• Title/Summary/Keyword: PolA

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Preparation and Properties of DMF-Based Polyurethanes Containing Bio-Polyol/Ester-Polyol for Wet-Type Polyurethane Artificial Leather (습식 인조피혁용 바이오 폴리올/폴리에스터 폴리올을 함유한 DMF 기반 폴리우레탄의 제조 및 물성)

  • Sur, Suk-Hun;Choi, Pil-Jun;Ko, Jae-Wang;Park, Ji-Hyeon;Lee, Jae-Yeon;Lee, Young-Hee;Kim, Han-Do
    • Clean Technology
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    • v.25 no.1
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    • pp.7-13
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    • 2019
  • Recently, attention has been paid to obtaining bio-polyols from renewable resources. Successful use of these natural ingredients successfully produced in the industry for the synthesis of various polyurethanes is a very important task. In this study, a series of dimethylformamide (DMF) based polyurethanes were synthesized from methylene diphenyl diisocyanate (MDI)/1, 4-butanediol and bio-polyol (polytrimethylene ether glycol based on 1, 3-propanediol : B-POL)/polyester polyol (polyadipate diol based on 1,4-butandiol : H-PET). The effect of different ratio of bio-polyol (B-POL)/polyester polyol (H-PET) on the physical properties of polyurethane was investigated. As the B-POL content in B-POL/H-PET mixture increased, the glass transition of soft segment (Tgs) and tensile strength of polyurethane decreased, however, the elongation at break and tear strength increased. On the other hand, artificial leather was produced by wet process using synthesized DMF-based polyurethanes. It was found that there was almost no difference in the effect of the B-POL/H-PET composition on the average size and density (the number of cells per unit volume) of the porous cells formed in artificial leather. These results show that there is no problem in using bio-polyol (B-POL) based polyurethane for artificial leather produced by wet process.

Reflection Symmetry of PALSAR Quad-Pol Imagery in the Amazon Rainforest (아마존 지역 PALSAR 다중편파 자료의 반사대칭성 특성)

  • Kim, Jae-Hun;Yoon, Sun Yong;Won, Joong-Sun
    • Korean Journal of Remote Sensing
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    • v.34 no.6_1
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    • pp.969-979
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    • 2018
  • This paper presents reflection symmetry of polarimetric SAR over the Amazon rainforest in terms of correlation coefficients between the pairs of HH- and HV-pol and VV- and VH-pol data by ALOS PALSAR. The reflection symmetry is defined as a non-zero correlation between HH- and HV-pol and VV- and VH-pol over natural distributed targets, and is a fundamental assumption for cross-talk calibration coefficient computation and for three-component decomposition for polarimetric SAR data. The Amazon rainforest is especially one of the common global reference sites for the reflection symmetry. The correlation coefficients for the pairs of reflection symmetry obtained in this study range from 0.018 to 0.097. The results imply that there exists a non-negligible dependency between co-pol and cross-pol in the distributed natural targets, and consequently the non-zero correlation must be considered as a potential contribution to errors of spaceborne SAR polarimetry to some extent.

Polyhedra Productions of Recombinant Autographa californica Nucle- opolyhedroyiruses Containing Additional Polyhedrin of Autographa Cali- fornica, Bombyx mori or Spodoptera exigua Nucleopolyhedrovirus

  • Chang, Jin-Hee;Roh, Jong-Yul;Jin, Byung-Rae;Je, Yeon-Ho
    • International Journal of Industrial Entomology and Biomaterials
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    • v.3 no.1
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    • pp.13-18
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    • 2001
  • The role of polyhedrin in the polyhedra production in baculovirus Autograha californica Nucelopolyhedro-sisvirus (AcNPV) was studied by over-expression of AcNPV polyhedrin or heterologous polyhedrin from Bombyx mori (Bm) NPV or Spodoptera exigua (Se) NPV. The transfer vectors containing additional polyhedrin from AcNPV, BmNPV, or SeNPV were constructed and cotransfected with bacmid bApGOZA into Sf9 cells. The resulting recombinants, designated as vApAcPol, vApBmPol, and vApSePol were tonstructed, and the polyhedra production of the recombinant was characterized. All of the recombinants produced polyhedra in the nucleus, and the polyhedrin was over-expressed. Among three recombinants, vApAcPol and vApBmPol were discriminated by their larger polyhedra size than that of wild type AcNPV, and vApSePol also produced larger polyhedra than wild type SeNPV polyhedra.

