• Title/Summary/Keyword: Physico-Chemical

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Inorganic-organic nano-hybrid; Preparation of Nano-sized TiO$_2$ Paste Trapped OMC Nano-emulsion and it's Application for Cosmetics (OMC Nano-emulsion을 포집하고 있는 Nano-TiO$_2$-Paste의 합성과 화장품의 응용)

  • Byung Gyu, Park;Jong Heon, Kim;Jin Hee, Im;Kyoung Chul, Lee
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.30 no.2
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    • pp.181-187
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    • 2004
  • Preparations of mesoporous materials using various templates and their applicability have been intensively investigated for many years. We studied on synthesizing mesoporous Ti02 with pores in which sensitive compounds having weak physico-chemical properties such as thermal or UV irradiation and low solubility in solvent are trapped. Prior to trapping OMC in the pores of mesoporous titania, OMC was nano-emulsified in O/W system using Lecithin. Thereafter the OMC was trapped in the pores of mesoporous titania using sol-gel method. Main focus of this work is to prepare OMC-trapped mesoporous titania and to trace the stability and solubility of nano-emulsified OMC in the pores of mesoporous titania, and compared with that of mesoporous silica. OMC-trapped mesoporous Inorganic-Organic hybrid titania showed higher factors in sun protecting and a skin penetration phenomenon was reduced.

A Study on the Physico-Chemical Characteristics of Sikhyes made of Different Various of Barley (보리의 종류를 달리한 보리식혜의 이화학적 특성)

  • Kim, An-Na;Choi, Soo-Keun
    • Culinary science and hospitality research
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    • v.21 no.1
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    • pp.30-41
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    • 2015
  • This study was prepared by varying the type of barley sikhye to promote the use of barley. to learn the quality characteristics of traditional beverage sikhye, sikhyes were made out of different kinds of barley such as amethyst barley, black naked barley, tetrastichum barley, tetrastichum waxy barley, naked barley and naked waxy barley. The result of the study is as following. Regarding the length/width ratio of barley grain, black naked barley was the biggest; while amethyst barley was the smallest. Moisture content of barley grain was in the range of 54.96~71.74%. The saccharification liquid pH was in the range of 5.40~5.63 and the soluble solid content was in the range of 15.37~18.73 brix %. The saccharification liquid of sikhye made of tetrastichum waxy barley had the highest soluble solid content; while the saccharification liquid of sikhye made of black naked barley had the lowest soluble solid content. Reducing sugar was in the range of 4.35~7.42 mg/ 100 g; at which tetrastichum waxy barley sikhye had the highest reducing sugar while black naked barley sikhye had the lowest reducing sugar. The result of reducing sugar was similar to the result of soluble solid content. Black naked barley had low Lightness, redness and yellowness in its cooked rice grain and saccharification liquid. The result of barley sikhye characteristics was as following. Black naked barley had the strongest fullness while tetrastichum waxy barley had the weakest fullness. Black naked barley had strong feeling after swallowing the barley rice grain; while tetrastichum waxy barley had weak feeling after swallowing the barley rice grain. The result of feeling after swallowing the barley rice grain had correlation with fullness. The result of preference test was as following. naked waxy barley sikhye and naked barley sikhye had best outlook. In the smell, amethyst barley sikhye was the best. regarding texture, naked barley sikhye and naked waxy barley sikhye had high preference. In overall preference, naked barley sikhye was the best. Like above, there were differences in quality in sikhyes dependent on the variety of barley. In particular, tetrastichum waxy barley and naked barley will be able to increase the amount of sweetness without malt production during sikhye.

Changes in Total Glucosinolates Levels and Physico-Chemical Properties of Kimchi using Korean Chinese Cabbage of Harvest Time according to Various Storage Conditions (수확기간별 배추를 이용한 김치의 저장조건에 따른 Total Glucosinolates 함량 및 이화학적 변화)

