• Korean Chemical Engineering Research
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• 제60권3호
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• pp.439-445
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• 2022

본 연구에서는 전기방사를 이용해 제조한 Si/C Fiber 표면에 실리콘과 석유계 피치를 코팅하여 전지의 용량 안정성을 개선하고자 하였다. TEOS와 PAN을 전기방사 Fiber의 전구체로 사용하여 DMF에 용해해 방사하였다. 전기 방사된 Fiber는 탄화, 환원, 피치 코팅 공정의 특성을 분석하여 최적 공정을 조사하였으며, TEOS와 PAN의 비율에 따라 제조한 음극 소재의 성능을 평가하였다. 탄화/환원 공정 후의 TEOS : PAN = 4 : 6 (CR-46)로 제조된 음극 복합 소재는 657 mAh/g의 용량을 보여주었다. 전기화학적 성능을 개선하기 위하여, CR-46 표면에 실리콘과 석유계 피치를 코팅하였다. 피치의 조성을 10 wt%로 고정하였을 때, 실리콘의 함량이 증가할수록 용량은 개선되지만, 안정성은 저하됨을 알 수 있었다. 실리콘의 조성을 10 wt%로 제조한 음극 복합 소재는 982.4 mAh/g의 높은 용량과 86.1%의 용량 안정성을 확인할 수 있었다. 고속 충·방전 특성을 분석하기 위한 율속 테스트에서는 80.2%의 용량비(5C/0.1C)를 나타내었다.

• Journal of the Korean Wood Science and Technology
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• 제39권5호
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• pp.390-397
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• 2011

In this study, bending test was conducted as beam members in timber roadside safety barrier. The flexural properties of pitch pine round timber according to the diameters were evaluated. And then grading based on the growth characteristics applied to choosing the pitch pine round timbers which is met the criteria of guideline (Japan, 2008). MOR of round timber 160 mm is higher than other specimens from 100 mm to 140 mm. Because of lower juvenile wood ratio and higher density. The MOE of round timber is decreased according to the increment of diameter. Only 32% of the specimens has passed the limitations. Performance of pitch pine round timbers has confirmed to suitability roadside safety beam members according to the guideline (Japan, 2008).

• 대한기계학회논문집B
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• 제41권1호
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• pp.29-36
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• 2017

본 논문은 환형노즐 이젝터를 이용하여 세정수 공급과 기포생성을 동시에 할 수 있는 세정기술 개발을 위한 기초연구를 목적으로 한다. 환형노즐 이젝터의 피치변화에 따른 구동 및 부유체의 정량적 유동특성과 세정수조에 분출되는 분류의 정성적 가시화 이미지를 분석하였으며, 세정물의 농약 잔류물 성분의 농도를 검증하였다. 피치가 증가하면 구동유량은 증가하는 반면에, 유량비는 감소하였다. 피치가 증가하면 분류는 부력분류나 평형분류 거동을 나타내며, 잔류농약의 농도는 감소 후 증가하였다.

• 말소리와 음성과학
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• 제4권1호
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• pp.49-54
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• 2012

Recent studies on acoustic correlates of stress in English compounds and English phrases have revealed the difference of changes in acoustic manifestation between English compounds and English phrases with different intonation patterns. However, little effort has been made to compare Korean compounds and Korean phrases in different intonational environments. Therefore, this study focuses on the analysis of acoustic characteristics of Korean compounds and Korean phrases produced in different intonational sentence patterns (Subject, Question, Clause-Final, and Statement-Final). Measurements of vowel duration, intensity (dB) and pitch (in semitones) were compared. The results of the experiment in which 30 native speakers of Korean pronounced Korean compounds and Korean phrases (obtained from $8{\times}30$ sentences) in controlled prosodic and intonational environments reveal clear patterns that distinguish Korean compounds from Korean phrases and support the evidence of acoustic salience for phrases. Duration differences turned out to be a significant cue to distinguish Korean compounds and Korean phrases in all but the Clause Final position. According to the size effect, duration ratio is the most reliable cue to distinguish Korean compounds and Korean phrases followed by the pitch differences between the first syllable and the second syllable and the intensity ratio. Implications for Korean and English intonation training were also discussed.