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Production and Rheological Properties of the Polysaccharide from Bacillus sp. A29 (Bacillus sp. A29에 의한 다당류의 생산과 물성)

  • Ahn, Sung-Ku;Suh, Hyun-Hyo;Lee, Chang-Ho;Oh, Hee-Mock;Kwon, Gi-Seok;Yi, Dong-Heui;Yoon, Byung-Dae
    • Microbiology and Biotechnology Letters
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    • v.22 no.2
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    • pp.175-181
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    • 1994
  • A bacterial strain producing highly viscous polysaccharide(A29 POL) was isolated from soil and identified sa Bacillus sp. A29. The cultural conditions of the Bacillus sp. A29 for the polysaccharide prouction were dextrin 12%, soytone 0.2%, SnCl$_{2}$ $\cdot $2H$_{2}$O 0.02%, Na$_{2}$HPO$_{4}$ $\CDOT $12H$_{2}$O 0.36%, L-alanine 0.01%, initial pH6.8, and 30$\circ $C at pH 3 FOR 4 days. Final viscosity of the culture broth was 65, 000 cp and then the amount of produced polysaccharide was 8.3 g/l. A29 POL was composed of glucose and xylose. A29 POL showed high viscosity at low concentration(0.1%) and in the presence of the salts such as NaCl or CaCl$_{2}$. A29 POL showed high viscosity acid condition and at alkali condition and high pseudoplasticity in the presence of a NaCl or CaCl$_{2}$. It was shown that the viscosity at high temperature(80$\circ $C) was decreased but it was recovered at low temperature (20$\circ $C. A29 POL was able to from film and gel in the presence of MgSO$_{4}$ $\CDOT $7H$_{2}$O, Na$_{2}$CO$_{3}$ \CDOT $H$_{2}$O, MnSO$_{4}$ $\CDOT $ 7H$_{2}$O. A29 POL had anionic charge.

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Obstacle Avoidance Technique for Chaotic Mobile Robot (카오스 이동 로봇에서의 장애물 회피 기법)

  • Bae Young-chul;Kim Chun-suk
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.8 no.8
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    • pp.1692-1699
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    • 2004
  • In this paper, we propose a method to avoid obstacles that have unstable limit cycles in a chaos trajectory surface. We assume all obstacles in the chaos trajectory surface have a Van der Pol equation with an unstable limit cycle. We also show computer simulation results of Arnold equation, Chua's equation, Hyper-chaos equation, Hamilton equation and Lorenz chaos trajectories with one or more Van der Pol obstacles.

Isolation and Characterization of a Novel Polysaccharide Producing Bacillus polymyxa A49 KCTC 4648P

  • Ahn, Sung-Gu;Suh, Hyun-Hyo;Lee, Chang-Ho;Moon, Seong-Hoon;Kim, Hee-Sik;Ahn, Keug-Hyun;Kwon, Gi-Seok;Oh, Hee-Mock;Yoon, Byung-Dae
    • Journal of Microbiology and Biotechnology
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    • v.8 no.2
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    • pp.171-177
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    • 1998
  • The strain A49, which produces a new type of extracellular polysaccharide was isolated from soil samples. From morphological, physiological and biochemical tests, the strain A49 was identified as a Bacillus polymyxa and named Bacillus polymyxa A49. Bacillus polymyxa A49 was found to produce a highly viscous extracellular polysaccharide when grown aerobically in a medium containing glucose as the sole source of carbon. The polysaccharide (A49 POL) showed a homogeneous pattern on gel permeation chromatography (GPC) and its molecular weight was estimated to be about 1.6 mega dalton (mDa). The FT-IR spectrum of A49-POL revealed typical characteristics of polysaccharides. As a result of investigations with HPLC and carbozole assay, A49-POL was found to consist of L-fucose, D-galactose, D-glucose, D-mannose, and D-glucuronic acid, with the molar ratio of these sugars being approximately 1:2:7:50:12. Rheological analysis of A49 POL revealed that it is pseudoplastic and has a higher apparent viscosity at dilute concentrations than does xanthan gum. The consistancy factor of A49 POL was found to be higher, and the flow index of A49 POL lower, than xanthan gum. Its apparent viscosity was comparatively unstable at various temperatures. the A49 POL showed the highest apparent viscosity at pH 3. When salts were added to A49 POL solution, the solution was compatible with up to 10% KCl, 35% NaCl, 55% $CaCl_2$, 55% $MgCl_2$, 55% $K_2HPO_4$, and 110% $Ca({NO_3})_2$, respectively.

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AN EXPERIMENTAL STUDY ON THE BONDING STRENGTH OF COMPOSITE RESINS TO ETCHED ENAMEL SURFACE WITH PHOSPHORIC ACID (산처리(酸處理)된 치아표면(齒牙表面)에 대(對)한 복합(複合)레진 접착강도(接着强度)에 관(關)한 실험적(實驗的) 연구(硏究))

  • Park, Kyung-Jung
    • Restorative Dentistry and Endodontics
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    • v.5 no.1
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    • pp.19-23
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    • 1979
  • This experimental study was made to investigate the tensile strength of composite resins to etched enamel surface with a 50% phosphoric acid. Recently extraced 40 maxillary incisors were chosen. These were divied into 4 groups: Group I: Restodent adaptation to the etched enamel surface with 50% phosphoric acid. Group II: Restodent adaptation to only the ground enamel surface. Group III: Hi-pol adaptation to the etched enamel surface with 50% phosphoric acid. Group IV: Hi-pol adaptation to only the ground enamel surface. The results were as follows: 1. The tensile strength of Hi-pol showed much better results than that of Restodent. 2. Hi-pol and Restodent on the ground enamel surfaces showed little difference. 3. Adhesion to enamel increased on the average over 200% after a 50% phosphoric acid etch.