  • Jung, Ji-In;Hong, Eun-Young;Kim, Mee-Kyung;Jung, Ji-Won;Oh, Ji-Young;Kwon, Min-Soo;Lee, Kang-Pyo;Kim, Gun-Hee
    • Food Science and Preservation
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    • v.16 no.5
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    • pp.612-617
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    • 2009
  • Kimchi is a traditional pickled food using Korean Chinese cabbage(Brassica campestris var. pekinensis) and also containing phytochemicals, glucosinolates. This study was carried out to investigate the changes in the total glucosinolates levels of Kimchi using Korean Chinese cabbage of harvest time(June-July, August-September, October-November, December-April, May) according to storage temperature(4, 10, $15^{\circ}C$) and storage duration(0, 1, 3, 5, 7, 10, 14, 21 and 28 day). For determination of glucosinolates, 50g of Baechu kimchi was used for analytical sample preparation provided with an anion exchanges column and measured by UV-visible Spectrophotometer. The highest contents of water occurred at August-September during fermentation. At 15, 10, $4^{\circ}C$, the pH in all of seasonal variation of Baechu kimchi declined, especially from 0 to 3 days at $15^{\circ}C$, from 0 to 7 days at $10^{\circ}C$ and from 0 to 14 days at $4^{\circ}C$. At that storage, the total glucosinolates levels in all of seasonal variation of Kimchi declined in storage temperature. Baechu kimchi at August-September showed the highest total glucosinolates levels. Also total glucosinolates levels decreased as storage period increased. Baechu kimchi fermented at $15^{\circ}C$ for 7days decreased rapidly and reached to the lowest at the 1day(ranged from $10.3{\pm}0.70$ to $23.4{\pm}0.37{\mu}mol/g$ dry weight). At $10^{\circ}C$ for 14days were ranged from $12.9{\pm}0.29$ to $33.7{\pm}1.81{\mu}mol/g$ dry weight before fermentation and decreased rapidly at the 3day(ranged from $9.5{\pm}0.54$ to $20.5{\pm}0.61{\mu}mol/g$ dry weight). Total glucosinolates levels of Baechu kimchi fermented at $4^{\circ}C$ for 28days decreased rapidly during 7day(ranged from $9.9{\pm}0.78$ to $21.1{\pm}0.96{\mu}mol/g$ dry weight) and then slowly decreased. Therefore the total glucosinolates levels decreased during storage time and depended on harvest time and storage conditions of Kimchi.

Effect of Particle Size on Physico-Chemical Properties and Antioxidant Activity of Corn Silk Powder (옥수수수염 분말의 입자크기별 이화학적 특성과 항산화활성)

  • Cha, Sun-Mi;Son, Beom-Young;Lee, Jin-Seok;Baek, Seong-Bum;Kim, Sun-Lim;Ku, Ja-Hwan;Hwang, Jong-Jin;Song, Beom-Heon;Woo, Sun-Hee;Kwon, Young-Up;Kim, Jung-Tae
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.57 no.1
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    • pp.41-50
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    • 2012
  • The study was carried out to analyze the relationship between analysis of antioxidant activity and the level of functional components according to particle size of corn silk. Particle size was classified into 5 groups. By particle size distribution and color difference, the total phenol content and DPPH radical scavenging activity were observed. The particle sizes of corn silk were $199.17{\mu}m$, $178.27{\mu}m$, $85.48{\mu}m$, $27.4{\mu}m$ and $20.97{\mu}m$, respectively. The lightness of colored pigments was increased when the particle size was decreased. The contents of free sugar (fructose, glucose, galactose, sucrose, and maltose) of corn silk were analyzed using a HPLC. The total phenol contents by the particle sizes of corn silk were 2.01 mg/g, 2.02 mg/g, 2.06 mg/g, 2.26 mg/g and 2.26 mg/g, respectively. DPPH radical scavenging activities of samples were 21.00%, 21.75%, 22.90%, 24.35% and 23.67%, respectively. Antioxidative activities of Trolox and Fe(II) in corn silk were measured by ferric reducing antioxidant power (FRAP) assay and Trolox equivalent antioxidant capacity (TEAC) assay. TEAC values of samples were $2.36{\mu}mol$ TE / g dw, $2.81{\mu}mol$ TE / g dw, $3.20{\mu}mol$ TE / g dw, $3.36{\mu}mol$ TE / g dw, and $3.44{\mu}mol$ TE / g dw, respectively. FRAP values of samples were $11.67{\mu}mol$ Fe(II) / g dw, $12.80{\mu}mol$ Fe(II) / g dw, $13.43{\mu}mol$ Fe(II) / g dw, $13.85{\mu}mol$ Fe(II) / g dw and $15.95{\mu}mol$ Fe(II) / g dw, respectively. Total phenolic content and antioxidantive activities based on FRAP assay and TEAC assay were increased with decreasing particle size. In addition, DPPH radical scavenging activity was also increased. A significant correlation was also noted between DPPH radical scavenging activities and the content of phenolic compounds.