• Nuclear Engineering and Technology
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• 제48권1호
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• pp.182-188
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• 2016

In this paper, a feasible strategy for the recycling of nuclear graphite is reported, based on the formation mechanism and the removal of carbon-14 by micro-oxidation. We investigated whether ground micro-oxidation graphite could be used as a filler to make new recycled graphite and which graphite/pitch coke ratio will give the recycled graphite outstanding properties (e.g., apparent density, flexural strength, compressive strength, and tensile strength). According to the existing properties of nuclear graphite, the ratio of graphite to pitch coke should not exceed 3. The recycled reactor graphite has been proven superior in density, strength, and thermal conductivity. The micro-oxidation process enhances the strength of the recycled graphite because there are more pores and unsmooth surfaces on the oxidized graphite particles, which is beneficial for the access of the pitch binder and leads to efficient joint adhesion among the graphite particles.

• 한국재료학회지
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• 제23권5호
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• pp.276-280
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• 2013

Coal tar is the primary feedstock of premium graphitizable carbon precursor. Coal tars are residues formed as byproducts of thermal treatments of coal. Coal tar pitches were prepared through two different heat treatment schedules and their properties were characterized. One was prepared with argon and oxidation treatment with oxygen; the other was prepared with oxygen treatment at low temperature and then argon treatment at high temperature; both used coal tar to prepare coal tar pitches. To modulate the properties, different heat treatment temperatures ($300{\sim}400^{\circ}C$) were used for the coal tar pitches. The prepared coal tar pitches were investigated to determine several properties, such as softening point, C/H ratio, coke yield, and aromaticity index. The coal tar pitches were subject to considerable changes in chemical composition that arose due to polymerization after heat treatment. Coal tar pitch showed considerable increases in softening point, C/H ratio, coke yields, and aromaticity index compared to those characteristics for coal tar. The contents of gamma resin, which consists of low molecular weight compounds in the pitches and is insoluble in toluene, showed that the degree of polymerization in the pitches was proportional to C/H ratio. Using an oxidizing atmosphere like air to prepare the pitches from coal tar was an effective way to increase the aromaticity index at relatively low temperature.

• 한국음향학회:학술대회논문집
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• 한국음향학회 1998년도 제15회 음성통신 및 신호처리 워크샵(KSCSP 98 15권1호)
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• pp.460-464
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• 1998

일반적으로 파형 부호화법에서는 발성자의 개성과 메시지 정보를 보존하여 음질의 명료성이 우수하다. 하지만 파형 부호화법이 규칙에 의한 합성에 적응되도록 하기 위해서는 운유 조절에서 피치 변경법이 요구되어 진다. 본 논문에서는 스펙트럼의 왜곡율을 최소화하면서도 위상을 그대로 보존할 수 있는 시간영역에서의 피치변경법을 적용하였다. 이러한 방법들은 시간영역에서만 처리됨으로써 계산량을 줄여 실시간 운율조절에 적합하다. 결과적으로 피치주기를 100%에서 50%로 압축한 경우 평균 스펙트럼 왜곡율은 5.62%이고, 피치주기를 100%에서 200%로 신장한 경우 평균 스펙트럼 왜곡율은 4.20%정도로 비교적 우수한 결과가 얻어졌다.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2008년도 학술대회
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• pp.367-373
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• 2008

Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. Activation energy is used as parameter as 10, 20, 27 and 35, and the specific heat ratio and the heat release are fixed as 1.2 and 50. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable pitch at Ea=10, periodical unstable pitch at Ea=20 and 27 and unstable pitch consisting of stable, periodical unstable and weak modes at Ea=35, respectively. In the weak mode, there is no Mach leg on the shock front, where the pressure level is much lower than the other modes. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of these stable and unstable modes. In the stable pitch at Ea=10, the maximum pressure history on the tube wall remained nearly constant, and the steady single Mach leg on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the periodical unstable pitch at Ea=20 and 27 of the maximum pressure history. The high frequency was one cycle of a self-induced oscillation by generation and decay in complex Mach interaction due to the variation in intensity of the transverse wave behind the shock front. Eventually, sequential high frequency oscillations formed the low frequency behavior because the frequency behavior was not always the same for each cycle. In unstable pitch at Ea=35, there are stable, periodical unstable and weak modes in one cycle of the low frequency oscillation in the maximum pressure history, and the pressure amplitude of low frequency was much larger than the others. The pressure peak appeared after weak mode, and the stable, periodical unstable and weak modes were sequentially observed with pressure decay. A series of simulations of spinning detonations clarified that the unsteady mechanism behind the shock front depending on the activation energy.

• 한국전산유체공학회:학술대회논문집
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• 한국전산유체공학회 2008년 추계학술대회논문집
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• pp.367-373
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• 2008

Spinning detonations propagating in a circular tube were numerically investigated with a one-step irreversible reaction model governed by Arrhenius kinetics. Activation energy is used as parameter as 10, 20, 27 and 35, and the specific heat ratio and the heat release are fixed as 1.2 and 50. The time evolution of the simulation results was utilized to reveal the propagation mechanism of single-headed spinning detonation. The track angle of soot record on the tube wall was numerically reproduced with various levels of activation energy, and the simulated unique angle was the same as that of the previous reports. The maximum pressure histories of the shock front on the tube wall showed stable pitch at Ea=10, periodical unstable pitch at Ea=20 and 27 and unstable pitch consisting of stable, periodical unstable and weak modes at Ea=35, respectively. In the weak mode, there is no Mach leg on the shock front, where the pressure level is much lower than the other modes. The shock front shapes and the pressure profiles on the tube wall clarified the mechanisms of these stable and unstable modes. In the stable pitch at Ea=10, the maximum pressure history on the tube wall remained nearly constant, and the steady single Mach leg on the shock front rotated at a constant speed. The high and low frequency pressure oscillations appeared in the periodical unstable pitch at Ea=20 and 27 of the maximum pressure history. The high frequency was one cycle of a self-induced oscillation by generation and decay in complex Mach interaction due to the variation in intensity of the transverse wave behind the shock front. Eventually, sequential high frequency oscillations formed the low frequency behavior because the frequency behavior was not always the same for each cycle. In unstable pitch at Ea=35, there are stable, periodical unstable and weak modes in one cycle of the low frequency oscillation in the maximum pressure history, and the pressure amplitude of low frequency was much larger than the others. The pressure peak appeared after weak mode, and the stable, periodical unstable and weak modes were sequentially observed with pressure decay. A series of simulations of spinning detonations clarified that the unsteady mechanism behind the shock front depending on the activation energy.

• 소음진동
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• 제4권2호
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• pp.199-208
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• 1994

Two-phase cross-flow exists in many shell-tube heat exchangers such as nuclear steam generators, condensers and reboilers. An understanding of damping and of flow-induced vibration excitation mechanisms in necessary to avoid problems due to excessive tube vibration. In this paper, we present the results of experiments on normal-triangular tube bundles of pitch to tube diameter ratio, p/d, 1.22, 1.32 and 1.47. The bundle were subjected to air-water mixtures to simulate realistic mass fluxes and vapour qualities corresponding to void fractions from 5 to 99%. Damping, fluidelastic instability and turbulence- induced excitation are discussed. The behaivior of damping and two vibration mechanisms are different for intermittent flows from for bubbly flows. The effect of pitch to tube diameter ratio and void fraction is dominant on damping and fluidelastic instability.