 한국산업정보학회 2002년도 춘계학술대회 논문집
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    • pp.76-79
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    • 2002
  • 고스트제거기는 수직공백구간 내에 삽입된 고스트제거기준신호 라인을 포획하여 송출된신호가 채널을 경유하면서 겪은 왜곡을 정확히 추정 하여야한다. 그런데 고스트가 심해지면 동기분리가 제대로 되지 않기 때문에 채널추정을 위한 데이터를 포획할 수 없게 된다. 본 논문에서는 이와 같은 문제점을 해결하고자 고스트제거기준신호의 상관특성을 활용해 프리 런(free run)하는 클록신호로 효과적으로 데이터를 획득하는 방법을 제안하고 컴퓨터 시뮬레이션을 동하여 검증하고자 한다. 고스트제거기준신호는 컬러 버스트를 제거하고 신호대잡음비를 개선하고자 4 필드에 걸쳐 그 각성이 반전되기 때문에 데이터 획득과정에서 수반되는 타이밍 지터 문제를 해결하는 방안도 제안한다. 시뮬레이션 결과 타이밍 지터 문제를 샘플간격의 약 4% 이하가지 고스트제거기준신호를 제대로 포획할 수 있음을 알 수 있었다.

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Detrended fluctuation analysis of magnetic parameters of solar active regions

  • Lee, Eo-Jin;Moon, Yong-Jae
    • 천문학회보
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    • 제41권1호
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    • pp.81.2-81.2
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    • 2016
  • Many signals in the nature have power-law behaviors, namely they are "scale-free". The method of detrended fluctuation analysis (DFA), as one of the popular methods (e.g., Rescaled range analysis and Spectral analysis) for determining scale-free nature of time series, has a very important advantage that the DFA can be applied to both stationary and non-stationary signals. The analysis of time series using the DFA has been broadly used in physiology, finance, hydrology, meteorology, geology, and so on. We performed the DFA of 16 Spaceweather HMI Active Region Patch (SHARP) parameters for 38 HMI Active Region Patches (HARPs) obtained by Solar Dynamics Observatory (SDO) from May 2010 to June 2014. The main results from this study are as follows. (1) The most of the time series data are non-stationary. (2) The DFA scaling exponents of "mean vertical current density" for 38 HARPs have a negative correlation coefficient (-0.41) with flare index. (3) The DFA scaling exponents of parameters such as "Sum of the absolute value of net currents per polarity", "Absolute value of the net current helicity", and "Mean photospheric excess magnetic energy density" for the most active HARPs having more than 10 major flares, have positive correlation coefficients (0.64, 0.59, and 0.53, respectively) with the ratio of "the number of CMEs associated with major flares" to "the number of major flares". Physical interpretations on our results will be discussed.

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실리콘 고무인상재의 물성에 미치는 충전제의 영향 (Effect of Filler on the Physical Properties of Silicone Rubber Impression Material)

  • 정경호;강승경
    • Elastomers and Composites
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    • 제41권3호
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    • pp.157-163
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    • 2006
  • 침전실리카와 친수성 및 소수성 흄실리카를 사용하여 첨가량에 따른 실리콘 고무인상재의 젖음성과 기계적 물성 향상 연구를 수행하였다. 고무인상재의 경화시간에는 흄실리카 종류보다는 입자크기가 영향을 미쳤으며, 입자크기가 가장 작은 A300을 사용할 경우 약 9분 정도의 경화시간 지연을 초래하였다. 소수성 흄실리카인 R972를 대체 사용할 경우 고무인상재의 젖음성 특성이 가장 우수하였다. 침전실리카와 A300 흄실리카를 85:15로 혼합하여 사용할 경우 인열강도가 약 1.5N/mm 정도 증가하지만 경화시간의 과도한 지연과 더불어 점도가 상승하기 때문에, 흐름성 및 기계적물성 측면에서 침전실리카와 흄실리가(A300)를 90:10으로 혼합하여 사용하는 것이 최적이었다.