Effect of Milk Vetch Utilization Rice Cultivation to Reduce Application Amount of Nitrogen at Plowing Time in Paddy Field (자운영 후작(後作) 벼 재배시(栽培時) 경운시기별(耕耘時期別) 질소시비량(窒素施肥量) 절감효과(節減效果))

  • Yang, Chang-Hyu;Yoo, Chul-Hyun;Kang, Seung-Won;Han, Sang-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.35 no.6
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    • pp.352-360
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    • 2002
  • This study was carried out to find out the effect of Milk vetch(Astragalus sinicus L.) on growth, and yield of rice, physicochemical properties of soil, reduction rate of nitrogen fertilization, and soil improvement under the different plowing time with Milk vetch cultivated in paddy field, plowing at maximum blooming, last blooming, fruiting stages. The fresh weight of Milk vetch at each plowing time of maximum blooming, last blooming and fruiting stage was 22,500, 20,000, $12,500kg\;ha^{-1}$ respectively. Content of total nitrogen at three plowing times was 2.95, 2.66, and 2.47% and the C/N ratio were 15.7, 18.0, and 19.2, respectively. Physico-chemical properties of soil were improved in cultivated milk vetch, the content of T-N. OM and porosity ratio were increased while the content of $P_2O_5$ and bulk density, solidphase ratio were decreased compared to noncultivated milk vetch. Content of $NH_4-N$ in soil was highest plowing at maximum blooming stage and appeared an increasing tendency according to increased nitrogen level. Amount of nitrogen fertilizer by rice was highest plowing at maximum blooming stage and appeared an increasing tendency according to increased nitrogen level. Nitrogen-use efficiency was high in $33kg\;ha^{-1}$ nitrogen level at three plowing times. The number of spikelets per $m^2$ was high in plowing at maximum blooming stage, last blooming stage and the percentage of ripeness was high in fruiting stage of milk vetch. So the rice yield was increased 9%, 8% in $55kg\;ha^{-1}$ nitrogen level plowing at maximum blooming stage, last blooming stage and 1% in $77kg\;ha^{-1}$ nitrogen level plowing at fruiting stage compared to conventional cultivation.

Studies on the Characteristics of Phosphorus in the Upland Soil -III. Yield Responses of Added Phosphorus for Soybean in Soils with Different Capacities of Phosphorus Sorbed (경작지(耕作地) 전토양(田土壤)의 인산특성(燐酸特性)에 관(關)한 연구(硏究) -III. 인산(燐酸) 흡수력(吸收力)이 상이(相異)한 밭토양(土壤)에서 대두(大豆)에 대(對)한 시용인산(施用燐酸)의 비효(肥效))

  • Shin, Cheol-Woo;Kim, Jeong-Je;Yoon, Jung-Hui
    • Korean Journal of Soil Science and Fertilizer
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    • v.21 no.3
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    • pp.272-279
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    • 1988
  • A pot experiment was conducted to define the effect of various soil phosphorus fractions for soybean yield and the relations of between various soil phosphorus fraction and each other in 11 upland soils with different capacities of phosphorus fixation and physico-chemical properties of soils. The effect of phosphorus fertilization was high in soils with high capacities of phosphorus fixation and low available phosphorus, and soybean yield was showed significant relationship with available phosphorus and inorganic soil phosphorus fractions. Fractional recovery of added phosphorus in soils were showed various range of 2.5-91.7%, and mean value of soils was 48.5%. In the relationships among the soybean yield, plant phosphorus content, phosphorus uptake and available phosphorus, inoganic phosphorus at flowering stage, soybean yield were showed significant relationship with available phosphorus content, phosphorus uptake were all showed significant correlation without Fe-P, but Fe-P was showed except Jeju soil. Al-P/Fe-P ratio was increased by phosphorus fertilization in soils at flowering stage, and in the relationships between Al-P/Fe-P ratio and soybean yield, phosphorus uptake, soil and plant phosphorus were showed high significant correlation, but Fe-P was not showed at flowering stage. P sorbed by soils from P 20ppm solution was decreased by phosphorus fertilization, and then decreasing rate was higher in soils with low capacity of phosphorus fixation then high phosphorus fixing soils. Also P sorbed was showed negatively high significant correlation with available phosphorus, plant phosphorus, phosphorus uptake and soil inorganic phosphours except Fe-P, and soybean yield was not showed.