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Policosanol Reduces Blood Cholesterol Levels by Inhibiting Sterol Regulatory Element-binding Proteins-1c and Fatty Acid Synthase (Sterol regulatory element-binding proteins-1c와 지방산 합성효소의 억제를 통한 폴리코사놀의 혈중 콜레스테롤 감소)

  • Min Jung Park;Byeong Min An;Dongjun Lee;Ji Myung Choi;Yung Hyun Choi;Bo Sun Joo
    • Journal of Life Science
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    • v.33 no.4
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    • pp.315-324
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    • 2023
  • The underlying action of policosanol in lowering cholesterol level has not yet been clearly elucidated. Several recent studies have suggested that sterol regulatory element-binding proteins (SREBP)-1c play a role in the regulation of cholesterol synthesis via the fatty acid synthesis pathway. To date, no study has evaluated the effects of policosanol on SREBP-1c-mediated fatty acid synthesis. Therefore, this study aimed to investigate whether the SREBP-1c-mediated fatty acid biosynthetic pathway is associated with the cholesterol-lowering effects of policosanol. Seven-week-old C57BL/6 male mice were randomly divided into 7 groups (n=7 per group) and treated for 8 weeks as follows: 1) normal diet (normal control), 2) high-fat diet (HFD), 3) HFD+ethanol (Pol-0), 4) HFD+policosanol 1 mg/kg (Pol-1), 5) HFD+policosanol 2 mg/kg (Pol-2), 6) HFD+policosanol 4 mg/kg (Pol-4), and 7) HFD+simvastatin 50 ㎍/kg (positive control). Policosanol and simvastatin were administered at the same time every day while maintaining the HFD. Body weight and food intake were measured weekly for 8 weeks. After 8 weeks, serum cholesterol levels were measured, histological analysis was carried out, and the expressions of SREBP-1c and fatty acid synthase (FAS) in the liver tissues were examined. Policosanol reduced body weight and the amount of food intake in a dose-dependent manner. Serum cholesterol levels were significantly lowered in the Pol-1 and Pol-4 groups. The expression of SREBP-1c and FAS was also significantly decreased in the Pol-4 group. These results suggest that the cholesterol-lowering effects of policosanol can occur due to the inhibition of the expression of SREBP-1c and FAS.

Effects of Polygalae Radix on Brain Tissue Oxidative Damage and Neuronal Apoptosis in Hippocampus Induced by Cerebral Hypoperfusion in Rats (원지(遠志)가 뇌혈류 저하에 의한 흰쥐 뇌조직의 산화적 손상과 해마신경세포 자연사에 미치는 영향)

  • Koo, Yong-Mo;Kwak, Hee-Jun;Kwon, Man-Jae;Song, Mincheol;Lee, Ji-Seung;Shin, Jung-Won;Sohn, Nak-Won
    • The Korea Journal of Herbology
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    • v.31 no.1
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    • pp.7-15
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    • 2016
  • Objectives : Polygalae Radix (POL) has an ameliorating effect on learning and memory impairment caused by cerebral hypoperfusion. In regard to POL's action mechanism, this study was carried out to investigate the effects of POL on oxidative damage and neuronal apoptosis induced by cerebral hypoperfusion in rats.Methods : The cerebral hypoperfusion was induced by permanent bilateral common carotid artery occlusion (pBCAO) in Sprague-Dawley rats. POL was administered orally once a day (130 mg/kg of water-extract) for 28 days starting at 4 weeks after the pBCAO. Superoxide dismutase (SOD) activities and malondialdehyde (MDA) levels in the brain tissue were measured using ELISA method. Expressions of 4-hydroxynonenal (4HNE) and 8-hydroxy-2'- deoxyguanosine (8-OHdG) were observed using immunohistochemistry. In addition, neuronal apoptosis was evaluated with Cresyl violet staining, TUNEL labeling, and immunohistochemistry against Bax and caspase-3.Results : POL treatment significantly increased SOD activities and significantly reduced MDA levels in the cerebral cortex. The up-regulations of 4HNE and 8-OHdG expression caused by pBCAO in the CA1 of hippocampus were significantly attenuated by POL treatment. POL treatment also restored the reduction of CA1 thickness and CA1 neurons caused by pBCAO and significantly attenuated the apoptotic markers including TUNEL-positive cells, Bax, and caspase-3 expression in the CA1 of hippocampus.Conclusions : The results show that POL attenuated the oxidative damage in brain tissue and neuronal apoptosis in the hippocampus caused by the cerebral hypoperfusion. It suggests that POL can be a beneficial medicinal herb to treat the brain diseases related to cerebral hypoperfusion.

Adaptive Immersion and Invariance Control of the Van der Pol Equation

  • Khovidhungij, Watcharapong;Santhanapipatkul, Ponesit
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.706-709
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    • 2005
  • We study the adaptive stabilization of the Van der Pol equation. A parameter update law is designed by the immersion and invariance method, and is used in conjunction with both the feedback linearization and backstepping control laws. Simulation results show that the responses obtained in the adaptive case are very similar to the known parameter case, and the parameter estimator converges to the true value.

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