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Physico-chemical and Sensory Characteristics of Cooked Sausage Substituted with KCl or MgCl2 for NaCl (KCl 또는 MgCl2의 NaCl 대체 소시지의 이화학적 및 관능적 특성)

  • Jin, Sang-Keun;Kim, Il-Suk;Hur, In-Chul;Nam, Sang-Hae;Kang, Suk-Nam;Shin, Daekeun
    • Journal of agriculture & life science
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    • v.45 no.5
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    • pp.81-89
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    • 2011
  • This study was carried out to investigate changes in physicochemical and sensory properties of cooked sausages replaced sodium chloride (NaCl) to potassium chloride (KCl) or magnesium chloride ($MgCl_2$) during storage for 30 days under $4^{\circ}C$. All sausages were prepared with different combination of salts as follow; CTL (1.5% NaCl), KCL (0.9% NaCl+0.6% KCl), MCL (0.9% NaCl+0.6% $MgCl_2$), KML (0.9% NaCl+0.3% KCl+0.3% $MgCl_2$) and PST (1.5% PanSalt). Among sausages moisture content in KML was the highest (p<0.05). Lightness and redness in CTL were lower than those of other treatments, but MCL and KML containing $MgCl_2$ showed higher CIE $L^*$ and $a^*$ values than CTL. The pH in CTL was the highest during storage, however, no significant difference was determined between two treatments, MCL and KML (p>0.05). Crude fat content and water holding capacity (WHC), hardness and cohesiveness of MCL sausages were higher than those of CTL. In sensory characteristics of cooked sausages, saltness in MCL was the lowest during 10 and 20 days of storage (p<0.05). Yellowness in PST was lower than other treatmeants. Gumminess and chewiness of texture property of sausages from MCL and KML were higher than CTL. The results indicate that the replacement of NaCl by KCl improved texture, but meat color was not improved as expected. In contrast, the replacement of NaCl by $MgCl_2$ enhanced color, texture and WHC, whereas partial replacement of NaCl by $MgCl_2$ must reduce bitter taste as compared to sausages manufactured with a NaCl only. Therefore, $MgCl_2$ may be a salt replacing NaCl in cooked pork sausages.

Taxonomical Classification and Genesis of Asan Series Distributed on Rolling and Hilly Areas (구릉지 토양인 아산통의 분류 및 생성)

  • Song, Kwan-Cheol;Hyun, Byung-Geun;Sonn, Yeon-Kyu;Park, Chan-Won;Chun, Hyen-Chung;Moon, Yong-Hee
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1258-1263
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    • 2011
  • This study was conducted to reclassify Asan series based on the second edition of Soil Taxonomy and to discuss the formation of Asan series distributed on the rolling to hilly areas. Morphological properties of typifying pedon of Asan series were investigated and physico-chemical properties were analyzed according to Soil survey laboratory methods manual. The typifying pedon of Asan series has dark yellowish brown (10YR 4/4) gravelly loam Ap horizon (0-18 cm), strong brown (7.5YR 5/6) gravelly clay loam BA horizon (18-30 cm), red (2.5YR 4/6) gravelly clay loam Bt1 horizon (30-52 cm), red (2.5YR 4/8) gravelly clay loam Bt2 horizon (52-98 cm), and red (2.5YR 4/8) gravelly clay loam C horizon (98-160 cm). The typifying pedon has an argillic horizon from a depth of 30 to 98 cm and a base saturation (sum of cations) of less than 35% at 125 cm below the upper boundary of the argillic horizon. It can be classified as Ultisol, not as Inceptisol. It has udic soil moisture regime, and can be classified as Udult. Also that meets the requirements of Typic Hapludults. It has 18-35% clay at the particle-size control section, and has mesic soil temperature regime. Therefore Asan series can be classified as fine loamy, mesic family of Typic Hapludults, not as fine loamy, mesic family of Typic Dystrudepts. Asan series occur on rolling to hilly areas in residual materials derived from granite gneiss, schist, and gneiss rocks. They are developed as Ultisols with clay mineral weathering, translocation of clays to accumulate in an argillic horizon, and leaching of base-forming cations from the profile for relatively long periods under humid and temperate climates in Korea.

Taxonomical Classification of Cheongweon Series Distributed on Broad Continental Alluvial Plains (하성평탄지 토양인 청원통의 분류 및 생성)

  • Song, Kwan-Cheol;Hyun, Byung-Geun;Sonn, Yeon-Kyu;Park, Chan-Won;Chun, Hyen-Chung;Moon, Yong-Hee
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.6
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    • pp.1272-1278
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    • 2011
  • This study was conducted to reclassify Cheongweon series based on the second edition of Soil Taxonomy and to discuss the formation of Cheongweon series distributed on broad continental alluvial plains. Morphological properties of typifying pedon of Cheongweon series were investigated and physico-chemical properties were analyzed according to Soil survey laboratory methods manual. The typifying pedon of Cheongweon series has dark grayish brown (2.5Y 4/2) silt loam Ap horizon (0~18 cm), dark grayish brown (2.5Y 4/2) silt loam BA horizon (18~30 cm), dark yellowish brown (10YR 4/6) silty clay loam Bt1 horizon (30~60 cm), strong brown (7.5YR 4/6) silty clay loam Bt2 horizon (60~91 cm), brown (10YR 4/4) silt loam BC horizon (91~104 cm), and mottled (7.5YR 4/6, and 7.5YR 5/2) silt loam C horizon (104~160 cm). The typifying pedon has an argillic horizon from a depth of 30 to 91 cm and a base saturation (sum of cations) of 35% or more at 125 cm below the upper boundary of the argillic horizon. It can be classified as Alfisol, not as Incceptisol. It has udic soil moisture regime, and can be classified as Udalf. Also that meets the requirements of Hapluadalf. It has anthraquic condition, and keys out as Anthraquic Hapludalf. That has fine silty textural family, and has mesic soil temperature regime. Therefore Cheongweon series can be classified as fine silty, mixed, mesic family of Anthraquic Hapludalfs, not as fine silty, mixed, mesic family of Fluvaquentic Epiaquepts.

Taxonomical Classification of Jangho Series (장호통의 분류)

  • Song, Kwan-Cheol;Hyun, Byung-Geun;Sonn, Yeon-Kyu;Zhang, Yong-Seon;Park, Chan-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.42 no.5
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    • pp.330-335
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    • 2009
  • This study was conducted to reclassify Jangho series based on the second edition of Soil Taxonomy : A Basic System of Soil Classification for Making and Interpreting Soil Surveys. Morphological properties of typifying pedon of Jangho series were investigated and physico-chemical properties were analyzed according to Soil Survey Laboratory Methods Manual. The typifying pedon of Jangho series has very dark grayish brown (10YR 3/2) gravelly silt loam A horizon (0~14 cm), very dark brown (7.5YR 3/2) silty clay BAt horizon (14~31 cm), dark brown (7.5YR 3/4) silty clay Bt1 horizon (31~58 cm), brown (7.5YR 4/4) silty clay Bt2 horizon (58~90 cm), and brown (7.5YR 4/4) clay Bt3 (90~120 cm) horizon. That is developed on river terraces. The typifying pedon has an argillic horizon from a depth of 14 to more than 120 cm and a base saturation (sum of cations) of less than 35% at 125 cm below the upper boundary of the argillic horizon. That can be classified as Ultisol. The typifying pedon has 0.9 % or more organic carbon in the upper 15 cm of the argillic horizon, and can be classified as Humult, which is reported for the first time in Korea. That does not have fragipan, kandic horizon, sombric horizon, plinthite, etc. in the given depths, and keys out as Haplohumult. Also that meets the requirements of Typic Haplohumult. That has 35 % or more clay at the particle-size control section, and has mesic soil temperature regime. Jangho series can be classified as fine, mixed, mesic family of Typic Haplohumults, not as fine silty over clayey, mixed, mesic family of Mollic Hapludalfs.